| Common Name: | ETR |
| Manufacturer: | SIMPSON STRONG-TIE |
| SDS Revision Date: | 9/1/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 2WLG9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SIMPSON STRONG-TIE(R*)
ETR CRACK INJECTION PASTE-OVER ADHESIVE
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFICATION:
PRODUCT IDENTIFIER: ETR
RECOMMENDED USE: EPOXY PASTE-OVER MATERIAL FOR CRACK REPAIR
USE RESTRICTIONS: NONE KNOWN.
COMPANY IDENTIFICATION:
COMPANY: SIMPSON STRONG-TIE COMPANY INC.
ADDRESS:
5956 W. LAS POSITAS BLVD.
PLEASANTON, CA 94588
PHONE: 1-800-999-5099
WEBSITE: WWW.STRONGTIE.COM
EMERGENCY:
1-800-535-5053 (US/CANADA)
1-352-323-3500 (INTERNATIONAL)
FOR MOST CURRENT SDS, PLEASE VISIT OUR WEBSITE AT WWW.STRONGTIE.COM/SDS
| 2. HAZARD IDENTIFICATION | |
GENERAL INFORMATION:
ETR IS A TWO PART SYSTEM. THE TWO PARTS OF THIS PRODUCT HAVE BEEN ASSESSED
ACCORDING TO GHS AND ARE CLASSIFIED BELOW. THE FINAL HARDENED MATERIAL IS
CONSIDERED NONHAZARDOUS. SOME HAZARDS APPLY UPON GRINDING OR CUTTING
THROUGH HARDENED PRODUCT.
PART A (WHITE SIDE) GHS CLASSIFICATION:
HEALTH HAZARD
EXCLAMATION MARK
ENVIRONMENT
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1
GERM CELL MUTAGENICITY: CATEGORY 2
STOT, SINGLE EXPOSURE: CATEGORY 2 (NARCOTIC EFFECTS)
ENVIRONMENTAL HAZARDS:
ACUTE AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 2
CHRONIC AQUATIC ENVIRONMENTAL HAZARD: CATEGORY 2
SIGNAL WORD: WARNING!
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE AN
ALLERGIC SKIN REACTION.
SUSPECTED OF CAUSING GENETIC DEFECTS. MAY CAUSE DROWSINESS OR
DIZZINESS. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE
GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. CONTAMINATED
WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID BREATHING
MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE
ENVIRONMENT.
RESPONSE:
IF EXPOSED OR CONCERNED: CALL A POISON CENTER/DOCTOR.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE RE-USE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. COLLECT SPILLAGE.
STORAGE:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. STORE BETWEEN
45-90 DEG. F (7-32 DEG. C).
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
PART B (BLACK SIDE) GHS CLASSIFICATION:
CORROSION
EXCLAMATION MARK
PHYSICAL HAZARDS:
FLAMMABLE LIQUID: CATEGORY 4
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 1C
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1
SENSITIZATION, SKIN: CATEGORY 1
STOT, SINGLE EXPOSURE: CATEGORY 2 (NARCOTIC EFFECTS)
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
SIGNAL WORD: DANGER!
HAZARD STATEMENTS:
COMBUSTIBLE LIQUID. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE
AN ALLERGIC SKIN REACTION. MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WASH THOROUGHLY AFTER
HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. AVOID BREATHING DUST/FUME/ GAS/MIST/VAPORS/SPRAY.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR. WASH CONTAMINATED CLOTHING BEFORE RE-USE.
STORAGE:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. STORE BETWEEN
45-90 DEG. F (7-32 DEG. C).
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/
NATIONAL/INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC):
THE ABOVE HAZARDS ARE FOR THE UNCURED COMPONENTS OF ETR. UPON COMBINATION
WITH THE COMPONENTS OF ETR FORM AN INNOCUOUS SOLID WHICH DOES NOT PRESENT
ANY IMMEDIATE HAZARDS. UPON GRINDING OR CUTTING THE CURED PRODUCT, THE
FOLLOWING HAZARDS MAY APPLY.
HEALTH HAZARD
HEALTH HAZARDS:
CARCINOGENICITY: CATEGORY 2
HAZARD STATEMENTS: SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS: DO NOT BREATHE DUST.
| 3. COMPOSITION INFORMATION | |
GENERAL INFORMATION:
THIS PRODUCT IS A MIXTURE. HAZARDOUS INGREDIENTS FOR EACH COMPONENT ARE
LISTED BELOW. MAY INCLUDE OTHER NONHAZARDOUS INGREDIENTS. MAY INCLUDE
OTHER TRACE INGREDIENTS, SEE SECTION 15.
PART A (WHITE SIDE):
CHEMICAL NAME CAS NUMBER WEIGHT %
BISPHENOL A/EPICHLOROHYDRIN 25068-38-6 40-60
WOLLASTONITE 13983-17-0 20-30
LIMESTONE 1317-65-3 10-20
O-CRESYL GLYCIDYL ETHER 2426-08-6 1-10
TITANIUM DIOXIDE 13463-67-1 1-5
PART B (BLACK SIDE):
CHEMICAL NAME CAS NUMBER WEIGHT %
WOLLASTONITE 13983-17-0 35-50
POLYMERCAPTAN N/A 15-30
DIETHYLENETRIAMINE 111-40-0 1-10
LIMESTONE 1317-65-3 1-10
TERPENE HYDROCARBON 8002-09-3 1-10
| 4. FIRST-AID MEASURES | |
GENERAL INFORMATION:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. SYMPTOMS
MAY BE DELAYED. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S)
INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
ROUTES OF EXPOSURE:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF COOL WATER FOR AT LEAST 15 MINUTES
WHILE HOLDING THE EYES OPEN. REMOVE CONTACT LENSES IF PRESENT AND EASY TO
DO. IF REDNESS, BURNING, BLURRED VISION, OR SWELLING PERSISTS, CONSULT
A PHYSICIAN.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND PRODUCT, IMMEDIATELY WASH AFFECTED AREA
WITH SOAP AND WATER. DO NOT APPLY GREASES OR OINTMENTS. IF SKIN IRRITATION
PERSISTS CONSULT A PHYSICIAN.
INGESTION:
RINSE MOUTH IMMEDIATELY. GIVE LARGE AMOUNTS OF MILK OR WATER, IF PERSON IS
CONSCIOUS. ONLY INDUCE VOMITING AT THE INSTRUCTION OF MEDICAL PERSONNEL.
CONSULT A PHYSICIAN.
INHALATION:
REMOVE PATIENT TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF
NEEDED. IF PATIENT CONTINUES TO EXPERIENCE DIFFICULTY BREATHING, CONSULT
A PHYSICIAN.
MOST IMPORTANT SYMPTOMS:
SYMPTOMS INCLUDE ITCHING, BURNING, REDNESS AND TEARING. SENSITIZATION.
RASH. DROWSINESS AND DIZZINESS. HEADACHES, NAUSEA AND VOMITING. CORROSIVE
EFFECTS. PERMANENT EYE DAMAGE INCLUDING BLINDNESS COULD RESULT.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
EXTINGUISH WITH FOAM, CARBON DIOXIDE, DRY POWDER, OR WATER FOG.
ADDITIONAL INFORMATION: NONE KNOWN.
HAZARDS DURING FIRE-FIGHTING:
HAZARDOUS DECOMPOSITION PRODUCTS MAY OCCUR WHEN MATERIALS POLYMERIZE AT
TEMPERATURES ABOVE 500 DEG. F (260 DEG. C). IRRITATING AND TOXIC GASES/
FUMES MAY BE RELEASED DURING A FIRE. DO NOT ALLOW RUN-OFF FROM FIRE-
FIGHTING TO ENTER DRAINS OR WATER COURSES.
FIRE-FIGHTING PROCEDURES:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE
IS OUT. PREVENT RUNOFF FROM FIRE CONTROL OR DILUTION FROM ENTERING
STREAMS, SEWERS, OR DRINKING WATER SUPPLY.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. ELIMINATE ALL IGNITION SOURCES (NO
SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. DO NOT TOUCH DAMAGED
CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE
CLOTHING. AVOID INHALATION OF VAPORS OR MISTS. ENSURE ADEQUATE
VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT
SPILLAGES CANNOT BE CONTAINED.
CLEAN-UP METHODS:
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). PLACE IN LEAK-PROOF
CONTAINERS. SEAL TIGHTLY FOR PROPER DISPOSAL. CLEAN SURFACE THOROUGHLY TO
REMOVE RESIDUAL CONTAMINATION.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE FAR AHEAD OF
SPILL. USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO
SOAK UP THE PRODUCT. PLACE IN LEAK-PROOF CONTAINERS. SEAL TIGHTLY FOR
PROPER DISPOSAL. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED AREAS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. CONTACT LOCAL AUTHORITIES IN CASE OF
SPILLAGE TO DRAIN/AQUATIC ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE
IF SAFE TO DO SO.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. OBSERVE GOOD
INDUSTRIAL HYGIENE PRACTICES.
STORAGE:
STORE IN A CLOSED CONTAINER AWAY FROM INCOMPATIBLE MATERIALS. KEEP IN
ORIGINAL CONTAINER. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A DRY PLACE
OUT OF DIRECT SUNLIGHT. KEEP OUT OF THE REACH OF CHILDREN. STORE BETWEEN
45-90 DEG. F (7-32 DEG. C). KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.
STORE IN A WELL-VENTILATED PLACE. STORE LOCKED UP.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
PERSONAL PROTECTIVE EQUIPMENT:
PROTECTIVE MEASURE:
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES OR SAFETY GLASSES WITH SIDE SHIELD.
HAND PROTECTION:
WEAR CHEMICAL-RESISTANT GLOVES SUCH AS: NITRILE, NEOPRENE, BUTYL.
SKIN AND BODY PROTECTION:
WEAR LONG SLEEVE SHIRT/LONG PANTS AND OTHER CLOTHING AS REQUIRED TO
MINIMIZE CONTACT.
RESPIRATOR PROTECTION:
THE USE OF A RESPIRATOR IS NOT REQUIRED DURING NORMAL USE OF THIS
PRODUCT. IF GRINDING OR CUTTING CURED PRODUCT THE USE OF A RESPIRATOR
IS RECOMMENDED.
GENERAL HYGIENE:
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS.
ENGINEERING CONTROLS:
WHEN USING INDOORS GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
READY ACCESS TO RUNNING WATER IS REQUIRED. PROVIDE EYEWASH STATION.
EXPOSURE LIMITS:
COMPONENT OSHA (PEL) ACGIH (TLV) NIOSH
POCKET GUIDE
TITANIUM DIOXIDE 15 MG/M3 10 MG/M3 N/E
(CAS 13463-67-7) (TOTAL DUST)
LIMESTONE 5 MG/M3 N/E 5 MG/M3
(CAS 1317-65-3) (RESPIRABLE) (RESPIRABLE)
15 MG/M3 10 MG/M3
(TOTAL DUST) (TOTAL DUST)
DIETHYLENETRIAMINE N/E 1 PPM (TWA) 4 MG/M3
(CAS 111-40-0) (REL, TWA)
1 PPM
(REL, TWA)
ADDITIONAL INFORMATION:
AFTER CURE:
PRODUCT FORMS AN INNOCUOUS SOLID. PROCESSING AFTER CURE (GRINDING OR
CUTTING) MAY PRODUCE DUST CONTAINING COMPOUNDS THAT PRESENT AN
INHALATION HAZARD.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PROPERTY PART A PART B
PHYSICAL STATE LIQUID, PASTE LIQUID, PASTE
COLOR WHITE BLACK
ODOR NO SIGNIFICANT STRONG
ODOR SKUNK LIKE
PH 8.4 10.2
FLAMMABILITY LIMIT - LOWER % NO DATA NO DATA
FLAMMABILITY LIMIT - UPPER % NO DATA NO DATA
VAPOR PRESSURE >1 TORR (356 DEG. F NO DATA
180 DEG. C)
VAPOR DENSITY NO DATA NO DATA
SOLUBILITY INSOLUBLE IN WATER APPRECIABLE
FREEZING/MELTING POINT NO DATA NO DATA
BOILING POINT >392 DEG. F NO DATA
(>200 DEG. C)
FLASH POINT >300 DEG. F 172 DEG. F
(>149 DEG. C) (78 DEG. C)
CLOSED CUP CLOSED CUP
EVAPORATION RATE NO DATA NO DATA
DECOMPOSITION TEMPERATURE NO DATA NO DATA
SPECIFIC GRAVITY 1.56 AT 72 DEG. F 1.55 AT 72 DEG. F
(22 DEG. C) (22 DEG. C)
VOC (AFTER CURE) 7 G/L 7 G/L
KOW NO DATA NO DATA
VISCOSITY NO DATA NO DATA
| 10. STABILITY AND REACTIVITY | |
PART A (WHITE SIDE):
REACTIVITY:
THIS PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
CONDITION TO AVOID: HIGH HEAT AND OPEN FLAME.
SUBSTANCES TO AVOID:
STRONG OXIDIZING AGENTS. ACIDS. AMINES. BASES, ALKALIS (ORGANIC).
HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, AND OTHER ORGANIC
COMPOUNDS.
PART B (BLACK SIDE):
REACTIVITY:
THIS PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
CONDITION TO AVOID: HIGH HEAT AND OPEN FLAME.
SUBSTANCES TO AVOID: STRONG OXIDIZING AGENTS. STRONG ACIDS.
HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, AND OTHER ORGANIC
COMPOUNDS.
| 11. TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF EXPOSURE:
INGESTION:
CAUSES DIGESTIVE TRACT BURNS. INGESTION MAY CAUSE IRRITATION TO THE
GASTROINTESTINAL TRACT.
INHALATION:
CAUSES RESPIRATORY TRACT BURNS. IF THIS MATERIAL IS HEATED OR MISTED,
COUGHING AND MILD, TEMPORARY IRRITATION MAY OCCUR.
SKIN CONTACT:
CAUSES SKIN IRRITATION. CAUSES SEVERE SKIN BURNS. MAY CAUSE AN ALLERGIC
SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION. CAUSES SERIOUS EYE BURNS.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
OCCUPATIONAL EXPOSURE TO THE SUBSTANCE OR MIXTURE MAY CAUSE ADVERSE
EFFECTS.
PRODUCT SPECIES TEST RESULT
O-CRESYL GLYCIDYL ETHER (2210-79-9):
ACUTE, DERMAL, LD50 RAT >2000 MG/KG
ACUTE, INHALATION, LC50 RAT >6.1 MG/L, 4 HOURS
ACUTE, ORAL, LD50 RAT >5000 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EYE DAMAGE/EYE IRRITATION:
CAUSES SERIOUS EYE IRRITATION. CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY SENSITIZATION: NO DATA AVAILABLE.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
CONTAINS A COMPONENT THAT IS SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY:
TITANIUM DIOXIDE IS CONSIDERED A CARCINOGEN ONLY IN ITS INHALABLE FORM.
EXPOSURE IS LIKELY ONLY WHEN GRINDING OR CUTTING CURED PRODUCT, ENSURE
GOOD WORK PRACTICE AND USE OF PERSONAL PROTECTIVE EQUIPMENT AS NEEDED
TO CONTROL EXPOSURE.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TITANIUM DIOXIDE (CAS 13463-67-7): 2B POSSIBLY CARCINOGENIC TO HUMANS
WOLLASTONITE (CAS 13983-17-0): 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE.
ASPIRATION HAZARD: NO DATA AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY:
SINGLE EXPOSURE MAY CAUSE DROWSINESS OR DIZZINESS.
REPEATED EXPOSURE NO DATA AVAILABLE.
FURTHER INFORMATION:
TOXICOLOGICAL, ECOTOXICOLOGICAL, PHYSICAL, AND CHEMICAL PROPERTIES MAY NOT
HAVE BEEN FULLY INVESTIGATED. HAZARD DATA ABOVE IS ESTIMATED BASED ON BEST
AVAILABLE INFORMATION. SOME WORKERS WITH PRE-EXISTING MEDICAL CONDITIONS
SUCH AS:
ASTHMA, ALLERGIES, OR IMPAIRED PULMONARY AND/OR LIVER FUNCTIONS, OR WHO MAY
BE PARTICULARLY SUSCEPTIBLE TO THIS MATERIAL, MAY BE AFFECTED BY EXPOSURE
TO THIS MATERIAL.
| 12. ECOLOGICAL INFORMATION | |
GENERAL INFORMATION:
INFORMATION GIVEN IS BASED ON DATA ON THE COMPONENTS AND SIMILAR PRODUCTS.
PART A IS CLASSIFIED AS TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PART B IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. AVOID RELEASE TO
THE ENVIRONMENT.
SUPPORTING DATA:
COMPONENT SPECIES TEST RESULT
BISPHENOL A/EPICHLOROHYDRIN
(25068-38-6):
FISH, LC50 SALMO GAIRDNERI 1.5 MG/L, 96 HOURS
AQUATIC, CRUSTACEA, EC50 DAPHNIA MAGNA 2.7 MG/L, 48 HOURS
TITANIUM DIOXIDE
(CAS 13463-67-7):
AQUATIC, CRUSTACEA, EC50 DAPHNIA >1000 MG/L, 48 HOURS
AQUATIC, FISH, LC50 MUMMICHOG >1000 MG/L, 96 HOURS
PERSISTENCE AND DEGRADABILITY:
THIS PRODUCT IS NOT SUSPECTED TO BE READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE FOR THIS PRODUCT.
MOBILITY IN SOIL: NO DATA AVAILABLE.
FURTHER INFORMATION:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION,
PHOTOCHEMICAL OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION,
GLOBAL WARMING POTENTIAL) ARE EXPECTED FROM THIS PRODUCT.
| 13. DISPOSAL CONSIDERATION | |
WASTE DISPOSAL OF SUBSTANCE:
DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT
CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
CONTAINER DISPOSAL:
EMPTY CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES; FOLLOW LABEL
WARNINGS EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN
TO AN APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
DISPOSAL OF CURED PRODUCT:
GRIND OR CHIP OFF SURFACE. SOLID MATERIAL DOES NOT NEED SPECIAL DISPOSAL
CONSIDERATIONS.
| 14. TRANSPORTATION INFORMATION | |
RESIN (WHITE SIDE):
UN NUMBER: UN3082
UN PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(BISPHENOL-A-EPICHLOROHYDRIN), 9, III, MARINE POLLUTANT
PRECAUTIONS: MARINE POLLUTANT
REQUIRED LABELS: 9
ERG CODE (IATA): 9L
EMS (IMDG): F-A, S-F
HARDENER (BLACK SIDE):
UN NUMBER: UN3259
UN PROPER SHIPPING NAME:
AMINES, SOLID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE), 8, III
PRECAUTIONS: CORROSIVE
REQUIRED LABELS: 8
ERG CODE (IATA): 8L
EMS (IMDG): F-A, S-B
ADDITIONAL INFORMATION:
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT INTENDED TO BE TRANSPORTED IN BULK.
THIS INFORMATION DOES NOT COVER ALL SPECIFIC REGULATORY OR OPERATIONAL
REQUIREMENTS OF THIS PRODUCT. THE CLASSIFICATIONS FOR TRANSPORTATION MAY
VARY BY CONTAINER VOLUME OR DIFFERENT REGIONAL OR NATIONAL REGULATIONS.
| 15. REGULATORY INFORMATION | |
UNITED STATES:
FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES IMMEDIATE DELAYED FIRE PRESSURE REACTIVITY
PART A YES YES NO NO NO
PART B YES YES YES NO NO
US STATE RIGHT-TO-KNOW LISTS:
CHEMICAL MASSACHUSETTS NEW JERSEY PENNSYLVANIA RHODE
RTK WORK AND WORKER AND ISLAND
COMMUNITY COMMUNITY RTK
RTK ACT RTK LAW
DIETHYLENETRIAMINE LISTED LISTED LISTED NOT ON LIST
(CAS 111-40-0)
LIMESTONE LISTED LISTED
(CAS 1317-65-3)
TITANIUM DIOXIDE LISTED LISTED
(CAS 13463-67-7)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS, OR REPRODUCTIVE HARM.
COMPONENT REGULATION % IN BLEND (APPROX.) REMARK
TITANIUM DIOXIDE ACGIH 1-10 CARCINOGENIC
(CAS 13463-67-7)
CANADA:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR AND THE SDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR.
WHMIS CLASSIFICATION:
CLASS E: CORROSIVE
CLASS B-3: COMBUSTIBLE LIQUID
CLASS D-2B: MATERIAL CAUSING OTHER TOXIC EFFECTS
INTERNATIONAL:
INTERNATIONAL INVENTORIES:
COUNTRY OR INVENTORY ON INVENTORY?
REGION (YES/NO)
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES NO
(AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) / NO
NON-DOMESTIC SUBSTANCES LIST (NDSL)
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
| 16. OTHER INFORMATION | |
DATE PREPARED OR REVISED: SEPTEMBER 2014
SUPERSEDES: AUGUST 2012
ADDITIONAL PART A (WHITE SIDE) CLASSIFICATIONS:
NFPA RATINGS:
2
1
0
HMIS RATING:
HEALTH HAZARD 2
FLAMMABILITY HAZARD 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
ADDITIONAL PART B (BLACK SIDE) CLASSIFICATIONS:
NFPA RATINGS:
3
2
0
HMIS RATING:
HEALTH HAZARD 3
FLAMMABILITY HAZARD 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
ABBREVIATIONS:
ACGIH:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
CAS NO.: CHEMICAL ABSTRACT SERVICE REGISTRY NUMBER
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT
(U.S. EPA)
CPR: CONTROLLED PRODUCT REGULATIONS (CANADA)
DOT: DEPARTMENT OF TRANSPORTATION (U.S.)
EPA: ENVIRONMENTAL PROTECTION AGENCY (U.S.)
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
HEPA: HIGH-EFFICIENCY PARTICULATE AIR
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS CODE
LPP: LIMITE PERMISIBLE PONDERADO (CHILE)
NIOSH:
NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH (U.S.)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (US)
NTP: NATIONAL TOXICOLOGY PROGRAM (US)
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (U.S.)
PEL: PERMISSIBLE EXPOSURE LIMIT
SARA:
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (U.S. EPA)
SDS: SAFETY DATA SHEET
STEL:
SHORT TERM EXPOSURE LIMIT (15 MINUTE TIME WEIGHTED AVERAGE)
STOT: SPECIFIC TARGET ORGAN TOXICITY (GHS CLASSIFICATION)
TLV: THRESHOLD LIMIT VALUE
TSCA: TOXIC SUBSTANCES CONTROL ACT (U.S.)
TWA:
TIME WEIGHTED AVERAGE (EXPOSURE FOR 8-HOUR WORKDAY)
U.S.: UNITED STATES
VOC: VOLATILE ORGANIC COMPOUNDS
WHMIS:
CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM
DISCLAIMER:
THIS SAFETY DATA SHEET (SDS) IS PREPARED BY SIMPSON STRONG-TIE CO. IN
COMPLIANCE WITH THE REQUIREMENTS OF OSHA 29 CFR PART 1910.1200. THE
INFORMATION IT CONTAINS IS OFFERED IN GOOD FAITH AS ACCURATE AS OF THE
DATE OF THIS SDS. THIS SDS IS PROVIDED SOLELY FOR THE PURPOSE OF CONVEYING
HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION. NO WARRANTY, EXPRESSED OR
IMPLIED, IS GIVEN. HEALTH AND SAFETY PRECAUTIONS MAY NOT BE ADEQUATE FOR
ALL INDIVIDUALS AND/OR SITUATIONS. IT IS THE USER'S OBLIGATION TO EVALUATE
AND USE THIS PRODUCT SAFELY AND TO COMPLY WITH ALL APPLICABLE LAWS AND
REGULATIONS.
(C) 2014 SIMPSON STRONG-TIE COMPANY INC.
INTERNAL:
FOR INTERNAL USE ONLY:
ETR PART A:
XCOM3B - 50% CARTRIDGE
ETR PART B:
XCOM3A - 50% CARTRIDGE
XCORR - 50% CARTRIDGE