| Common Name: | LOCTITE SF 7452 ACCELERATOR, AEROSOL KNOWN AS TAK PAK 7452 ACCELERATOR, 18637, L |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 6/10/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 2VFH7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 005.1
ISSUE DATE: 06/10/2016
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE SF 7452 ACCELERATOR, AEROSOL KNOWN AS TAK PAK(R*) 7452(TM)
ACCELERATOR
PRODUCT TYPE: ACCELERATOR
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 229784
ITEM NUMBER: 18637
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CONTENTS UNDER PRESSURE.
EXTREMELY FLAMMABLE AEROSOL.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE AEROSOL. 1
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S):
FLAME
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN,
EVEN AFTER USE. AVOID BREATHING MIST OR SPRAY. WASH AFFECTED AREA
THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR
PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
ACETONE 67-64-1 60 - 100
BUTANE 106-97-8 10 - 30
PROPANE 74-98-6 10 - 30
N,N-DIMETHYL-P-TOLUIDINE 99-97-8 0.1 - 1
FRAGRANCE UNKNOWN 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE.
GET MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET IMMEDIATE
MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. WATER SHOULD BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CONTENTS UNDER PRESSURE. VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS,
TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION, AND FLASH BACK.
EXPOSURE TO TEMPERATURES ABOVE 49 DEG. C (120 DEG. F) MAY CAUSE CONTAINER
TO BURST. DO NOT PUNCTURE OR INCINERATE PRESSURIZED CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF NITROGEN. OXIDES OF CARBON. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. ENSURE ADEQUATE VENTILATION. KEEP
UNNECESSARY PERSONNEL AWAY. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND,
SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH
MATERIAL AS POSSIBLE. STORE IN A CLOSED METAL CONTAINER UNTIL READY FOR
DISPOSAL. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND OR
BE MOVED BY VENTILATION AND SUBSEQUENTLY IGNITED BY HEAT, PILOT LIGHTS OR
OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM THE MATERIAL HANDLING
POINT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR
TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. DURING USE AND UNTIL ALL VAPORS ARE
GONE: KEEP AREA VENTILATED - DO NOT SMOKE; EXTINGUISH ALL FLAMES, PILOT
LIGHTS, AND HEATERS; TURN OFF STOVES, ELECTRICAL TOOLS AND APPLIANCES, AND
ANY OTHER SOURCES OF IGNITION. DO NOT PUNCTURE OR INCINERATE PRESSURIZED
CONTAINERS. REFER TO SECTION 8.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
ACETONE 250 PPM TWA 1,000 PPM (2,400 MG/M3) PEL
500 PPM STEL
BUTANE 1,000 PPM STEL NONE
PROPANE INCLUDED IN THE 1,000 PPM (1,800 MG/M3) PEL
REGULATION BUT WITH
NO DATA VALUES. SEE
REGULATION FOR
FURTHER DETAILS
N,N-DIMETHYL-P-TOLUIDINE NONE NONE
FRAGRANCE NONE NONE
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
ACETONE NONE NONE
BUTANE NONE NONE
PROPANE NONE NONE
N,N-DIMETHYL-P-TOLUIDINE 0.5 PPM TWA NONE
FRAGRANCE NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NEOPRENE GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: AEROSOL
COLOR: AMBER, CLEAR
ODOR: ACETONE
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: 185 MMHg APPROXIMATELY
BOILING POINT/RANGE: 135 DEG. F (57.2 DEG. C)NONE
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.7926
VAPOR DENSITY: 2 APPROXIMATELY
FLASH POINT: -91 DEG. C (-131.8 DEG. F) ; (VALUE FOR PROPELLANT).
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 2.8 %
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 12.8 %
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: EXTREMELY FLAMMABLE AEROSOL.
EVAPORATION RATE: 1.9 (ETHER = 1)
SOLUBILITY IN WATER: SOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 1.02 %; 80 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO TEMPERATURES ABOVE 48.9 DEG. C
(120 DEG. F). HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION. STORE
AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM. CENTRAL NERVOUS SYSTEM DEPRESSION, INCLUDING DIZZINESS,
DROWSINESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND
DIARRHEA.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
ACETONE ORAL LD50 (MOUSE): CENTRAL NERVOUS
3,000 MG/KG SYSTEM, IRRITANT
ORAL LD50 (RABBIT):
5,340 MG/KG
ORAL LD50 (RAT):
5,800 MG/KG
ORAL LD50 (RAT):
9,800 MG/KG
ORAL LD50 (MOUSE):
5.2 G/KG
DERMAL LD50 (RABBIT):
20,000 MG/KG
INHALATION LC50
(RAT, 4 H): 76 MG/L
BUTANE INHALATION LC50 CARDIAC, CENTRAL
(RAT, 4 H): 658 MG/L NERVOUS SYSTEM,
IRRITANT
PROPANE NONE CARDIAC, CENTRAL
NERVOUS SYSTEM,
IRRITANT
N,N-DIMETHYL-P-TOLUIDINE NONE MUTAGEN, ALLERGEN
FRAGRANCE NONE NO DATA
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
ACETONE NO NO NO
BUTANE NO NO NO
PROPANE NO NO NO
N,N-DIMETHYL-P-TOLUIDINE NO NO NO
FRAGRANCE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
EXCEPTIONS:
ID8000, (NOT MORE THAN 500 ML), MAY QUALIFY AS CONSUMER COMMODITY
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
EXCEPTIONS: LIMITED QUANTITY (NOT MORE THAN 1 L).
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: FIRE, DELAYED HEALTH, IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY:
ACETONE (CAS# 67-64-1): 5,000 LBS. (2,270 KG)
BUTANE (CAS# 106-97-8): 100 LBS. (45.4 KG)
PROPANE (CAS# 74-98-6): 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ONE OR MORE COMPONENTS ARE NOT LISTED ON, AND ARE NOT EXEMPT FROM LISTING
ON EITHER THE DOMESTIC SUBSTANCES LIST OR THE NON-DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: CATHERINE BIMLER, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 06/10/2016
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 006.1
ISSUE DATE: 03/05/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE 382 TAKPAK KNOWN AS LOCTITE(R) 382 ULTRA PERFORMAN
PRODUCT TYPE: CYANOACRYLATE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 691336
ITEM NUMBER: 8200239
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
BONDS SKIN IN SECONDS.
COMBUSTIBLE LIQUID.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 4
EYE IRRITATION 2B
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. AVOID
BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR PROTECTIVE
GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A
WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
ETHYL 2-CYANOACRYLATE 7085-85-0 80 - 90
TREATED FUMED SILICA 67762-90-7 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
DO NOT PULL BONDED SKIN APART. SOAK IN WARM SOAPY WATER. GENTLY PEEL APART
USING A BLUNT INSTRUMENT. IF SKIN IS BURNED DUE TO THE RAPID GENERATION OF
HEAT BY A LARGE DROP, SEEK MEDICAL ATTENTION. IF LIPS ARE BONDED, APPLY
WARM WATER TO THE LIPS AND ENCOURAGE WETTING AND PRESSURE FROM SALIVA IN
MOUTH. PEEL OR ROLL LIPS APART. DO NOT PULL LIPS APART WITH DIRECT OPPOSING
FORCE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION. IF EYELIDS ARE BONDED CLOSED, RELEASE EYELASHES WITH WARM WATER
BY COVERING WITH A WET PAD. DO NOT FORCE EYE OPEN. CYANOACRYLATE WILL BOND
TO EYE PROTEIN AND WILL CAUSE A LACHRYMATORY EFFECT WHICH WILL HELP TO
DEBOND THE ADHESIVE. KEEP EYE COVERED UNTIL DEBONDING IS COMPLETE, USUALLY
WITHIN 1-3 DAYS. MEDICAL ATTENTION SHOULD BE SOUGHT IN CASE SOLID PARTICLES
OF POLYMERIZED CYANOACRYLATE TRAPPED BEHIND THE EYELID CAUSED ABRASIVE
DAMAGE.
INGESTION:
ENSURE BREATHING PASSAGES ARE NOT OBSTRUCTED. THE PRODUCT WILL POLYMERIZE
RAPIDLY AND BOND TO THE MOUTH MAKING IT ALMOST IMPOSSIBLE TO SWALLOW.
SALIVA WILL SEPARATE ANY SOLIDIFIED PRODUCT IN SEVERAL HOURS. PREVENT THE
PATIENT FROM SWALLOWING ANY SEPARATED MASS.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN:
SURGERY IS NOT NECESSARY TO SEPARATE ACCIDENTALLY BONDED TISSUES.
EXPERIENCE HAS SHOWN THAT BONDED TISSUES ARE BEST TREATED BY PASSIVE,
NON-SURGICAL FIRST AID. IF RAPID CURING HAS CAUSED THERMAL BURNS THEY
SHOULD BE TREATED SYMPTOMATICALLY AFTER ADHESIVE IS REMOVED.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR A SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE PIECE OPERATED
IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS:
TRACE AMOUNTS OF TOXIC AND/OR IRRITATING FUMES MAY BE RELEASED AND THE USE
OF BREATHING APPARATUS IS RECOMMENDED.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
VENTILATE AREA. DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
DO NOT USE CLOTHS FOR MOPPING UP. FLOOD WITH WATER TO COMPLETE
POLYMERIZATION AND SCRAPE OFF THE FLOOR. CURED MATERIAL CAN BE DISPOSED OF
AS NON-HAZARDOUS WASTE. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL
PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH FABRIC OR PAPER
GOODS. CONTACT WITH THESE MATERIALS MAY CAUSE RAPID POLYMERIZATION WHICH
CAN GENERATE SMOKE AND STRONG IRRITATING VAPORS, AND CAUSE THERMAL BURNS.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
ETHYL 2-CYANOACRYLATE 0.2 PPM TWA NONE
TREATED FUMED SILICA 10 MG/M3 TWA 15 MG/M3 TWA
NHALABLE DUST. TOTAL DUST.
3 MG/M3 TWA 5 MG/M3 TWA
RESPIRABLE FRACTION. RESPIRABLE FRACTION.
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
ETHYL 2-CYANOACRYLATE NONE NONE
TREATED FUMED SILICA NONE NONE
ENGINEERING CONTROLS:
USE POSITIVE DOWN-DRAFT EXHAUST VENTILATION IF GENERAL VENTILATION IS
INSUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE
LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE NITRILE GLOVES AND APRONS AS NECESSARY TO PREVENT CONTACT. DO NOT USE
PVC, NYLON OR COTTON.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: CLEAR
ODOR: IRRITATING, SHARP
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <0.5 MMHg (77 DEG. F (25 DEG. C))
BOILING POINT/RANGE: >300 DEG. F (>148.9 DEG. C)NONE
MELTING POINT/RANGE: NOT DETERMINED
SPECIFIC GRAVITY: 1.05 AT 75 DEG. F (23.89 DEG. C)
VAPOR DENSITY: 3 APPROXIMATELY
FLASH POINT: 86.95 DEG. C (188.51 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT DETERMINED
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: 485 DEG. C (905 DEG. F)
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: POLYMERISES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT APPLICABLE
VOC CONTENT: <2 %; <20 G/L (CALIFORNIA SCAQMD METHOD 316B) (ESTIMATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
HAZARDOUS REACTIONS:
RAPID EXOTHERMIC POLYMERIZATION WILL OCCUR IN THE PRESENCE OF WATER,
AMINES, ALKALIS AND ALCOHOLS.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE
INCOMPATIBLE MATERIALS: WATER, AMINES, ALKALIS AND ALCOHOLS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: SPONTANEOUS POLYMERIZATION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. EXPOSURE TO VAPORS ABOVE THE
ESTABLISHED EXPOSURE LIMIT RESULTS IN RESPIRATORY IRRITATION, WHICH
MAY LEAD TO DIFFICULTY IN BREATHING AND TIGHTNESS IN THE CHEST.
SKIN CONTACT:
BONDS SKIN IN SECONDS. MAY CAUSE SKIN IRRITATION. CYANOACRYLATES HAVE BEEN
REPORTED TO CAUSE ALLERGIC REACTION BUT DUE TO RAPID POLYMERIZATION AT THE
SKIN SURFACE, AN ALLERGIC RESPONSE IS RARE. CYANOACRYLATES GENERATE HEAT ON
SOLIDIFICATION. IN RARE CIRCUMSTANCES A LARGE DROP WILL BURN THE SKIN.
CURED ADHESIVE DOES NOT PRESENT A HEALTH HAZARD EVEN IF BONDED TO THE SKIN.
EYE CONTACT:
IRRITATING TO EYES. CAUSES EXCESSIVE TEARING. EYELIDS MAY BOND.
INGESTION:
NOT EXPECTED TO BE HARMFUL BY INGESTION. RAPIDLY POLYMERIZES (SOLIDIFIES)
AND BONDS IN MOUTH. IT IS ALMOST IMPOSSIBLE TO SWALLOW.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
ETHYL 2-CYANOACRYLATE NONE IRRITANT, ALLERGEN,
RESPIRATORY
TREATED FUMED SILICA NONE IRRITANT
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
ETHYL 2-CYANOACRYLATE NO NO NO
TREATED FUMED SILICA NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S. (CYANOACRYLATE ESTER)
HAZARD CLASS OR DIVISION: COMBUSTIBLE LIQUID
IDENTIFICATION NUMBER: NA 1993
PACKING GROUP: III
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AVIATION REGULATED LIQUID, N.O.S. (CYANOACRYLATE ESTER)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3334
PACKING GROUP: III
EXCEPTIONS:
PRIMARY PACKS CONTAINING LESS THAN 500ML ARE UNREGULATED BY THIS MODE OF
TRANSPORT AND MAY BE SHIPPED UNRESTRICTED.
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, REACTIVE, FIRE
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES LIST.
ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE
DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE TRACKED BY
ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT CANADA. THEY
MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE CONTACT
REGULATORY AFFAIRS FOR ADDITIONAL DETAILS.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 03/05/2018
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.