| Common Name: | LOCTITE SF 7471 PRIMER KNOWN AS LOCTITE 7471 PRIMER LOCQUIC, 19267 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 4/2/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2VFK6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 008.0
ISSUE DATE: 04/02/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE SF 7471 PRIMER KNOWN AS LOCTITE(R*) 7471(TM) PRIMER LOCQUIC(R*)
PRODUCT TYPE: ACTIVATOR
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 135285
ITEM NUMBER: 19267
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CONTENTS UNDER PRESSURE.
HIGHLY FLAMMABLE LIQUID AND VAPOR.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
ASPIRATION HAZARD 1
PICTOGRAM(S):
FLAME
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. NO RELEASE INTO WATER. USE EXPLOSION-PROOF
EQUIPMENT. USE NON-SPARKING TOOLS. TAKE ACTION TO PREVENT STATIC
DISCHARGES. AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA
THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. DO NOT INDUCE VOMITING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN
A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
ACETONE 67-64-1 80 - 90
2-PROPANOL 67-63-0 10 - 20
2-MERCAPTOBENZOTHIAZOLE 149-30-4 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE.
GET MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. GET
MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. WATER SHOULD BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SULFUR. IRRITATING ORGANIC
VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. ENSURE ADEQUATE VENTILATION. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. KEEP UNNECESSARY PERSONNEL AWAY.
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST). STORE IN A PARTLY FILLED, CLOSED CONTAINER
UNTIL DISPOSAL. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL
PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
DURING USE AND UNTIL ALL VAPORS ARE GONE: KEEP AREA VENTILATED - DO NOT
SMOKE; EXTINGUISH ALL FLAMES, PILOT LIGHTS, AND HEATERS; TURN OFF STOVES,
ELECTRICAL TOOLS AND APPLIANCES, AND ANY OTHER SOURCES OF IGNITION. PREVENT
CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH
THOROUGHLY AFTER HANDLING. WASH THOROUGHLY AFTER HANDLING. REFER TO
SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 49 DEG. C (120.2 DEG. F)
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
ACETONE 250 PPM TWA 1,000 PPM (2,400 MG/M3) PEL
500 PPM STEL
2-PROPANOL 200 PPM TWA 400 PPM (980 MG/M3) PEL
400 PPM STEL
2-MERCAPTOBENZOTHIAZOLE NONE NONE
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
ACETONE NONE NONE
2-PROPANOL NONE NONE
2-MERCAPTOBENZOTHIAZOLE 5 MG/M3 TWA NONE
(SKIN) (SKIN SENSITIZER)
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NEOPRENE, BUTYL-RUBBER, OR
NITRILE-RUBBER GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: AMBER TO YELLOWISH
ODOR: ACETONE
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: 172 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: 56 DEG. C (132.8 DEG. F)NO METHOD
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.7953
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: -8 DEG. C (17.6 DEG. F); ESTIMATED
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 13.3 %; 106 G/L EPA METHOD 24
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SULFUR. IRRITATING ORGANIC
VAPOURS.
INCOMPATIBLE MATERIALS: ACIDS. STRONG OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION. STORE AWAY FROM
INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE DIZZINESS, INCOORDINATION, HEADACHE, NAUSEA, AND VOMITING.
CENTRAL NERVOUS SYSTEM EFFECTS.
SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. SOLVENT
ACTION CAN DRY AND DEFAT THE SKIN, CAUSING THE SKIN TO CRACK, LEADING TO
DERMATITIS.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
THIS PRODUCT MAY BE FATAL IF IT IS SWALLOWED. MAY CAUSE AN ASPIRATION
HAZARD IF SWALLOWED. MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF
SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
ACETONE ORAL LD50 (MOUSE): CENTRAL NERVOUS
5.2 G/KG SYSTEM, IRRITANT
ORAL LD50 (MOUSE):
3,000 MG/KG
ORAL LD50 (RABBIT):
5,340 MG/KG
ORAL LD50 (RAT):
5,800 MG/KG
ORAL LD50 (RAT):
9,800 MG/KG
DERMAL LD50 (RABBIT):
20,000 MG/KG
INHALATION LC50
(RAT, 4 H): 76 MG/L
2-PROPANOL ORAL LD50 (RAT): ALLERGEN, CENTRAL
5,045 MG/KG NERVOUS SYSTEM,
IRRITANT
ORAL LD50 (MOUSE):
3,600 MG/KG
ORAL LD50 (RABBIT):
6,410 MG/KG
ORAL LD50 (RAT):
4.7 G/KG
ORAL LD50 (MOUSE):
4.5 G/KG
ORAL LD50 (RABBIT):
8.0 G/KG
ORAL LD50 (RABBIT):
5.03 G/KG
DERMAL LD50 (RABBIT):
12,800 MG/KG
2-MERCAPTOBENZOTHIAZOLE ORAL LD50 (MOUSE): ALLERGEN, KIDNEY, SOME
3,148 MG/KG EVIDENCE OF
CARCINOGENICITY
ORAL LD50 (MOUSE):
1,558 MG/KG
ORAL LD50 (MOUSE):
1,490 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
ACETONE NO NO NO
2-PROPANOL NO NO NO
2-MERCAPTOBENZOTHIAZOLE NO GROUP 2A NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
THIS PRODUCT MAY CONTAIN TRACES OF:
D018: BENZENE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, N.O.S. (ACETONE, ISOPROPANOL)
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1993
PACKING GROUP: II
DOT HAZARDOUS SUBSTANCE(S): ACETONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (ACETONE, ISOPROPANOL)
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1993
PACKING GROUP: II
EXCEPTIONS:
(NOT MORE THAN 500 ML), MAY QUALIFY AS CONSUMER COMMODITY, ID8000
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: FLAMMABLE LIQUID, N.O.S. (ACETONE, ISOPROPANOL)
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1993
PACKING GROUP: II
EXCEPTIONS: LIMITED QUANTITY (NOT MORE THAN 1 L).
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: DELAYED HEALTH, IMMEDIATE HEALTH, FIRE
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY:
ACETONE (CAS# 67-64-1): 5,000 LBS. (2,270 KG)
2-PROPANOL (CAS# 67-63-0): 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: REVIEWED SDS. REISSUED WITH NEW DATE.
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 04/02/2018
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.