| Common Name: | LU 100L WHITE LITHIUM GREASE |
| Manufacturer: | SPRAYON PRODUCTS |
| SDS Revision Date: | 6/28/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 30WK46 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
S10005000
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: LU(TM)100L WHITE LITHIUM GREASE
PRODUCT CODE: S10005000
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
MANUFACTURER:
SPRAYON PRODUCTS
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: (800)247-3266
REGULATORY INFORMATION TELEPHONE NUMBER: (216)566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800)424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 2
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
52.5%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION. KEEP AWAY FROM HEAT,
HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING.
USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING AND ALL
MATERIAL-HANDLING EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. KEEP CONTAINER TIGHTLY
CLOSED. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. DO NOT BREATHE
VAPOR. WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF CONTAMINATED CLOTHING AND WASH
IT BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN
CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR
FATAL.
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR INDUSTRIAL USE
ONLY.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. DO NOT TRANSFER CONTENTS TO OTHER CONTAINERS FOR STORAGE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
LIGHT ALIPHATIC HYDROCARBON SOLVENT 45 64742-49-0
HEAVY NAPHTHENIC PETROLEUM OIL 37 64742-52-5
HIGHLY REFINED NAPHTHENIC OIL 6.5 64742-53-6
LT. ALIPHATIC HYDROCARBON SOLVENT 2.5 64742-89-8
ZINC OXIDE 2.5 1314-13-2
METHYL CYCLOHEXANE 2.5 108-87-2
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION. IF NECESSARY,
CALL A POISON CENTER OR PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION: CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HIGHLY FLAMMABLE LIQUID AND VAPOR. IN A FIRE OR IF HEATED, A PRESSURE
INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A
SUBSEQUENT EXPLOSION. THE VAPOR/GAS IS HEAVIER THAN AIR AND WILL SPREAD
ALONG THE GROUND. VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL
A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. RUNOFF TO
SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD
AREA. AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
BREATHE VAPOR OR MIST. DO NOT INGEST. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR
WHEN VENTILATION IS INADEQUATE. DO NOT ENTER STORAGE AREAS AND CONFINED
SPACES UNLESS ADEQUATELY VENTILATED. KEEP IN THE ORIGINAL CONTAINER OR AN
APPROVED ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED
WHEN NOT IN USE. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY
OTHER IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL (VENTILATING,
LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST ELECTROSTATIC DISCHARGES. EMPTY
CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE
CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. STORE LOCKED UP. ELIMINATE ALL
IGNITION SOURCES. SEPARATE FROM OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED
MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT
STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME EXPOSURE LIMITS
LIGHT ALIPHATIC HYDROCARBON SOLVENT NONE.
HEAVY NAPHTHENIC PETROLEUM OIL ACGIH TLV (UNITED STATES, 3/2015).
TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
HIGHLY REFINED NAPHTHENIC OIL ACGIH TLV (UNITED STATES, 3/2015).
TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
LT. ALIPHATIC HYDROCARBON SOLVENT NONE.
ZINC OXIDE NIOSH REL (UNITED STATES, 10/2013).
CEIL: 15 MG/M3 FORM: DUST
TWA: 5 MG/M3 10 HOURS.
FORM: DUST AND FUMES
STEL: 10 MG/M3 15 MINUTES.
FORM: FUME
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
FORM: FUME
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ACGIH TLV (UNITED STATES, 3/2015).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE FRACTION
METHYL CYCLOHEXANE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 400 PPM 8 HOURS.
TWA: 1610 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 400 PPM 10 HOURS.
TWA: 1600 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 500 PPM 8 HOURS.
TWA: 2000 MG/M3 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME EXPOSURE LIMITS
HEAVY NAPHTHENIC PETROLEUM OIL CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 5 MG/M3 8 HOURS.
FORM: MIST 15 MIN
OEL: 10 MG/M3 15 MINUTES.
FORM: MIST
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 5 MG/M3 8 HOURS.
FORM: MIST
STEV: 10 MG/M3 15 MINUTES.
FORM: MIST
HIGHLY REFINED NAPHTHENIC OIL CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 5 MG/M3 8 HOURS.
FORM: MIST 15 MIN
OEL: 10 MG/M3 15 MINUTES.
FORM: MIST
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 5 MG/M3 8 HOURS.
FORM: MIST
STEV: 10 MG/M3 15 MINUTES.
FORM: MIST
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 100 DEG. C (212 DEG. F)
FLASH POINT:
CLOSED CUP: -23 DEG. C (-9.4 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 1.5 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 0.8%
UPPER: 6.7%
VAPOR PRESSURE: 0.71 KPA (5.332 MM Hg) [AT 20 DEG. C]
VAPOR DENSITY: 3.39 [AIR = 1]
RELATIVE DENSITY: 0.78
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (ROOM TEMPERATURE): <0.205 CM2/S (<20.5 CST)
KINEMATIC (40 DEG. C (104 DEG. F)): <0.205 CM2/S (<20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
HEAT OF COMBUSTION: 36.46 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION. DO NOT ALLOW VAPOR TO ACCUMULATE IN LOW OR CONFINED
AREAS.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
HEAVY NAPHTHENIC LD50 ORAL RAT >5000 MG/KG
PETROLEUM OIL
HIGHLY REFINED LC50 INHALATION RAT 2180 MG/M3 4 HOURS
NAPHTHENIC OIL DUSTS AND MISTS
LD50 ORAL RAT >5000 MG/KG
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
HEAVY NAPHTHENIC SKIN - SEVERE RABBIT 500
PETROLEUM OIL IRRITANT MILLIGRAMS
HIGHLY REFINED SKIN - RABBIT 24 HOURS
NAPHTHENIC OIL MODERATE 0.5
IRRITANT MILILITERS
SKIN - SEVERE RABBIT 500
IRRITANT MILLIGRAMS
ZINC OXIDE EYES - MILD RABBIT 24 HOURS
IRRITANT 500
MILLIGRAMS
SKIN - MILD RABBIT 24 HOURS
IRRITANT 500
MILLIGRAMS
METHYL CYCLOHEXANE EYES - MILD RABBIT 24 HOURS
IRRITANT 100
MICROLITERS
SKIN - MILD RABBIT 24 HOURS
IRRITANT 500
MICROLITERS
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
LIGHT ALIPHATIC CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
HYDROCARBON SOLVENT IRRITATION AND
NARCOTIC EFFECTS
HIGHLY REFINED CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
NAPHTHENIC OIL IRRITATION AND
NARCOTIC EFFECTS
LT. ALIPHATIC CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
HYDROCARBON SOLVENT IRRITATION AND
NARCOTIC EFFECTS
METHYL CYCLOHEXANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
LIGHT ALIPHATIC CATEGORY 2 NOT DETERMINED NOT DETERMINED
HYDROCARBON SOLVENT
HIGHLY REFINED CATEGORY 2 NOT DETERMINED NOT DETERMINED
NAPHTHENIC OIL
LT. ALIPHATIC CATEGORY 2 NOT DETERMINED NOT DETERMINED
HYDROCARBON SOLVENT
METHYL CYCLOHEXANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
LT. ALIPHATIC HYDROCARBON SOLVENT ASPIRATION HAZARD - CATEGORY 1
METHYL CYCLOHEXANE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION: CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES
ROUTE ATE VALUE
INHALATION (DUSTS AND MISTS) 15.93 MG/L
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
LT. ALIPHATIC ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
HYDROCARBON SOLVENT >100000 PPM MYKISS
FRESH WATER
ZINC OXIDE ACUTE IC50: ALGAE - SKELETONEMA 96 HOURS
1.85 MG/L COSTATUM
MARINE WATER
ACUTE IC50: ALGAE - 72 HOURS
46 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA -
EXPONENTIAL GROWTH
PHASE
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
98 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
1.1 PPM MYKISS
FRESH WATER
METHYL CYCLOHEXANE ACUTE LC50: FISH - MORONE 96 HOURS
5800 SAXATILIS - JUVENILE
(MICRO)G/L (FLEDGLING,
MARINE WATER HATCHLING, WEANLING)
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
LIGHT ALIPHATIC HYDROCARBON SOLVENT 10 TO 2500 HIGH
LT. ALIPHATIC HYDROCARBON SOLVENT 10 TO 2500 HIGH
ZINC OXIDE - 60960 HIGH METHYL CYCLOHEXANE 186.21 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. VAPOR FROM PRODUCT
RESIDUES MAY CREATE A HIGHLY FLAMMABLE OR EXPLOSIVE ATMOSPHERE INSIDE THE
CONTAINER. DO NOT CUT, WELD OR GRIND USED CONTAINERS UNLESS THEY HAVE BEEN
CLEANED THOROUGHLY INTERNALLY. AVOID DISPERSAL OF SPILLED MATERIAL AND
RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1993 UN1993 UN1993
UN PROPER FLAMMABLE FLAMMABLE FLAMMABLE
SHIPPING NAME LIQUIDS, N.O.S. LIQUIDS, N.O.S. LIQUIDS, N.O.S.
(LIGHT ALIPHATIC (LIGHT ALIPHATIC (LIGHT ALIPHATIC
HYDROCARBON HYDROCARBON HYDROCARBON
SOLVENT, METHYL SOLVENT, METHYL SOLVENT, METHYL
CYCLOHEXANE) CYCLOHEXANE) CYCLOHEXANE)
TRANSPORT 3 3 3
HAZARD CLASS(ES) FLAMMABLE LIQUID, CLASS 3, CLASS 3,
CLASS/DIVISION FLAMMABLE FLAMMABLE
3.1, 3.2, 3.3 LIQUIDS LIQUIDS
PACKING GROUP II II II
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL ERG NO.: PRODUCT ERG NO.:
INFORMATION 128 CLASSIFIED 128
AS PER THE
FOLLOWING
SECTIONS
OF THE
TRANSPORTATION
OF DANGEROUS
GOODS
REGULATIONS:
2.18-2.19
(CLASS 3).
ERG NO.: 128
IATA IMDG
UN NUMBER UN1993 UN1993
UN PROPER FLAMMABLE FLAMMABLE
SHIPPING NAME LIQUIDS, N.O.S. LIQUIDS, N.O.S.
(LIGHT ALIPHATIC (LIGHT ALIPHATIC
HYDROCARBON HYDROCARBON
SOLVENT, METHYL SOLVENT, METHYL
CYCLOHEXANE) CYCLOHEXANE)
MARINE POLLUTANT
(ZINC OXIDE)
TRANSPORT 3 3
HAZARD CLASS(ES) CLASS 3, CLASS 3 - FLAMMABLE LIQUIDS
FLAMMABLE
LIQUIDS
ENVIRONMENT
PACKING GROUP II II
ENVIRONMENTAL NO. YES.
HAZARDS
ADDITIONAL THE THE MARINE
INFORMATION ENVIRONMENTALLY POLLUTANT MARK IS
HAZARDOUS NOT REQUIRED WHEN
SUBSTANCE MARK TRANSPORTED IN
MAY APPEAR IF SIZES OF </=5 L OR </=5 KG.
REQUIRED BY OTHER
TRANSPORTATION EMERGENCY SCHEDULES (EMS):
REGULATIONS. F-E, S-E
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON ALL
ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2
FLAMMABILITY 3
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE LIQUIDS - CATEGORY 2 ON BASIS OF TEST DATA
SKIN CORROSION/IRRITATION - CATEGORY 2 CALCULATION METHOD
SERIOUS EYE DAMAGE/ EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (SINGLE CALCULATION METHOD
EXPOSURE) (RESPIRATORY TRACT IRRITATION) -
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE CALCULATION METHOD
EXPOSURE) (NARCOTIC EFFECTS) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED CALCULATION METHOD
EXPOSURE) - CATEGORY 2
HISTORY:
DATE OF PRINTING: 6/28/2016
DATE OF ISSUE/DATE OF REVISION: 6/28/2016
DATE OF PREVIOUS ISSUE: 6/4/2016
VERSION: 3.01
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA SHEET
(SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE
HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE INFORMATION
PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE ADDITION OF ANY
MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF THE PRODUCT.
PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT AS
SPECIFICALLY INSTRUCTED BY SHERWIN-WILLIAMS, INCLUDING BUT NOT LIMITED TO
THE INCORPORATION OF NON SHERWIN-WILLIAMS PRODUCTS OR THE USE OR ADDITION
OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY SHERWIN-WILLIAMS. REGULATORY
REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS
AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE TO ENSURE THAT
HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE, PROVINCIAL OR LOCAL
LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE CONTROL OF
THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS RESPONSIBLE TO DETERMINE THE
CONDITIONS NECESSARY FOR THE SAFE USE OF THIS PRODUCT. THE
CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE OTHER THAN
THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT FIRST
REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING INSTRUCTIONS. DUE
TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.