SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. HENKEL SAFETY DATA SHEET REVISION NUMBER: 004.1 ISSUE DATE: 07/20/2017
PRODUCT NAME: LOCTITE 480 INSTANT ADHESIVE, BLACK KNOWN AS 480 PRISM(R*) INSTANT ADHESIVE, B PRODUCT TYPE: CYANOACRYLATE RESTRICTION OF USE: NONE IDENTIFIED IDH NUMBER: 135466 ITEM NUMBER: 48040 REGION: UNITED STATES COMPANY ADDRESS: HENKEL CORPORATION ONE HENKEL WAY ROCKY HILL, CONNECTICUT 06067 CONTACT INFORMATION: TELEPHONE: +1 (860) 571-5100 MEDICAL EMERGENCY PHONE: POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711 TRANSPORT EMERGENCY PHONE: CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887 INTERNET: WWW.HENKELNA.COM
EMERGENCY OVERVIEW: DANGER: BONDS SKIN IN SECONDS. COMBUSTIBLE LIQUID. CAUSES EYE IRRITATION. MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE GENETIC DEFECTS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE LIQUID 4 EYE IRRITATION 2B GERM CELL MUTAGENICITY 1B SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 PICTOGRAM(S): HEALTH HAZARD EXCLAMATION MARK PRECAUTIONARY STATEMENTS: PREVENTION: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE PROTECTION. RESPONSE: IF INHALED: REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL. IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION. IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION. IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH. STORAGE: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP. DISPOSAL: DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS. CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS (GHS). SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE* ETHYL 2-CYANOACRYLATE 7085-85-0 80 - 90 CARBON BLACK 1333-86-4 1 - 5 PHTHALIC ANHYDRIDE 85-44-9 0.1 - 1 HYDROQUINONE 123-31-9 0.1 - 1 * EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
INHALATION: MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION. SKIN CONTACT: DO NOT PULL BONDED SKIN APART. SOAK IN WARM SOAPY WATER. GENTLY PEEL APART USING A BLUNT INSTRUMENT. IF SKIN IS BURNED DUE TO THE RAPID GENERATION OF HEAT BY A LARGE DROP, SEEK MEDICAL ATTENTION. IF LIPS ARE BONDED, APPLY WARM WATER TO THE LIPS AND ENCOURAGE WETTING AND PRESSURE FROM SALIVA IN MOUTH. PEEL OR ROLL LIPS APART. DO NOT PULL LIPS APART WITH DIRECT OPPOSING FORCE. EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. IF EYELIDS ARE BONDED CLOSED, RELEASE EYELASHES WITH WARM WATER BY COVERING WITH A WET PAD. DO NOT FORCE EYE OPEN. CYANOACRYLATE WILL BOND TO EYE PROTEIN AND WILL CAUSE A LACHRYMATORY EFFECT WHICH WILL HELP TO DEBOND THE ADHESIVE. KEEP EYE COVERED UNTIL DEBONDING IS COMPLETE, USUALLY WITHIN 1-3 DAYS. MEDICAL ATTENTION SHOULD BE SOUGHT IN CASE SOLID PARTICLES OF POLYMERIZED CYANOACRYLATE TRAPPED BEHIND THE EYELID CAUSED ABRASIVE DAMAGE. INGESTION: ENSURE BREATHING PASSAGES ARE NOT OBSTRUCTED. THE PRODUCT WILL POLYMERIZE RAPIDLY AND BOND TO THE MOUTH MAKING IT ALMOST IMPOSSIBLE TO SWALLOW. SALIVA WILL SEPARATE ANY SOLIDIFIED PRODUCT IN SEVERAL HOURS. PREVENT THE PATIENT FROM SWALLOWING ANY SEPARATED MASS. SYMPTOMS: SEE SECTION 11. NOTES TO PHYSICIAN: SURGERY IS NOT NECESSARY TO SEPARATE ACCIDENTALLY BONDED TISSUES. EXPERIENCE HAS SHOWN THAT BONDED TISSUES ARE BEST TREATED BY PASSIVE, NON-SURGICAL FIRST AID. IF RAPID CURING HAS CAUSED THERMAL BURNS THEY SHOULD BE TREATED SYMPTOMATICALLY AFTER ADHESIVE IS REMOVED.
EXTINGUISHING MEDIA: WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE. SPECIAL FIREFIGHTING PROCEDURES: WEAR A SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE PIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE HAZARDOUS COMBUSTION PRODUCTS: TRACE AMOUNTS OF TOXIC AND/OR IRRITATING FUMES MAY BE RELEASED AND THE USE OF BREATHING APPARATUS IS RECOMMENDED.
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL. ENVIRONMENTAL PRECAUTIONS: VENTILATE AREA. DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS. CLEAN-UP METHODS: DO NOT USE CLOTHS FOR MOPPING UP. FLOOD WITH WATER TO COMPLETE POLYMERIZATION AND SCRAPE OFF THE FLOOR. CURED MATERIAL CAN BE DISPOSED OF AS NON-HAZARDOUS WASTE. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
HANDLING: PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH FABRIC OR PAPER GOODS. CONTACT WITH THESE MATERIALS MAY CAUSE RAPID POLYMERIZATION WHICH CAN GENERATE SMOKE AND STRONG IRRITATING VAPORS, AND CAUSE THERMAL BURNS. STORAGE: FOR SAFE STORAGE, STORE BETWEEN 2 DEG. C (35.6 DEG. F) AND 8 DEG. C (46.4 DEG. F) KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE EQUIPMENT FOR EACH TASK PERFORMED. HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER ETHYL 2-CYANOACRYLATE 0.2 PPM TWA NONE NONE NONE CARBON BLACK 3 MG/M3 TWA 3.5 MG/M3 PEL NONE NONE INHALABLE FRACTION. PHTHALIC ANHYDRIDE 1 PPM TWA 2 PPM (12 MG/M3) NONE NONE (DERMAL PEL SENSITIZATION) (RESPIRATORY SENSITIZATION) HYDROQUINONE 1 MG/M3 TWA 2 MG/M3 PEL NONE NONE (DERMAL SENSITIZATION) ENGINEERING CONTROLS: USE POSITIVE DOWN-DRAFT EXHAUST VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS. RESPIRATORY PROTECTION: USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE. EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT EXISTS. SKIN PROTECTION: USE NITRILE GLOVES AND APRONS AS NECESSARY TO PREVENT CONTACT. DO NOT USE PVC, NYLON OR COTTON.
PHYSICAL STATE: LIQUID COLOR: BLACK ODOR: SHARP, IRRITATING ODOR THRESHOLD: 1 - 2 PPM PH: NOT APPLICABLE VAPOR PRESSURE: <0.5 MM Hg (25 DEG. C (77 DEG. F)) BOILING POINT/RANGE: >149 DEG. C (>300.2 DEG. F) MELTING POINT/RANGE: NOT DETERMINED SPECIFIC GRAVITY: 1.1 AT 20 DEG. C (68 DEG. F) VAPOR DENSITY: 3 APPROXIMATELY FLASH POINT: 80 - 93 DEG. C (176 DEG. F - 199.4 DEG. F) TAGLIABUE CLOSED CUP FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT DETERMINED FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT DETERMINED AUTOIGNITION TEMPERATURE: 485 DEG. C (905 DEG. F) FLAMMABILITY: NOT APPLICABLE EVAPORATION RATE: NOT AVAILABLE. SOLUBILITY IN WATER: POLYMERIZES IN PRESENCE OF WATER. PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED VOC CONTENT: <2%; <20 G/L (CALIFORNIA SCAQMD METHOD 316B) (ESTIMATED) VISCOSITY: NOT AVAILABLE. DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS. HAZARDOUS REACTIONS: RAPID EXOTHERMIC POLYMERIZATION WILL OCCUR IN THE PRESENCE OF WATER, AMINES, ALKALIS AND ALCOHOLS. HAZARDOUS DECOMPOSITION PRODUCTS: NONE INCOMPATIBLE MATERIALS: WATER, AMINES, ALKALIS AND ALCOHOLS. REACTIVITY: NOT AVAILABLE. CONDITIONS TO AVOID: SPONTANEOUS POLYMERIZATION.
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES POTENTIAL HEALTH EFFECTS/SYMPTOMS: INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. EXPOSURE TO VAPORS ABOVE THE ESTABLISHED EXPOSURE LIMIT RESULTS IN RESPIRATORY IRRITATION, WHICH MAY LEAD TO DIFFICULTY IN BREATHING AND TIGHTNESS IN THE CHEST. SKIN CONTACT: BONDS SKIN IN SECONDS. MAY CAUSE SKIN IRRITATION. CYANOACRYLATES HAVE BEEN REPORTED TO CAUSE ALLERGIC REACTION BUT DUE TO RAPID POLYMERIZATION AT THE SKIN SURFACE, AN ALLERGIC RESPONSE IS RARE. CYANOACRYLATES GENERATE HEAT ON SOLIDIFICATION. IN RARE CIRCUMSTANCES A LARGE DROP WILL BURN THE SKIN. CURED ADHESIVE DOES NOT PRESENT A HEALTH HAZARD EVEN IF BONDED TO THE SKIN. EYE CONTACT: IRRITATING TO EYES. CAUSES EXCESSIVE TEARING. EYELIDS MAY BOND. INGESTION: NOT EXPECTED TO BE HARMFUL BY INGESTION. RAPIDLY POLYMERIZES (SOLIDIFIES) AND BONDS IN MOUTH. IT IS ALMOST IMPOSSIBLE TO SWALLOW. HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH EFFECTS ETHYL 2-CYANOACRYLATE NONE IRRITANT, ALLERGEN, RESPIRATORY CARBON BLACK ORAL LD50 (RAT): RESPIRATORY, SOME EVIDENCE >8,000 MG/KG OF CARCINOGENICITY PHTHALIC ANHYDRIDE ORAL LD50 (RAT): ALLERGEN, CORROSIVE, 800 MG/KG IRRITANT, RESPIRATORY ORAL LD50 (MOUSE): 1,500 MG/KG ORAL LD50 (RAT): 1,530 MG/KG ORAL LD50 (RAT): 4,020 MG/KG ORAL LD50 (RABBIT): >1,000 MG/KG DERMAL LD50 (RABBIT): >3,160 MG/KG HYDROQUINONE ORAL LD50 (RAT): BLOOD, BONE MARROW, CENTRAL 320 MG/KG NERVOUS SYSTEM, ORAL LD50 (MOUSE): DEVELOPMENTAL, EYES, IMMUNE 245 MG/KG SYSTEM, IRRITANT, LIVER, ORAL LD50 (RABBIT): MUTAGEN, SKIN, THYROID 540 MG/KG DERMAL LD50 (RAT): >900 MG/KG HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN (SPECIFICALLY REGULATED) ETHYL 2-CYANOACRYLATE NO NO NO CARBON BLACK NO NO NO PHTHALIC ANHYDRIDE NO NO NO HYDROQUINONE NO NO NO
ECOLOGICAL INFORMATION: NOT KNOWN.
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY. RECOMMENDED METHOD OF DISPOSAL: FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL. HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY PACKAGE/CONFIGURATION. U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR): PROPER SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S. (CYANOACRYLATE ESTER) HAZARD CLASS OR DIVISION: COMBUSTIBLE LIQUID IDENTIFICATION NUMBER: NA 1993 PACKING GROUP: III INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA): PROPER SHIPPING NAME: AVIATION REGULATED LIQUID, N.O.S. (CYANOACRYLATE ESTER) HAZARD CLASS OR DIVISION: 9 IDENTIFICATION NUMBER: UN 3334 PACKING GROUP: III EXCEPTIONS: PRIMARY PACKS CONTAINING LESS THAN 500ML ARE UNREGULATED BY THIS MODE OF TRANSPORT AND MAY BE SHIPPED UNRESTRICTED. WATER TRANSPORTATION (IMO/IMDG): PROPER SHIPPING NAME: NOT REGULATED HAZARD CLASS OR DIVISION: NONE IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE
UNITED STATES REGULATORY INFORMATION: TSCA 8 (B) INVENTORY STATUS: ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC SUBSTANCES CONTROL ACT INVENTORY. TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS CERCLA/SARA SECTION 302 EHS: HYDROQUINONE (CAS# 123-31-9). CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH, FIRE, REACTIVE CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS. CALIFORNIA PROPOSITION 65: THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE CANCER. CANADA REGULATORY INFORMATION: CEPA DSL/NDSL STATUS: ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN DOMESTIC SUBSTANCES LIST.
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN SECTIONS: NEW SAFETY DATA SHEET FORMAT. PREPARED BY: CATHERINE BIMLER, REGULATORY AFFAIRS SPECIALIST ISSUE DATE: 07/20/2017 DISCLAIMER: THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES ("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS. |