| Common Name: | SCOTCH-WELD GENERAL PURPOSE PIPE SEALANT PS65, WHITE |
| Manufacturer: | 3M |
| SDS Revision Date: | 12/11/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 2XLN2, 2XLN3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SCOTCH-WELD(TM) GENERAL PURPOSE PIPE SEALANT PS65, WHITE
12/11/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 32-7559-1
VERSION NUMBER: 2.00
ISSUE DATE: 12/11/17
SUPERCEDES DATE: 09/11/14
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) SCOTCH-WELD(TM) GENERAL PURPOSE PIPE SEALANT PS65, WHITE
PRODUCT IDENTIFICATION NUMBERS:
62-3701-3967-7, 62-3701-5067-4, 62-3701-5068-2, 62-3701-8360-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
REPRODUCTIVE TOXICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
34% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYETHYLENE GLYCOL DIMETHACRYLATE 25852-47-5 30 - 60 TRADE SECRET *
TETRAETHYLENE GLYCOL DIOCTANOATE 18268-70-7 15 - 40 TRADE SECRET *
CELLULOSE ESTER 9004-36-8 10 - 30 TRADE SECRET *
FLUOROPOLYMER (NJTS REG. NO. TRADE SECRET* 1 - 10 TRADE SECRET *
04499600-6701)
AMORPHOUS TREATED SILICA 112945-52-5 <=5 TRADE SECRET *
CUMENE HYDROPEROXIDE 80-15-9 1 - 5 TRADE SECRET *
SACCHARIN 81-07-2 1 - 5 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 1 - 5 TRADE SECRET *
METHYL ALCOHOL 67-56-1 <1 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
OXIDES OF SULFUR DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN
SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) USE
PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
PROTECT FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
SILICA, 112945-52-5 OSHA TWA CONCENTRATION:
AMORPHOUS 0.8 MG/M3
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
TITANIUM 13463-67-7 ACGIH TWA: 10 MG/M3 A4:
DIOXIDE NOT CLASS. AS
HUMAN CARCIN
TITANIUM 13463-67-7 OSHA TWA (AS TOTAL DUST):
DIOXIDE 15 MG/M3
METHYL ALCOHOL 67-56-1 ACGIH TWA: 200 PPM SKIN
STEL: 250 PPM
METHYL ALCOHOL 67-56-1 OSHA TWA:
260 MG/M3 (200 PPM)
CUMENE 80-15-9 AIHA TWA: 6 MG/M3 (1 PPM) SKIN
HYDROPEROXIDE
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: FLUOROELASTOMER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR ORGANIC VAPORS AND
PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: WHITE PASTE MILD ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=300 DEG. F [@ 760 MMHg]
FLASH POINT: >=212 DEG. F [TEST METHOD:TAGLIABUE CLOSED CUP]
EVAPORATION RATE: NEGLIGIBLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=5 MMHg
VAPOR DENSITY: 1.01 [REF STD: AIR=1]
DENSITY: 1.1 G/ML [@ 20 DEG. C]
SPECIFIC GRAVITY: 1.1 [@ 20 DEG. C] [REF STD:WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
300,000 - 400,000 CENTIPOISE [@ 20 DEG. C ] [TEST METHOD: BROOKFIELD]
HAZARDOUS AIR POLLUTANTS: <1 % WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
<15 G/L [TESTMETHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
LIGHT
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN CARC. FOR RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR (4 HR) CALCULATED ATE >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
POLYETHYLENE DERMAL LD50 ESTIMATED TO BE
GLYCOL >5,000 MG/KG
DIMETHACRYLATE
POLYETHYLENE INGESTION RAT LD50: >5,000 MG/KG
GLYCOL
DIMETHACRYLATE
TETRAETHYLENE DERMAL RABBIT LD50: >20,000 MG/KG
GLYCOL
DIOCTANOATE
TETRAETHYLENE INGESTION RAT LD50: 18,000 MG/KG
GLYCOL
DIOCTANOATE
CELLULOSE ESTER DERMAL GUINEA PIG LD50: >1,000 MG/KG
CELLULOSE ESTER INGESTION RAT LD50: >6,400 MG/KG
FLUOROPOLYMER DERMAL LD50 ESTIMATED TO BE
(NJTS REG. NO. >5,000 MG/KG
04499600-6701)
FLUOROPOLYMER INGESTION LD50 ESTIMATED TO BE
(NJTS REG. NO. >5,000 MG/KG
04499600-6701)
AMORPHOUS DERMAL RABBIT LD50: >5,000 MG/KG
TREATED SILICA
AMORPHOUS INHALATION- RAT LC50: >0.691 MG/L
TREATED SILICA DUST/MIST
(4 HOURS)
AMORPHOUS INGESTION RAT LD50: >5,110 MG/KG
TREATED SILICA
SACCHARIN DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
SACCHARIN INGESTION MOUSE LD50: 17,000 MG/KG
CUMENE DERMAL RAT LD50: 500 MG/KG
HYDROPEROXIDE
CUMENE INHALATION- RAT LC50: 1.4 MG/L
HYDROPEROXIDE VAPOR
(4 HOURS)
CUMENE INGESTION RAT LD50: 382 MG/KG
HYDROPEROXIDE
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
METHYL ALCOHOL DERMAL LD50 ESTIMATED TO BE
1,000 - 2,000 MG/KG
METHYL ALCOHOL INHALATION- LC50 ESTIMATED TO BE
VAPOR 10 - 20 MG/L
METHYL ALCOHOL INGESTION LD50 ESTIMATED TO BE
50 - 300 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
CELLULOSE ESTER GUINEA PIG MINIMAL IRRITATION
FLUOROPOLYMER HUMAN AND NO SIGNIFICANT IRRITATION
(NJTS REG. NO. 04499600-6701) ANIMAL
AMORPHOUS TREATED SILICA RABBIT NO SIGNIFICANT IRRITATION
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
METHYL ALCOHOL RABBIT MILD IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
FLUOROPOLYMER PROFESSIONAL NO SIGNIFICANT IRRITATION
(NJTS REG. NO. 04499600-6701) JUDGEMENT
AMORPHOUS TREATED SILICA RABBIT NO SIGNIFICANT IRRITATION
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
METHYL ALCOHOL RABBIT MODERATE IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
CELLULOSE ESTER GUINEA PIG NOT CLASSIFIED
FLUOROPOLYMER HUMAN NOT CLASSIFIED
(NJTS REG. NO. 04499600-6701)
AMORPHOUS TREATED SILICA HUMAN AND ANIMAL NOT CLASSIFIED
TITANIUM DIOXIDE HUMAN AND ANIMAL NOT CLASSIFIED
METHYL ALCOHOL GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
AMORPHOUS TREATED SILICA IN VITRO NOT MUTAGENIC
CUMENE HYDROPEROXIDE IN VIVO NOT MUTAGENIC
CUMENE HYDROPEROXIDE IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
METHYL ALCOHOL IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ALCOHOL IN VIVO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
FLUOROPOLYMER NOT MULTIPLE SOME POSITIVE DATA
(NJTS REG. NO. 04499600-6701) SPECIFIED ANIMAL EXIST, BUT THE DATA
SPECIES ARE NOT SUFFICIENT
FOR CLASSIFICATION
AMORPHOUS TREATED SILICA NOT MOUSE SOME POSITIVE DATA
SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
METHYL ALCOHOL INHALATION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
AMORPHOUS TREATED SILICA INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
AMORPHOUS TREATED SILICA INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
AMORPHOUS TREATED SILICA INGESTION NOT CLASSIFIED FOR DEVELOPMENT
METHYL ALCOHOL INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
METHYL ALCOHOL INGESTION TOXIC TO DEVELOPMENT
METHYL ALCOHOL INHALATION TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
AMORPHOUS TREATED SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
AMORPHOUS TREATED SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
AMORPHOUS TREATED SILICA RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
METHYL ALCOHOL RAT NOAEL: 21 DAYS
1,600 MG/KG/DAY
METHYL ALCOHOL MOUSE LOAEL: DURING
4,000 MG/KG/DAY ORGANOGENESIS
METHYL ALCOHOL MOUSE NOAEL: 1.3 MG/L DURING
ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CUMENE HYDROPEROXIDE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
CUMENE HYDROPEROXIDE INHALATION RESPIRATORY MAY CAUSE
IRRITATION RESPIRATORY
IRRITATION
CUMENE HYDROPEROXIDE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ALCOHOL INHALATION BLINDNESS CAUSES DAMAGE TO
ORGANS
METHYL ALCOHOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ALCOHOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ALCOHOL INGESTION BLINDNESS CAUSES DAMAGE TO
ORGANS
METHYL ALCOHOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
CUMENE HYDROPEROXIDE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
CUMENE HYDROPEROXIDE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
CUMENE HYDROPEROXIDE PROFESSIONAL NOAEL:
JUDGEMENT NOT AVAILABLE
METHYL ALCOHOL HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
METHYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE
NOT AVAILABLE
METHYL ALCOHOL RAT NOAEL: 6 HOURS
NOT AVAILABLE
METHYL ALCOHOL HUMAN NOAEL: POISONING AND/OR
NOT AVAILABLE ABUSE
METHYL ALCOHOL HUMAN NOAEL: POISONING AND/OR
NOT AVAILABLE ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
FLUOROPOLYMER (NJTS REG. INGESTION HEMATOPOIETIC NOT CLASSIFIED
NO. 04499600-6701) SYSTEM
AMORPHOUS TREATED SILICA INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
SILICOSIS
CUMENE HYDROPEROXIDE INHALATION NERVOUS SYSTEM CAUSES DAMAGE TO
RESPIRATORY SYSTEM ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
CUMENE HYDROPEROXIDE INHALATION HEART NOT CLASSIFIED
LIVER
KIDNEY AND/OR
BLADDER
TITANIUM DIOXIDE INHALATION RESPIRATORY SYSTEM SOME POSITIVE
DATA EXIST, BUT
THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY FIBROSIS NOT CLASSIFIED
METHYL ALCOHOL INHALATION LIVER NOT CLASSIFIED
METHYL ALCOHOL INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
METHYL ALCOHOL INGESTION LIVER NOT CLASSIFIED
NERVOUS SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
FLUOROPOLYMER (NJTS REG. RAT NOAEL: 90 DAYS
NO. 04499600-6701) NOT AVAILABLE
AMORPHOUS TREATED SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
CUMENE HYDROPEROXIDE RAT LOAEL: 0.2 MG/L 7 DAYS
CUMENE HYDROPEROXIDE RAT NOAEL: 0.03 MG/L 90 DAYS
TITANIUM DIOXIDE RAT LOAEL: 0.01 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
METHYL ALCOHOL RAT NOAEL: 6.55 MG/L 4 WEEKS
METHYL ALCOHOL RAT NOAEL: 13.1 MG/L 6 WEEKS
METHYL ALCOHOL RAT NOAEL: 90 DAYS
2,500 MG/KG/DAY
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
SACCHARIN 81-07-2 TRADE SECRET 1 - 5
CUMENE HYDROPEROXIDE 80-15-9 TRADE SECRET 1 - 5
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 32-7559-1
VERSION NUMBER: 2.00
ISSUE DATE: 12/11/17
SUPERCEDES DATE: 09/11/14
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE3MPRODUCT IS FIT FOR
A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL,IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M PRODUCT
TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR
USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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