| Common Name: | ETI-GV (ETIGV22, ETIGV) |
| Manufacturer: | SIMPSON STRONG-TIE |
| SDS Revision Date: | 9/1/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2WLG3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SIMPSON STRONG-TIE(R*)
ETI-GV INJECTION EPOXY
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFICATION:
PRODUCT IDENTIFIER: ETI-GV (ETIGV22, ETIGV)
RECOMMENDED USE: GEL VISCOSITY INJECTION EPOXY
USE RESTRICTIONS: NONE KNOWN.
COMPANY IDENTIFICATION:
COMPANY: SIMPSON STRONG-TIE COMPANY INC.
ADDRESS:
5956 W. LAS POSITAS BLVD.
PLEASANTON, CA 94588
PHONE: 1-800-999-5099
WEBSITE: WWW.STRONGTIE.COM
EMERGENCY:
1-800-535-5053 (US/CANADA)
1-352-323-3500 (INTERNATIONAL)
FOR MOST CURRENT SDS, PLEASE VISIT OUR WEBSITE AT WWW.STRONGTIE.COM/SDS
| 2. HAZARD IDENTIFICATION | |
ETI-GV INJECTION EPOXY IS A TWO PART SYSTEM. THE TWO PARTS OF THIS PRODUCT
HAVE BEEN ASSESSED ACCORDING TO GHS AND ARE CLASSIFIED BELOW. THE FINAL
HARDENED MATERIAL IS CONSIDERED NONHAZARDOUS. SOME HAZARDS APPLY UPON
GRINDING OR CUTTING THROUGH HARDENED PRODUCT.
RESIN (WHITE SIDE) GHS CLASSIFICATION:
HEALTH HAZARD
EXCLAMATION MARK
ENVIRONMENT
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1
GERM CELL MUTAGENICITY: CATEGORY 2
ENVIRONMENTAL HAZARDS:
CHRONIC AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 2
SIGNAL WORD: WARNING!
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE AN
ALLERGIC SKIN REACTION. SUSPECTED OF CAUSING GENETIC DEFECTS. TOXIC
TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES/
PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID BREATHING
MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE
ENVIRONMENT.
RESPONSE:
IF EXPOSED OR CONCERNED: CALL A POISON CENTER/DOCTOR.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE RE-USE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. COLLECT SPILLAGE.
STORAGE:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. STORE BETWEEN
45-90 DEG. F (7-32 DEG. C).
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
HARDENER (BLACK SIDE) GHS CLASSIFICATION:
CORROSION
HEALTH HAZARD
EXCLAMATION MARK
ENVIRONMENT
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 4
HEALTH HAZARDS:
ACUTE TOXICITY, DERMAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1C
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1
SENSITIZATION, SKIN: CATEGORY 1
REPRODUCTIVE TOXICITY: CATEGORY 2
STOT, SINGLE EXPOSURE: CATEGORY 2 (NARCOTIC EFFECTS)
ENVIRONMENTAL HAZARDS:
ACUTE AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 1
CHRONIC AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 1
SIGNAL WORD: DANGER!
HAZARD STATEMENTS:
COMBUSTIBLE LIQUID. HARMFUL IN CONTACT WITH SKIN. CAUSES SEVERE SKIN BURNS
AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE DROWSINESS
OR DIZZINESS. SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. VERY
TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT EAT, DRINK OR SMOKE
WHEN USING THIS PRODUCT. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE
PROTECTION/FACE PROTECTION. DO NOT BREATHE MIST OR VAPOR. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR. WASH CONTAMINATED CLOTHING BEFORE RE-USE. COLLECT SPILLAGE.
STORAGE:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED. STORE BETWEEN 45-90 DEG F (7-32 DEG. C).
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC):
THE ABOVE HAZARDS ARE FOR THE UNCURED RESIN COMPONENT OF ETI-GV. UPON
COMBINATION WITH THE HARDENER COMPONENT OF ETI-GV AN INNOCUOUS SOLID IS
FORMED WHICH DOES NOT PRESENT ANY IMMEDIATE HAZARDS. UPON GRINDING OR
CUTTING THE CURED PRODUCT THE FOLLOWING HAZARDS MAY APPLY.
HEALTH HAZARD
HEALTH HAZARDS:
CARCINOGENICITY: CATEGORY 2
HAZARD STATEMENTS: SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS: DO NOT BREATHE DUST.
| 3. COMPOSITION INFORMATION | |
GENERAL INFORMATION:
THIS PRODUCT IS A MIXTURE. HAZARDOUS INGREDIENTS FOR EACH COMPONENT ARE
LISTED BELOW. MAY INCLUDE OTHER NONHAZARDOUS INGREDIENTS. MAY INCLUDE
OTHER TRACE INGREDIENTS, SEE SECTION 15.
RESIN (WHITE SIDE):
CHEMICAL NAME CAS NUMBER WEIGHT %
BISPHENOL A/EPICHLOROHYDRIN 25068-38-6 40-60
PHENOL, POLYMER WITH FORMALDEHYDE, 28064-14-4 40-60
GLYCIDYL ETHER
BUTYL GLYCIDYL ETHER 2426-08-6 1-10
TITANIUM DIOXIDE 13463-67-1 1-10
HARDENER (BLACK SIDE):
CHEMICAL NAME CAS NUMBER WEIGHT %
BENZYL ALCOHOL 100-51-6 10-30
PHENOL, 2,4,6-TRISDIMETHYLAMINOMETHYL 90-72-2 1-10
NONYLPHENOL 84852-15-3 1-10
TRIETHYLENETETRAMINE 112-24-3 1-10
CARBON BLACK 1333-86-4 0.1 - <1
| 4. FIRST-AID MEASURES | |
GENERAL INFORMATION:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. SYMPTOMS
MAY BE DELAYED. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S)
INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. YOU SHOULD CALL THE
POISONS INFORMATION CENTER IS YOU FEEL YOU MAY HAVE BEEN HARMED, BURNED,
OR IRRITATED BY THIS PRODUCT. THE NUMBER IS 13 11 26 (24HR). READY ACCESS
TO RUNNING WATER AND ACCESSIBLE EYEWASH IS REQUIRED. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
ROUTES OF EXPOSURE:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF COOL WATER FOR AT LEAST 15 MINUTES
WHILE HOLDING THE EYES OPEN. REMOVE CONTACT LENSES IF PRESENT AND EASY
TO DO. IF REDNESS, BURNING, BLURRED VISION, OR SWELLING PERSISTS, CONSULT
A PHYSICIAN.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND PRODUCT, IMMEDIATELY WASH AFFECTED AREA
WITH SOAP AND WATER. DO NOT APPLY GREASES OR OINTMENTS. CHEMICAL BURNS
MUST BE TREATED BY A PHYSICIAN.
INGESTION:
RINSE MOUTH IMMEDIATELY. GIVE LARGE AMOUNTS OF MILK OR WATER, IF PERSON IS
CONSCIOUS. ONLY INDUCE VOMITING AT THE INSTRUCTION OF MEDICAL PERSONNEL.
CONSULT A PHYSICIAN.
INHALATION:
REMOVE PATIENT TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF
NEEDED. IF PATIENT CONTINUES TO EXPERIENCE DIFFICULTY BREATHING, CONSULT
A PHYSICIAN.
MOST IMPORTANT SYMPTOMS:
IRRITANT EFFECTS. SENSITIZATION. SYMPTOMS INCLUDE ITCHING, BURNING,
REDNESS AND TEARING. MAY CAUSE DROWSINESS OR DIZZINESS. RASH. HEADACHES,
NAUSEA AND VOMITING. CORROSIVE EFFECTS. PERMANENT EYE DAMAGE INCLUDING
BLINDNESS COULD RESULT.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
EXTINGUISH WITH FOAM, CARBON DIOXIDE, DRY POWDER, OR WATER FOG.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
FIRE AND EXPLOSION HAZARD: NONE KNOWN.
HAZARDS DURING FIRE-FIGHTING:
HAZARDOUS DECOMPOSITION PRODUCTS MAY OCCUR WHEN MATERIALS POLYMERIZE AT
TEMPERATURES ABOVE 500 DEG. F (260 DEG. C). IRRITATING AND TOXIC GASES/
FUMES MAY BE RELEASED DURING A FIRE. WATER RUN-OFF CAN CAUSE
ENVIRONMENTAL DAMAGE.
FIRE-FIGHTING PROCEDURES:
USE STANDARD FIRE-FIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. COOL
CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT.
PREVENT RUNOFF FROM FIRE CONTROL OR DILUTION FROM ENTERING STREAMS,
SEWERS, OR DRINKING WATER SUPPLY.
HAZCHEM CODE: 2Y (RESIN) / 2X (HARDENER)
COMBUSTION PRODUCTS:
CARBON DIOXIDE. CARBON MONOXIDE. NITROGEN OXIDES (NOX). AMMONIA.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. ELIMINATE ALL IGNITION SOURCES (NO
SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID
INHALATION OF VAPORS OR MISTS. ENSURE ADEQUATE VENTILATION. LOCAL
AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
CLEAN-UP METHODS:
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). PLACE IN LEAK-PROOF
CONTAINERS. SEAL TIGHTLY FOR PROPER DISPOSAL. CLEAN SURFACE THOROUGHLY TO
REMOVE RESIDUAL CONTAMINATION.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE FAR AHEAD OF
SPILL FOR LATER DISPOSAL. USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE,
SAND OR EARTH TO SOAK UP THE PRODUCT. PLACE IN LEAK-PROOF CONTAINERS. SEAL
TIGHTLY FOR PROPER DISPOSAL. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH
WATER.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. CONTACT LOCAL AUTHORITIES IN CASE OF
SPILLAGE TO DRAIN/AQUATIC ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE
IF SAFE TO DO SO.
| 7. HANDLING AND STORAGE | |
HANDLING:
MECHANICAL VENTILATION OR LOCAL EXHAUST VENTILATION IS RECOMMENDED. KEEP
AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. PREGNANT WOMEN SHOULD NOT WORK
WITH THE PRODUCT, IF THERE IS THE LEAST RISK OF EXPOSURE. AVOID ANY
EXPOSURE. WHEN USING, DO NOT EAT, DRINK OR SMOKE. AVOID CONTACT WITH
EYES, SKIN, AND CLOTHING. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
STORAGE:
STORE IN A CLOSED CONTAINER AWAY FROM INCOMPATIBLE MATERIALS. KEEP IN
ORIGINAL CONTAINER. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A DRY PLACE
OUT OF DIRECT SUNLIGHT. STORE BETWEEN 45-90 DEG. F (7-32 DEG. C). KEEP
AWAY FROM HEAT AND SOURCES OF IGNITION. STORE IN A WELL-VENTILATED PLACE.
STORE LOCKED UP. KEEP OUT OF THE REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS:
COMPONENT OSHA (PEL) US. ACGIH (TLV) NIOSH POCKET GUIDE
N-BUTYL GLYCIDYL 270 MG/M3 3 PPM 30 MG/M3 (CEILING)
ETHER 50 PPM 5.6 PPM (CEILING)
(2426-08-6)
TITANIUM DIOXIDE 5 MG/M3 10 MG/M3 N/E
(13463-67-7) (RESPIRABLE)
10 MG/M3
(TOTAL DUST)
PHENOL* 19 MG/M3 5 PPM 60 MG/M3 (CEILING)
(CAS 108-95-2) 5 PPM 15.6 PPM (CEILING)
CARBON BLACK 3.5 MG/M3 3.5 MG/M3 0.1 MG/M3 (TWA)
(CAS 1333-86-4) (INHALABLE)
BENZYL ALCOHOL N/E N/E 44.2 MG/M3
(CAS 100-51-6)
TRIETHYLENETETRAMINE* N/E N/E 6 MG/M3
(CAS 112-24-3) 1 PPM
*SKIN DESIGNATION: MATERIAL CAN BE ABSORBED THROUGH THE SKIN.
PERSONAL PROTECTIVE EQUIPMENT:
PROTECTIVE MEASURE: WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES OR SAFETY GLASSES WITH SIDE SHIELD.
HAND PROTECTION:
WEAR CHEMICAL-RESISTANT GLOVES SUCH AS: NITRILE, NEOPRENE, BUTYL.
SKIN AND BODY PROTECTION:
WEAR LONG SLEEVE SHIRT/LONG PANTS AND OTHER CLOTHING AS REQUIRED TO
MINIMIZE CONTACT.
RESPIRATOR PROTECTION:
THE USE OF A RESPIRATOR IS NOT REQUIRED DURING NORMAL USE OF THIS PRODUCT.
IF GRINDING OR CUTTING CURED PRODUCT THE USE OF AN APPROVED RESPIRATOR IS
RECOMMENDED.
GENERAL HYGIENE:
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS.
ENGINEERING CONTROLS:
WHEN USING INDOORS GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES
PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS. READY ACCESS TO RUNNING WATER IS REQUIRED. PROVIDE EYEWASH
STATION.
ADDITIONAL INFORMATION:
AFTER CURE:
PRODUCT FORMS AN INNOCUOUS SOLID. PROCESSING AFTER CURE (GRINDING OR
CUTTING) MAY PRODUCE DUST CONTAINING COMPOUNDS THAT PRESENT AN INHALATION
HAZARD.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PROPERTY RESIN HARDENER
PHYSICAL STATE LIQUID, PASTE LIQUID, PASTE
COLOR WHITE BLACK
ODOR SWEET AMMONIA
PH 6.9 10.7
FLAMMABILITY LIMIT - LOWER % NO DATA NO DATA
FLAMMABILITY LIMIT - UPPER % NO DATA NO DATA
VAPOR PRESSURE NON-VOLATILE NO DATA
VAPOR DENSITY NO DATA NO DATA
SOLUBILITY INSOLUBLE IN WATER SLIGHTLY SOLUBLE
IN WATER
FREEZING/MELTING POINT NO DATA NO DATA
BOILING POINT >500 DEG. F NO DATA
(>260 DEG. C)
FLASH POINT 250 DEG. F 175 DEG. F
(121 DEG. C) (79.4 DEG. C)
OPEN CUP CLOSED CUP
EVAPORATION RATE NO DATA NO DATA
DECOMPOSITION TEMPERATURE NO DATA NO DATA
SPECIFIC GRAVITY 1.21 AT 72 DEG. F 1.02 AT 72 DEG. F
(22 DEG. C) (22 DEG. C)
VOC (AFTER CURE) 4 G/L 4 G/L
KOW NO DATA NO DATA
VISCOSITY NO DATA NO DATA
| 10. STABILITY AND REACTIVITY | |
RESIN (WHITE SIDE):
REACTIVITY:
THIS PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
CONDITION TO AVOID: HIGH HEAT AND OPEN FLAME.
SUBSTANCES TO AVOID: OXIDIZING AGENTS, ACIDS, ORGANIC BASES, AND AMINES.
HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, AND OTHER ORGANIC
COMPOUNDS.
HARDENER (BLACK SIDE):
REACTIVITY:
THIS PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
CONDITION TO AVOID:
CONTACT WITH INCOMPATIBLE MATERIALS. HIGH HEAT AND OPEN FLAME.
SUBSTANCES TO AVOID: STRONG OXIDIZING AGENTS. STRONG ACIDS.
HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, AND OTHER ORGANIC
COMPOUNDS.
| 11. TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF EXPOSURE:
INGESTION: MAY BE HARMFUL IF SWALLOWED. CAUSES DIGESTIVE TRACT BURNS
INHALATION:
MAY BE HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT BURNS. INHALATION OF
DUST FROM GRINDING OR CUTTING MAY IRRITATE THE RESPIRATORY TRACT.
SKIN CONTACT:
HARMFUL IN CONTACT WITH SKIN. CAUSES SKIN IRRITATION. CAUSES SEVERE SKIN
BURNS. MAY CAUSE SENSITIZATION BY SKIN CONTACT.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION. CAUSES EYE BURNS.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
OCCUPATIONAL EXPOSURE TO THE SUBSTANCE OR MIXTURE MAY CAUSE ADVERSE
EFFECTS.
PRODUCT SPECIES TEST RESULT
ETIGV RESIN (CAS MIXTURE)
ACUTE, DERMAL, LC50 RABBIT >2000 MG/KG
ACUTE, ORAL, LD50 RAT >5000 MG/KG
BENZYL ALCOHOL (CAS 100-51-6)
ACUTE, DERMAL, LC50 RABBIT 2000 MG/KG
ACUTE, ORAL, LD50 RAT 1230-3100 MG/KG
ACUTE, INHALATION, LD50 RAT >4173 MG/M3, 4 HOURS
SKIN CORROSION/IRRITATION:
CAUSES SKIN IRRITATION. CAUSES SEVERE SKIN BURNS.
EYE DAMAGE/EYE IRRITATION:
CAUSES SERIOUS EYE IRRITATION. CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY SENSITIZATION: NO DATA AVAILABLE.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
CONTAINS A COMPONENT THAT IS SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY:
BOTH THE RESIN AND HARDENER COMPONENTS OF THIS PRODUCT CONTAIN A COMPONENT
THAT IS SUSPECTED OF CAUSING CANCER. TITANIUM DIOXIDE AND CARBON BLACK ARE
CONSIDERED CARCINOGENS ONLY IN THEIR INHALABLE FORM. DUE TO THE NATURE OF
THIS PRODUCT INHALATION IS HIGHLY UNLIKELY. EXPOSURE TO RESPIRABLE
TITANIUM DIOXIDE AND CARBON BLACK IS LIKELY ONLY WHEN GRINDING OR CUTTING
CURED PRODUCT, ENSURE GOOD WORK PRACTICE AND USE OF PERSONAL PROTECTIVE
EQUIPMENT AS NEEDED TO CONTROL EXPOSURE.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TITANIUM DIOXIDE (13463-67-7): 2B POSSIBLY CARCINOGENIC TO HUMANS.
CARBON BLACK (1333-86-4): 2B POSSIBLY CARCINOGENIC TO HUMANS.
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
ASPIRATION HAZARD: NO DATA AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY:
SINGLE EXPOSURE: MAY CAUSE DROWSINESS OR DIZZINESS.
REPEATED EXPOSURE: NO DATA AVAILABLE.
FURTHER INFORMATION:
TOXICOLOGICAL, ECOTOXICOLOGICAL, PHYSICAL, AND CHEMICAL PROPERTIES MAY NOT
HAVE BEEN FULLY INVESTIGATED. HAZARD DATA ABOVE IS ESTIMATED BASED ON BEST
AVAILABLE INFORMATION.
SOME WORKERS WITH PRE-EXISTING MEDICAL CONDITIONS SUCH AS:
ASTHMA, ALLERGIES, OR IMPAIRED PULMONARY AND/OR LIVER FUNCTIONS, OR WHO
MAY BE PARTICULARLY SUSCEPTIBLE TO THIS MATERIAL, MAY BE AFFECTED BY
EXPOSURE TO THIS MATERIAL.
| 12. ECOLOGICAL INFORMATION | |
GENERAL INFORMATION:
INFORMATION GIVEN IS BASED ON DATA ON THE COMPONENTS AND THE ECOTOXICOLOGY
OF SIMILAR PRODUCTS. RESIN IS CLASSIFIED AS TOXIC TO AQUATIC LIFE WITH
LONG LASTING EFFECTS. HARDENER IS CLASSIFIED AS VERY TOXIC TO AQUATIC LIFE
WITH LONG LASTING EFFECTS. AVOID RELEASE TO THE ENVIRONMENT.
SUPPORTING DATA:
COMPONENT SPECIES TEST RESULT
ETIGV RESIN (CAS MIXTURE)
AQUATIC ACUTE, ALGAE, EC50 ALGAE >1000 MG/L, 72 HOURS
AQUATIC ACUTE, CRUSTACEA, EC50 DAPHNIA MAGNA 324.87 MG/L, 48 HOURS
AQUATIC ACUTE, FISH, LC50 FISH 707.11 MG/L, 96 HOURS
BENZYL ALCOHOL (CAS 100-51-6)
AQUATIC ACUTE, FISH, LC50 BLUEGILL 10 MG/L, 96 HOURS
NONYLPHENOL (CAS 84852-15-3)
AQUATIC, CRUSTACEA, EC50 CLAM 0.0379 MG/L, 48 HOURS
AQUATIC, FISH, LC50 WINTER FLOUNDER 0.017 MG/L, 96 HOURS
PERSISTENCE AND DEGRADABILITY:
THIS PRODUCT IS NOT EXPECTED TO BE READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE FOR THIS PRODUCT.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
BUTYL GLYCIDYL ETHER (2426-08-6): 0.63
BENZYL ALCOHOL (CAS 100-51-6): 1.1
MOBILITY IN SOIL: THIS PRODUCT IS NON-VOLATILE.
FURTHER INFORMATION:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION,
PHOTOCHEMICAL OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL
WARMING POTENTIAL) ARE EXPECTED FROM THIS PRODUCT.
| 13. DISPOSAL CONSIDERATION | |
WASTE DISPOSAL OF SUBSTANCE:
DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT
CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
CONTAINER DISPOSAL:
EMPTY CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES; FOLLOW LABEL
WARNINGS EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN
TO AN APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
DISPOSAL OF CURED PRODUCT:
GRIND OR CHIP OFF SURFACE. SOLID MATERIAL DOES NOT NEED SPECIAL
CONSIDERATION.
| 14. TRANSPORTATION INFORMATION | |
RESIN (WHITE SIDE):
UN NUMBER: UN3082
UN PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL-A-
EPICHLOROHYDRIN), 9, III, MARINE POLLUTANT
PRECAUTIONS: MARINE POLLUTANT
REQUIRED LABELS: 9
ERG CODE (IATA): 9L
EMS (IMDG): F-A, S-F
HARDENER (BLACK SIDE):
UN NUMBER: UN2735
UN PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (NONYLPHENOL), 8, III, MARINE POLLUTANT
PRECAUTIONS: CORROSIVE, MARINE POLLUTANT
REQUIRED LABELS: 8
ERG CODE (IATA): 8L
EMS (IMDG): F-A, S-F
ADDITIONAL INFORMATION:
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
THIS SUBSTANCE/MIXTURE IS NOT INTENDED TO BE TRANSPORTED IN BULK
THIS INFORMATION DOES NOT COVER ALL SPECIFIC REGULATORY OR OPERATIONAL
REQUIREMENTS OF THIS PRODUCT. THE CLASSIFICATIONS FOR TRANSPORTATION MAY
VARY BY CONTAINER VOLUME OR DIFFERENT REGIONAL OR NATIONAL REGULATIONS.
| 15. REGULATORY INFORMATION | |
UNITED STATES:
FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES IMMEDIATE DELAYED FIRE PRESSURE REACTIVITY
RESIN YES YES NO NO NO
HARDENER YES YES YES NO NO
US STATE RIGHT-TO-KNOW LISTS:
CHEMICAL MASSACHUSETTS NEW JERSEY PENNSYLVANIA RHODE
RTK WORK AND WORKER AND ISLAND RTK
COMMUNITY COMMUNITY
RTK ACT RTK LAW
BUTYL GLYCIDYL LISTED LISTED
ETHER
(CAS 2426-08-6)
TITANIUM DIOXIDE LISTED LISTED
(CAS 13463-67-7)
BENZYL ALCOHOL LISTED LISTED
(CAS 100-51-6)
CARBON BLACK LISTED LISTED
(CAS 1333-86-4)
TRIETHYLENETE- LISTED LISTED
TRAMINE
(CAS 112-24-3)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL LISTED BY THE STATE OF CALIFORNIA AS
KNOWN TO CAUSE CANCER, BIRTH DEFECTS, OR REPRODUCTIVE HARM.
COMPONENT REGULATION % IN BLEND (APPROX.) REMARK
TITANIUM DIOXIDE ACGIH 1-10 CARCINOGENIC
(CAS 13463-67-7)
CARBON BLACK ACGIH <1 CARCINOGENIC
(1333-86-4)
CANADA:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE SDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
WHMIS CLASSIFICATION:
CLASS E: CORROSIVE
CLASS B-3: COMBUSTIBLE LIQUID
CLASS D-2A: MATERIAL CAUSING OTHER TOXIC EFFECTS
INTERNATIONAL:
INTERNATIONAL INVENTORIES:
COUNTRY OR REGION INVENTORY ON INVENTORY?
(YES/NO)
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) / YES
NON-DOMESTIC SUBSTANCES LIST (NDSL)
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
| 16. OTHER INFORMATION | |
DATE PREPARED OR REVISED: SEPTEMBER 2014
SUPERSEDES: AUGUST 2012
ADDITIONAL RESIN (WHITE SIDE) CLASSIFICATIONS:
NFPA RATINGS:
2
1
0
HMIS RATING:
HEALTH HAZARD 2
FLAMMABILTY HAZARD 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
ADDITIONAL HARDENER (BLACK SIDE) CLASSIFICATIONS:
NFPA RATINGS:
3
1
0
HMIS RATING:
HEALTH HAZARD 3
FLAMMABILTY HAZARD 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
ABBREVIATIONS:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CAS NO.: CHEMICAL ABSTRACT SERVICE REGISTRY NUMBER
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT
(U.S. EPA)
CPR: CONTROLLED PRODUCT REGULATIONS (CANADA)
DOT: DEPARTMENT OF TRANSPORTATION (U.S.)
EPA: ENVIRONMENTAL PROTECTION AGENCY (U.S.)
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
HEPA: HIGH-EFFICIENCY PARTICULATE AIR
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS CODE
LPP: LIMITE PERMISIBLE PONDERADO (CHILE)
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH (U.S.)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (US)
NTP: NATIONAL TOXICOLOGY PROGRAM (US)
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (U.S.)
PEL: PERMISSIBLE EXPOSURE LIMIT
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (U.S. EPA)
SDS: SAFETY DATA SHEET
STEL: SHORT TERM EXPOSURE LIMIT (15 MINUTE TIME WEIGHTED AVERAGE)
STOT: SPECIFIC TARGET ORGAN TOXICITY (GHS CLASSIFICATION)
TLV: THRESHOLD LIMIT VALUE
TSCA: TOXIC SUBSTANCES CONTROL ACT (U.S.)
TWA: TIME WEIGHTED AVERAGE (EXPOSURE FOR 8-HOUR WORKDAY)
U.S.: UNITED STATES
VOC: VOLATILE ORGANIC COMPOUNDS
WHMIS: CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM
DISCLAIMER:
THIS SAFETY DATA SHEET (SDS) IS PREPARED BY SIMPSON STRONG-TIE CO. IN
COMPLIANCE WITH THE REQUIREMENTS OF OSHA 29 CFR PART 1910.1200. THE
INFORMATION IT CONTAINS IS OFFERED IN GOOD FAITH AS ACCURATE AS OF THE
DATE OF THIS SDS. THIS SDS IS PROVIDED SOLELY FOR THE PURPOSE OF
CONVEYING HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION. NO WARRANTY,
EXPRESSED OR IMPLIED, IS GIVEN. HEALTH AND SAFETY PRECAUTIONS MAY NOT
BE ADEQUATE FOR ALL INDIVIDUALS AND/OR SITUATIONS. IT IS THE USER'S
OBLIGATION TO EVALUATE AND USE THIS PRODUCT SAFELY AND TO COMPLY WITH
ALL APPLICABLE LAWS AND REGULATIONS.
(C) 2014 SIMPSON STRONG-TIE COMPANY INC.
INTERNAL:
FOR INTERNAL USE ONLY:
ETI-GV RESIN:
XCOM3B - 50% CARTRIDGE
ETI-GV HARDENER:
XCOM3A - 50% CARTRIDGE
XCORR - 50% CARTRIDGE