| Common Name: | ETI-LV (ETILV22, ETILV56, ETILV) |
| Manufacturer: | SIMPSON STRONG-TIE |
| SDS Revision Date: | 9/1/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2WLG2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SIMPSON STRONG-TIE(R*)
ETI-LV INJECTION EPOXY
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFICATION:
PRODUCT IDENTIFIER: ETI-LV (ETILV22, ETILV56, ETILV)
RECOMMENDED USE: LOW VISCOSITY INJECTION EPOXY
USE RESTRICTIONS: NONE KNOWN.
COMPANY IDENTIFICATION:
COMPANY: SIMPSON STRONG-TIE COMPANY INC.
ADDRESS:
5956 W. LAS POSITAS BLVD.
PLEASANTON, CA 94588
USA
PHONE: 1-800-999-5099
WEBSITE: WWW.STRONGTIE.COM
EMERGENCY:
1-800-535-5053 (US/CANADA)
1-352-323-3500 (INTERNATIONAL)
FOR MOST CURRENT SDS, PLEASE VISIT OUR WEBSITE AT WWW.STRONGTIE.COM/SDS
| 2. HAZARD IDENTIFICATION | |
GENERAL INFORMATION:
ETI-LV INJECTION EPOXY IS A TWO PART SYSTEM. THE TWO PARTS OF THIS PRODUCT
HAVE BEEN ASSESSED ACCORDING TO GHS AND ARE CLASSIFIED BELOW. THE FINAL
HARDENED MATERIAL IS CONSIDERED NONHAZARDOUS.
RESIN (CLEAR SIDE) GHS CLASSIFICATION:
EXCLAMATION MARK
ENVIRONMENT
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1
ENVIRONMENTAL HAZARDS:
ACUTE AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 2
CHRONIC AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 2
SIGNAL WORD: WARNING!
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE AN
ALLERGIC SKIN REACTION. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
AVOID BREATHING MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. AVOID
RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE RE-USE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION. COLLECT SPILLAGE.
STORAGE:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. STORE BETWEEN
45-90 DEG. F (7-32 DEG. C).
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL REGULATIONS.
HARDENER (AMBER SIDE) GHS CLASSIFICATION:
CORROSION
EXCLAMATION MARK
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 4
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 4
ACUTE TOXICITY, DERMAL: CATEGORY 4
ACUTE TOXICITY, INHALATION: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1C
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1
SENSITIZATION, SKIN: CATEGORY 1
ENVIRONMENTAL HAZARDS:
ACUTE AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 3
CHRONIC AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 3
SIGNAL WORD: DANGER!
HAZARD STATEMENTS:
COMBUSTIBLE LIQUID. HARMFUL IF SWALLOWED. HARMFUL IN CONTACT WITH SKIN.
HARMFUL IF INHALED. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE
AN ALLERGIC SKIN REACTION. HARMFUL TO AQUATIC LIFE WITH LONG LASTING
EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. DO
NOT BREATHE VAPOR. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. DO NOT
EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER
HANDLING. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IN CASE OF FIRE: USE APPROPRIATE MEDIA TO EXTINGUISH.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE RE-USE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR. COLLECT SPILLAGE.
STORAGE:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. STORE BETWEEN
45-90 DEG. F (7-32 DEG. C).
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
| 3. COMPOSITION INFORMATION | |
GENERAL INFORMATION:
THIS PRODUCT IS A MIXTURE. HAZARDOUS INGREDIENTS FOR EACH COMPONENT ARE
LISTED BELOW. MAY INCLUDE OTHER NONHAZARDOUS INGREDIENTS. MAY INCLUDE
OTHER TRACE INGREDIENTS, SEE SECTION 15.
RESIN (CLEAR SIDE):
CHEMICAL NAME CAS NUMBER WEIGHT %
BISPHENOL A/EPICHLOROHYDRIN 25068-38-6 50-80
1,3-PROPANEDIOL, 2-ETHYL-2-(HYDROXYMETHYL)- 30499-70-8 10-30
POLYMER WITH 2-(CHLOROMETHYL)OXIRANE
1,3-BIS(2,3-EPOXYPROPOXY)-2,2-DIMETHYLPROPANE 17557-23-2 5-15
HARDENER (AMBER SIDE):
CHEMICAL NAME CAS NUMBER WEIGHT %
BENZYL ALCOHOL 100-51-6 40-80
TRIETHYLENETETRAMINE 112-24-3 40-80
FORMALDEHYDE, POLYMER WITH 1,3-DIMETHYLBENZENE 26139-75-3 5-15
PHENOL, 2,4,6-TRISDIMETHYLAMINOMETHYL 90-72-2 <10
| 4. FIRST-AID MEASURES | |
GENERAL INFORMATION:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. SYMPTOMS
MAY BE DELAYED. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S)
INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. IF EXPOSED OR
CONCERNED:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
ROUTES OF EXPOSURE:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF COOL WATER FOR AT LEAST 15 MINUTES
WHILE HOLDING THE EYES OPEN. REMOVE CONTACT LENSES IF PRESENT AND EASY TO
DO. IF REDNESS, BURNING, BLURRED VISION, OR SWELLING PERSISTS, CONSULT A
PHYSICIAN.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND PRODUCT, IMMEDIATELY WASH AFFECTED AREA
WITH SOAP AND WATER. DO NOT APPLY GREASES OR OINTMENTS. IF SKIN IRRITATION
PERSISTS CONSULT A PHYSICIAN.
INGESTION:
RINSE MOUTH IMMEDIATELY. GIVE LARGE AMOUNTS OF MILK OR WATER, IF PERSON IS
CONSCIOUS. ONLY INDUCE VOMITING AT THE INSTRUCTION OF MEDICAL PERSONNEL.
CONSULT A PHYSICIAN.
INHALATION:
REMOVE PATIENT TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF
NEEDED. IF PATIENT CONTINUES TO EXPERIENCE DIFFICULTY BREATHING, CONSULT
A PHYSICIAN.
MOST IMPORTANT SYMPTOMS:
IRRITANT EFFECTS. SENSITIZATION. SYMPTOMS INCLUDE ITCHING, BURNING,
REDNESS AND TEARING. MAY CAUSE DAMAGE TO MUCOUS MEMBRANES IN NOSE, THROAT,
LUNGS AND BRONCHIAL SYSTEM. COUGH. LABORED BREATHING. SHORTNESS OF BREATH.
PROLONGED CONTACT CAUSES SERIOUS EYE AND TISSUE DAMAGE. VISUAL
DISTURBANCES INCLUDING BLURRED VISION. MAY CAUSE SERIOUS CHEMICAL BURNS TO
THE SKIN. MAY CAUSE BURNS IN MUCOUS MEMBRANES, THROAT, ESOPHAGUS AND
STOMACH.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
EXTINGUISH WITH FOAM, CARBON DIOXIDE, DRY POWDER, OR WATER FOG.
ADDITIONAL INFORMATION: NONE KNOWN.
HAZARDS DURING FIRE-FIGHTING:
HAZARDOUS DECOMPOSITION PRODUCTS MAY OCCUR WHEN MATERIALS POLYMERIZE AT
TEMPERATURES ABOVE 500 DEG. F (260 DEG. C). IRRITATING AND TOXIC
GASES/FUMES MAY BE RELEASED DURING A FIRE. WATER RUN-OFF CAN CAUSE
ENVIRONMENTAL DAMAGE. DO NOT ALLOW RUN-OFF FROM FIRE-FIGHTING TO ENTER
DRAINS OR WATER COURSES.
FIRE-FIGHTING PROCEDURES:
USE STANDARD FIRE-FIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. COOL
CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT.
PREVENT RUNOFF FROM FIRE CONTROL OR DILUTION FROM ENTERING STREAMS,
SEWERS, OR DRINKING WATER SUPPLY.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. ELIMINATE ALL IGNITION SOURCES (NO
SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED
MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID INHALATION
OF VAPORS OR MISTS. ENSURE ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD
BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED.
CLEAN-UP METHODS:
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). PLACE IN LEAK-PROOF
CONTAINERS. SEAL TIGHTLY FOR PROPER DISPOSAL. CLEAN SURFACE THOROUGHLY TO
REMOVE RESIDUAL CONTAMINATION.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE FAR AHEAD OF
SPILL FOR LATER DISPOSAL. USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE,
SAND OR EARTH TO SOAK UP THE PRODUCT. PLACE IN LEAK-PROOF CONTAINERS. SEAL
TIGHTLY FOR PROPER DISPOSAL. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH
WATER. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED AREAS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. CONTACT LOCAL AUTHORITIES IN CASE OF
SPILLAGE TO DRAIN/AQUATIC ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE
IF SAFE TO DO SO.
| 7. HANDLING AND STORAGE | |
HANDLING:
MECHANICAL VENTILATION OR LOCAL EXHAUST VENTILATION IS RECOMMENDED. KEEP
AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. OBSERVE GOOD
INDUSTRIAL HYGIENE PRACTICES.
STORAGE:
STORE IN A CLOSED CONTAINER AWAY FROM INCOMPATIBLE MATERIALS. KEEP IN
ORIGINAL CONTAINER. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A DRY PLACE
OUT OF DIRECT SUNLIGHT. STORE BETWEEN 45-90 DEG. F (7-32 DEG. C). KEEP
AWAY FROM HEAT AND SOURCES OF IGNITION. STORE IN A WELL-VENTILATED PLACE.
STORE LOCKED UP. KEEP OUT OF THE REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
PERSONAL PROTECTIVE EQUIPMENT:
PROTECTIVE MEASURE: WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES OR SAFETY GLASSES WITH SIDE SHIELD.
HAND PROTECTION:
WEAR CHEMICAL-RESISTANT GLOVES SUCH AS: NITRILE, NEOPRENE, BUTYL.
SKIN AND BODY PROTECTION:
WEAR LONG SLEEVE SHIRT/LONG PANTS AND OTHER CLOTHING AS REQUIRED TO
MINIMIZE CONTACT.
RESPIRATOR PROTECTION:
IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW
RECOMMENDED EXPOSURE LIMITS (WHERE APPLICABLE) OR TO AN ACCEPTABLE LEVEL
(IN COUNTRIES WHERE EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED), AN
APPROVED RESPIRATOR MUST BE WORN.
GENERAL HYGIENE:
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS.
ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. PROVIDE EYEWASH STATION.
EXPOSURE LIMITS:
COMPONENT OSHA (PEL) ACGIH (TLV) NIOSH
POCKET GUIDE
BENZYL ALCOHOL N/E N/E 44.2 MG/M3
(CAS 100-51-6) 10 PPM
TRIETHYLENETETRAMINE N/E N/E 6 MG/M3
(CAS 112-24-3) 1 PPM
ADDITIONAL INFORMATION:
AFTER CURE:
PRODUCT FORMS AN INNOCUOUS SOLID. PROCESSING AFTER CURE (GRINDING OR
CUTTING) MAY PRODUCE DUST CONTAINING COMPOUNDS THAT PRESENT AN INHALATION
HAZARD.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PROPERTY RESIN HARDENER
PHYSICAL STATE LIQUID LIQUID
COLOR CLEAR AMBER
ODOR SWEET AMMONIA
PH 5.6 10.9
FLAMMABILITY LIMIT - LOWER % NO DATA NO DATA
FLAMMABILITY LIMIT - UPPER % NO DATA NO DATA
VAPOR PRESSURE NON-VOLATILE NO DATA
VAPOR DENSITY NO DATA NO DATA
SOLUBILITY INSOLUBLE IN WATER SLIGHTLY SOLUBLE
IN WATER
FREEZING/MELTING POINT NO DATA NO DATA
BOILING POINT NO DATA NO DATA
FLASH POINT 256 DEG. F 180 DEG. F
(124.4 DEG. C) (85 DEG. C)
CLOSED CUP CLOSED CUP
EVAPORATION RATE NO DATA NO DATA
DECOMPOSITION TEMPERATURE NO DATA NO DATA
SPECIFIC GRAVITY 1.21 AT 72 DEG. F 1.01 AT 72 DEG.
(22 DEG. C) F (22 DEG. C)
VOC (AFTER CURE) 6 G/L 6 G/L
KOW NO DATA NO DATA
VISCOSITY 2000 CP 2000 CP
| 10. STABILITY AND REACTIVITY | |
RESIN (CLEAR SIDE):
REACTIVITY:
THIS PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
CONDITION TO AVOID: HIGH HEAT AND OPEN FLAME.
SUBSTANCES TO AVOID: OXIDIZING AGENTS, ACIDS, ORGANIC BASES, AND AMINES.
HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, AND OTHER ORGANIC
COMPOUNDS.
HARDENER (CLEAR SIDE):
REACTIVITY:
THIS PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
CONDITION TO AVOID: HIGH HEAT AND OPEN FLAME.
SUBSTANCES TO AVOID: STRONG OXIDIZING AGENTS. STRONG ACIDS.
HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, AND OTHER ORGANIC
COMPOUNDS.
| 11. TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF EXPOSURE:
INGESTION: HARMFUL IF SWALLOWED. CAUSES DIGESTIVE TRACT BURNS.
INHALATION:
HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT BURNS. IF THIS MATERIAL IS
HEATED OR MISTED, COUGHING AND MILD, TEMPORARY IRRITATION MAY OCCUR.
SKIN CONTACT:
HARMFUL IN CONTACT WITH SKIN. CAUSES SEVERE SKIN BURNS. CAUSES SKIN
IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION. CAUSES SERIOUS EYE BURNS.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
OCCUPATIONAL EXPOSURE TO THE SUBSTANCE OR MIXTURE MAY CAUSE ADVERSE
EFFECTS.
PRODUCT SPECIES TEST RESULT
BENZYL ALCOHOL (CAS 100-51-6):
ACUTE, DERMAL, LC50 RABBIT 2000 MG/KG
ACUTE, ORAL, LD50 RAT 1230-3100 MG/KG
ACUTE, INHALATION, LD50 RAT >4173 MG/M3, 4 HOURS
SKIN CORROSION/IRRITATION:
CAUSES SKIN IRRITATION. CAUSES SEVERE SKIN BURNS.
EYE DAMAGE/EYE IRRITATION:
CAUSES SERIOUS EYE IRRITATION. CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY SENSITIZATION:
MAY CAUSE AN ALLERGIC RESPIRATORY REACTION BECOMING EVIDENT UPON
RE-EXPOSURE TO THIS MATERIAL, AND MAY CAUSE BREATHING DIFFICULTIES.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
THE PRODUCT CONTAINS A SUBSTANCE WHICH HAS DEMONSTRATED ANIMAL EFFECTS OF
MUTAGENICITY.
CARCINOGENICITY:
CONTAINS TRACES OF CARBON BLACK. INHALATION OF CARBON BLACK DUST MAY CAUSE
CANCER, HOWEVER DUE TO THE PHYSICAL FORM OF THE PRODUCT; INHALATION OF
DUST IS NOT LIKELY. TAKE CARE WHEN CUTTING OR GRINDING CURED PRODUCT.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE.
ASPIRATION HAZARD: NO DATA AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY:
SINGLE EXPOSURE: NO DATA AVAILABLE.
REPEATED EXPOSURE: NO DATA AVAILABLE.
FURTHER INFORMATION:
TOXICOLOGICAL, ECOTOXICOLOGICAL, PHYSICAL, AND CHEMICAL PROPERTIES MAY NOT
HAVE BEEN FULLY INVESTIGATED. HAZARD DATA ABOVE IS ESTIMATED BASED ON BEST
AVAILABLE INFORMATION. SOME WORKERS WITH PRE-EXISTING MEDICAL CONDITIONS
SUCH AS:
ASTHMA, ALLERGIES, OR IMPAIRED PULMONARY AND/OR LIVER FUNCTIONS, OR WHO
MAY BE PARTICULARLY SUSCEPTIBLE TO THIS MATERIAL, MAY BE AFFECTED BY
EXPOSURE TO THIS MATERIAL.
| 12. ECOLOGICAL INFORMATION | |
GENERAL INFORMATION:
INFORMATION GIVEN IS BASED ON DATA ON THE COMPONENTS AND THE ECOTOXICOLOGY
OF SIMILAR PRODUCTS. RESIN IS CLASSIFIED AS TOXIC TO AQUATIC LIFE WITH
LONG LASTING EFFECTS. HARDENER IS CLASSIFIED AS HARMFUL TO AQUATIC LIFE
WITH LONG LASTING EFFECTS. AVOID RELEASE TO THE ENVIRONMENT.
SUPPORTING DATA:
COMPONENT SPECIES TEST RESULT
BISPHENOLA/EPICHLOROHYDRIN
(25068-38-6):
FISH, LC50 SALMO GAIRDNERI 1.5 MG/L, 96 HOURS
AQUATIC, CRUSTACEA, EC50 DAPHNIA MAGNA 2.7 MG/L, 48 HOURS
BENZYL ALCOHOL
(CAS 100-51-6):
AQUATIC ACUTE, FISH, LC50 BLUEGILL 10 MG/L, 96 HOURS
PERSISTENCE AND DEGRADABILITY:
THIS PRODUCT IS NOT EXPECTED TO BE READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE FOR THIS PRODUCT.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
BENZYL ALCOHOL (CAS 100-51-6) 1.1
MOBILITY IN SOIL: THIS PRODUCT IS NON-VOLATILE.
FURTHER INFORMATION:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION,
PHOTOCHEMICAL OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL
WARMING POTENTIAL) ARE EXPECTED FROM THIS PRODUCT.
| 13. DISPOSAL CONSIDERATION | |
WASTE DISPOSAL OF SUBSTANCE:
DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT
CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
CONTAINER DISPOSAL:
EMPTY CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES; FOLLOW LABEL
WARNINGS EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN
TO AN APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
DISPOSAL OF CURED PRODUCT:
GRIND OR CHIP OFF SURFACE. SOLID MATERIAL DOES NOT NEED SPECIAL DISPOSAL
CONSIDERATIONS.
| 14. TRANSPORTATION INFORMATION | |
RESIN (WHITE SIDE):
UN NUMBER: UN3082
UN PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(BISPHENOL-A-EPICHLOROHYDRIN), 9, III, MARINE POLLUTANT
PRECAUTIONS: MARINE POLLUTANT
REQUIRED LABELS: 9
ERG CODE (IATA): 9L
EMS (IMDG): F-A, S-F
HARDENER (BLACK SIDE):
UN NUMBER: UN2735
UN PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (PHENOL, 2,4,6-TRISDIMETHYLAMINOMETHYL),
8, III
PRECAUTIONS: CORROSIVE
REQUIRED LABELS: 8
ERG CODE (IATA): 8L
EMS (IMDG): F-A, S-B
ADDITIONAL INFORMATION:
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
THIS SUBSTANCE/MIXTURE IS NOT INTENDED TO BE TRANSPORTED IN BULK
THIS INFORMATION DOES NOT COVER ALL SPECIFIC REGULATORY OR OPERATIONAL
REQUIREMENTS OF THIS PRODUCT. THE CLASSIFICATIONS FOR TRANSPORTATION MAY
VARY BY CONTAINER VOLUME OR DIFFERENT REGIONAL OR NATIONAL REGULATIONS.
| 15. REGULATORY INFORMATION | |
UNITED STATES:
FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES IMMEDIATE DELAYED FIRE PRESSURE REACTIVITY
RESIN YES NO NO NO NO
HARDENER YES YES YES NO NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING): NOT REGULATED.
US STATE RIGHT-TO-KNOW LISTS:
CHEMICAL MASSACHUSETTS NEW JERSEY PENNSYLVANIA RHODE
RTK WORK AND WORKER AND ISLAND
COMMUNITY COMMUNITY RTK
RTK ACT RTK LAW
BENZYL ALCOHOL LISTED LISTED
(CAS 100-51-6)
TRIETHYLENETETRAMINE LISTED LISTED
(CAS 112-24-3)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS, OR REPRODUCTIVE HARM.
COMPONENT REGULATION % IN BLEND (APPROX.) REMARK
CARBON BLACK (1333-86-4) ACGIH TRACE CARCINOGENIC
CANADA:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE SDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
WHMIS CLASSIFICATION:
CLASS E: CORROSIVE
CLASS B-3: COMBUSTIBLE LIQUID
CLASS D-2A: MATERIAL CAUSING OTHER TOXIC EFFECTS
INTERNATIONAL:
INTERNATIONAL INVENTORIES:
COUNTRY OR REGION INVENTORY ON INVENTORY?
(YES/NO)
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) / YES
NON-DOMESTIC SUBSTANCES LIST (NDSL)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
| 16. OTHER INFORMATION | |
DATE PREPARED OR REVISED: SEPTEMBER 2014
SUPERSEDES: OCTOBER 2013
ADDITIONAL RESIN (CLEAR SIDE) CLASSIFICATIONS:
NFPA RATINGS:
2
1
0
HMIS RATING:
HEALTH HAZARD 2
FLAMMABILTY HAZARD 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
ADDITIONAL HARDENER (BLACK SIDE) CLASSIFICATIONS:
NFPA RATINGS:
3
2
0
HMIS RATING:
HEALTH HAZARD 3
FLAMMABILTY HAZARD 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
ABBREVIATIONS:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CAS NO.: CHEMICAL ABSTRACT SERVICE REGISTRY NUMBER
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT
(U.S. EPA)
CPR: CONTROLLED PRODUCT REGULATIONS (CANADA)
DOT: DEPARTMENT OF TRANSPORTATION (U.S.)
EPA: ENVIRONMENTAL PROTECTION AGENCY (U.S.)
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
HEPA: HIGH-EFFICIENCY PARTICULATE AIR
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS CODE
LPP: LIMITE PERMISIBLE PONDERADO (CHILE)
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH (U.S.)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (US)
NTP: NATIONAL TOXICOLOGY PROGRAM (US)
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (U.S.)
PEL: PERMISSIBLE EXPOSURE LIMIT
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (U.S. EPA)
SDS: SAFETY DATA SHEET
STEL: SHORT TERM EXPOSURE LIMIT (15 MINUTE TIME WEIGHTED AVERAGE)
STOT: SPECIFIC TARGET ORGAN TOXICITY (GHS CLASSIFICATION)
TLV: THRESHOLD LIMIT VALUE
TSCA: TOXIC SUBSTANCES CONTROL ACT (U.S.)
TWA: TIME WEIGHTED AVERAGE (EXPOSURE FOR 8-HOUR WORKDAY)
U.S.: UNITED STATES
VOC: VOLATILE ORGANIC COMPOUNDS
WHMIS: CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM
DISCLAIMER:
THIS SAFETY DATA SHEET (SDS) IS PREPARED BY SIMPSON STRONG-TIE CO. IN
COMPLIANCE WITH THE REQUIREMENTS OF OSHA 29 CFR PART 1910.1200. THE
INFORMATION IT CONTAINS IS OFFERED IN GOOD FAITH AS ACCURATE AS OF THE
DATE OF THIS SDS. THIS SDS IS PROVIDED SOLELY FOR THE PURPOSE OF CONVEYING
HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION. NO WARRANTY, EXPRESSED OR
IMPLIED, IS GIVEN. HEALTH AND SAFETY PRECAUTIONS MAY NOT BE ADEQUATE FOR
ALL INDIVIDUALS AND/OR SITUATIONS. IT IS THE USER'S OBLIGATION TO EVALUATE
AND USE THIS PRODUCT SAFELY AND TO COMPLY WITH ALL APPLICABLE LAWS AND
REGULATIONS.
(C) 2014 SIMPSON STRONG-TIE COMPANY INC.
INTERNAL:
FOR INTERNAL USE ONLY:
ETI-LV RESIN: XCOM3B - 50% CARTRIDGE
ETI-LV HARDENER:
XCOM3A - 50% CARTRIDGE
XCORR - 50% CARTRIDGE