| Common Name: | FIRE BARRIER MP+ STICK |
| Manufacturer: | 3M |
| SDS Revision Date: | 6/18/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2UYE9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) FIRE BARRIER MP+ STICK
06/18/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 23-6572-4
VERSION NUMBER: 6.03
ISSUE DATE: 06/18/18
SUPERCEDES DATE: 01/18/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) FIRE BARRIER MP+ STICK
PRODUCT IDENTIFICATION NUMBERS: 98-0400-5454-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: PASSIVE FIRE BARRIER PRODUCT FOR INDUSTRIAL APPLICATIONS
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
PETROLATUM 8009-03-8 10 - 30 TRADE SECRET*
SODIUM SILICATE 1344-09-8 10 - 30 TRADE SECRET*
ZINC BORATE 138265-88-0 10 - 30 TRADE SECRET*
POLYMER NJTS REG. NO. 04499600-7315 TRADE SECRET* 10 - 30 TRADE SECRET*
MELAMINE PHOSPHATE 41583-09-9 7 - 13 TRADE SECRET*
POLYBUTYLENE 9003-29-6 7 - 13 TRADE SECRET*
BUTADIENE-STYRENE-META- 26471-45-4 3 - 7 TRADE SECRET*
DIVINYLBENZENE POLYMER
GLASS WOOL 65997-17-3 3 - 7 TRADE SECRET*
AMORPHOUS SILICA 112945-52-5 1 - 5 TRADE SECRET*
WATER 7732-18-5 1 - 5 TRADE SECRET*
RAYON FIBER NONE <5 TRADE SECRET*
4,4'-ISOPROPYLIDENEDIPHENOL- 25068-38-6 <2 TRADE SECRET*
EPICHLOROHYDRIN POLYMER
ALPHA-METHYLSTYRENE-ISOAMYLENE- 62258-49-5 <2 TRADE SECRET*
PIPERYLENE POLYMER
ROSIN 8050-09-7 <1 TRADE SECRET*
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CHLORIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED, POSITIVE
PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND PANTS,
BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE COVERING FOR
EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/
SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK
OR SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED CLOTHING BEFORE REUSE.
USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM AREAS WHERE PRODUCT MAY COME INTO CONTACT WITH FOOD OR
PHARMACEUTICALS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
SILICA, 112945-52-5 OSHA TWA CONCENTRATION:
AMORPHOUS 0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
MINERAL OILS, 8009-03-8 ACGIH TWA (INHALABLE A4:
HIGHLY- FRACTION): 5 MG/M3 NOT CLASS. AS HUMAN
REFINED OILS CARCIN
PARAFFIN OIL 8009-03-8 OSHA TWA (AS MIST):
5 MG/M3
ROSIN 8050-09-7 ACGIH LIMIT VALUE NOT DERMAL/RESPIRATORY
ESTABLISHED: SENSITIZER, CNTRL
ALL EXPOSR-LOW AS
POSSIB
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
SELECT AND USE BODY PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS OF
AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PUTTY
ODOR, COLOR, GRADE: RED PUTTY WITH NEGLIGIBLE ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT FLASH POINT: >93 DEG. C (200 DEG. F)
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.25 G/CM3
SPECIFIC GRAVITY: 1.25 [REF STD: WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS: <1 % WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS: <1 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE
2,000 - 5,000 MG/KG
ZINC BORATE DERMAL RABBIT LD50: >5,000 MG/KG
ZINC BORATE INHALATION- RAT LC50: >4.95 MG/L
DUST/MIST
ZINC BORATE INGESTION RAT LD50: >5,000 MG/KG
SODIUM SILICATE DERMAL RABBIT LD50: >4,640 MG/KG
SODIUM SILICATE INGESTION RAT LD50: 500 MG/KG
PETROLATUM DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
PETROLATUM INGESTION RAT LD50: >5,000 MG/KG
POLYMER NJTS REG. DERMAL RABBIT LD50: >2,000 MG/KG
NO. 04499600-7315
POLYMER NJTS REG. INGESTION RAT LD50: >5,000 MG/KG
NO. 04499600-7315
POLYBUTYLENE DERMAL RAT LD50: >10,250 MG/KG
POLYBUTYLENE INGESTION RAT LD50: >34,600 MG/KG
MELAMINE PHOSPHATE DERMAL LD50 ESTIMATED TO BE
2,000 - 5,000 MG/KG
MELAMINE PHOSPHATE INGESTION RAT LD50: >4,000 MG/KG
GLASS WOOL DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
GLASS WOOL INGESTION LD50 ESTIMATED TO BE
2,000 - 5,000 MG/KG
BUTADIENE-STYRENE- DERMAL LD50 ESTIMATED TO BE
META-DIVINYLBENZENE >5,000 MG/KG
POLYMER
BUTADIENE-STYRENE- INGESTION LD50 ESTIMATED TO BE
META-DIVINYLBENZENE 2,000 - 5,000 MG/KG
POLYMER
AMORPHOUS SILICA DERMAL RABBIT LD50: >5,000 MG/KG
AMORPHOUS SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
AMORPHOUS SILICA INGESTION RAT LD50: >5,110 MG/KG
4,4'-ISOPRO- DERMAL RAT LD50: >1,600 MG/KG
PYLIDENEDIPHENOL-
EPICHLOROHYDRIN
POLYMER
4,4'-ISOPRO- INGESTION RAT LD50: >1,000 MG/KG
PYLIDENEDIPHENOL-
EPICHLOROHYDRIN
POLYMER
ALPHA-METHYLSTYRENE- DERMAL LD50 ESTIMATED TO BE
ISOAMYLENE- >5,000 MG/KG
PIPERYLENE POLYMER
ALPHA-METHYLSTYRENE- INGESTION RAT LD50: >40,000 MG/KG
ISOAMYLENE-
PIPERYLENE POLYMER
ROSIN DERMAL RABBIT LD50: >2,500 MG/KG
ROSIN INGESTION RAT LD50: 7,600 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
ZINC BORATE RABBIT NO SIGNIFICANT IRRITATION
SODIUM SILICATE RABBIT CORROSIVE
POLYMER NJTS REG. PROFESSIONAL NO SIGNIFICANT IRRITATION
NO. 04499600-7315 JUDGEMENT
POLYBUTYLENE RABBIT MINIMAL IRRITATION
GLASS WOOL PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
BUTADIENE-STYRENE-META- PROFESSIONAL MINIMAL IRRITATION
DIVINYLBENZENE POLYMER JUDGEMENT
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MILD IRRITANT
EPICHLOROHYDRIN POLYMER
ROSIN RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
ZINC BORATE RABBIT SEVERE IRRITANT
SODIUM SILICATE RABBIT CORROSIVE
POLYBUTYLENE RABBIT MILD IRRITANT
GLASS WOOL PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MODERATE IRRITANT
EPICHLOROHYDRIN POLYMER
ROSIN RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
ZINC BORATE GUINEA PIG NOT CLASSIFIED
SODIUM SILICATE MOUSE NOT CLASSIFIED
AMORPHOUS SILICA HUMAN AND ANIMAL NOT CLASSIFIED
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN AND ANIMAL SENSITIZING
EPICHLOROHYDRIN POLYMER
ROSIN GUINEA PIG SENSITIZING
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN NOT CLASSIFIED
EPICHLOROHYDRIN POLYMER
ROSIN HUMAN NOT CLASSIFIED
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ZINC BORATE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
SODIUM SILICATE IN VITRO NOT MUTAGENIC
SODIUM SILICATE IN VIVO NOT MUTAGENIC
GLASS WOOL IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
AMORPHOUS SILICA IN VITRO NOT MUTAGENIC
4,4'-ISOPROPYLIDENEDIPHENOL- IN VIVO NOT MUTAGENIC
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- IN VITRO SOME POSITIVE DATA EXIST,
EPICHLOROHYDRIN POLYMER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
GLASS WOOL INHALATION MULTIPLE SOME POSITIVE DATA EXIST, BUT
ANIMAL THE DATA ARE NOT SUFFICIENT
SPECIES FOR CLASSIFICATION
AMORPHOUS SILICA NOT MOUSE SOME POSITIVE DATA EXIST, BUT
SPECIFIED THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
4,4'-ISOPRO- DERMAL MOUSE SOME POSITIVE DATA EXIST, BUT
PYLIDENEDIPHENOL- THE DATA ARE NOT SUFFICIENT
EPICHLOROHYDRIN FOR CLASSIFICATION
POLYMER
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
ZINC BORATE INGESTION TOXIC TO MALE REPRODUCTION
ZINC BORATE INGESTION TOXIC TO DEVELOPMENT
SODIUM SILICATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR DEVELOPMENT
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT CLASSIFIED FOR FEMALE
EPICHLOROHYDRIN POLYMER REPRODUCTION
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT CLASSIFIED FOR MALE
EPICHLOROHYDRIN POLYMER REPRODUCTION
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL NOT CLASSIFIED FOR DEVELOPMENT
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT CLASSIFIED FOR DEVELOPMENT
EPICHLOROHYDRIN POLYMER
NAME SPECIES TEST RESULT EXPOSURE DURATION
ZINC BORATE RAT NOAEL: 92 DAYS
100 MG/KG/DAY
ZINC BORATE RAT LOAEL: DURING GESTATION
100 MG/KG/DAY
SODIUM SILICATE MOUSE NOAEL: DURING GESTATION
200 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT NOAEL: DURING
EPICHLOROHYDRIN POLYMER 300 MG/KG/DAY ORGANOGENESIS
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ZINC BORATE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
SODIUM SILICATE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
ZINC BORATE SIMILAR NOAEL:
HEALTH NOT AVAILABLE
HAZARDS
SODIUM SILICATE OFFICIAL NOAEL:
CLASSIFICATION NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ZINC BORATE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
RESPIRATORY SYSTEM
HEART
ENDOCRINE SYSTEM
HEMATOPOIETIC SYSTEM
LIVER
NERVOUS SYSTEM
KIDNEY AND/OR BLADDER
ZINC BORATE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
LIVER
KIDNEY AND/OR BLADDER
HEART
SKIN
BONE, TEETH, NAILS,
AND/OR HAIR
HEMATOPOIETIC SYSTEM
IMMUNE SYSTEM
NERVOUS SYSTEM
EYES
RESPIRATORY SYSTEM
VASCULAR SYSTEM
SODIUM SILICATE INGESTION KIDNEY AND/OR BLADDER SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
SODIUM SILICATE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
BLOOD
SODIUM SILICATE INGESTION HEART NOT CLASSIFIED
LIVER
POLYBUTYLENE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
POLYBUTYLENE INHALATION LIVER NOT CLASSIFIED
GLASS WOOL INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
AMORPHOUS SILICA INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
SILICOSIS
4,4'-ISOPRO- DERMAL LIVER NOT CLASSIFIED
PYLIDENEDIPHENOL-
EPICHLOROHYDRIN
POLYMER
4,4'-ISOPRO- DERMAL NERVOUS SYSTEM NOT CLASSIFIED
PYLIDENEDIPHENOL-
EPICHLOROHYDRIN
POLYMER
4,4'-ISOPRO- INGESTION AUDITORY SYSTEM NOT CLASSIFIED
PYLIDENEDIPHENOL- HEART
EPICHLOROHYDRIN ENDOCRINE SYSTEM
POLYMER HEMATOPOIETIC SYSTEM
LIVER
EYES
KIDNEY AND/OR BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
ZINC BORATE RAT NOAEL: 0.15 MG/L 2 WEEKS
ZINC BORATE RAT NOAEL: 375 MG/KG/DAY 92 DAYS
SODIUM SILICATE DOG LOAEL: 4 WEEKS
2,400 MG/KG/DAY
SODIUM SILICATE RAT NOAEL: 804 MG/KG/DAY 3 MONTHS
SODIUM SILICATE RAT NOAEL: 8 WEEKS
1,259 MG/KG/DAY
POLYBUTYLENE RAT NOAEL: 0.07 MG/L 2 WEEKS
POLYBUTYLENE RAT NOAEL: 0.7 MG/L 2 WEEKS
GLASS WOOL HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
AMORPHOUS SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
4,4'-ISOPRO- RAT NOAEL: 2 YEARS
PYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN
POLYMER
4,4'-ISOPRO- RAT NOAEL: 13 WEEKS
PYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN
POLYMER
4,4'-ISOPRO- RAT NOAEL: 28 DAYS
PYLIDENEDIPHENOL- 1,000 MG/KG/DAY
EPICHLOROHYDRIN
POLYMER
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. COMBUSTION PRODUCTS WILL INCLUDE HALOGEN ACID
(HCL/HF/HBR). FACILITY MUST BE CAPABLE OF HANDLING HALOGENATED MATERIALS.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC BORATE (ZINC COMPOUNDS) 138265-88-0 10 - 30
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 23-6572-4
VERSION NUMBER: 6.03
ISSUE DATE: 06/18/18
SUPERCEDES DATE: 01/18/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL,IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M PRODUCT
TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR
USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM