| Common Name: | SCOTCH-WELD THREADLOCKER TL42, BLUE |
| Manufacturer: | 3M |
| SDS Revision Date: | 12/7/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 2XLH9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SCOTCH-WELD(TM) THREADLOCKER TL42, BLUE
12/07/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 32-6766-3
VERSION NUMBER: 3.00
ISSUE DATE: 12/07/17
SUPERCEDES DATE: 05/31/16
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) SCOTCH-WELD(TM) THREADLOCKER TL42, BLUE
PRODUCT IDENTIFICATION NUMBERS:
62-3494-0160-4, 62-3494-1060-5, 62-3494-1065-4, 62-3494-3960-4,
62-3494-5060-1, 62-3494-8360-2
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: STRUCTURAL ADHESIVE
1.3. SUPPLIER'S DETAILS
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER, ST. PAUL
MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
SKIN SENSITIZER: CATEGORY 1.
CARCINOGENICITY: CATEGORY 1B.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE: NERVOUS
SYSTEM
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
TRIETHYLENE GLYCOL 109-16-0 30 - 50 TRADE SECRET *
DIISOPROPYLNAPHTHALENE 38640-62-9 20 - 40 TRADE SECRET *
DIMETHACRYLATE
AMORPHOUS SILICA 68909-20-6 1 - 10 TRADE SECRET *
HYDROXYPROPYL 27813-02-1 1 - 10 TRADE SECRET *
METHACRYLATE
POLYESTER RESIN (NJTS TRADE SECRET* 1 - 10 TRADE SECRET *
REG. NO. 04499600-7087)
CUMENE HYDROPEROXIDE 80-15-9 1 - 5 TRADE SECRET *
SACCHARIN 81-07-2 1 - 5 TRADE SECRET *
ACRYLIC ACID 79-10-7 <= 1 TRADE SECRET *
1-ACETYL-2-PHENYLHYDRAZINE 114-83-0 <= 0.8 TRADE SECRET *
N,N-DIMETHYL-P-TOLUIDINE 99-97-8 <= 0.5 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
OXIDES OF SULFUR DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE,
CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS,
ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
PROTECT FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
SILICA, AMORPHOUS 68909-20-6 OSHA TWA CONCENTRATION:
0.8 MG/M3
TWA: 20 MILLIONS
OF PARTICLES/CU.
FT.
ACRYLIC ACID 79-10-7 ACGIH TWA: 2 PPM SKIN, A4:
NOT CLASS. AS
HUMAN CARCIN
CUMENE 80-15-9 AIHA TWA: 6 MG/M3(1 PPM) SKIN
HYDROPEROXIDE
N,N-DIMETHYL-P- 99-97-8 AIHA TWA: 0.5 PPM
TOLUIDINE
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR ORGANIC VAPORS AND
PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: THIXOTROPIC LIQUID
ODOR, COLOR, GRADE: MILD ODOR, BLUE LIQUID
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=300 DEG. F [@ 760 MMHG]
FLASH POINT: >=212 DEG. F [TEST METHOD: TAGLIABUE CLOSED CUP]
EVAPORATION RATE: NEGLIGIBLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=5 MMHg
VAPOR DENSITY: 1.01 [REF STD: AIR=1]
DENSITY: 1.1 G/ML [@ 20 DEG. C]
SPECIFIC GRAVITY: 1.1 [@ 20 DEG. C] [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
10,000 - 18,000 CENTIPOISE [@ 20 DEG. C ] [TEST METHOD. BROOKFIELD]
HAZARDOUS AIR POLLUTANTS:
<2 % WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
<15 G/L [TESTMETHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
LIGHT
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
CARCINOGENICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
N,N-DIMETHYL-P-TOLUIDINE 99-97-8 GRP. 2B: INTERNATIONAL
POSSIBLE HUMAN AGENCY FOR
CARC. RESEARCH ON
CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE
VAPOR(4 HR) CALCULATED ATE:
>50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE
CALCULATED ATE:
>5,000 MG/KG
TRIETHYLENE GLYCOL DERMAL PROFESSIONAL LD50 ESTIMATED TO BE:
DIMETHACRYLATE JUDGMENT >5,000 MG/KG
TRIETHYLENE GLYCOL INGESTION RAT LD50: 10,837 MG/KG
DIMETHACRYLATE
HYDROXYPROPYL DERMAL RABBIT LD50: >5,000 MG/KG
METHACRYLATE
HYDROXYPROPYL INGESTION RAT LD50: >2,000 MG/KG
METHACRYLATE
AMORPHOUS SILICA DERMAL RABBIT LD50: >5,000 MG/KG
AMORPHOUS SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
AMORPHOUS SILICA INGESTION RAT LD50: >5,110 MG/KG
SACCHARIN DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
SACCHARIN INGESTION MOUSE LD50: 17,000 MG/KG
CUMENE DERMAL RAT LD50: 500 MG/KG
HYDROPEROXIDE
CUMENE INHALATION- RAT LC50: 1.4 MG/L
HYDROPEROXIDE VAPOR
(4 HOURS)
CUMENE INGESTION RAT LD50: 382 MG/KG
HYDROPEROXIDE
ACRYLIC ACID DERMAL RABBIT LD50: >2,000 MG/KG
ACRYLIC ACID INHALATION- RAT LC50: 3.8 MG/L
DUST/MIST
(4 HOURS)
ACRYLIC ACID INGESTION RAT LD50: 1,250 MG/KG
1-ACETYL-2- DERMAL LD50 ESTIMATED TO BE
PHENYLHYDRAZINE 200 - 1,000 MG/KG
1-ACETYL-2- INGESTION MOUSE LD50: 270 MG/KG
PHENYLHYDRAZINE
N,N-DIMETHYL-P- DERMAL RABBIT LD50: >2,000 MG/KG
TOLUIDINE
N,N-DIMETHYL-P- INHALATION- RAT LC50: 1.4 MG/L
TOLUIDINE DUST/MIST
(4 HOURS)
N,N-DIMETHYL-P- INGESTION RAT LD50: 1,650 MG/KG
TOLUIDINE
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TRIETHYLENE GLYCOL DIMETHACRYLATE GUINEA PIG MILD IRRITANT
HYDROXYPROPYL METHACRYLATE RABBIT MINIMAL IRRITATION
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
ACRYLIC ACID RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TRIETHYLENE GLYCOL PROFESSIONAL MODERATE IRRITANT
DIMETHACRYLATE JUDGMENT
HYDROXYPROPYL METHACRYLATE RABBIT MODERATE IRRITANT
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
ACRYLIC ACID RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
TRIETHYLENE GLYCOL HUMAN AND ANIMAL SENSITIZING
DIMETHACRYLATE
HYDROXYPROPYL METHACRYLATE HUMAN AND ANIMAL SENSITIZING
AMORPHOUS SILICA HUMAN AND ANIMAL NOT CLASSIFIED
ACRYLIC ACID GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TRIETHYLENE GLYCOL IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
DIMETHACRYLATE ARE NOT SUFFICIENT FOR CLASSIFICATION
HYDROXYPROPYL IN VIVO NOT MUTAGENIC
METHACRYLATE
HYDROXYPROPYL IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
METHACRYLATE ARE NOT SUFFICIENT FOR CLASSIFICATION
AMORPHOUS SILICA IN VITRO NOT MUTAGENIC
CUMENE IN VIVO NOT MUTAGENIC
HYDROPEROXIDE
CUMENE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
HYDROPEROXIDE ARE NOT SUFFICIENT FOR CLASSIFICATION
ACRYLIC ACID IN VIVO NOT MUTAGENIC
ACRYLIC ACID IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TRIETHYLENE GLYCOL DERMAL MOUSE NOT CARCINOGENIC
DIMETHACRYLATE
HYDROXYPROPYL INHALATION MULTIPLE NOT CARCINOGENIC
METHACRYLATE ANIMAL SPECIES
AMORPHOUS SILICA NOT SPECIFIED MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ACRYLIC ACID INGESTION RAT NOT CARCINOGENIC
ACRYLIC ACID DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
N,N-DIMETHYL-P- INGESTION MULTIPLE CARCINOGENIC
TOLUIDINE ANIMAL
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
TRIETHYLENE GLYCOL DIMETHACRYLATE INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
TRIETHYLENE GLYCOL DIMETHACRYLATE INGESTION NOT CLASSIFIED FOR
MALE REPRODUCTION
TRIETHYLENE GLYCOL DIMETHACRYLATE INGESTION NOT CLASSIFIED FOR
DEVELOPMENT
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR
MALE REPRODUCTION
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR
DEVELOPMENT
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR
MALE REPRODUCTION
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR
DEVELOPMENT
ACRYLIC ACID INGESTION NOT CLASSIFIED FOR
FEMALE REPRODUCTION
ACRYLIC ACID INGESTION NOT CLASSIFIED FOR
MALE REPRODUCTION
ACRYLIC ACID INHALATION NOT CLASSIFIED FOR
DEVELOPMENT
ACRYLIC ACID INGESTION NOT CLASSIFIED FOR
DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
TRIETHYLENE GLYCOL MOUSE NOAEL: 1 GENERATION
DIMETHACRYLATE 1 MG/KG/DAY
TRIETHYLENE GLYCOL MOUSE NOAEL: 1 GENERATION
DIMETHACRYLATE 1 MG/KG/DAY
TRIETHYLENE GLYCOL MOUSE NOAEL: 1 GENERATION
DIMETHACRYLATE 1 MG/KG/DAY
HYDROXYPROPYL RAT NOAEL: PREMATING INTO
METHACRYLATE 1,000 MG/KG/DAY LACTATION
HYDROXYPROPYL RAT NOAEL: 49 DAYS
METHACRYLATE 1,000 MG/KG/DAY
HYDROXYPROPYL RAT NOAEL: DURING GESTATION
METHACRYLATE 1,000 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: DURING ORGANOGENESIS
1,350 MG/KG/DAY
ACRYLIC ACID RAT NOAEL: 2 GENERATION
460 MG/KG/DAY
ACRYLIC ACID RAT NOAEL: 2 GENERATION
460 MG/KG/DAY
ACRYLIC ACID RAT NOAEL: DURING ORGANOGENESIS
1.1 MG/L
ACRYLIC ACID RAT NOAEL: 2 GENERATION
53 MG/KG/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
HYDROXYPROPYL INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
METHACRYLATE EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HAZARDS
CUMENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
HYDROPEROXIDE SYSTEM DEPRESSION OR HUMAN DIZZINESS
CUMENE INHALATION RESPIRATORY IRRITATION MAY CAUSE RESPIRATORY
HYDROPEROXIDE IRRITATION
CUMENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
HYDROPEROXIDE SYSTEM DEPRESSION DIZZINESS
ACRYLIC ACID INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROXYPROPYL SIMILAR NOAEL:
METHACRYLATE HEALTH NOT AVAILABLE
HAZARDS
CUMENE HUMAN NOAEL: OCCUPATIONAL
HYDROPEROXIDE NOT AVAILABLE EXPOSURE
CUMENE HUMAN NOAEL: OCCUPATIONAL
HYDROPEROXIDE NOT AVAILABLE EXPOSURE
CUMENE PROFESSIONAL NOAEL:
HYDROPEROXIDE JUDGEMENT NOT AVAILABLE
ACRYLIC ACID HUMAN NOAEL:
NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TRIETHYLENE GLYCOL DERMAL KIDNEY AND/OR NOT CLASSIFIED
DIMETHACRYLATE BLADDER
BLOOD
HYDROXYPROPYL INHALATION BLOOD NOT CLASSIFIED
METHACRYLATE
HYDROXYPROPYL INGESTION HEMATOPOIETIC NOT CLASSIFIED
METHACRYLATE SYSTEM
HEART
ENDOCRINE SYSTEM
LIVER
IMMUNE SYSTEM
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
AMORPHOUS INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
SILICA SILICOSIS
CUMENE INHALATION NERVOUS SYSTEM CAUSES DAMAGE TO
HYDROPEROXIDE RESPIRATORY SYSTEM ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
CUMENE INHALATION HEART NOT CLASSIFIED
HYDROPEROXIDE LIVER
KIDNEY AND/OR
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
TRIETHYLENE GLYCOL MOUSE NOAEL: 78 WEEKS
DIMETHACRYLATE 833 MG/KG/DAY
HYDROXYPROPYL RAT NOAEL: 21 DAYS
METHACRYLATE 0.5 MG/L
HYDROXYPROPYL RAT NOAEL: 41 DAYS
METHACRYLATE 1,000 MG/KG/DAY
AMORPHOUS SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
CUMENE RAT LOAEL: 7 DAYS
HYDROPEROXIDE 0.2 MG/L
CUMENE RAT NOAEL: 90 DAYS
HYDROPEROXIDE 0.03 MG/L
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF
ADDITIONAL FUEL DURING INCINERATION PROCESSES.
AS A DISPOSAL ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL
FACILITY. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
CARCINOGENICITY
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
SACCHARIN 81-07-2 TRADE SECRET 1 - 5
CUMENE HYDROPEROXIDE 80-15-9 TRADE SECRET 1 - 5
ACRYLIC ACID 79-10-7 TRADE SECRET <=1
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 32-6766-3
VERSION NUMBER: 3.00
ISSUE DATE: 12/07/17
SUPERCEDES DATE: 05/31/16
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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