| Common Name: | LOCTITE EA 3476 RESIN KNOWN AS FIXMASTER STAINLESS STEEL PUTTY, 97443_10234000, |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 2/16/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 2TKP8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 02/16/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE EA 3476 RESIN KNOWN AS FIXMASTER STAINLESS STEEL PUTTY
IDH NUMBER: 702236
PRODUCT TYPE: EPOXY RESIN
ITEM NUMBER: 97443_10234000
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF CAUSING CANCER.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
CARCINOGENICITY 2
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING VAPORS, MIST,
OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES, CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
IRON 7439-89-6 50 - 60
EPICHLOROHYDRIN-4,4'-ISOPROPYLIDENE 25068-38-6 20 - 30
DIPHENOL RESIN
CHROMIUM 7440-47-3 10 - 20
NICKEL 7440-02-0 5 - 10
MOLYBDENUM 7439-98-7 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL AND
DISPERSE VAPORS. CAUTION SHOULD BE EXERCISED WHEN USING WATER OR FOAM AS
FROTHING MAY OCCUR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO
EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. ACIDS. PHENOLICS. ALDEHYDES. TOXIC FUMES. IRRITATING
VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION"
PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL
AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY
FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME. PROTECT
FROM DIRECT SUNLIGHT.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
IRON NONE NONE NONE NONE
EPICHLOROHYDRIN-4,4'- NONE NONE NONE NONE
ISOPROPYLIDENE
DIPHENOL RESIN
CHROMIUM 0.5 MG/M3 TWA 1 MG/M3 PEL NONE NONE
(AS Cr) (AS Cr)
NICKEL 1.5 MG/M3 TWA 1 MG/M3 PEL NONE NONE
INHALABLE (AS Ni)
FRACTION.
MOLYBDENUM 3 MG/M3 TWA 15 MG/M3 PEL NONE NONE
(AS Mo) (AS Mo)
RESPIRABLE TOTAL DUST.
FRACTION.
10 MG/M3 TWA
(AS Mo)
INHALABLE
FRACTION.
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: GRAY
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 3.832
VAPOR DENSITY: >1 (AIR = 1)
FLASH POINT: 149 DEG. C (300.2 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: LESS THAN BUTYL ACETATE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT:
<1.0 %; <10 G/L (VALUE FOR RESIN AND HARDENER TOGETHER) (ESTIMATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. ACIDS. ALDEHYDES. PHENOLICS. TOXIC FUMES. IRRITATING
VAPORS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. COMBUSTIBLE MATERIALS. METALS. ACIDS. ALKALIS.
WATER. STRONG BASES. AMINES. MERCAPTANS. STRONG LEWIS ACIDS. STRONG MINERAL
ACIDS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: NONE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
IRON NONE EYES, LUNG
EPICHLOROHYDRIN-4,4'- NONE ALLERGEN, IRRITANT
ISOPROPYLIDENE DIPHENOL
RESIN
CHROMIUM NONE IRRITANT, ALLERGEN, EYES
NICKEL NONE ALLERGEN, CARCINOGEN,
IRRITANT, KIDNEY, MUTAGEN,
REPRODUCTIVE, RESPIRATORY
MOLYBDENUM NONE BLOOD, GASTROINTESTINAL,
IMMUNE SYSTEM, IRRITANT,
KIDNEY, LIVER, LUNG,
METABOLIC, SKIN, SPLEEN, LESS
WEIGHT GAIN AND FOOD INTAKE.
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
IRON NO NO NO
EPICHLOROHYDRIN-4,4'- NO NO NO
ISOPROPYLIDENE
DIPHENOL RESIN
CHROMIUM NO NO NO
NICKEL REASONABLY GROUP 2B NO
ANTICIPATED TO
BE A HUMAN
CARCINOGEN.
MOLYBDENUM NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: D007. CHROMIUM.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
CHROMIUM (CAS# 7440-47-3). NICKEL (CAS# 7440-02-0).
CERCLA REPORTABLE QUANTITY:
CHROMIUM (CAS# 7440-47-3): 5,000 LBS. (2,270 KG)
NICKEL (CAS# 7440-02-0): 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 8, 15
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 02/16/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 010.0
ISSUE DATE: 10/10/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME:
LOCTITE EA 3476 HARDENER KNOWN AS FIXMASTER STAINLES STEEL PUTTY
IDH NUMBER: 702237
PRODUCT TYPE: EPOXY HARDENER
ITEM NUMBER: 97443_653356
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
SUSPECTED OF CAUSING CANCER.
HAZARD CLASS HAZARD CATEGORY
SKIN CORROSION 1B
SERIOUS EYE DAMAGE 1
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
CARCINOGENICITY 2
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE DUST OR FUMES.
WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES,
CLOTHING, EYE AND FACE PROTECTION. IN CASE OF INADEQUATE VENTILATION WEAR
RESPIRATORY PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
CALCIUM CARBONATE 471-34-1 30 - 40
EPOXY POLYAMINE ADDUCT UNKNOWN 10 - 20
C18 FATTY ACID DIMER, 68082-29-1 10 - 20
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE POLYMER
TRIETHYLENETETRAMINE 112-24-3 5 - 10
DIETHYLENETRIAMINE 111-40-0 5 - 10
SILICA FILLER 112926-00-8 5 - 10
NONYLPHENOL 25154-52-3 1 - 5
TITANIUM DIOXIDE 13463-67-7 1 - 5
4-METHYLIMIDAZOLE 822-36-6 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER (USING SOAP, IF AVAILABLE). GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION.
INGESTION:
RINSE THE MOUTH. DRINK 1-2 GLASSES OF WATER. DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO SO BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
BURNING PRODUCES OBNOXIOUS AND TOXIC FUMES. PERSONNEL IN VICINITY AND
DOWNWIND SHOULD BE EVACUATED. USE OF WATER MAY RESULT IN THE FORMATION OF
VERY TOXIC AQUEOUS SOLUTIONS. DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO
ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. ACIDS. AMMONIA. CALCIUM OXIDE.
CHLORINE. PHENOLICS. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
EVACUATE AND VENTILATE SPILL AREA; DIKE SPILL TO PREVENT ENTRY INTO WATER
SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT DURING CLEAN-UP. REFER TO SECTION 8
"EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP. SOAK UP WITH
INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL
BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A CLOSED
CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 2 DEG. C (35.6 DEG. F) AND 8 DEG. C
(46.4 DEG. F) STORE IN ORIGINAL CONTAINER UNTIL READY TO USE. KEEP
CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM
INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
CALCIUM CARBONATE 10 MG/M3 TWA 5 MG/M3 PEL NONE NONE
TOTAL DUST. RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
EPOXY POLYAMINE ADDUCT NONE NONE NONE NONE
C18 FATTY ACID DIMER, NONE NONE NONE NONE
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
TRIETHYLENETETRAMINE NONE NONE 1 PPM NONE
(6 MG/M3)
TWA (SKIN)
DIETHYLENETRIAMINE (SKIN) NONE NONE NONE
1 PPM TWA
SILICA FILLER 6 MG/M3 TWA 20 MPPCF TWA NONE NONE
0.8 MG/M3 TWA
NONYLPHENOL NONE NONE NONE NONE
TITANIUM DIOXIDE 10 MG/M3 TWA 15 MG/M3 PEL NONE NONE
TOTAL DUST.
15 MPPCF TWA
RESPIRABLE
FRACTION.
15 MG/M3 TWA
TOTAL DUST.
50 MPPCF TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE
FRACTION.
4-METHYLIMIDAZOLE NONE NONE NONE NONE
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE, SOLID, PRODUCT IS A SOLID BY ASTM D4359-90
COLOR: DARK, BLUE, GRAY
ODOR: AMINE-LIKE
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT DETERMINED
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.57
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT:
<1.0 %; <10 G/L (VALUE FOR RESIN AND HARDENER TOGETHER) (ESTIMATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. ACIDS. AMMONIA. CALCIUM OXIDE.
CHLORINE. PHENOLICS. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
ACIDS. OXIDIZING AGENTS. PEROXIDES. SODIUM HYPOCHLORITE. AMINES. THIS
PRODUCT SLOWLY CORRODES COPPER, ALUMINUM, ZINC AND GALVANIZED SURFACES.
NITROUS ACID AND OTHER NITROSATING AGENTS.
CAUTION!
N-NITROSAMINES (MANY OF WHICH ARE KNOWN TO BE POTENT CARCINOGENS) MAY BE
FORMED WHEN THE PRODUCT COMES IN CONTACT WITH NITROUS ACID, NITRITES OR
ATMOSPHERES WITH HIGH NITROUS OXIDE CONCENTRATIONS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
CAN CAUSE SEVERE IRRITATION AND BURNS TO THE RESPIRATORY TRACT. MAY CAUSE
ALLERGIC RESPIRATORY REACTION. SHORTNESS OF BREATH.
SKIN CONTACT:
CAUSES SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION. PRODUCT MAY BE
ABSORBED THROUGH SKIN AND CAUSE NAUSEA, HEADACHE AND GENERAL DISCOMFORT.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
IF INGESTED, SEVERE BURNS OF THE MOUTH AND THROAT MAY OCCUR, AS WELL AS
PERFORATION OF THE ESOPHAGUS AND THE STOMACH. INGESTION CAN CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
CALCIUM CARBONATE ORAL LD50 (RAT): NUISANCE DUST
6,450 MG/KG
ORAL LD50 (MOUSE):
6,450 MG/KG
EPOXY POLYAMINE ADDUCT NONE NO DATA
C18 FATTY ACID DIMER, NONE NO RECORDS
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
TRIETHYLENETETRAMINE NONE ALLERGEN, CORROSIVE,
DEVELOPMENTAL, IRRITANT,
MUTAGEN
DIETHYLENETRIAMINE ORAL LD50 (RAT) ALLERGEN, IRRITANT, EYES
APPROXIMATE: 1,140 MG/KG
ORAL LD50 (RAT):
1,080 MG/KG
ORAL LD50 (RAT):
2.33 G/KG
SILICA FILLER NONE NUISANCE DUST
NONYLPHENOL ORAL LD50 (RAT): ALLERGEN, CORROSIVE,
1,600 MG/KG IRRITANT, KIDNEY
DERMAL LDE50
(RABBIT): 2,140 MG/KG
TITANIUM DIOXIDE NONE IRRITANT, RESPIRATORY,
SOME EVIDENCE OF
CARCINOGENICITY
4-METHYLIMIDAZOLE ORAL LD50 (MOUSE): NO DATA
370 MG/KG
ORAL LD50 (RAT):
751 MG/KG
DERMAL LD50 (RABBIT):
440 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
CALCIUM CARBONATE NO NO NO
EPOXY POLYAMINE ADDUCT NO NO NO
C18 FATTY ACID DIMER, NO NO NO
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
TRIETHYLENETETRAMINE NO NO NO
DIETHYLENETRIAMINE NO NO NO
SILICA FILLER NO NO NO
NONYLPHENOL NO NO NO
TITANIUM DIOXIDE NO GROUP 2B NO
4-METHYLIMIDAZOLE NO GROUP 2B NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF AN ITEM IS HAZARDOUS
AS DEFINED IN THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) AT THE TIME
OF DISPOSAL. PRODUCT USES, TRANSFORMATIONS, MIXTURES, PROCESSES, ETC., MAY
RENDER THE RESULTING MATERIAL HAZARDOUS, UNDER THE CRITERIA OF
IGNITABILITY, CORROSIVITY, REACTIVITY AND TOXICITY CHARACTERISTICS OF THE
TOXICITY CHARACTERISTICS LEACHING PROCEDURE (TCLP) 40 CFR 261.20-24.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
AMINES, SOLID, CORROSIVE, N.O.S. (TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE,
NONYLPHENOL)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 3259
PACKING GROUP: II
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AMINES, SOLID, CORROSIVE, N.O.S. (TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE,
NONYLPHENOL)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 3259
PACKING GROUP: II
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
AMINES, SOLID, CORROSIVE, N.O.S. (TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE,
NONYLPHENOL)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 3259
PACKING GROUP: II
MARINE POLLUTANT: NONYLPHENOL
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: ALKYL PHENOL (CAS# 25154-52-3).
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). NONYLPHENOL (CAS#
25154-52-3).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES LIST.
ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE
DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE TRACKED BY
ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT CANADA. THEY
MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE CONTACT
REGULATORY AFFAIRS FOR ADDITIONAL DETAILS.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2, 3
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 10/10/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.