| Common Name: | MAGNESIUM CHLORIDE HEXAHYDRATE, M9272 |
| Manufacturer: | SIGMA-ALDRICH GERMANY |
| SDS Revision Date: | 12/14/2018 |
| SDS Format: | GHS-EU |
| Item Number(s): | 2TPX7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SIGMA-ALDRICH(R*)
WWW.SIGMAALDRICH.COM
SAFETY DATA SHEET
ACCORDING TO REGULATION (EC) NO. 1907/2006
VERSION: 6.2
REVISION DATE: 14.12.2018
PRINT DATE: 16.04.2020
GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIERS:
PRODUCT NAME: MAGNESIUM CHLORIDE HEXAHYDRATE
PRODUCT NUMBER: M9272
BRAND: SIGALD
REACH NO.: 01-2119485597-19-XXXX
CAS-NO.: 7791-18-6
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: LABORATORY CHEMICALS, MANUFACTURE OF SUBSTANCES
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIGMA-ALDRICH CHEMIE GMBH
ESCHENSTRASSE 5
D-82024 TAUFKIRCHEN
TELEPHONE: +49 (0)89 6513-1130
FAX: +49 (0)89 6513-1161
1.4 EMERGENCY TELEPHONE NUMBER
EMERGENCY PHONE #:
0800 181 7059 (CHEMTREC DEUTSCHLAND)
+49 (0)696 43508409 (CHEMTREC WELTWEIT)
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
NOT A HAZARDOUS SUBSTANCE OR MIXTURE ACCORDING TO REGULATION (EC) NO.
1272/2008.
2.2 LABEL ELEMENTS:
NOT A HAZARDOUS SUBSTANCE OR MIXTURE ACCORDING TO REGULATION (EC) NO.
1272/2008.
2.3 OTHER HAZARDS: NONE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
FORMULA: CL2MG - 6H2O
MOLECULAR WEIGHT: 203,30 G/MOL
CAS-NO.: 7791-18-6
EC-NO.: 232-094-6
NO COMPONENTS NEED TO BE DISCLOSED ACCORDING TO THE APPLICABLE REGULATIONS.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION.
IN CASE OF SKIN CONTACT: WASH OFF WITH SOAP AND PLENTY OF WATER.
IN CASE OF EYE CONTACT: FLUSH EYES WITH WATER AS A PRECAUTION.
IF SWALLOWED:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. RINSE MOUTH WITH
WATER.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELING (SEE SECTION 2.2) AND/OR IN SECTION 11
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO DATA AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HYDROGEN CHLORIDE GAS, MAGNESIUM OXIDE
5.3 ADVICE FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
5.4 FURTHER INFORMATION: THE PRODUCT ITSELF DOES NOT BURN.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
AVOID DUST FORMATION. AVOID BREATHING VAPOURS, MIST OR GAS.
FOR PERSONAL PROTECTION SEE SECTION 8.
6.2 ENVIRONMENTAL PRECAUTIONS: DO NOT LET PRODUCT ENTER DRAINS.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SWEEP UP AND SHOVEL. KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
6.4 REFERENCE TO OTHER SECTIONS: FOR DISPOSAL SEE SECTION 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
PROVIDE APPROPRIATE EXHAUST VENTILATION AT PLACES WHERE DUST IS FORMED.
FOR PRECAUTIONS SEE SECTION 2.2.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN COOL PLACE. KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND
WELL-VENTILATED PLACE.
MOISTURE SENSITIVE. HYGROSCOPIC.
7.3 SPECIFIC END USE(S):
APART FROM THE USES MENTIONED IN SECTION 1.2 NO OTHER SPECIFIC USES ARE
STIPULATED
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
8.2 EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS: GENERAL INDUSTRIAL HYGIENE PRACTICE.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
USE EQUIPMENT FOR EYE PROTECTION TESTED AND APPROVED UNDER APPROPRIATE
GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR EN 166(EU).
SKIN PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE PROPER GLOVE
REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVE'S OUTER SURFACE) TO AVOID SKIN
CONTACT WITH THIS PRODUCT. DISPOSE OF CONTAMINATED GLOVES AFTER USE IN
ACCORDANCE WITH APPLICABLE LAWS AND GOOD LABORATORY PRACTICES. WASH AND DRY
HANDS.
THE SELECTED PROTECTIVE GLOVES HAVE TO SATISFY THE SPECIFICATIONS OF EU
DIRECTIVE 89/686/EEC AND THE STANDARD EN 374 DERIVED FROM IT.
FULL CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0,11 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: DERMATRIL(R*) (KCL 740 / ALDRICH Z677272, SIZE M)
SPLASH CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0,11 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: DERMATRIL(R*) (KCL 740 / ALDRICH Z677272, SIZE M)
DATA SOURCE:
KCL GMBH, D-36124 EICHENZELL, PHONE +49 (0)6659 87300, E-MAIL
SALES@KCL.DE, TEST METHOD: EN374
IF USED IN SOLUTION, OR MIXED WITH OTHER SUBSTANCES, AND UNDER CONDITIONS
WHICH DIFFER FROM EN 374, CONTACT THE SUPPLIER OF THE CE APPROVED GLOVES.
THIS RECOMMENDATION IS ADVISORY ONLY AND MUST BE EVALUATED BY AN INDUSTRIAL
HYGIENIST AND SAFETY OFFICER FAMILIAR WITH THE SPECIFIC SITUATION OF
ANTICIPATED USE BY OUR CUSTOMERS. IT SHOULD NOT BE CONSTRUED AS OFFERING AN
APPROVAL FOR ANY SPECIFIC USE SCENARIO.
BODY PROTECTION:
CHOOSE BODY PROTECTION IN RELATION TO ITS TYPE, TO THE CONCENTRATION AND
AMOUNT OF DANGEROUS SUBSTANCES, AND TO THE SPECIFIC WORK-PLACE., THE TYPE
OF PROTECTIVE EQUIPMENT MUST BE SELECTED ACCORDING TO THE CONCENTRATION AND
AMOUNT OF THE DANGEROUS SUBSTANCE AT THE SPECIFIC WORKPLACE.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS NOT REQUIRED. WHERE PROTECTION FROM NUISANCE
LEVELS OF DUSTS ARE DESIRED, USE TYPE N95 (US) OR TYPE P1 (EN 143) DUST
MASKS. USE RESPIRATORS AND COMPONENTS TESTED AND APPROVED UNDER APPROPRIATE
GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR CEN (EU).
CONTROL OF ENVIRONMENTAL EXPOSURE: DO NOT LET PRODUCT ENTER DRAINS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE:
FORM: SOLID
B) ODOUR: NO DATA AVAILABLE
C) ODOUR THRESHOLD: NO DATA AVAILABLE
D) PH: NO DATA AVAILABLE
E) MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
F) INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
G) FLASH POINT: NO DATA AVAILABLE
H) EVAPORATION RATE: NO DATA AVAILABLE
I) FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
K) VAPOUR PRESSURE: NO DATA AVAILABLE
L) VAPOUR DENSITY: NO DATA AVAILABLE
M) RELATIVE DENSITY: 1,570 G/CM3
N) WATER SOLUBILITY: NO DATA AVAILABLE
O) PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
P) AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
Q) DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
R) VISCOSITY: NO DATA AVAILABLE
S) EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
T) OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2 OTHER SAFETY INFORMATION: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DATA AVAILABLE
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE
10.4 CONDITIONS TO AVOID: EXPOSURE TO MOISTURE MAY AFFECT PRODUCT QUALITY.
10.5 INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS FORMED UNDER FIRE CONDITIONS. - HYDROGEN
CHLORIDE GAS, MAGNESIUM OXIDE
OTHER DECOMPOSITION PRODUCTS: NO DATA AVAILABLE
IN THE EVENT OF FIRE: SEE SECTION 5
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NO DATA AVAILABLE
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: OM2975000
VOMITING, DIARRHOEA, ABDOMINAL PAIN, TO THE BEST OF OUR KNOWLEDGE, THE
CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
INVESTIGATED.
LIVER - IRREGULARITIES - BASED ON HUMAN EVIDENCE
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY: NO DATA AVAILABLE
12.2 PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
12.3 BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED
12.6 OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
OFFER SURPLUS AND NON-RECYCLABLE SOLUTIONS TO A LICENSED DISPOSAL COMPANY.
CONTAMINATED PACKAGING: DISPOSE OF AS UNUSED PRODUCT.
| SECTION 14: TRANSPORT INFORMATION | |
14.1 UN NUMBER
ADR/RID:
IMDG:
IATA:
14.2 UN PROPER SHIPPING NAME:
ADR/RID: NOT DANGEROUS GOODS
IMDG: NOT DANGEROUS GOODS
IATA: NOT DANGEROUS GOODS
14.3 TRANSPORT HAZARD CLASS(ES):
ADR/RID:
IMDG:
IATA:
14.4 PACKAGING GROUP:
ADR/RID:
IMDG:
IATA:
14.5 ENVIRONMENTAL HAZARDS:
ADR/RID: NO
IMDG MARINE POLLUTANT: NO
IATA: NO
14.6 SPECIAL PRECAUTIONS FOR USER: NO DATA AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
THIS SAFETY DATASHEET COMPLIES WITH THE REQUIREMENTS OF REGULATION (EC) NO.
1907/2006.
15.2 CHEMICAL SAFETY ASSESSMENT:
FOR THIS PRODUCT A CHEMICAL SAFETY ASSESSMENT WAS NOT CARRIED OUT
| SECTION 16: OTHER INFORMATION | |
FURTHER INFORMATION:
COPYRIGHT 2018 SIGMA-ALDRICH CO. LLC. LICENSE GRANTED TO MAKE UNLIMITED
PAPER COPIES FOR INTERNAL USE ONLY.
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE
ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. THE INFORMATION IN THIS
DOCUMENT IS BASED ON THE PRESENT STATE OF OUR KNOWLEDGE AND IS APPLICABLE
TO THE PRODUCT WITH REGARD TO APPROPRIATE SAFETY PRECAUTIONS. IT DOES NOT
REPRESENT ANY GUARANTEE OF THE PROPERTIES OF THE PRODUCT. SIGMA-ALDRICH
CORPORATION AND ITS AFFILIATES SHALL NOT BE HELD LIABLE FOR ANY DAMAGE
RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE
WWW.SIGMA-ALDRICH.COM AND/OR THE REVERSE SIDE OF INVOICE OR PACKING SLIP
FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
THE BRANDING ON THE HEADER AND/OR FOOTER OF THIS DOCUMENT MAY TEMPORARILY
NOT VISUALLY MATCH THE PRODUCT PURCHASED AS WE TRANSITION OUR BRANDING.
HOWEVER, ALL OF THE INFORMATION IN THE DOCUMENT REGARDING THE PRODUCT
REMAINS UNCHANGED AND MATCHES THE PRODUCT ORDERED. FOR FURTHER INFORMATION
PLEASE CONTACT MLSBRANDING@SIAL.COM.
SIGALD - M9272
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