| Common Name: | LOCTITE 4203 THERM. RESIST. INST. AD. KNOWN AS 4203 PRISM INSTANT ADHESIV, 28026 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 4/2/2020 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2VFH3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 002.1
ISSUE DATE: 04/02/2020
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE 4203 THERM. RESIST. INST. AD. KNOWN AS 4203 PRISM(R*) INSTANT
ADHESIVE T
PRODUCT TYPE: CYANOACRYLATE
IDH NUMBER: 232837
ITEM NUMBER: 28026
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING
BONDS SKIN IN SECONDS.
COMBUSTIBLE LIQUID.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 4
EYE IRRITATION 2B
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING.
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY
AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR
PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
IN A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL,
STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
ETHYL 2-CYANOACRYLATE 7085-85-0 80 - 90
THICKENER UNKNOWN 5 - 10
PHTHALIC ANHYDRIDE 85-44-9 0.1 - 1
METHYL ACRYLATE 96-33-3 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
DO NOT PULL BONDED SKIN APART. SOAK IN WARM SOAPY WATER. GENTLY PEEL
APART USING A BLUNT INSTRUMENT. IF SKIN IS BURNED DUE TO THE RAPID
GENERATION OF HEAT BY A LARGE DROP, SEEK MEDICAL ATTENTION. IF LIPS ARE
BONDED, APPLY WARM WATER TO THE LIPS AND ENCOURAGE WETTING AND PRESSURE
FROM SALIVA IN MOUTH. PEEL OR ROLL LIPS APART. DO NOT PULL LIPS APART WITH
DIRECT OPPOSING FORCE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION. IF EYELIDS ARE BONDED CLOSED, RELEASE EYELASHES WITH
WARM WATER BY COVERING WITH A WET PAD. DO NOT FORCE EYE OPEN.
CYANOACRYLATE WILL BOND TO EYE PROTEIN AND WILL CAUSE A LACHRYMATORY
EFFECT WHICH WILL HELP TO DEBOND THE ADHESIVE. KEEP EYE COVERED UNTIL
DEBONDING IS COMPLETE, USUALLY WITHIN 1-3 DAYS. MEDICAL ATTENTION SHOULD
BE SOUGHT IN CASE SOLID PARTICLES OF POLYMERIZED CYANOACRYLATE TRAPPED
BEHIND THE EYELID CAUSED ABRASIVE DAMAGE.
INGESTION:
ENSURE BREATHING PASSAGES ARE NOT OBSTRUCTED. THE PRODUCT WILL POLYMERIZE
RAPIDLY AND BOND TO THE MOUTH MAKING IT ALMOST IMPOSSIBLE TO SWALLOW.
SALIVA WILL SEPARATE ANY SOLIDIFIED PRODUCT IN SEVERAL HOURS. PREVENT
THE PATIENT FROM SWALLOWING ANY SEPARATED MASS.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN:
SURGERY IS NOT NECESSARY TO SEPARATE ACCIDENTALLY BONDED TISSUES.
EXPERIENCE HAS SHOWN THAT BONDED TISSUES ARE BEST TREATED BY PASSIVE,
NON-SURGICAL FIRST AID. IF RAPID CURING HAS CAUSED THERMAL BURNS THEY
SHOULD BE TREATED SYMPTOMATICALLY AFTER ADHESIVE IS REMOVED.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR A SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE PIECE OPERATED
IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS:
TRACE AMOUNTS OF TOXIC AND/OR IRRITATING FUMES MAY BE RELEASED AND THE USE
OF BREATHING APPARATUS IS RECOMMENDED.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
VENTILATE AREA. DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
DO NOT USE CLOTHS FOR MOPPING UP. FLOOD WITH WATER TO COMPLETE
POLYMERIZATION AND SCRAPE OFF THE FLOOR. CURED MATERIAL CAN BE
DISPOSED OF AS NON-HAZARDOUS WASTE. REFER TO SECTION 8 "EXPOSURE
CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH FABRIC OR PAPER GOODS. CONTACT WITH THESE MATERIALS
MAY CAUSE RAPID POLYMERIZATION WHICH CAN GENERATE SMOKE AND STRONG
IRRITATING VAPORS, AND CAUSE THERMAL BURNS. PREVENT CONTACT WITH EYES,
SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER
HANDLING.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN
FLAME. KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
ETHYL 2-CYANOACRYLATE 1 PPM STEL NONE NONE NONE
0.2 PPM TWA
(RESPIRATORY
SENSITIZATION)
(DERMAL
SENSITIZATION)
THICKENER NONE NONE NONE NONE
PHTHALIC ANHYDRIDE (SKIN) INHALABLE 2 PPM NONE NONE
FRACTION AND (12 MG/M3)
VAPOR. PEL
0.005 MG/M3 STEL
INHALABLE
FRACTION AND
VAPOR.
0.002 MG/M3 TWA
INHALABLE
FRACTION AND
VAPOR.
(RESPIRATORY
SENSITIZATION)
(DERMAL
SENSITIZATION)
METHYL ACRYLATE 2 PPM TWA 10 PPM NONE NONE
(SKIN) (DERMAL (35 MG/M3)
SENSITIZATION) PEL (SKIN)
ENGINEERING CONTROLS:
USE POSITIVE DOWN-DRAFT EXHAUST VENTILATION IF GENERAL VENTILATION IS
INSUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE
LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR
CARTRIDGE.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE NITRILE GLOVES AND APRONS AS NECESSARY TO PREVENT CONTACT. DO NOT USE
PVC, NYLON OR COTTON.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: IRRITATING, SHARP
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <0.2 MM Hg
BOILING POINT/RANGE: >149 DEG. C (>300.2 DEG. F)
MELTING POINT/ RANGE: NOT DETERMINED
SPECIFIC GRAVITY: 1.057
VAPOR DENSITY: 3 APPROXIMATELY
FLASH POINT: 80 DEG. C (176 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT DETERMINED
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: POLYMERISES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT APPLICABLE
VOC CONTENT:
<20 G/L (CALIFORNIA SCAQMD METHOD 316B) (ESTIMATED)
<2 %; <20 G/L (CALIFORNIA SCAQMD METHOD 316B) (ESTIMATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
HAZARDOUS REACTIONS:
RAPID EXOTHERMIC POLYMERIZATION WILL OCCUR IN THE PRESENCE OF WATER,
AMINES, ALKALIS AND ALCOHOLS.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE
INCOMPATIBLE MATERIALS: WATER, AMINES, ALKALIS AND ALCOHOLS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: SPONTANEOUS POLYMERIZATION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. EXPOSURE TO VAPORS ABOVE THE
ESTABLISHED EXPOSURE LIMIT RESULTS IN RESPIRATORY IRRITATION, WHICH MAY
LEAD TO DIFFICULTY IN BREATHING AND TIGHTNESS IN THE CHEST.
SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. BONDS SKIN IN SECONDS. CYANOACRYLATES HAVE BEEN
REPORTED TO CAUSE ALLERGIC REACTION BUT DUE TO RAPID POLYMERIZATION AT THE
SKIN SURFACE, AN ALLERGIC RESPONSE IS RARE. CYANOACRYLATES GENERATE HEAT
ON SOLIDIFICATION. IN RARE CIRCUMSTANCES A LARGE DROP WILL BURN THE SKIN.
CURED ADHESIVE DOES NOT PRESENT A HEALTH HAZARD EVEN IF BONDED TO THE
SKIN.
EYE CONTACT:
IRRITATING TO EYES. CAUSES EXCESSIVE TEARING. EYELIDS MAY BOND.
INGESTION:
NOT EXPECTED TO BE HARMFUL BY INGESTION. RAPIDLY POLYMERIZES (SOLIDIFIES)
AND BONDS IN MOUTH. IT IS ALMOST IMPOSSIBLE TO SWALLOW.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
ETHYL 2-CYANOACRYLATE NONE IRRITANT, ALLERGEN,
RESPIRATORY
THICKENER NONE NO DATA
PHTHALIC ANHYDRIDE ORAL LD50 (RAT): ALLERGEN, CORROSIVE,
800 MG/KG IRRITANT, RESPIRATORY
ORAL LD50 (MOUSE):
1,500 MG/KG
ORAL LD50 (RAT):
1,530 MG/KG
ORAL LD50 (RAT):
4,020 MG/KG
ORAL LD50 (RABBIT):
>1,000 MG/KG
DERMAL LD50 (RABBIT):
>3,160 MG/KG
METHYL ACRYLATE ORAL LD50 (MOUSE): ALLERGEN, CENTRAL
827 MG/KG NERVOUS SYSTEM, HEART,
IRRITANT, KIDNEY,
LIVER, MUTAGEN
ORAL LD50 (RAT):
277 MG/KG
ORAL LD50 (RABBIT):
0.2 G/KG
DERMAL LD50 (RABBIT):
1,243 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
ETHYL 2-CYANOACRYLATE NO NO NO
THICKENER NO NO NO
PHTHALIC ANHYDRIDE NO NO NO
METHYL ACRYLATE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S. (CYANOACRYLATE ESTER)
HAZARD CLASS OR DIVISION: COMBUSTIBLE LIQUID
IDENTIFICATION NUMBER: NA 1993
PACKING GROUP: III
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AVIATION REGULATED LIQUID, N.O.S. (CYANOACRYLATE ESTER)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3334
PACKING GROUP: III
EXCEPTIONS: NOT MORE THAN 500 ML (EACH INNER PACKAGE) - UNRESTRICTED
EXCEPTIONS:
PRIMARY PACKS CONTAINING LESS THAN 500ML ARE UNREGULATED BY THIS MODE OF
TRANSPORT AND MAY BE SHIPPED UNRESTRICTED.
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312:
IMMEDIATE HEALTH, DELAYED HEALTH, FIRE, REACTIVE
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY:
METHYL ACRYLATE (CAS# 96-33-3) 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES
LIST. ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON
THE DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE
TRACKED BY ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT
CANADA. THEY MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE
CONTACT REGULATORY AFFAIRS FOR ADDITIONAL DETAILS.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS:
NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 04/02/2020
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF
ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY
OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION
PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY
OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY
AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.