| Common Name: | 2ZXE6 TOSS BLOCK PDCB GRAINGER PINK CHERRY |
| Manufacturer: | INDUSTRIAS SALCOM MEXICO |
| SDS Revision Date: | 10/5/2023 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2ZXE6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ACC. TO OSHA HCS
PRINTING DATE: 05/10/2023
REVIEWED ON: 05/10/2023
| 1 IDENTIFICATION |  |
|
PRODUCT IDENTIFIER:
TRADE NAME: 2ZXE6 TOSS BLOCK PDCB GRAINGER PINK CHERRY
MANUFACTURER ARTICLE NUMBER: EPAMI37
CAS NUMBER: 106-46-7
EC NUMBER: 203-400-5
INDEX NUMBER: 602-035-00-2
APPLICATION OF THE SUBSTANCE / THE MIXTURE: AIR FRESHENER.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: (755)(21)
MANUFACTURER/SUPPLIER:
INDUSTRIAS SALCOM, SA DE CV
CALLE 2 NO. 10540
PARQUE INDUSTRIAL EL SALTO
EL SALTO, JAL, ZP.45680
MEXICO
FREDCOMINU@WIESE.COM.MX
INFORMATION DEPARTMENT: PRODUCT SAFETY DEPARTMENT
EMERGENCY TELEPHONE NUMBER: +52 33 3688 0850
| 2 HAZARD(S) IDENTIFICATION | |
|
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS08: HEALTH HAZARD
CARCINOGENICITY 2:
H351: SUSPECTED OF CAUSING CANCER.
GHS07: EXCLAMATION MARK
ACUTE TOXICITY - ORAL 4:
H302: HARMFUL IF SWALLOWED.
EYE IRRITATION 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE SUBSTANCE IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELING: 1,4-DICHLOROBENZENE
HAZARD STATEMENTS:
NONE
H302: HARMFUL IF SWALLOWED.
H319: CAUSES SERIOUS EYE IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P264: WASH THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P330: RINSE MOUTH.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
CLASSIFICATION SYSTEM:
NFPA RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 2
REACTIVITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 2
REACTIVITY 0
OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
|
CHEMICAL CHARACTERIZATION: SUBSTANCES
CAS NO. DESCRIPTION: 106-46-7 1,4-DICHLOROBENZENE
IDENTIFICATION NUMBER(S):
EC NUMBER: 203-400-5
INDEX NUMBER: 602-035-00-2
| 4 FIRST-AID MEASURES | |
|
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE
MEDICAL OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
AFTER SKIN CONTACT: GENERALLY THE PRODUCT DOES NOT IRRITATE THE SKIN.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
IF SWALLOWED, RINSE MOUTH WITH WATER (ONLY IF THE PERSON IS CONSCIOUS).
CALL A POISON CENTER OR DOCTOR/PHYSICIAN. OBTAIN EMERGENCY MEDICAL
ATTENTION.
INFORMATION FOR DOCTOR:
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE-EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING MATERIALS.
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT: NO SPECIAL MEASURES REQUIRED.
| 6 ACCIDENTAL RELEASE MEASURES | |
|
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
AVOID CONTACT WITH SKIN AND EYES. ELIMINATE ALL IGNITION SOURCES IF SAFE
TO DO SO. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. DO NOT BREATHE DUST, FUME. SPILLED MATERIAL MAY PRESENT A
SLIPPING HAZARD.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO SECTION 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
PROTECTIVE ACTION CRITERIA FOR CHEMICALS:
PAC-1: 30 PPM
PAC-2: 170 PPM
PAC-3: 1,000 PPM
| 7 HANDLING AND STORAGE | |
|
HANDLING:
PRECAUTIONS FOR SAFE HANDLING: OPEN AND HANDLE RECEPTACLE WITH CARE.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
KEEP RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
NO SPECIAL REQUIREMENTS.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
NOT REQUIRED.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
KEEP RECEPTACLE TIGHTLY SEALED.
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
|
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL SYSTEMS:
NO FURTHER DATA; SEE SECTION 7.
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
106-46-7 1,4-DICHLOROBENZENE:
PEL:
LONG-TERM VALUE: 450 MG/M3, 75 PPM
REL: SEE POCKET GUIDE APP. A
TLV:
LONG-TERM VALUE:
10 PPM
A3
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE CREATION WERE USED AS BASIS.
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
STORE PROTECTIVE CLOTHING SEPARATELY.
AVOID CONTACT WITH THE EYES.
AVOID CONTACT WITH THE EYES AND SKIN.
BREATHING EQUIPMENT: NOT REQUIRED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION. DUE TO MISSING TESTS NO RECOMMENDATION TO THE
GLOVE MATERIAL CAN BE GIVEN FOR THE PRODUCT/ THE PREPARATION/ THE
CHEMICAL MIXTURE.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: TIGHTLY SEALED GOGGLES
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
|
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: SOLID
COLOR: ACCORDING TO PRODUCT SPECIFICATION
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT APPLICABLE.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: 54 DEG. C (129.2 DEG. F)
BOILING POINT/BOILING RANGE: 175 DEG. C (347 DEG. F)
FLASH POINT: 66 DEG. C (150.8 DEG. F)
FLAMMABILITY (SOLID, GASEOUS): PRODUCT IS NOT FLAMMABLE.
AUTO IGNITING: 640 DEG. C (1,184 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
IGNITION TEMPERATURE: NOT DETERMINED.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
EXPLOSION LIMITS:
LOWER: 2.2 VOL %
UPPER: 12 VOL %
VAPOR PRESSURE AT 20 DEG. C (68 DEG. F): 1.7 HPA (1.3 MM Hg)
DENSITY AT 20 DEG. C (68 DEG. F): 1.45904 G/CM3 (12.17569 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT APPLICABLE.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH:
WATER AT 20 DEG. C (68 DEG. F): 0.1 G/L
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT APPLICABLE.
KINEMATIC: NOT APPLICABLE.
ORGANIC SOLVENTS: 0.0 %
VOC CONTENT: 99.82 %
SOLIDS CONTENT: 99.8 %
OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NO DANGEROUS REACTIONS KNOWN.
CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE.
INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO DANGEROUS DECOMPOSITION PRODUCTS KNOWN.
| 11 TOXICOLOGICAL INFORMATION | |
|
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
106-46-7 1,4-DICHLOROBENZENE:
ORAL:
LD50: 500 MG/KG (RAT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: NO IRRITANT EFFECT.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION: NO SENSITIZING EFFECTS KNOWN.
ADDITIONAL TOXICOLOGICAL INFORMATION:
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER): 2B
NTP (NATIONAL TOXICOLOGY PROGRAM): R
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS IS LISTED.
| 12 ECOLOGICAL INFORMATION | |
|
TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
BEHAVIOR IN ENVIRONMENTAL SYSTEMS:
BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
|
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
|
UN-NUMBER:
DOT, IMDG, IATA: NOT REGULATED
UN PROPER SHIPPING NAME:
DOT, IMDG, IATA: NOT REGULATED
TRANSPORT HAZARD CLASS(ES):
DOT, ADN, IMDG, IATA:
CLASS: NOT REGULATED
PACKING GROUP:
DOT, IMDG, IATA: NOT REGULATED
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
UN "MODEL REGULATION": NOT REGULATED
| 15 REGULATORY INFORMATION | |
|
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
106-46-7 1,4-DICHLOROBENZENE
TSCA (TOXIC SUBSTANCES CONTROL ACT):
106-46-7 1,4-DICHLOROBENZENE ACTIVE
138-86-3 DIPENTENE ACTIVE
5392-40-5 CITRAL ACTIVE
78-70-6 LINALOOL ACTIVE
HAZARDOUS AIR POLLUTANTS:
106-46-7 1,4-DICHLOROBENZENE
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER:
106-46-7 1,4-DICHLOROBENZENE
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
NONE OF THE INGREDIENTS IS LISTED.
TLV (THRESHOLD LIMIT VALUE): A3
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
106-46-7 1,4-DICHLOROBENZENE
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
|
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
DEPARTMENT ISSUING SDS: PRODUCT SAFETY DEPARTMENT
CONTACT: +52 33 3688 0850
DATE OF PREPARATION / LAST REVISION: 05/10/2023
ABBREVIATIONS AND ACRONYMS:
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
VOC: VOLATILE ORGANIC COMPOUNDS (USA, EU)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
TLV: THRESHOLD LIMIT VALUE
PEL: PERMISSIBLE EXPOSURE LIMIT
REL: RECOMMENDED EXPOSURE LIMIT
ACUTE TOXICITY - ORAL 4: ACUTE TOXICITY - CATEGORY 4
EYE IRRITATION 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
CARCINOGENICITY 2: CARCINOGENICITY - CATEGORY 2
| DATA COMPARED TO THE PREVIOUS VERSION ALTERED.
US