| Common Name: | SCOTCH-WELD GASKET MAKER GM18, RED |
| Manufacturer: | 3M |
| SDS Revision Date: | 1/19/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2XLP1, 2XLP2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) SCOTCH-WELD(TM) GASKET MAKER GM18, RED
01/19/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 32-7227-5
VERSION NUMBER: 2.01
ISSUE DATE: 01/19/18
SUPERCEDES DATE: 06/15/16
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) SCOTCH-WELD(TM) GASKET MAKER GM18, RED
PRODUCT IDENTIFICATION NUMBERS:
62-3454-3362-7, 62-3454-5067-0, 62-3454-5068-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1C.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BUMS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/
SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/
NATIONAL/INTERNATIONAL REGULATIONS.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
5% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYURETHANE RESIN TRADE SECRET* 40 - 70 TRADE SECRET*
(NJTS REG. NO. 04499600-7086)
HYDROXYPROPYL METHACRYLATE 27813-02-1 10 - 30 TRADE SECRET*
POLYETHYLENE GLYCOL 25852-47-5 10 - 30 TRADE SECRET*
DIMETHACRYLATE
AMORPHOUS SILICA 67762-90-7 1 - 10 TRADE SECRET*
ACRYLIC ACID 79-10-7 1 - 5 TRADE SECRET*
CUMENE HYDROPEROXIDE 80-15-9 1 - 5 TRADE SECRET*
SACCHARIN 81-07-2 1 - 5 TRADE SECRET*
1-ACETYL-2-PHENYLHYDRAZINE 114-83-0 <0.5 TRADE SECRET*
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
OXIDES OF SULFUR DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. FOR LARGE SPILLS, IF NECESSARY, GET ASSISTANCE FROM
PROFESSIONAL SPILL CLEAN UP TEAM. FOR SMALL SPILLS, CAREFULLY COVER THE
SPILL WITH SODA ASH (SODIUM CARBONATE) OR SODIUM BICARBONATE. WORK FROM
AROUND THE PERIMETER INWARD. AVOID SPLASHING. ADD ENOUGH WATER TO EASE
MIXING AND STIR. CONTINUE STIRRING AND ADDING WATER AND NEUTRALIZING AGENT
UNTIL THE REACTION STOPS. LET COOL BEFORE COLLECTING. OR USE A COMMERCIALLY
AVAILABLE 'ACID SPILL' CLEAN-UP KIT. FOLLOW THE KIT DIRECTIONS EXACTLY, AS
SPECIFIED. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH
BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A METAL CONTAINER APPROVED FOR USE IN TRANSPORTATION BY
APPROPRIATE AUTHORITIES. THE CONTAINER MUST BE LINED WITH POLYETHYLENE
PLASTIC OR CONTAIN A PLASTIC DRUM LINER MADE OF POLYETHYLENE. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE
ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS
(EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
PROTECT FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
SILICA, AMORPHOUS 67762-90-7 OSHA TWA CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS
OF PARTICLES/CU. FT.
ACRYLIC ACID 79-10-7 ACGIH TWA: 2 PPM SKIN, A4:
NOT CLASS.
AS HUMAN
CARCIN
CUMENE HYDROPEROXIDE 80-15-9 AIHA TWA: 6 MG/M3(1 PPM) SKIN
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: BUTYL RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES FOR QUESTIONS ABOUT SUITABILITY FOR A
SPECIFIC APPLICATION, CONSULT WITH YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: THIXOTROPIC LIQUID
ODOR, COLOR, GRADE: RED GEL SHARP ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=300 DEG. F [@ 760 MMHG]
FLASH POINT: >=212 DEG. F [TEST METHOD:TAGLIABUE CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
EVAPORATION RATE: NEGLIGIBLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=10 MMHg
VAPOR DENSITY: 1.01 [REF STD: AIR=1]
DENSITY: 1.08 G/ML [@ 20 DEG. C]
SPECIFIC GRAVITY: 1.08 [@ 20 DEG. C] [REF STD:WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 500,000 CENTIPOISE [@ 20 DEG. C ]
HAZARDOUS AIR POLLUTANTS: <2 % WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
<5 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
LIGHT
10.5. INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION: SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING,
NASAL DISCHARGE, HEADACHE, HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
CORROSIVE (SKIN BURNS): SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS,
SWELLING, ITCHING, INTENSE PAIN, BLISTERING, ULCERATION, AND TISSUE
DESTRUCTION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED): SIGNS/SYMPTOMS MAY INCLUDE
REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE:
>50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
HYDROXYPROPYL METHACRYLATE DERMAL RABBIT LD50: >5,000 MG/KG
HYDROXYPROPYL METHACRYLATE INGESTION RAT LD50: >2,000 MG/KG
POLYETHYLENE GLYCOL DERMAL LD50 ESTIMATED TO
DIMETHACRYLATE BE >5,000 MG/KG
POLYETHYLENE GLYCOL INGESTION RAT LD50: >5,000 MG/KG
DIMETHACRYLATE
AMORPHOUS SILICA DERMAL RABBIT LD50: >5,000 MG/KG
AMORPHOUS SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
AMORPHOUS SILICA INGESTION RAT LD50: >5,110 MG/KG
ACRYLIC ACID DERMAL RABBIT LD50: >2,000 MG/KG
ACRYLIC ACID INHALATION- RAT LC50: 3.8 MG/L
DUST/MIST
(4 HOURS)
ACRYLIC ACID INGESTION RAT LD50: 1,250 MG/KG
SACCHARIN DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
SACCHARIN INGESTION MOUSE LD50: 17,000 MG/KG
CUMENE HYDROPEROXIDE DERMAL RAT LD50: 500 MG/KG
CUMENE HYDROPEROXIDE INHALATION- RAT LC50: 1.4 MG/L
VAPOR
(4 HOURS)
CUMENE HYDROPEROXIDE INGESTION RAT LD50: 382 MG/KG
1-ACETYL-2-PHENYLHYDRAZINE DERMAL LD50 ESTIMATED TO BE
200 - 1,000 MG/KG
1-ACETYL-2-PHENYLHYDRAZINE INGESTION MOUSE LD50: 270 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
HYDROXYPROPYL METHACRYLATE RABBIT MINIMAL IRRITATION
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
ACRYLIC ACID RABBIT CORROSIVE
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
HYDROXYPROPYL METHACRYLATE RABBIT MODERATE IRRITANT
AMORPHOUS SILICA RABBIT NO SIGNIFICANT IRRITATION
ACRYLIC ACID RABBIT CORROSIVE
CUMENE HYDROPEROXIDE RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
HYDROXYPROPYL METHACRYLATE HUMAN AND ANIMAL SENSITIZING
AMORPHOUS SILICA HUMAN AND ANIMAL NOT CLASSIFIED
ACRYLIC ACID GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
HYDROXYPROPYL METHACRYLATE IN VIVO NOT MUTAGENIC
HYDROXYPROPYL METHACRYLATE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
AMORPHOUS SILICA IN VITRO NOT MUTAGENIC
ACRYLIC ACID IN VIVO NOT MUTAGENIC
ACRYLIC ACID IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
CUMENE HYDROPEROXIDE IN VIVO NOT MUTAGENIC
CUMENE HYDROPEROXIDE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
HYDROXYPROPYL METHACRYLATE INHALATION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
AMORPHOUS SILICA NOT MOUSE SOME POSITIVE DATA EXIST,
SPECIFIED BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACRYLIC ACID INGESTION RAT NOT CARCINOGENIC
ACRYLIC ACID DERMAL MOUSE SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
HYDROXYPROPYL METHACRYLATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
AMORPHOUS SILICA INGESTION NOT CLASSIFIED FOR DEVELOPMENT
ACRYLIC ACID INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
ACRYLIC ACID INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
ACRYLIC ACID INHALATION NOT CLASSIFIED FOR DEVELOPMENT
ACRYLIC ACID INGESTION NOT CLASSIFIED FOR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROXYPROPYL METHACRYLATE RAT NOAEL: PREMATING INTO
1,000 MG/KG/DAY LACTATION
HYDROXYPROPYL METHACRYLATE RAT NOAEL: 49 DAYS
1,000 MG/KG/DAY
HYDROXYPROPYL METHACRYLATE RAT NOAEL: DURING
1,000 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: 1 GENERATION
509 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: 1 GENERATION
497 MG/KG/DAY
AMORPHOUS SILICA RAT NOAEL: DURING
1,350 MG/KG/DAY ORGANOGENESIS
ACRYLIC ACID RAT NOAEL:
460 MG/KG/DAY 2 GENERATION
ACRYLIC ACID RAT NOAEL: 2 GENERATION
460 MG/KG/DAY
ACRYLIC ACID RAT NOAEL: DURING
1.1 MG/L ORGANOGENESIS
ACRYLIC ACID RAT NOAEL: 2 GENERATION
53 MG/KG/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
HYDROXYPROPYL INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
METHACRYLATE IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACRYLIC ACID INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CUMENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
HYDROPEROXIDE SYSTEM DEPRESSION DIZZINESS
CUMENE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
HYDROPEROXIDE IRRITATION IRRITATION
CUMENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
HYDROPEROXIDE SYSTEM DEPRESSION DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROXYPROPYL SIMILAR HEALTH NOAEL:
METHACRYLATE HAZARDS NOT AVAILABLE
ACRYLIC ACID HUMAN NOAEL:
NOT AVAILABLE
CUMENE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
HYDROPEROXIDE NOT AVAILABLE
CUMENE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
HYDROPEROXIDE NOT AVAILABLE
CUMENE PROFESSIONAL NOAEL:
HYDROPEROXIDE JUDGMENT NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
HYDROXYPROPYL INHALATION BLOOD NOT CLASSIFIED
METHACRYLATE
HYDROXYPROPYL INGESTION HEMATOPOIETIC NOT CLASSIFIED
METHACRYLATE SYSTEM HEART
ENDOCRINE SYSTEM
LIVER IMMUNE
SYSTEM NERVOUS
SYSTEM KIDNEY
AND/OR BLADDER
AMORPHOUS SILICA INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
SILICOSIS
CUMENE INHALATION NERVOUS SYSTEM CAUSES DAMAGE TO ORGANS
HYDROPEROXIDE RESPIRATORY THROUGH PROLONGED OR
SYSTEM REPEATED EXPOSURE
CUMENE INHALATION HEART LIVER NOT CLASSIFIED
HYDROPEROXIDE KIDNEY AND/OR
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROXYPROPYL RAT NOAEL: 0.5 MG/L 21 DAYS
METHACRYLATE
HYDROXYPROPYL RAT NOAEL: 41 DAYS
1,000 MG/KG/DAY
AMORPHOUS SILICA HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
CUMENE
HYDROPEROXIDE RAT LOAEL: 0.2 MG/L 7 DAYS
CUMENE RAT NOAEL: 0.03 MG/L 90 DAYS
HYDROPEROXIDE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE LOCAL/REGIONAL/
NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. AS A
DISPOSAL ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL
FACILITY. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D002 (CORROSIVE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
HAZARD NOT OTHERWISE CLASSIFIED (HNOC)
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ACRYLIC ACID 79-10-7 TRADE SECRET 1 - 5
SACCHARIN 81-07-2 TRADE SECRET 1 - 5
CUMENE HYDROPEROXIDE 80-15-9 TRADE SECRET 1 - 5
15.2. STATE REGULATIONS:
CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. LISTING
ETHYLENE GLYCOL 107-21-1 DEVELOPMENTAL TOXIN
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS:
CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 32-7227-5
VERSION NUMBER: 2.01
ISSUE DATE: 01/19/18
SUPERCEDES DATE: 06/15/16
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY
OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS
FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM