| Common Name: | NITRILE PLASTIC ADHESIVE 826 |
| Manufacturer: | 3M |
| SDS Revision Date: | 5/8/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2RUE6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) NITRILE PLASTIC ADHESIVE 826
05/08/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-2459-5
VERSION NUMBER: 26.00
ISSUE DATE: 05/08/15
SUPERCEDES DATE: 09/11/13
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) NITRILE PLASTIC ADHESIVE 826
PRODUCT IDENTIFICATION NUMBERS:
62-0826-6530-8, 62-0826-6535-7, 62-0826-8530-6
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, INDUSTRIAL USE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 2.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 2.
CARCINOGENICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
CAUSES DAMAGE TO ORGANS:
BLOOD OR BLOOD-FORMING ORGANS
CARDIOVASCULAR SYSTEM
NERVOUS SYSTEM
KIDNEY/URINARY TRACT
RESPIRATORY SYSTEM
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
BLOOD OR BLOOD-FORMING ORGANS
CARDIOVASCULAR SYSTEM
LIVER
KIDNEY/URINARY TRACT
RESPIRATORY SYSTEM
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
KEEP COOL.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
CRESYLIC ACID 1319-77-3 <0.5 TRADE SECRET *
ETHYL ACETATE 141-78-6 50 - 60 TRADE SECRET *
PHENOLIC RESIN 9039-25-2 10 - 20 TRADE SECRET *
ACRYLONITRILE-BUTADIENE POLYMER 9003-18-3 10 - 20 TRADE SECRET *
ETHYL ALCOHOL 64-17-5 10 - 20 TRADE SECRET *
METHYL ETHYL KETONE 78-93-3 5 - 10 TRADE SECRET *
METHYL ALCOHOL 67-56-1 <0.5 TRADE SECRET *
PHENOL 108-95-2 1 - 5 TRADE SECRET *
METHYL ISOBUTYL KETONE 108-10-1 <0.2 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
HYDROCARBONS DURING COMBUSTION
FORMALDEHYDE DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN
APPROPRIATE AQUEOUS FILM FORMING FOAM (AFFF) IS RECOMMENDED. WORKING FROM
AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR
COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT
ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES
NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF
THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS
(EG. CHLORINE, CHROMIC ACID ETC.) WEAR LOW STATIC OR PROPERLY GROUNDED
SHOES. USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS
REQUIRED. TO MINIMIZE THE RISK OF IGNITION, DETERMINE APPLICABLE ELECTRICAL
CLASSIFICATIONS FOR THE PROCESS USING THIS PRODUCT AND SELECT SPECIFIC
LOCAL EXHAUST VENTILATION EQUIPMENT TO AVOID FLAMMABLE VAPOR ACCUMULATION.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT IF THERE IS POTENTIAL FOR
STATIC ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
METHYL 108-10-1 ACGIH TWA: 20 PPM A3:
ISOBUTYL STEL: 75 PPM CONFIRMED ANIMAL
KETONE CARCIN.
METHYL 108-10-1 OSHA TWA:
ISOBUTYL 410 MG/M3
KETONE (100 PPM)
PHENOL 108-95-2 OSHA TWA: SKIN NOTATION
19 MG/M3
(5 PPM)
PHENOL 108-95-2 ACGIH TWA: 5 PPM A4:
NOT CLASS. AS HUMAN
CARCIN, SKIN
NOTATION
CRESYLIC ACID 1319-77-3 ACGIH TWA (INHALABLE A4:
FRACTION AND NOT CLASS. AS HUMAN
VAPOR): 20 MG/M3 CARCIN, SKIN
NOTATION
CRESYLIC ACID 1319-77-3 OSHA TWA: SKIN NOTATION
22 MG/M3 (5 PPM)
ETHYL ACETATE 141-78-6 OSHA TWA:
1400 MG/M3
(400 PPM)
ETHYL ACETATE 141-78-6 ACGIH TWA: 400 PPM
ETHYL ALCOHOL 64-17-5 ACGIH STEL: 1000 PPM A3:
CONFIRMED ANIMAL
CARCIN.
ETHYL ALCOHOL 64-17-5 OSHA TWA:
1900 MG/M3
(1000 PPM)
METHYL ALCOHOL 67-56-1 ACGIH TWA: 200 PPM SKIN NOTATION
STEL: 250 PPM
METHYL ALCOHOL 67-56-1 OSHA TWA:
260 MG/M3
(200 PPM)
METHYL ETHYL 78-93-3 OSHA TWA:
KETONE 590 MG/M3
(200 PPM)
METHYL ETHYL 78-93-3 ACGIH TWA: 200 PPM
KETONE STEL: 300 PPM
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
FLUOROELASTOMER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
BOOTS - RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR ORGANIC VAPORS AND
PARTICULATES
FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: LIGHT AMBER, SOLVENT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=77 DEG. C
FLASH POINT: 35 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: 3.00 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): 1.8% VOLUME
FLAMMABLE LIMITS (UEL): 19.0% VOLUME
VAPOR PRESSURE: <=100 MMHg [@ 81 DEG. F]
VAPOR DENSITY: 3.0 [REF STD: AIR=1]
DENSITY: 0.94 G/ML
SPECIFIC GRAVITY: 0.94 [REF STD: WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: 365 DEG. C [DETAILS: ETHYL ALCOHOL]
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 2,000 CENTIPOISE [@ 27 DEG. C]
HAZARDOUS AIR POLLUTANTS: <=5% WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
<=740 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
SOLIDS CONTENT: 20 - 40%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CARDIAC EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), CHANGES IN
HEART RATE, DAMAGE TO HEART MUSCLE, HEART ATTACK, AND MAY BE FATAL.
HEMATOPOIETIC EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE GENERALIZED WEAKNESS, FATIGUE AND ALTERATIONS IN
NUMBERS OF CIRCULATING BLOOD CELLS.
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
KIDNEY/BLADDER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE CHANGES IN URINE PRODUCTION, ABDOMINAL OR LOWER
BACK PAIN, INCREASED PROTEIN IN URINE, INCREASED BLOOD UREA NITROGEN (BUN),
BLOOD IN URINE, AND PAINFUL URINATION.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CARDIAC EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), CHANGES IN
HEART RATE, DAMAGE TO HEART MUSCLE, HEART ATTACK, AND MAY BE FATAL.
HEMATOPOIETIC EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE GENERALIZED WEAKNESS, FATIGUE AND ALTERATIONS IN
NUMBERS OF CIRCULATING BLOOD CELLS.
LIVER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE LOSS OF APPETITE, WEIGHT LOSS, FATIGUE,
WEAKNESS, ABDOMINAL TENDERNESS AND JAUNDICE.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
KIDNEY/BLADDER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE CHANGES IN URINE PRODUCTION, ABDOMINAL OR LOWER
BACK PAIN, INCREASED PROTEIN IN URINE, INCREASED BLOOD UREA NITROGEN (BUN),
BLOOD IN URINE, AND PAINFUL URINATION.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
METHYL 108-10-1 GRP. 2B: INTERNATIONAL AGENCY FOR
ISOBUTYL POSSIBLE HUMAN CARC. RESEARCH ON CANCER
KETONE
ADDITIONAL INFORMATION:
THIS PRODUCT CONTAINS ETHANOL. ALCOHOLIC BEVERAGES AND ETHANOL IN ALCOHOLIC
BEVERAGES HAVE BEEN CLASSIFIED BY THE INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER AS CARCINOGENIC TO HUMANS. THERE ARE ALSO DATA ASSOCIATING HUMAN
CONSUMPTION OF ALCOHOLIC BEVERAGES WITH DEVELOPMENTAL TOXICITY AND LIVER
TOXICITY. EXPOSURE TO ETHANOL DURING THE FORESEEABLE USE OF THIS PRODUCT IS
NOT EXPECTED TO CAUSE CANCER, DEVELOPMENTAL TOXICITY, OR LIVER TOXICITY.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR (4 HR) CALCULATED ATE: >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
ETHYL ACETATE DERMAL RABBIT LD50: >18,000 MG/KG
ETHYL ACETATE INHALATION- RAT LC50: 70.5 MG/L
VAPOR (4
HOURS)
ETHYL ACETATE INGESTION RAT LD50: 5,620 MG/KG
ETHYL ALCOHOL DERMAL RABBIT LD50: >15,800 MG/KG
ETHYL ALCOHOL INHALATION- RAT LC50: 124.7 MG/L
VAPOR (4
HOURS)
ETHYL ALCOHOL INGESTION RAT LD50: 17,800 MG/KG
PHENOLIC RESIN DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
PHENOLIC RESIN INHALATION- LC50 ESTIMATED TO BE:
DUST/MIST >12.5 MG/L
PHENOLIC RESIN INGESTION LD50 ESTIMATED TO BE:
>5,000 MG/KG
ACRYLONITRILE- DERMAL RABBIT LD50: >15,000 MG/KG
BUTADIENE POLYMER
ACRYLONITRILE- INGESTION RAT LD50: >30,000 MG/KG
BUTADIENE POLYMER
METHYL ETHYL KETONE DERMAL RABBIT LD50: >8,050 MG/KG
METHYL ETHYL KETONE INHALATION- RAT LC50: 34.5 MG/L
VAPOR (4
HOURS)
METHYL ETHYL KETONE INGESTION RAT LD50: 2,737 MG/KG
PHENOL INHALATION- LC50 ESTIMATED TO BE:
VAPOR 2 - 10 MG/L
PHENOL DERMAL RAT LD50: 670 MG/KG
PHENOL INGESTION RAT LD50: 340 MG/KG
CRESYLIC ACID DERMAL RAT LD50: 242 MG/KG
CRESYLIC ACID INGESTION RAT LD50: 1,454 MG/KG
METHYL ALCOHOL DERMAL LD50 ESTIMATED TO BE:
1,000 - 2,000 MG/KG
METHYL ALCOHOL INHALATION- LC50 ESTIMATED TO BE:
VAPOR 10 - 20 MG/L
METHYL ALCOHOL INGESTION LD50 ESTIMATED TO BE:
50 - 300 MG/KG
METHYL ISOBUTYL DERMAL RABBIT LD50: >16,000 MG/KG
KETONE
METHYL ISOBUTYL INHALATION- RAT LC50: >8.2, <16.4 MG/L
KETONE VAPOR (4
HOURS)
METHYL ISOBUTYL INGESTION RAT LD50: 3,038 MG/KG
KETONE
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
ETHYL ACETATE RABBIT MINIMAL IRRITATION
ETHYL ALCOHOL RABBIT NO SIGNIFICANT IRRITATION
PHENOLIC RESIN PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
ACRYLONITRILE-BUTADIENE PROFESSIONAL NO SIGNIFICANT IRRITATION
POLYMER JUDGEMENT
METHYL ETHYL KETONE RABBIT MINIMAL IRRITATION
PHENOL RAT CORROSIVE
METHYL ALCOHOL RABBIT MILD IRRITANT
METHYL ISOBUTYL KETONE RABBIT MILD IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
ETHYL ACETATE RABBIT MILD IRRITANT
ETHYL ALCOHOL RABBIT MODERATE IRRITANT
PHENOLIC RESIN PROFESSIONAL MILD IRRITANT
JUDGEMENT
ACRYLONITRILE-BUTADIENE PROFESSIONAL NO SIGNIFICANT IRRITATION
POLYMER JUDGEMENT
METHYL ETHYL KETONE RABBIT SEVERE IRRITANT
PHENOL RABBIT CORROSIVE
METHYL ALCOHOL RABBIT MODERATE IRRITANT
METHYL ISOBUTYL KETONE RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
ETHYL ACETATE GUINEA NOT SENSITIZING
PIG
ETHYL ALCOHOL HUMAN SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PHENOL GUINEA NOT SENSITIZING
PIG
METHYL ALCOHOL GUINEA NOT SENSITIZING
PIG
METHYL ISOBUTYL KETONE GUINEA NOT SENSITIZING
PIG
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ETHYL ACETATE IN VITRO NOT MUTAGENIC
ETHYL ACETATE IN VIVO NOT MUTAGENIC
ETHYL ALCOHOL IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ETHYL ALCOHOL IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL KETONE IN VITRO NOT MUTAGENIC
PHENOL IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PHENOL IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ALCOHOL IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ALCOHOL IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ISOBUTYL KETONE IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
ETHYL ALCOHOL INGESTION MULTIPLE SOME POSITIVE DATA EXIST,
ANIMAL BUT THE DATA ARE NOT
SPECIES SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INHALATION HUMAN NOT CARCINOGENIC
KETONE
PHENOL DERMAL MOUSE SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PHENOL INGESTION RAT SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ALCOHOL INHALATION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
METHYL ISOBUTYL INHALATION MULTIPLE CARCINOGENIC
KETONE ANIMAL
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
ETHYL INHALATION NOT TOXIC TO RAT NOAEL: DURING
ALCOHOL DEVELOPMENT 38 MG/L GESTATION
ETHYL INGESTION SOME POSITIVE RAT NOAEL: PREMATING &
ALCOHOL DEVELOPMENTAL 5,200 DURING
DATA EXIST, MG/KG/DAY GESTATION
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL INHALATION NOT TOXIC TO RAT NOAEL: 90 DAYS
ETHYL FEMALE 14.7 MG/L
KETONE REPRODUCTION
METHYL INHALATION NOT TOXIC TO RAT NOAEL: 90 DAYS
ETHYL MALE 14.7 MG/L
KETONE REPRODUCTION
METHYL INHALATION SOME POSITIVE RAT LOAEL: DURING
ETHYL DEVELOPMENTAL 8.8 MG/L GESTATION
KETONE DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PHENOL INGESTION SOME POSITIVE RAT NOAEL: 2 GENERATION
FEMALE 321
REPRODUCTIVE MG/KG/DAY
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PHENOL INGESTION SOME POSITIVE RAT NOAEL: 2 GENERATION
MALE 321
REPRODUCTIVE MG/KG/DAY
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PHENOL INGESTION SOME POSITIVE RAT NOAEL: DURING
DEVELOPMENTAL 120 ORGANOGENESIS
DATA EXIST, MG/KG/DAY
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL INGESTION SOME POSITIVE RAT NOAEL: 21 DAYS
ALCOHOL MALE 1,600
REPRODUCTIVE MG/KG/DAY
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL INGESTION TOXIC TO MOUSE LOAEL: DURING
ALCOHOL DEVELOPMENT 4,000 ORGANOGENESIS
MG/KG/DAY
METHYL INHALATION TOXIC TO MOUSE NOAEL: DURING
ALCOHOL DEVELOPMENT 1.3 MG/L ORGANOGENESIS
METHYL INHALATION NOT TOXIC TO MULTIPLE NOAEL: 2 GENERATION
ISOBUTYL FEMALE ANIMAL 8.2 MG/L
KETONE REPRODUCTION SPECIES
METHYL INGESTION SOME POSITIVE RAT NOAEL: 13 WEEKS
ISOBUTYL MALE 1,000
KETONE REPRODUCTIVE MG/KG/DAY
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL INHALATION SOME POSITIVE MULTIPLE NOAEL: 2 GENERATION
ISOBUTYL MALE ANIMAL 8.2 MG/L
KETONE REPRODUCTIVE SPECIES
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL INHALATION SOME POSITIVE MOUSE NOAEL: DURING
ISOBUTYL DEVELOPMENTAL 12.3 MG/L ORGANOGENESIS
KETONE DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ETHYL ACETATE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ETHYL ACETATE INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
ETHYL ACETATE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ETHYL ALCOHOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ETHYL ALCOHOL INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
ETHYL ALCOHOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ETHYL ALCOHOL INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
KETONE SYSTEM DEPRESSION DIZZINESS
METHYL ETHYL INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
KETONE EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INGESTION LIVER SOME POSITIVE DATA
KETONE EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INGESTION KIDNEY AND/OR SOME POSITIVE DATA
KETONE BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
PHENOL DERMAL HEMATOPPOITIC CAUSES DAMAGE TO ORGANS
SYSTEM
PHENOL DERMAL HEART CAUSES DAMAGE TO ORGANS
NERVOUS SYSTEM
KIDNEY AND/OR BLADDER
PHENOL DERMAL LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
PHENOL INHALATION RESPIRATORY IRRITATION MAY CAUSE RESPIRATORY
IRRITATION
PHENOL INGESTION KIDNEY AND/OR BLADDER CAUSES DAMAGE TO ORGANS
PHENOL INGESTION RESPIRATORY SYSTEM CAUSES DAMAGE TO ORGANS
PHENOL INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA
LIVER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
PHENOL INGESTION HEART SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL INHALATION BLINDNESS CAUSES DAMAGE TO ORGANS
ALCOHOL
METHYL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
ALCOHOL SYSTEM DEPRESSION DIZZINESS
METHYL INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
ALCOHOL EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL INGESTION BLINDNESS CAUSES DAMAGE TO ORGANS
ALCOHOL
METHYL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
ALCOHOL SYSTEM DEPRESSION DIZZINESS
METHYL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
ISOBUTYL SYSTEM DEPRESSION DIZZINESS
KETONE
METHYL INHALATION RESPIRATORY IRRITATION MAY CAUSE RESPIRATORY
ISOBUTYL IRRITATION
KETONE
METHYL INHALATION VASCULAR SYSTEM SOME POSITIVE DATA
ISOBUTYL EXIST, BUT THE DATA ARE
KETONE NOT SUFFICIENT FOR
CLASSIFICATION
METHYL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
ISOBUTYL SYSTEM DEPRESSION DIZZINESS
KETONE
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHYL ACETATE HUMAN NOAEL: NOT AVAILABLE
ETHYL ACETATE HUMAN NOAEL: NOT AVAILABLE
ETHYL ACETATE HUMAN NOAEL: NOT AVAILABLE
ETHYL ALCOHOL HUMAN LOAEL: 2.6 MG/L 30 MINUTES
ETHYL ALCOHOL HUMAN LOAEL: 9.4 MG/L NOT AVAILABLE
ETHYL ALCOHOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
ETHYL ALCOHOL DOG NOAEL: 3,000 MG/KG
METHYL ETHYL OFFICIAL NOAEL: NOT AVAILABLE
KETONE CLASSIFICATION
METHYL ETHYL HUMAN NOAEL: NOT AVAILABLE
KETONE
METHYL ETHYL RAT NOAEL: NOT AVAILABLE NOT APPLICABLE
KETONE
METHYL ETHYL RAT LOAEL: 1,080 MG/KG NOT APPLICABLE
KETONE
PHENOL RAT LOAEL: 108 MG/KG NOT AVAILABLE
PHENOL RAT LOAEL: 107 MG/KG 24 HOURS
PHENOL HUMAN NOAEL: NOT AVAILABLE NOT AVAILABLE
PHENOL MULTIPLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ANIMAL
SPECIES
PHENOL RAT NOAEL: 120 MG/KG/DAY NOT APPLICABLE
PHENOL HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
PHENOL RAT NOAEL: 224 MG/KG NOT APPLICABLE
PHENOL HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
METHYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
METHYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE NOT AVAILABLE
METHYL ALCOHOL RAT NOAEL: NOT AVAILABLE 6 HOURS
METHYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
METHYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
METHYL HUMAN LOAEL: 0.10 MG/L 2 HOURS
ISOBUTYL
KETONE
METHYL HUMAN NOAEL: 0.9 MG/L 7 MINUTES
ISOBUTYL
KETONE
METHYL DOG NOAEL: NOT AVAILABLE NOT AVAILABLE
ISOBUTYL
KETONE
METHYL RAT LOAEL: 900 MG/KG NOT APPLICABLE
ISOBUTYL
KETONE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ETHYL ACETATE INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
LIVER EXIST, BUT THE DATA ARE
NERVOUS SYSTEM NOT SUFFICIENT FOR
CLASSIFICATION
ETHYL ACETATE INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
ETHYL ACETATE INGESTION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
LIVER NOT SUFFICIENT FOR
KIDNEY AND/OR BLADDER CLASSIFICATION
ETHYL ALCOHOL INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
ETHYL ALCOHOL INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
IMMUNE SYSTEM NOT SUFFICIENT FOR
CLASSIFICATION
ETHYL ALCOHOL INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
ETHYL ALCOHOL INGESTION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL DERMAL NERVOUS SYSTEM ALL DATA ARE NEGATIVE
KETONE
METHYL ETHYL INHALATION LIVER SOME POSITIVE DATA
KETONE KIDNEY AND/OR BLADDER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INHALATION HEART ALL DATA ARE NEGATIVE
KETONE ENDOCRINE SYSTEM
BONE, TEETH, NAILS,
AND/OR HAIR
HEMATOPOIETIC SYSTEM
IMMUNE SYSTEM
MUSCLES
METHYL ETHYL INGESTION LIVER SOME POSITIVE DATA
KETONE EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INGESTION NERVOUS SYSTEM ALL DATA ARE NEGATIVE
KETONE
PHENOL DERMAL NERVOUS SYSTEM MAY CAUSE DAMAGE TO
ORGANS THOUGH PROLONGED
OR REPEATED EXPOSURE
PHENOL INHALATION HEART CAUSES DAMAGE TO ORGANS
LIVER THROUGH PROLONGED OR
KIDNEY AND/OR BLADDER REPEATED EXPOSURE
RESPIRATORY SYSTEM
PHENOL INHALATION NERVOUS SYSTEM MAY CAUSE DAMAGE TO
ORGANS THOUGH PROLONGED
OR REPEATED EXPOSURE
PHENOL INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
PHENOL INHALATION IMMUNE SYSTEM ALL DATA ARE NEGATIVE
PHENOL INGESTION KIDNEY AND/OR BLADDER CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
PHENOL INGESTION HEMATOPOIETIC SYSTEM CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
PHENOL INGESTION NERVOUS SYSTEM MAY CAUSE DAMAGE TO
ORGANS THOUGH PROLONGED
OR REPEATED EXPOSURE
PHENOL INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
PHENOL INGESTION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
PHENOL INGESTION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
PHENOL INGESTION ENDOCRINE SYSTEM ALL DATA ARE NEGATIVE
PHENOL INGESTION SKIN ALL DATA ARE NEGATIVE
BONE, TEETH, NAILS,
AND/OR HAIR
METHYL INHALATION LIVER ALL DATA ARE NEGATIVE
ALCOHOL
METHYL INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
ALCOHOL
METHYL INGESTION LIVER SOME POSITIVE DATA
ALCOHOL NERVOUS SYSTEM EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL INHALATION LIVER SOME POSITIVE DATA
ISOBUTYL EXIST, BUT THE DATA ARE
KETONE NOT SUFFICIENT FOR
CLASSIFICATION
METHYL INHALATION HEART SOME POSITIVE DATA
ISOBUTYL EXIST, BUT THE DATA ARE
KETONE NOT SUFFICIENT FOR
CLASSIFICATION
METHYL INHALATION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
ISOBUTYL EXIST, BUT THE DATA ARE
KETONE NOT SUFFICIENT FOR
CLASSIFICATION
METHYL INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
ISOBUTYL
KETONE
METHYL INHALATION ENDOCRINE SYSTEM ALL DATA ARE NEGATIVE
ISOBUTYL HEMATOPOIETIC SYSTEM
KETONE
METHYL INHALATION NERVOUS SYSTEM ALL DATA ARE NEGATIVE
ISOBUTYL
KETONE
METHYL INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA
ISOBUTYL HEMATOPOIETIC SYSTEM EXIST, BUT THE DATA ARE
KETONE LIVER NOT SUFFICIENT FOR
KIDNEY AND/OR BLADDER CLASSIFICATION
METHYL INGESTION HEART ALL DATA ARE NEGATIVE
ISOBUTYL IMMUNE SYSTEM
KETONE MUSCLES
NERVOUS SYSTEM
RESPIRATORY SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHYL ACETATE RAT NOAEL: 0.043 MG/L 90 DAYS
ETHYL ACETATE RABBIT LOAEL: 16 MG/L 40 DAYS
ETHYL ACETATE RAT NOAEL: 3,600 MG/KG/DAY 90 DAYS
ETHYL ALCOHOL RABBIT LOAEL: 124 MG/L 365 DAYS
ETHYL ALCOHOL RAT NOAEL: 25 MG/L 14 DAYS
ETHYL ALCOHOL RAT LOAEL: 8,000 MG/KG/DAY 4 MONTHS
ETHYL ALCOHOL DOG NOAEL: 3,000 MG/KG/DAY 7 DAYS
METHYL ETHYL GUINEA NOAEL: NOT AVAILABLE 31 WEEKS
KETONE PIG
METHYL ETHYL RAT NOAEL: 14.7 MG/L 90 DAYS
KETONE
METHYL ETHYL RAT NOAEL: 14.7 MG/L 90 DAYS
KETONE
METHYL ETHYL RAT NOAEL: NOT AVAILABLE 7 DAYS
KETONE
METHYL ETHYL RAT NOAEL: 173 MG/KG/DAY 90 DAYS
KETONE
PHENOL RABBIT LOAEL: 260 MG/KG/DAY 18 DAYS
PHENOL GUINEA LOAEL: 0.1 MG/L 41 DAYS
PIG
PHENOL MULTIPLE LOAEL: 0.1 MG/L 14 DAYS
ANIMAL
SPECIES
PHENOL HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
PHENOL RAT NOAEL: 0.1 MG/L 2 WEEKS
PHENOL RAT NOAEL: 12 MG/KG/DAY 14 DAYS
PHENOL MOUSE LOAEL: 1.8 MG/KG/DAY 28 DAYS
PHENOL RAT LOAEL: 308 MG/KG/DAY 13 WEEKS
PHENOL RAT NOAEL: 40 MG/KG/DAY 14 DAYS
PHENOL RAT LOAEL: 40 MG/KG/DAY 14 DAYS
PHENOL MOUSE NOAEL: 1.8 MG/KG/DAY 28 DAYS
PHENOL RAT NOAEL: 120 MG/KG/DAY 14 DAYS
PHENOL MULTIPLE NOAEL: 1,204 MG/KG/DAY 103 WEEKS
ANIMAL
SPECIES
METHYL ALCOHOL RAT NOAEL: 6.55 MG/L 4 WEEKS
METHYL ALCOHOL RAT NOAEL: 13.1 MG/L 6 WEEKS
METHYL ALCOHOL RAT NOAEL: 2,500 MG/KG/DAY 90 DAYS
METHYL RAT NOAEL: 0.41 MG/L 13 WEEKS
ISOBUTYL
KETONE
METHYL MULTIPLE NOAEL: 0.8 MG/L 2 WEEKS
ISOBUTYL ANIMAL
KETONE SPECIES
METHYL MULTIPLE NOAEL: 0.4 MG/L 90 DAYS
ISOBUTYL ANIMAL
KETONE SPECIES
METHYL MULTIPLE NOAEL: 4.1 MG/L 14 WEEKS
ISOBUTYL ANIMAL
KETONE SPECIES
METHYL MULTIPLE NOAEL: 0.41 MG/L 90 DAYS
ISOBUTYL ANIMAL
KETONE SPECIES
METHYL MULTIPLE NOAEL: 0.41 MG/L 13 WEEKS
ISOBUTYL ANIMAL
KETONE SPECIES
METHYL RAT NOAEL: 1,000 MG/KG/DAY 13 WEEKS
ISOBUTYL
KETONE
METHYL RAT NOAEL: 1,040 MG/KG/DAY 120 DAYS
ISOBUTYL
KETONE
ASPIRATION HAZARD:
NAME VALUE
METHYL ISOBUTYL KETONE SOME POSITIVE DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. AS A DISPOSAL
ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA):
D001 (IGNITABLE), D026 (CRESOL), D035 (METHYL ETHYL KETONE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
PHENOL 108-95-2 1 - 5
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-2459-5
VERSION NUMBER: 26.00
ISSUE DATE: 05/08/15
SUPERCEDES DATE: 09/11/13
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM