| Common Name: | NITRILE HIGH PERFORMANCE PLASTIC ADHESIVE 1099 |
| Manufacturer: | 3M |
| SDS Revision Date: | 9/20/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 205YP3, 2RUE7, 3XH42, 802Z81 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) NITRILE HIGH PERFORMANCE PLASTIC ADHESIVE 1099
09/20/21
3M
SAFETY DATA SHEET
COPYRIGHT, 2021, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-2442-1
VERSION NUMBER: 46.00
ISSUE DATE: 09/20/21
SUPERCEDES DATE: 06/25/21
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) NITRILE HIGH PERFORMANCE PLASTIC ADHESIVE 1099
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
62-1099-2631-1 00-21200-19808-3
62-1099-6530-1 00-21200-19811-3
62-1099-8530-9 00-21200-19814-4
XS-0414-0885-6
62-1099-2635-2
62-1099-7530-0 00-21200-19813-7
62-1099-9530-8 00-21200-19815-1
7000000796, 7000121197, 7000000797, 7000121198, 7000000798, 7010309716,
7000149596
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, INDUSTRIAL USE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 2.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
ACETONE 67-64-1 60 - 70 TRADE SECRET *
ACRYLONITRILE-BUTADIENE POLYMER 9003-18-3 10 - 20 TRADE SECRET *
PHENOLIC POLYMER 55185-45-0 5 - 10 TRADE SECRET *
PHENOLIC RESIN 25085-50-1 5 - 10 TRADE SECRET *
SALICYLIC ACID 69-72-7 <2.5 TRADE SECRET *
ZINC OXIDE 1314-13-2 <2 TRADE SECRET *
TOLUENE 108-88-3 <1 TRADE SECRET *
METHYL ETHYL KETONE 78-93-3 <0.5 TRADE SECRET *
PHENOL 108-95-2 <0.5 TRADE SECRET *
O-CRESOL 95-48-7 <0.3 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
CENTRAL NERVOUS SYSTEM DEPRESSION (HEADACHE, DIZZINESS, DROWSINESS,
INCOORDINATION, NAUSEA, SLURRED SPEECH, GIDDINESS, AND UNCONSCIOUSNESS).
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
HYDROCARBONS DURING COMBUSTION
FORMALDEHYDE DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE. WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED,
POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND
PANTS, BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE
COVERING FOR EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. WORKING
FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX
IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING
TOOLS. PLACE IN A METAL CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND
SDS. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE
IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL/OCCUPATIONAL USE ONLY. NOT FOR CONSUMER SALE OR USE. DO NOT
HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP
AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY
NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) WEAR LOW
STATIC OR PROPERLY GROUNDED SHOES. USE PERSONAL PROTECTIVE EQUIPMENT
(GLOVES, RESPIRATORS, ETC.) AS REQUIRED. TO MINIMIZE THE RISK OF IGNITION,
DETERMINE APPLICABLE ELECTRICAL CLASSIFICATIONS FOR THE PROCESS USING THIS
PRODUCT AND SELECT SPECIFIC LOCAL EXHAUST VENTILATION EQUIPMENT TO AVOID
FLAMMABLE VAPOR ACCUMULATION. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
IF THERE IS POTENTIAL FOR STATIC ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
TOLUENE 108-88-3 ACGIH TWA: 20 PPM A4:
NOT CLASS.
AS HUMAN
CARCIN,
OTOTOXICANT
TOLUENE 108-88-3 OSHA TWA: 200 PPM
CEIL: 300 PPM
PHENOL 108-95-2 ACGIH TWA: 5 PPM A4:
NOT CLASS.
AS HUMAN
CARCIN,
DANGER OF
CUTANEOUS
ABSORPTION
PHENOL 108-95-2 OSHA TWA: SKIN
19 MG/M3
(5 PPM)
ZINC OXIDE 1314-13-2 ACGIH TWA
(RESPIRABLE
FRACTION):
2 MG/M3
STEL
(RESPIRABLE
FRACTION):
10 MG/M3
ZINC OXIDE 1314-13-2 OSHA TWA (AS
TOTAL DUST):
15 MG/M3
TWA
(RESPIRABLE
FRACTION):
5 MG/M3
TWA
(AS FUME):
5 MG/M3
ACETONE 67-64-1 ACGIH TWA: 250 PPM A4:
STEL: 500 PPM NOT CLASS.
AS HUMAN
CARCIN
ACETONE 67-64-1 OSHA TWA:
2400 MG/M3
(1000 PPM)
METHYL ETHYL 78-93-3 ACGIH TWA: 200 PPM
KETONE STEL: 300 PPM
METHYL ETHYL 78-93-3 OSHA TWA:
KETONE 590 MG/M3
(200 PPM)
CRESOLS 95-48-7 OSHA TWA: SKIN
(ORTHO-; 22 MG/M3
META-; PARA-) (5 PPM)
O-CRESOL 95-48-7 ACGIH TWA A4:
(INHALABLE NOT CLASS.
FRACTION AS HUMAN
AND VAPOR): CARCIN,
20 MG/M3 DANGER OF
CUTANEOUS
ABSORPTION
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY
AND DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER
USE CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING
MANUFACTURER FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE
CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES ORGANIC VAPOR RESPIRATORS MAY HAVE SHORT
SERVICE LIFE.
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
PHYSICAL STATE: LIQUID
COLOR: LIGHT TAN, PINK, WHITE
ODOR: KETONES
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: >=56 DEG. C
FLASH POINT: -4 DEG. F [TEST METHOD: CLOSED CUP] [DETAILS: ACETONE]
EVAPORATION RATE: 1.9 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): 2.6% VOLUME [DETAILS: ACETONE]
FLAMMABLE LIMITS (UEL): 12.8% VOLUME [DETAILS: ACETONE]
VAPOR PRESSURE: <=185 MMHg [@ 68 DEG. F]
VAPOR DENSITY: 2.0 [REF STD: AIR=1]
DENSITY: 0.89 G/ML
SPECIFIC GRAVITY: 0.89 [REF STD: WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 2,000 - 4,000 CENTIPOISE [@ 27 DEG. C]
HAZARDOUS AIR POLLUTANTS: <=1.6% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
<=101 G/L [TEST METHOD.CALCULATED SCAQMD RULE 443.1]
SOLIDS CONTENT: 20 - 40%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED) IN SENSITIVE PEOPLE:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR CALCULATED ATE:
(4 HR) >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
ACETONE DERMAL RABBIT LD50: >15,688 MG/KG
ACETONE INHALATION- RAT LC50: 76 MG/L
VAPOR
(4 HOURS)
ACETONE INGESTION RAT LD50: 5,800 MG/KG
ACRYLONITRILE-BUTADIENE DERMAL RABBIT LD50: >15,000 MG/KG
POLYMER
ACRYLONITRILE-BUTADIENE INGESTION RAT LD50: >30,000 MG/KG
POLYMER
PHENOLIC RESIN DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
PHENOLIC RESIN INGESTION RAT LD50: 5,660 MG/KG
PHENOLIC POLYMER DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
PHENOLIC POLYMER INGESTION LD50 ESTIMATED TO BE:
2,000 - 5,000 MG/KG
SALICYLIC ACID DERMAL RAT LD50: >2,000 MG/KG
SALICYLIC ACID INGESTION RAT LD50: 891 MG/KG
ZINC OXIDE DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
ZINC OXIDE INHALATION- RAT LC50: >5.7 MG/L
DUST/MIST
(4 HOURS)
ZINC OXIDE INGESTION RAT LD50: >5,000 MG/KG
TOLUENE DERMAL RAT LD50: 12,000 MG/KG
TOLUENE INHALATION- RAT LC50: 30 MG/L
VAPOR
(4 HOURS)
TOLUENE INGESTION RAT LD50: 5,550 MG/KG
METHYL ETHYL KETONE DERMAL RABBIT LD50: >8,050 MG/KG
METHYL ETHYL KETONE INHALATION- RAT LC50: 34.5 MG/L
VAPOR
(4 HOURS)
METHYL ETHYL KETONE INGESTION RAT LD50: 2,737 MG/KG
PHENOL INHALATION- LC50 ESTIMATED TO
VAPOR BE: 2 - 10 MG/L
PHENOL DERMAL RAT LD50: 670 MG/KG
PHENOL INGESTION RAT LD50: 340 MG/KG
O-CRESOL DERMAL RABBIT LD50: 890 MG/KG
O-CRESOL INHALATION- RAT LC50: >24.5 MG/L
VAPOR
(4 HOURS)
O-CRESOL INGESTION RAT LD50: 121 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
ACETONE MOUSE MINIMAL IRRITATION
ACRYLONITRILE-BUTADIENE PROFESSIONAL NO SIGNIFICANT IRRITATION
POLYMER JUDGMENT
SALICYLIC ACID RABBIT NO SIGNIFICANT IRRITATION
ZINC OXIDE HUMAN AND NO SIGNIFICANT IRRITATION
ANIMAL
TOLUENE RABBIT IRRITANT
METHYL ETHYL KETONE RABBIT MINIMAL IRRITATION
PHENOL RAT CORROSIVE
O-CRESOL RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
ACETONE RABBIT SEVERE IRRITANT
ACRYLONITRILE-BUTADIENE PROFESSIONAL NO SIGNIFICANT IRRITATION
POLYMER JUDGMENT
SALICYLIC ACID RABBIT CORROSIVE
ZINC OXIDE RABBIT MILD IRRITANT
TOLUENE RABBIT MODERATE IRRITANT
METHYL ETHYL KETONE RABBIT SEVERE IRRITANT
PHENOL RABBIT CORROSIVE
O-CRESOL RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
PHENOLIC RESIN HUMAN SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
SALICYLIC ACID MOUSE NOT CLASSIFIED
ZINC OXIDE GUINEA PIG NOT CLASSIFIED
TOLUENE GUINEA PIG NOT CLASSIFIED
PHENOL GUINEA PIG NOT CLASSIFIED
PHOTOSENSITIZATION:
NAME SPECIES VALUE
SALICYLIC ACID MOUSE NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ACETONE IN VIVO NOT MUTAGENIC
ACETONE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
SALICYLIC ACID IN VITRO NOT MUTAGENIC
SALICYLIC ACID IN VIVO NOT MUTAGENIC
ZINC OXIDE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
ZINC OXIDE IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
METHYL ETHYL KETONE IN VITRO NOT MUTAGENIC
PHENOL IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
PHENOL IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
O-CRESOL IN VIVO NOT MUTAGENIC
O-CRESOL IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
ACETONE NOT MULTIPLE NOT CARCINOGENIC
SPECIFIED ANIMAL
SPECIES
TOLUENE DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ETHYL KETONE INHALATION HUMAN NOT CARCINOGENIC
PHENOL DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PHENOL INGESTION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
O-CRESOL DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
O-CRESOL INGESTION MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
ACETONE INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
ACETONE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
SALICYLIC ACID INGESTION TOXIC TO DEVELOPMENT
ZINC OXIDE INGESTION NOT CLASSIFIED FOR REPRODUCTION
AND/OR DEVELOPMENT
TOLUENE INHALATION NOT CLASSIFIED FOR FEMALE REPRODUCTION
TOLUENE INHALATION NOT CLASSIFIED FOR MALE REPRODUCTION
TOLUENE INGESTION TOXIC TO DEVELOPMENT
TOLUENE INHALATION TOXIC TO DEVELOPMENT
METHYL ETHYL KETONE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
PHENOL INGESTION NOT CLASSIFIED FOR FEMALE REPRODUCTION
PHENOL INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
PHENOL INGESTION NOT CLASSIFIED FOR DEVELOPMENT
O-CRESOL INGESTION NOT CLASSIFIED FOR FEMALE REPRODUCTION
O-CRESOL INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
O-CRESOL INGESTION NOT CLASSIFIED FOR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
ACETONE RAT NOAEL: 13 WEEKS
1,700 MG/KG/DAY
ACETONE RAT NOAEL: 5.2 MG/L DURING
ORGANOGENESIS
SALICYLIC ACID RAT NOAEL: DURING
75 MG/KG/DAY ORGANOGENESIS
ZINC OXIDE MULTIPLE NOAEL: PREMATING &
ANIMAL 125 MG/KG/DAY DURING GESTATION
SPECIES
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE RAT NOAEL: 2.3 MG/L 1 GENERATION
TOLUENE RAT LOAEL: DURING
520 MG/KG/DAY GESTATION
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
METHYL ETHYL KETONE RAT LOAEL: 8.8 MG/L DURING GESTATION
PHENOL RAT NOAEL: 2 GENERATION
321 MG/KG/DAY
PHENOL RAT NOAEL: 2 GENERATION
321 MG/KG/DAY
PHENOL RAT NOAEL: DURING
120 MG/KG/DAY ORGANOGENESIS
O-CRESOL RAT NOAEL: 2 GENERATION
450 MG/KG/DAY
O-CRESOL RAT NOAEL: 2 GENERATION
450 MG/KG/DAY
O-CRESOL RAT NOAEL: 2 GENERATION
175 MG/KG/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ACETONE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
ACETONE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ACETONE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
ACETONE INHALATION LIVER NOT CLASSIFIED
ACETONE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
TOLUENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
TOLUENE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ETHYL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
KETONE SYSTEM DEPRESSION OR DIZZINESS
METHYL ETHYL INHALATION RESPIRATORY SOME POSITIVE DATA
KETONE IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ETHYL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
KETONE SYSTEM DEPRESSION OR DIZZINESS
METHYL ETHYL INGESTION LIVER NOT CLASSIFIED
KETONE
METHYL ETHYL INGESTION KIDNEY AND/OR NOT CLASSIFIED
KETONE BLADDER
PHENOL DERMAL HEMATOPPOITIC CAUSES DAMAGE TO
SYSTEM ORGANS
PHENOL DERMAL HEART CAUSES DAMAGE TO
NERVOUS SYSTEM ORGANS
KIDNEY AND/OR
BLADDER
PHENOL DERMAL LIVER NOT CLASSIFIED
PHENOL INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
PHENOL INGESTION KIDNEY AND/OR CAUSES DAMAGE TO
BLADDER ORGANS
PHENOL INGESTION RESPIRATORY SYSTEM CAUSES DAMAGE TO
ORGANS
PHENOL INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
LIVER
PHENOL INGESTION HEART NOT CLASSIFIED
O-CRESOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
O-CRESOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
ACETONE HUMAN NOAEL:
NOT AVAILABLE
ACETONE HUMAN NOAEL:
NOT AVAILABLE
ACETONE HUMAN NOAEL: 6 HOURS
1.19 MG/L
ACETONE GUINEA PIG NOAEL:
NOT AVAILABLE
ACETONE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 3 HOURS
0.004 MG/L
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
METHYL ETHYL OFFICIAL NOAEL:
KETONE CLASSIFICATION NOT AVAILABLE
METHYL ETHYL HUMAN NOAEL:
KETONE NOT AVAILABLE
METHYL ETHYL PROFESSIONAL NOAEL:
KETONE JUDGMENT NOT AVAILABLE
METHYL ETHYL RAT NOAEL: NOT APPLICABLE
KETONE NOT AVAILABLE
METHYL ETHYL RAT LOAEL: NOT APPLICABLE
KETONE 1,080 MG/KG
PHENOL RAT LOAEL: NOT AVAILABLE
108 MG/KG
PHENOL RAT LOAEL: 24 HOURS
107 MG/KG
PHENOL HUMAN NOAEL: NOT AVAILABLE
NOT AVAILABLE
PHENOL MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL NOT AVAILABLE
SPECIES
PHENOL RAT NOAEL: NOT APPLICABLE
120 MG/KG/DAY
PHENOL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
PHENOL RAT NOAEL: NOT APPLICABLE
224 MG/KG
PHENOL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
O-CRESOL HUMAN NOAEL:
NOT AVAILABLE
O-CRESOL RAT LOAEL:
68 MG/KG
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ACETONE DERMAL EYES NOT CLASSIFIED
ACETONE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
ACETONE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
ACETONE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
ACETONE INHALATION HEART NOT CLASSIFIED
LIVER
ACETONE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
ACETONE INGESTION HEART NOT CLASSIFIED
ACETONE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
ACETONE INGESTION LIVER NOT CLASSIFIED
ACETONE INGESTION EYES NOT CLASSIFIED
ACETONE INGESTION RESPIRATORY SYSTEM NOT CLASSIFIED
ACETONE INGESTION MUSCLES NOT CLASSIFIED
ACETONE INGESTION SKIN NOT CLASSIFIED
BONE, TEETH,
NAILS, AND/OR HAIR
SALICYLIC ACID INGESTION LIVER NOT CLASSIFIED
ZINC OXIDE INGESTION NERVOUS SYSTEM NOT CLASSIFIED
ZINC OXIDE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO
EYES ORGANS THROUGH
OLFACTORY SYSTEM PROLONGED OR
REPEATED EXPOSURE
TOLUENE INHALATION NERVOUS SYSTEM MAY CAUSE DAMAGE
TO ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
TOLUENE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INHALATION HEART NOT CLASSIFIED
LIVER
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION BONE, TEETH, NOT CLASSIFIED
NAILS, AND/OR HAIR
TOLUENE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
VASCULAR SYSTEM
TOLUENE INHALATION GASTROINTESTINAL NOT CLASSIFIED
TRACT
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE INGESTION HEART NOT CLASSIFIED
TOLUENE INGESTION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
TOLUENE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
TOLUENE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION IMMUNE SYSTEM NOT CLASSIFIED
METHYL ETHYL DERMAL NERVOUS SYSTEM NOT CLASSIFIED
KETONE
METHYL ETHYL INHALATION LIVER NOT CLASSIFIED
KETONE KIDNEY AND/OR
BLADDER
HEART
ENDOCRINE SYSTEM
GASTROINTESTINAL
TRACT
BONE, TEETH,
NAILS, AND/OR HAIR
HEMATOPOIETIC
SYSTEM
IMMUNE SYSTEM
MUSCLES
METHYL ETHYL INGESTION LIVER NOT CLASSIFIED
KETONE
METHYL ETHYL INGESTION NERVOUS SYSTEM NOT CLASSIFIED
KETONE
PHENOL DERMAL NERVOUS SYSTEM MAY CAUSE DAMAGE
TO ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
PHENOL INHALATION HEART CAUSES DAMAGE TO
LIVER ORGANS THROUGH
KIDNEY AND/OR PROLONGED OR
BLADDER REPEATED EXPOSURE
RESPIRATORY SYSTEM
PHENOL INHALATION NERVOUS SYSTEM MAY CAUSE DAMAGE
TO ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
PHENOL INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
PHENOL INHALATION IMMUNE SYSTEM NOT CLASSIFIED
PHENOL INGESTION KIDNEY AND/OR CAUSES DAMAGE TO
BLADDER ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
PHENOL INGESTION HEMATOPOIETIC CAUSES DAMAGE TO
SYSTEM ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
PHENOL INGESTION NERVOUS SYSTEM MAY CAUSE DAMAGE
TO ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
PHENOL INGESTION LIVER NOT CLASSIFIED
PHENOL INGESTION RESPIRATORY SYSTEM NOT CLASSIFIED
PHENOL INGESTION IMMUNE SYSTEM NOT CLASSIFIED
PHENOL INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
PHENOL INGESTION SKIN NOT CLASSIFIED
BONE, TEETH,
NAILS, AND/OR HAIR
O-CRESOL INGESTION NERVOUS SYSTEM NOT CLASSIFIED
O-CRESOL INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
LIVER
IMMUNE SYSTEM
KIDNEY AND/OR
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
ACETONE GUINEA PIG NOAEL: 3 WEEKS
NOT AVAILABLE
ACETONE HUMAN NOAEL: 3 MG/L 6 WEEKS
ACETONE HUMAN NOAEL: 6 DAYS
1.19 MG/L
ACETONE GUINEA PIG NOAEL: 119 MG/L NOT AVAILABLE
ACETONE RAT NOAEL: 45 MG/L 8 WEEKS
ACETONE RAT NOAEL: 13 WEEKS
900 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
200 MG/KG/DAY
ACETONE MOUSE NOAEL: 14 DAYS
3,896 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
3,400 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
ACETONE RAT NOAEL: 13 WEEKS
2,500 MG/KG
ACETONE MOUSE NOAEL: 13 WEEKS
11,298 MG/KG/DAY
SALICYLIC ACID RAT NOAEL: 3 DAYS
500 MG/KG/DAY
ZINC OXIDE RAT NOAEL: 10 DAYS
600 MG/KG/DAY
ZINC OXIDE OTHER NOAEL: 6 MONTHS
500 MG/KG/DAY
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
TOLUENE RAT LOAEL: 2.3 MG/L 15 MONTHS
TOLUENE RAT NOAEL: 15 WEEKS
11.3 MG/L
TOLUENE RAT NOAEL: 1.1 MG/L 4 WEEKS
TOLUENE MOUSE NOAEL: 20 DAYS
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 1.1 MG/L 8 WEEKS
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE MULTIPLE NOAEL: 15 WEEKS
ANIMAL 11.3 MG/L
SPECIES
TOLUENE RAT NOAEL: 13 WEEKS
625 MG/KG/DAY
TOLUENE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
TOLUENE MULTIPLE NOAEL: 13 WEEKS
ANIMAL 2,500 MG/KG/DAY
SPECIES
TOLUENE MOUSE NOAEL: 14 DAYS
600 MG/KG/DAY
TOLUENE MOUSE NOAEL: 28 DAYS
105 MG/KG/DAY
TOLUENE MOUSE NOAEL: 4 WEEKS
105 MG/KG/DAY
METHYL ETHYL KETONE GUINEA PIG NOAEL: 31 WEEKS
NOT AVAILABLE
METHYL ETHYL KETONE RAT NOAEL: 90 DAYS
14.7 MG/L
METHYL ETHYL KETONE RAT NOAEL: 7 DAYS
NOT AVAILABLE
METHYL ETHYL KETONE RAT NOAEL: 90 DAYS
173 MG/KG/DAY
PHENOL RABBIT LOAEL: 18 DAYS
260 MG/KG/DAY
PHENOL GUINEA PIG LOAEL: 0.1 MG/L 41 DAYS
PHENOL MULTIPLE LOAEL: 0.1 MG/L 14 DAYS
ANIMAL
SPECIES
PHENOL HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
PHENOL RAT NOAEL: 0.1 MG/L 2 WEEKS
PHENOL RAT NOAEL: 14 DAYS
12 MG/KG/DAY
PHENOL MOUSE LOAEL: 28 DAYS
1.8 MG/KG/DAY
PHENOL RAT LOAEL: 13 WEEKS
308 MG/KG/DAY
PHENOL RAT NOAEL: 14 DAYS
40 MG/KG/DAY
PHENOL RAT LOAEL: 14 DAYS
40 MG/KG/DAY
PHENOL MOUSE NOAEL: 28 DAYS
1.8 MG/KG/DAY
PHENOL RAT NOAEL: 14 DAYS
120 MG/KG/DAY
PHENOL MULTIPLE NOAEL: 103 WEEKS
ANIMAL 1,204 MG/KG/DAY
SPECIES
O-CRESOL RAT NOAEL: 90 DAYS
600 MG/KG/DAY
O-CRESOL RAT NOAEL: 90 DAYS
2,024 MG/KG/DAY
ASPIRATION HAZARD:
NAME VALUE
TOLUENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. AS A DISPOSAL
ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA):
D001 (IGNITABLE), D023 (O-CRESOL), D035 (METHYL ETHYL KETONE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
SERIOUS EYE DAMAGE OR EYE IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC OXIDE (ZINC COMPOUNDS) 1314-13-2 TRADE SECRET <2
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-2442-1
VERSION NUMBER: 46.00
ISSUE DATE: 09/20/21
SUPERCEDES DATE: 06/25/21
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AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
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