SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. HENKEL SAFETY DATA SHEET REVISION NUMBER: 002.0 ISSUE DATE: 05/12/2015
PRODUCT NAME: LOCTITE UK U-09FL KNOWN AS HYSOL U-09FL URETH ADH ULTRA PRODUCT TYPE: 2-COMPONENT POLYURETHANE ADHESIVE RESTRICTION OF USE: NONE IDENTIFIED IDH NUMBER: 702027 ITEM NUMBER: 29460_2026309 REGION: UNITED STATES COMPANY ADDRESS: HENKEL CORPORATION ONE HENKEL WAY ROCKY HILL, CONNECTICUT 06067 CONTACT INFORMATION: TELEPHONE: (860) 571-5100 MEDICAL EMERGENCY PHONE: POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711 TRANSPORT EMERGENCY PHONE: CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887 INTERNET: WWW.HENKELNA.COM
EMERGENCY OVERVIEW: WARNING: CAUSES SKIN AND EYE IRRITATION. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2B PICTOGRAM(S): EXCLAMATION MARK PRECAUTIONARY STATEMENTS: PREVENTION: WASH THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES. RESPONSE: IF ON SKIN: WASH WITH PLENTY OF WATER. IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO REMOVE. CONTINUE RINSING. IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION. IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING. STORAGE: NOT PRESCRIBED DISPOSAL: NOT PRESCRIBED CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS (GHS). SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE* SUBSTITUTED POLYOL PROPRIETARY 10 - 30 DIMETHYLTINDINEODECANOATE 68928-76-7 1 - 5 * EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
INHALATION: MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE). REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. EYE CONTACT: RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. SYMPTOMS: SEE SECTION 11.
EXTINGUISHING MEDIA: WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE. SPECIAL FIREFIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY. UNUSUAL FIRE OR EXPLOSION HAZARDS: CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON. OXIDES OF TIN. ALCOHOLS. ETHERS. KETONES. IRRITATING VAPORS.
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL. ENVIRONMENTAL PRECAUTIONS: DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS. CLEAN-UP METHODS: REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT DURING CLEANUP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
HANDLING: PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED. REFER TO SECTION 8. STORAGE: FOR SAFE STORAGE, STORE AT OR BELOW 38 DEG. C (100.4 DEG. F) AVOID MOISTURE. KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE EQUIPMENT FOR EACH TASK PERFORMED. HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL SUBSTITUTED POLYOL NONE NONE DIMETHYLTINDINEODECANOATE 0.1 MG/M3 TWA (AS Sn) 0.1 MG/M3 PEL (AS Sn) 0.2 MG/M3 STEL (AS Sn) (SKIN) (AS Sn) HAZARDOUS COMPONENT(S) AIHA WEEL OTHER SUBSTITUTED POLYOL NONE NONE DIMETHYLTINDINEODECANOATE NONE NONE ENGINEERING CONTROLS: PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE BELOW EXPOSURE LIMITS. RESPIRATORY PROTECTION: USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR IF THE POTENTIAL TO EXCEED ESTABLISHED EXPOSURE LIMITS EXISTS. EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE. SKIN PROTECTION: USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
PHYSICAL STATE: CLEAR, LIQUID COLOR: COLORLESS ODOR: FAINT ODOR THRESHOLD: NOT AVAILABLE. PH: NOT AVAILABLE. VAPOR PRESSURE: NOT AVAILABLE. BOILING POINT/RANGE: NOT AVAILABLE. MELTING POINT/RANGE: NOT AVAILABLE. SPECIFIC GRAVITY: 1.1 VAPOR DENSITY: NOT AVAILABLE. FLASH POINT: >96.11 DEG. C (>205 DEG. F) ASTM D3278 SETAFLASH CLOSED CUP FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE. FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE. AUTOIGNITION TEMPERATURE: NOT AVAILABLE. EVAPORATION RATE: NOT AVAILABLE. SOLUBILITY IN WATER: NOT AVAILABLE. PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE. VOC CONTENT: 0% (CALIFORNIA SCAQMD METHOD 316B) (ESTIMATED) VISCOSITY: NOT AVAILABLE. DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE. HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING. HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON. OXIDES OF TIN. ALCOHOLS. ETHERS. KETONES. IRRITATING VAPORS. INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ACIDS. BASES. REACTIVITY: NOT AVAILABLE. CONDITIONS TO AVOID: ELEVATED TEMPERATURES. AVOID MOISTURE. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION. STORE AWAY FROM INCOMPATIBLE MATERIALS.
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION POTENTIAL HEALTH EFFECTS/SYMPTOMS: INHALATION: INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE RESPIRATORY SYSTEM. SKIN CONTACT: CAUSES SKIN IRRITATION. EYE CONTACT: CAUSES EYE IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED. HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH EFFECTS SUBSTITUTED POLYOL NONE IRRITANT DIMETHYLTINDINEODECANOATE NONE NO TARGET ORGANS HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED) SUBSTITUTED POLYOL NO NO NO DIMETHYLTINDINEODECANOATE NO NO NO
ECOLOGICAL INFORMATION: NOT AVAILABLE.
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY. RECOMMENDED METHOD OF DISPOSAL: FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL. HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY PACKAGE/CONFIGURATION. U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR): PROPER SHIPPING NAME: NOT REGULATED HAZARD CLASS OR DIVISION: NONE IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA): PROPER SHIPPING NAME: NOT REGULATED HAZARD CLASS OR DIVISION: NONE IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE WATER TRANSPORTATION (IMO/IMDG): PROPER SHIPPING NAME: NOT REGULATED HAZARD CLASS OR DIVISION: NONE IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE
UNITED STATES REGULATORY INFORMATION: TSCA 8 (B) INVENTORY STATUS: ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC SUBSTANCES CONTROL ACT INVENTORY. TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS CALIFORNIA PROPOSITION 65: NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT. CANADA REGULATORY INFORMATION: CEPA DSL/NDSL STATUS: ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN DOMESTIC SUBSTANCES LIST.
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN SECTIONS: NEW SAFETY DATA SHEET FORMAT. PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST ISSUE DATE: 05/12/2015 DISCLAIMER: THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES ("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS. HENKEL SAFETY DATA SHEET REVISION NUMBER: 006.0 ISSUE DATE: 06/07/2016
PRODUCT NAME: LOCTITE UK U-09FL KNOWN AS HYSOL U-09FL URETH ADH ULTRA PRODUCT TYPE: POLYURETHANE RESIN RESTRICTION OF USE: NONE IDENTIFIED IDH NUMBER: 702028 ITEM NUMBER: 29460_210248 REGION: UNITED STATES COMPANY ADDRESS: HENKEL CORPORATION ONE HENKEL WAY ROCKY HILL, CONNECTICUT 06067 CONTACT INFORMATION: TELEPHONE: (860) 571-5100 MEDICAL EMERGENCY PHONE: POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711 TRANSPORT EMERGENCY PHONE: CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887 INTERNET: WWW.HENKELNA.COM
EMERGENCY OVERVIEW: DANGER: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. FATAL IF INHALED. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. MAY CAUSE RESPIRATORY IRRITATION. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. HAZARD CLASS HAZARD CATEGORY ACUTE TOXICITY INHALATION 2 SKIN IRRITATION 2 EYE IRRITATION 2A RESPIRATORY SENSITIZATION 1 SKIN SENSITIZATION 1 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1 PICTOGRAM(S): SKULLS AND CROSSBONES HEALTH HAZARD EXCLAMATION MARK PRECAUTIONARY STATEMENTS: PREVENTION: DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION. [IN CASE OF INADEQUATE VENTILATION] WEAR RESPIRATORY PROTECTION. RESPONSE: IF ON SKIN: WASH WITH PLENTY OF WATER. IF INHALED: REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION. IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION. IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER OR PHYSICIAN. TAKE OFF CONTAMINATED CLOTHING. STORAGE: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE LOCKED UP. DISPOSAL: DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS. CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS (GHS). SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE* POLYURETHANE PREPOLYMER PROPRIETARY 60 - 100 DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE 5124-30-1 10 - 30 * EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. ASTHMATIC-TYPE SYMPTOMS MAY DEVELOP AND MAY BE IMMEDIATE OR DELAYED UP TO SEVERAL HOURS. GET MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE). REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. FOR SEVERE EXPOSURES, GET UNDER SAFETY SHOWER AFTER REMOVING CLOTHING, THEN GET MEDICAL ATTENTION. FOR LESSER EXPOSURE, SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS AFTER AREA IS WASHED. WASH CLOTHING BEFORE REUSE. EYE CONTACT: RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. SYMPTOMS: SEE SECTION 11. NOTES TO PHYSICIAN: EYES: STAIN FOR EVIDENCE OF CORNEAL INJURY. IF CORNEA IS BURNED, INSTILL ANTIBIOTIC STEROID PREPARATION FREQUENTLY. WORKPLACE VAPORS HAVE PRODUCED REVERSIBLE CORNEAL EPITHELIAL EDEMA IMPAIRING VISION. SKIN: THIS COMPOUND IS A KNOWN SKIN SENSITIZER. TREAT SYMPTOMATICALLY AS FOR CONTACT DERMATITIS OR THERMAL BURNS. INGESTION: TREAT SYMPTOMATICALLY. THERE IS NO SPECIFIC ANTIDOTE. INDUCING VOMITING IS CONTRAINDICATED BECAUSE OF THE IRRITATING NATURE OF THIS COMPOUND. RESPIRATORY: THIS COMPOUND IS A KNOWN PULMONARY SENSITIZER. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. AN INDIVIDUAL HAVING A DERMAL OR PULMONARY SENSITIZATION REACTION TO THIS MATERIAL SHOULD BE REMOVED FROM FURTHER EXPOSURE TO ANY DIISOCYANATE.
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE. SPECIAL FIREFIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH AS TURN-OUT GEAR. DURING A FIRE, MDI VAPORS AND OTHER IRRITATING, HIGHLY TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR COMBUSTION. EXPLOSIVE RUPTURE IS POSSIBLE. UNUSUAL FIRE OR EXPLOSION HAZARDS: SEALED CONTAINERS AT ELEVATED TEMPERATURES OR CONTAMINATED WITH WATER MAY RUPTURE EXPLOSIVELY. WATER OR FOG MAY CAUSE FROTHING WHICH CAN BE VIOLENT ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT OR BURNING LIQUID. DO NOT ALLOW RUNOFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES. HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON. OXIDES OF NITROGEN. HYDROGEN CYANIDE. ISOCYANATES. IRRITATING ORGANIC VAPOURS.
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL. ENVIRONMENTAL PRECAUTIONS: DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS. CLEAN-UP METHODS: REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT DURING CLEANUP. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP. IF TEMPORARY CONTROL OF ISOCYANATE VAPOR IS REQUIRED, A BLANKET OF PROTEIN FOAM (AVAILABLE AT MOST FIRE DEPARTMENTS) MAY BE PLACED OVER SPILL. LARGE QUANTITIES MAY BE PUMPED INTO CLOSED, BUT NOT SEALED CONTAINERS FOR DISPOSAL. FOR MINOR SPILLS, ABSORB ISOCYANATES WITH SAWDUST OR OTHER ABSORBENT, SHOVEL INTO SUITABLE UNSEALED CONTAINERS, TRANSPORT TO WELL VENTILATED AREA (OUTSIDE) AND TREAT WITH NEUTRALIZING SOLUTION: MIXTURE OF 80% WATER AND 20% NON-IONIC SURFACTANT TERGITOL TMN-10; OR 90% WATER, 3-8% CONCENTRATED AMMONIA AND 2% DETERGENT. ADD ABOUT TEN PARTS OF NEUTRALIZER PER PART OF ISOCYANATE, WITH MIXING. ALLOW TO STAND UNCOVERED FOR 48 HOURS TO LET CARBON DIOXIDE ESCAPE. DECONTAMINATE FLOOR WITH DECONTAMINATION SOLUTION LETTING STAND FOR AT LEAST 15 MINUTES.
HANDLING: PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION. PROTECT FROM MOISTURE. KEEP CONTAINER CLOSED. EMPLOYEE EDUCATION AND TRAINING IN THE SAFE USE AND HANDLING OF THIS COMPOUND ARE REQUIRED UNDER THE OSHA HAZARD COMMUNICATION STANDARD. REFER TO SECTION 8. STORAGE: KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. STORE AWAY FROM HEAT, SPARKS, FLAMES, OR OTHER SOURCES OF IGNITION. DO NOT LET MOISTURE CONTAMINATE THIS MATERIAL. PRODUCT REACTS WITH WATER TO RELEASE CARBON DIOXIDE, WHICH COULD BUILD UP PRESSURE IN CLOSED CONTAINERS AND LEAD TO BURSTING. DO NOT RESEAL IF MOISTURE CONTAMINATION IS SUSPECTED. IF CONTAINER IS EXPOSED TO HIGH HEAT (204.4 DEG. C (400 DEG. F)), IT CAN BE PRESSURIZED AND POSSIBLY RUPTURE.
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE EQUIPMENT FOR EACH TASK PERFORMED. HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL POLYURETHANE PREPOLYMER NONE NONE DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE 0.005 PPM TWA NONE HAZARDOUS COMPONENT(S) AIHA WEEL OTHER POLYURETHANE PREPOLYMER NONE NONE DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE NONE NONE ENGINEERING CONTROLS: LOCAL EXHAUST SHOULD BE USED TO MAINTAIN LEVELS BELOW THE TLV WHENEVER MDI IS PROCESSED, HEATED OR SPRAY APPLIED. STANDARD REFERENCE SOURCES REGARDING INDUSTRIAL VENTILATION (I.E., ACGIH INDUSTRIAL VENTILATION) SHOULD BE CONSULTED FOR GUIDANCE ABOUT ADEQUATE VENTILATION. AIR MONITORING: MONITORING OF AIRBORNE ISOCYANATES IN THE BREATHING ZONE OF INDIVIDUALS SHOULD BECOME PART OF THE OVERALL EMPLOYEE EXPOSURE CHARACTERIZATION PROGRAM. ISOCYANATE EXPOSURE LEVELS MUST BE MONITORED. MONITORING TECHNIQUES HAVE BEEN DEVELOPED BY NIOSH AND OSHA. MEDICAL SURVEILLANCE: MEDICAL SUPERVISION OF ALL EMPLOYEES WHO HANDLE OR COME IN CONTACT WITH ISOCYANATES IS RECOMMENDED. THESE SHOULD INCLUDE PREEMPLOYMENT AND PERIODIC MEDICAL EXAMINATIONS WITH PULMONARY FUNCTION TESTS (FEV, FVC AS A MINIMUM). PERSONS WITH ASTHMATICTYPE CONDITIONS, CHRONIC BRONCHITIS, OTHER CHRONIC RESPIRATORY DISEASES OR RECURRENT SKIN ECZEMA OR SENSITIZATION SHOULD BE EXCLUDED FROM WORKING WITH ISOCYANATES. ONCE A PERSON IS DIAGNOSED AS SENSITIZED TO AN ISOCYANATE, NO FURTHER EXPOSURE CAN BE PERMITTED. RESPIRATORY PROTECTION: A POSITIVE PRESSURE, SUPPLIED-AIR RESPIRATOR OR A SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED WHEN: AIRBORNE CONCENTRATIONS OF ISOCYANATE ARE KNOWN TO EXCEED 0.005 PPM; OPERATIONS ARE PERFORMED IN A CONFINED SPACE OR AREA WITH LIMITED VENTILATION; MATERIAL IS HEATED OR SPRAYED. OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29 CFR 1910.134). EYE/FACE PROTECTION: SAFETY GLASSES WITH SIDESHIELDS OR CHEMICAL SAFETY GOGGLES SHOULD BE WORN IF THERE IS A RISK OF SPLASHING. FULL FACE PROTECTION SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE. VAPOR RESISTANT GOGGLES SHOULD BE WORN WHEN CONTACT LENSES ARE IN USE. SKIN PROTECTION: USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. IF SKIN CREAMS ARE USED, KEEP THE AREA COVERED BY THE CREAM TO A MINIMUM. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE. EDUCATE AND TRAIN EMPLOYEES IN SAFE USE OF PRODUCT.
PHYSICAL STATE: LIQUID COLOR: CLEAR ODOR: MILD ODOR THRESHOLD: NOT AVAILABLE. PH: NOT AVAILABLE. VAPOR PRESSURE: NOT AVAILABLE. BOILING POINT/RANGE: NOT AVAILABLE. MELTING POINT/RANGE: NOT AVAILABLE. SPECIFIC GRAVITY: 1.09 VAPOR DENSITY: NOT AVAILABLE. FLASH POINT: >93.3 DEG. C (>199.94 DEG. F) ASTM D3278 FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE. FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE. AUTOIGNITION TEMPERATURE: NOT AVAILABLE. FLAMMABILITY: NOT APPLICABLE EVAPORATION RATE: NOT AVAILABLE. SOLUBILITY IN WATER: NEGLIGIBLE. REACTS SLOWLY WITH WATER TO LIBERATE CARBON DIOXIDE GAS. PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE. VOC CONTENT: <1%; <10 G/L ESTIMATED VISCOSITY: NOT AVAILABLE. DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE. HAZARDOUS REACTIONS: CONTACT WITH MOISTURE, OTHER MATERIALS WHICH CAN REACT WITH ISOCYANATES, OR TEMPERATURES ABOVE 204.4 DEG. C (400 DEG. F), MAY CAUSE POLYMERIZATION. HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON AND NITROGEN, TRACES OF HCN, VOLATILIZED ISOCYANATES (HDI) AND OTHER IRRITATING HIGHLY TOXIC GASES MAY BE GENERATED. INCOMPATIBLE MATERIALS: WATER. AMINES. STRONG ACIDS AND STRONG BASES. ALCOHOLS. WILL CAUSE SOME CORROSION OF COPPER ALLOYS AND ALUMINUM. REACTIVITY: NOT AVAILABLE. CONDITIONS TO AVOID: CONTAMINATION WITH WATER. KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION POTENTIAL HEALTH EFFECTS/SYMPTOMS: INHALATION: THIS PRODUCT IS HARMFUL OR FATAL BY INHALATION. ACUTE: INHALATION OF DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE AT CONCENTRATIONS ABOVE THE TLV CAN IRRITATE THE MUCOUS MEMBRANES IN THE RESPIRATORY TRACT (NOSE, THROAT, LUNGS) CAUSING RUNNY NOSE, SORE THROAT, COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION (BREATHING OBSTRUCTION). PERSONS WITH PREEXISTING, NONSPECIFIC BRONCHIAL HYPER-REACTIVITY CAN RESPOND TO CONCENTRATIONS BELOW THE TLV WITH SIMILAR SYMPTOMS AS WELL AS LEAD TO BRONCHITIS, BRONCHIAL SPASM AND PULMONARY EDEMA (FLUID IN LUNGS). CHEMICAL OR HYPERSENSITIVE PNEUMONITIS WITH FLU-LIKE SYMPTOMS (E.G. FEVER, CHILLS) HAVE ALSO BEEN REPORTED. THESE SYMPTOMS CAN BE DELAYED UP TO SEVERAL HOURS AFTER EXPOSURE. THESE EFFECTS ARE USUALLY REVERSIBLE. CHRONIC: AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURES OR A SINGLE LARGE DOSE, CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION (CHEMICAL ASTHMA) WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE TO ISOCYANATE AT LEVELS WELL BELOW THE TLV. CHRONIC OVEREXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE. MAY CAUSE ALLERGIC RESPIRATORY REACTION. THESE SYMPTOMS, WHICH CAN INCLUDE CHEST TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF BREATH OR ASTHMA ATTACK, COULD BE IMMEDIATE OR DELAYED (UP TO SEVERAL HOURS AFTER EXPOSURE). SIMILAR TO MANY NON-SPECIFIC ASTHMATIC RESPONSES, THERE ARE REPORTS THAT ONCE SENSITIZED AN INDIVIDUAL CAN EXPERIENCE THESE SYMPTOMS UPON EXPOSURE TO DUST, COLD AIR, OR OTHER IRRITANTS. THIS INCREASED LUNG SENSITIVITY CAN PERSIST FOR WEEKS AND IN SEVERE CASES FOR SEVERAL YEARS. OVER EXPOSURE TO ISOCYANATES HAS ALSO BEEN REPORTED TO CAUSE LUNG DAMAGE (INCLUDING DECREASE IN LUNG FUNCTION) WHICH MAY BE PERMANENT. SENSITIZATION CAN EITHER BE TEMPORARY OR PERMANENT. SKIN CONTACT: ACUTE: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. ISOCYANATES REACT WITH SKIN PROTEIN AND MOISTURE AND CAN CAUSE IRRITATION WHICH MAY INCLUDE THE FOLLOWING SYMPTOMS: REDDENING, SWELLING, RASH, SCALING OR BLISTERING. DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE IS ALSO A POTENT SENSITIZER. EXPERIENCE INDICATES THAT DIRECT CONTACT IS THE ROUTE OF EXPOSURE MOST LIKELY TO CAUSE SENSITIZATION. CURED MATERIAL IS DIFFICULT TO REMOVE. CHRONIC: PROLONGED CONTACT CAN CAUSE REDDENING, SWELLING, RASH, SCALING, BLISTERING AND IN SOME CASES, SKIN SENSITIZATION. INDIVIDUALS WHO HAVE SKIN SENSITIZATION CAN DEVELOP THESE SYMPTOMS FROM CONTACT WITH LIQUID OR VAPOR. ONCE SENSITIZED, AN INDIVIDUAL MAY REACT EVEN TO AIRBORNE LEVELS BELOW THE TLV WITH THE FOLLOWING SYMPTOMS: ITCHING AND TINGLING OF THE EARLOBES AND NECK, RASH, HIVES, SWELLING OF THE ARMS AND LEGS OR OTHER SYMPTOMS COMMON TO ALLERGIC DERMATITIS. ANIMAL TESTS HAVE INDICATED THAT RESPIRATORY SENSITIZATION CAN RESULT FROM SKIN CONTACT WITH DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE. EYE CONTACT: CAUSES SERIOUS EYE IRRITATION. STINGING. LIQUID, AEROSOLS OR VAPOR ARE IRRITATING AND CAN CAUSE TEARING, REDDENING AND SWELLING. IF LEFT UNTREATED, CORNEAL DAMAGE CAN OCCUR AND INJURY IS SLOW TO HEAL. DAMAGE HOWEVER IS USUALLY REVERSIBLE. SEE SECTION 4 FOR FIRST AID MEASURES. INGESTION: IRRITATION AND CORROSIVE ACTION CAN OCCUR IN THE MOUTH, STOMACH TISSUE AND DIGESTIVE TRACT IF SWALLOWED. SYMPTOMS CAN INCLUDE SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA. HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH EFFECTS POLYURETHANE PREPOLYMER NONE IRRITANT, ALLERGEN DICYCLOHEXYLMETHANE- ORAL LD50 (RAT): IRRITANT, ALLERGEN, 4,4'-DIISOCYANATE 1,065 MG/KG RESPIRATORY DERMAL LD50 (RABBIT): >10,000 MG/KG INHALATION LC50 (RAT, 4 H): 0.295 MG/L INHALATION LC50 (RAT, 4 H): 0.307 MG/L HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED) POLYURETHANE PREPOLYMER NO NO NO DICYCLOHEXYLMETHANE- NO NO NO 4,4'-DIISOCYANATE
ECOLOGICAL INFORMATION: NOT AVAILABLE.
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY. RECOMMENDED METHOD OF DISPOSAL: FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL. HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY PACKAGE/CONFIGURATION. U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR): PROPER SHIPPING NAME: OTHER REGULATED SUBSTANCES, LIQUID, N.O.S. (DICYCLOHEXYL METHANE DIISOCYANATE) HAZARD CLASS OR DIVISION: 9 IDENTIFICATION NUMBER: NA 3082 PACKING GROUP: III INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA): PROPER SHIPPING NAME: AVIATION REGULATED LIQUID, N.O.S. (DICYCLOHEXYL METHANE DIISOCYANATE) HAZARD CLASS OR DIVISION: 9 IDENTIFICATION NUMBER: UN 3334 PACKING GROUP: III EXCEPTIONS: PRIMARY PACKS CONTAINING LESS THAN 500ML ARE UNREGULATED BY THIS MODE OF TRANSPORT AND MAY BE SHIPPED UNRESTRICTED. WATER TRANSPORTATION (IMO/IMDG): PROPER SHIPPING NAME: NOT REGULATED HAZARD CLASS OR DIVISION: NONE IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE
UNITED STATES REGULATORY INFORMATION: TSCA 8 (B) INVENTORY STATUS: ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC SUBSTANCES CONTROL ACT INVENTORY. TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS. CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH CERCLA/SARA SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE (CAS# 5124-30-1). CALIFORNIA PROPOSITION 65: NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT. CANADA REGULATORY INFORMATION: CEPA DSL/NDSL STATUS: ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN DOMESTIC SUBSTANCES LIST.
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN SECTIONS: 2 PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST ISSUE DATE: 06/07/2016 DISCLAIMER: THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES ("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS. |