| Common Name: | ROHPER 1-GL 2PK V7400 NAVY GRAY, 245443 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 8/13/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 2ZLN4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 8/14/2018
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: ROHPER 1-GL 2PK V7400 NAVY GRAY
PRODUCT IDENTIFIER: 245443
RECOMMENDED USE: TOPCOAT/ALKYD
REVISION DATE: 8/13/2018
SUPERCEDES DATE: 3/14/2018
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
RUST-OLEUM CANADA (ROCA):
200 CONFEDERATION PARKWAY
CONCORD, ON L4K 4T8
CANADA
EMERGENCY PHONE: 800-387-3625
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
30% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
GHS HAZARD STATEMENTS:
FLAMMABLE LIQUID, CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOUR.
GERM CELL MUTAGENICITY, CATEGORY 1B:
H340: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY, CATEGORY 1B:
H350: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY, CATEGORY 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT, REPEATED EXPOSURE, CATEGORY 1:
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
GHS LABEL PRECAUTIONARY STATEMENTS:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/
SHOWER.
P370+P378:
IN CASE OF FIRE:
USE ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND TO
EXTINGUISH.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL AND
NATIONAL REGULATIONS.
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P405: STORE LOCKED UP.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P321: FOR SPECIFIC TREATMENT SEE LABEL
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
GHS SDS PRECAUTIONARY STATEMENTS:
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT. % GHS SYMBOLS GHS STATEMENTS
1-CHLORO-4- 98-56-6 19 GHS07 H315-319-332-335
(TRIFLUOROMETHYL)
BENZENE
MINERAL SPIRITS 64742-88-7 15 GHS08 H304-372
HYDROTREATED LIGHT 64742-47-8 8.1 GHS08 H304
DISTILLATE
OCTAMETHYLCYCLO- 556-67-2 4.6 GHS08 H361
TETRASILOXANE
NANOSCALE TITANIUM 1317-80-2 2.1 NOT AVAILABLE NOT AVAILABLE
DIOXIDE
TITANIUM DIOXIDE 13463-67-7 1.9 NOT AVAILABLE NOT AVAILABLE
XYLENES 1330-20-7 1.1 GHS02-GHS07 H226-315-319-332
(O-, M-, P- ISOMERS)
METHYL ETHYL KETOXIME 96-29-7 0.3 GHS05-GHS06- H302-312-317-
GHS08 318-331-351
ETHYLBENZENE 100-41-4 0.2 GHS02-GHS07- H225-304-332-
GHS08 351-373
NAPHTHA, HYDROTREATED 64742-48-9 0.2 GHS08 H304-340-350
HEAVY
NAPHTHA, HYDROTREATED 64742-48-9 0.1 GHS08 H304
HEAVY
CARBON BLACK 1333-86-4 0.1 NOT AVAILABLE NOT AVAILABLE
2,2,4-TRIMETHYL- 6846-50-0 0.1 GHS06 H331
1,3-PENTANEDIOL
DIISOBUTYRATE
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL
CAN ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. VAPORS CAN
TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS MAY FORM EXPLOSIVE
MIXTURES WITH AIR. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP OF
STEAM. KEEP CONTAINERS TIGHTLY CLOSED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP AND
POSSIBLE AUTOIGNITION OR EXPLOSION. EVACUATE AREA AND FIGHT FIRE FROM A
SAFE DISTANCE. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
CONTAINERS MAY EXPLODE WHEN HEATED.
SPECIAL FIRE AND EXPLOSION HAZARD (COMBUSTIBLE DUST): NO INFORMATION
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. ELIMINATE ALL IGNITION SOURCES; USE EXPLOSION-PROOF
EQUIPMENT. PLACE MATERIAL IN A CONTAINER AND DISPOSE OF ACCORDING TO LOCAL,
PROVINCIAL, STATE AND FEDERAL REGULATIONS. REMOVE ALL SOURCES OF IGNITION,
VENTILATE AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS.
DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS.
DO NOT INCINERATE CLOSED CONTAINERS. VENTILATE AREA, ISOLATE SPILLED
MATERIAL, AND REMOVE WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED
ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE,
AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY WITH
ADEQUATE VENTILATION. FOLLOW ALL SDS AND LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF
IGNITION. KEEP CONTAINER CLOSED WHEN NOT IN USE. PRODUCT SHOULD BE STORED
IN TIGHTLY SEALED CONTAINERS AND PROTECTED FROM HEAT, MOISTURE, AND FOREIGN
MATERIALS. STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. AVOID EXCESS HEAT. DO NOT STORE ABOVE 120 DEG. F.
STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF
NFPA CLASS II COMBUSTIBLE LIQUIDS.
ADVICE ON SAFE HANDLING OF COMBUSTIBLE DUST: NO INFORMATION
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
1-CHLORO-4-(TRIFLUOROMETHYL) BENZENE 98-56-6 20.0
MINERAL SPIRITS 64742-88-7 20.0
HYDROTREATED LIGHT DISTILLATE 64742-47-8 10.0
OCTAMETHYLCYCLOTETRASILOXANE 556-67-2 5.0
NANOSCALE TITANIUM DIOXIDE 1317-80-2 5.0
TITANIUM DIOXIDE 13463-67-7 5.0
XYLENES (O-, M-, P- ISOMERS) 1330-20-7 5.0
METHYL ETHYL KETOXIME 96-29-7 1.0
ETHYLBENZENE 100-41-4 1.0
NAPHTHA, HYDROTREATED HEAVY 64742-48-9 1.0
NAPHTHA, HYDROTREATED HEAVY 64742-48-9 1.0
CARBON BLACK 1333-86-4 1.0
2,2,4-TRIMETHYL-1,3-PENTANEDIOL 6846-50-0 1.0
DIISOBUTYRATE
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
1-CHLORO-4-(TRIFLUOROMETHYL) N.E. N.E. N.E. N.E.
BENZENE
MINERAL SPIRITS N.E. N.E. N.E. N.E.
HYDROTREATED LIGHT DISTILLATE N.E. N.E. N.E. N.E.
OCTAMETHYLCYCLOTETRASILOXANE N.E. N.E. N.E. N.E.
NANOSCALE TITANIUM DIOXIDE N.E. N.E. N.E. N.E.
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
XYLENES (O-, M-, P- ISOMERS) 100 PPM 150 PPM 100 PPM N.E.
METHYL ETHYL KETOXIME 10 PPM N.E. N.E. N.E.
ETHYLBENZENE 20 PPM N.E. 100 PPM N.E.
NAPHTHA, HYDROTREATED HEAVY N.E. N.E. N.E. N.E.
NAPHTHA, HYDROTREATED HEAVY N.E. N.E. N.E. N.E.
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
2,2,4-TRIMETHYL- N.E. N.E. N.E. N.E.
1,3-PENTANEDIOL
DIISOBUTYRATE
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH AN
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE
LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR IN ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION. USE GLOVES TO PREVENT PROLONGED SKIN CONTACT.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. REFER TO
SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE REGARDING
TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
ENGINEERING MEASURES FOR COMBUSTIBLE DUST: NO INFORMATION
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.038
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: NEGLIGIBLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: 136 - 1,649
EXPLOSIVE LIMITS, VOL%: 0.8 - 10.5
FLAMMABILITY: SUPPORTS COMBUSTION
FLASH POINT, DEG. C: 36
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION. AVOID TEMPERATURES ABOVE 120 DEG. F
(49 DEG. C).
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. CONTAINS SOLVENTS
WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES SERIOUS EYE IRRITATION
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION. CAUSES SKIN
IRRITATION. ALLERGIC REACTIONS ARE POSSIBLE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. MAY
CAUSE HEADACHES AND DIZZINESS. HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO
THE EYES, NOSE, THROAT AND LUNGS. HIGH GAS, VAPOR, MIST OR DUST
CONCENTRATIONS MAY BE HARMFUL IF INHALED. PROLONGED OR EXCESSIVE INHALATION
MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND
CAUSE DAMAGE.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER
ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE. IARC
LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B). CONTAINS
TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP 2B-"POSSIBLY
CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO TITANIUM
DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH TITANIUM
DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND
THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC
MONOGRAPH, VOL. 93, 2010)CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG
FIBROSIS, AND LUNG TUMORS HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY
EXPOSED FOR LONG PERIODS OF TIME TO EXCESSIVE CONCENTRATIONS OF CARBON
BLACK AND SEVERAL INSOLUBLE FINE DUST PARTICLES. TUMORS HAVE NOT BEEN
OBSERVED IN OTHER ANIMAL SPECIES (I.E., MOUSE AND HAMSTER) UNDER SIMILAR
CIRCUMSTANCES AND STUDY CONDITIONS. EPIDEMIOLOGICAL STUDIES OF NORTH
AMERICAN WORKERS SHOW NO EVIDENCE OF CLINICALLY SIGNIFICANT ADVERSE HEALTH
EFFECTS DUE TO OCCUPATIONAL EXPOSURE TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND
THE ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. HIGH CONCENTRATIONS MAY
LEAD TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS, DIZZINESS, NAUSEA,
HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
98-56-6 1-CHLORO-4- 13000 MG/KG >2684 MG/KG N.E.
(TRIFLUOROMETHYL) RAT RABBIT
BENZENE
64742-88-7 MINERAL SPIRITS >19748 MG/KG >3000 MG/KG 4951 MG/L RAT
RAT RABBIT
64742-47-8 HYDROTREATED LIGHT >5000 MG/KG >2000 MG/KG >5000 MG/L
DISTILLATE RAT RABBIT RAT
556-67-2 OCTAMETHYLCYCLO- 4800 MG/KG >2400 MG/KG 36 MG/L RAT
TETRASILOXANE RAT RAT
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG 2500 MG/KG N.E.
RAT
1330-20-7 XYLENES 3500 MG/KG >4350 MG/KG 29.08 MG/L
(O-, M-, P- ISOMERS) RAT RABBIT RAT
96-29-7 METHYL ETHYL 930 MG/KG 1100 MG/KG >4.8 MG/L RAT
KETOXIME RAT RABBIT
100-41-4 ETHYLBENZENE 3500 MG/KG 15400 MG/KG 17.4 MG/L RAT
RAT RABBIT
64742-48-9 NAPHTHA, HYDROTREATED >6000 MG/KG >3160 MG/KG N.E.
HEAVY RAT RABBIT
64742-48-9 NAPHTHA, HYDROTREATED >6000 MG/KG >3160 MG/KG N.E.
HEAVY RAT RABBIT
1333-86-4 CARBON BLACK >15400 MG/KG N.E. N.E.
RAT
6846-50-0 2,2,4-TRIMETHYL- >3200 MG/KG N.E. >5.3 MG/L RAT
1,3-PENTANEDIOL RAT
DIISOBUTYRATE
N.E. - NOT ESTABLISHED
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
PRODUCT IS A MIXTURE OF LISTED COMPONENTS. PRODUCT IS A MIXTURE OF LISTED
COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS. DO NOT INCINERATE CLOSED CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1263 1263 N.A.
PROPER SHIPPING PAINT PRODUCTS PAINT PAINT PAINT PRODUCTS
NAME IN LIMITED IN LIMITED
QUANTITIES QUANTITIES
HAZARD CLASS N.A. 3 3 N.A.
PACKING GROUP N.A. III III N.A.
LIMITED QUANTITY YES YES YES YES
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS), CARCINOGENICITY, ACUTE
TOXICITY (ANY ROUTE OF EXPOSURE), REPRODUCTIVE TOXICITY, SKIN CORROSION OR
IRRITATION, RESPIRATORY OR SKIN SENSITIZATION, SERIOUS EYE DAMAGE OR EYE
IRRITATION, SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE),
GERM CELL MUTAGENICITY
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
XYLENES (O-, M-, P- ISOMERS) 1330-20-7
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
CHEMICAL NAME CAS-NO.
1-CHLORO-4-(TRIFLUOROMETHYL)BENZENE 98-56-6
OCTAMETHYLCYCLOTETRASILOXANE 556-67-2
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS: 337 G/L
SDS REVISION DATE: 8/13/2018
REASON FOR REVISION:
SUBSTANCE REGULATORY CAS NUMBER CHANGED
SUBSTANCE HAZARDOUS FLAG CHANGED
SUBSTANCE HAZARD THRESHOLD % CHANGED
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
03 - COMPOSITION/INFORMATION ON INGREDIENTS
08 - EXPOSURE CONTROLS/PERSONAL PROTECTION
15 - REGULATORY INFORMATION
16 - OTHER INFORMATION
SUBSTANCE CHEMICAL NAME CHANGED
REVISION STATEMENT(S) CHANGED
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
THE MANUFACTURER BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION AND
BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS OF
THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. THE MANUFACTURER MAKES NO
WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
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REGULATIONS.