| Common Name: | SEED SLIK - SG BLEND |
| Manufacturer: | SUPERIOR GRAPHITE |
| SDS Revision Date: | 3/27/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 31ER17, 31ER18 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SEED SLIK - SG BLEND
SUPERIOR GRAPHITE
SAFETY DATA SHEET
| SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
PRODUCT NAME: SEED SLIK - SG BLEND
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RELEVANT IDENTIFIED USE(S): DRY LUBRICANT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
SUPERIOR GRAPHITE
10 S. RIVERSIDE PLAZA
CHICAGO, IL 60606
UNITED STATES
TELEPHONE (GENERAL): 312-559-2999 - (8AM-5PM CST, M-F)
1.4 EMERGENCY TELEPHONE NUMBER:
MANUFACTURER:
1-800-424-9300 - FOR HAZARDOUS MATERIALS [OR DANGEROUS GOODS] INCIDENT
SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT CALL CHEMTREC DAY OR NIGHT
MANUFACTURER:
+1 703-527-3887 - OUTSIDE USA AND CANADA (COLLECT CALLS ACCEPTED)
| SECTION 2 - HAZARDS IDENTIFICATION | |
EU/EEC:
ACCORDING TO:
REGULATION (EC) NO 1272/2008 (CLP)/REACH 1907/2006 [AMENDED BY 453/2010]
ACCORDING TO: EU DIRECTIVE 67/548/EEC (DSD) OR 1999/45/EC (DPD)
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLP:
CARCINOGENICITY 1A - H350
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 1 - H372
DSD/DPD:
TOXIC (T)
CARCINOGENIC SUBSTANCES: CATEGORY 1
R48/23, R49
2.2 LABEL ELEMENTS:
CLP:
DANGER: HEALTH HAZARD
HAZARD STATEMENTS:
H350: MAY CAUSE CANCER.
H372:
CAUSES DAMAGE TO ORGANS - LUNGS THROUGH PROLONGED OR REPEATED EXPOSURE
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P260: DO NOT BREATHE.
P264: WASH THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
RESPONSE:
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE/DISPOSAL:
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
DSD/DPD: TOXIC OR VERY TOXIC
RISK PHRASES:
R48/23:
TOXIC:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
R49: MAY CAUSE CANCER BY INHALATION.
SAFETY PHRASES:
S37: WEAR SUITABLE GLOVES.
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
S53: AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
2.3 OTHER HAZARDS:
CLP:
MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.
ACCORDING TO REGULATION (EC) NO. 1272/2008 (CLP) THIS MATERIAL IS
CONSIDERED HAZARDOUS.
DSD/DPD:
MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.
ACCORDING TO EUROPEAN DIRECTIVE 1999/45/EC THIS MATERIAL IS CONSIDERED
DANGEROUS.
UNITED STATES (US):
ACCORDING TO: OSHA 29 CFR 1910.1200 HCS
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012:
CARCINOGENICITY 1A
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 1
COMBUSTIBLE DUST
2.2 LABEL ELEMENTS:
OSHA HCS 2012:
DANGER: HEALTH HAZARD
HAZARD STATEMENTS:
MAY CAUSE CANCER.
CAUSES DAMAGE TO ORGANS - LUNGS THROUGH PROLONGED OR REPEATED EXPOSURE VIA
INHALATION
MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST.
WASH THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE/DISPOSAL:
STORE LOCKED UP.
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
2.3 OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
CANADA:
ACCORDING TO: WHMIS
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
WHMIS: OTHER TOXIC EFFECTS - D2A
2.2 LABEL ELEMENTS:
WHMIS: OTHER TOXIC EFFECTS - D2A
2.3 OTHER HAZARDS:
WHMIS:
MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.
IN CANADA, THE PRODUCT MENTIONED ABOVE IS CONSIDERED HAZARDOUS UNDER THE
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS).
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE IN ACCORDANCE WITH
REGULATION (EC) NO 1272/2008.
3.2 MIXTURES:
COMPOSITION:
CHEMICAL NAME IDENTIFIERS %
GRAPHITE CAS: 7782-42-5 20%
EC NUMBER: 231-955-3
TALC CAS: 14807-96-6 80%
EC NUMBER: 238-877-9
QUARTZ CAS: 14808-60-7 <1%
EC NUMBER: 238-878-4
CHEMICAL NAME LD50/LC50 CLASSIFICATIONS ACCORDING TO COMMENTS
REGULATION/DIRECTIVE
GRAPHITE NDA EU DSD/DPD: NOT CLASSIFIED NDA
EU CLP: NOT CLASSIFIED
OSHA HCS 2012: COMB. DUST
TALC NDA EU DSD/DPD: NDA
SELF CLASSIFIED: T R48/23
EU CLP:
SELF CLASSIFIED:
STOT RE 1 (LUNGS, INHL), H372
OSHA HCS 2012:
STOT RE 1 (LUNGS, INHL)
QUARTZ NDA EU DSD/DPD: NDA
SELF CLASSIFIED:
T R48/20; CARC. 1 R49
EU CLP:
SELF CLASSIFIED:
STOT RE 1 (LUNGS, INHL), H372; CARC.
1A, H350
OSHA HCS 2012:
STOT RE 1 (LUNGS, INHL); CARC. 1A
SEE SECTION 16 FOR FULL TEXT OF H-STATEMENTS AND R-PHRASES.
| SECTION 4 - FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
MOVE VICTIM TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF VICTIM IS NOT
BREATHING. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. IF BREATHING IS
DIFFICULT GET MEDICAL ATTENTION.
SKIN:
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF IRRITATION DEVELOPS AND PERSISTS, GET MEDICAL
ATTENTION.
EYE:
IN CASE OF CONTACT WITH SUBSTANCE, IMMEDIATELY FLUSH EYES WITH RUNNING
WATER FOR AT LEAST 20 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. RINSE MOUTH. DO NOT GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED.
4.4 OTHER INFORMATION:
CALL 911 OR EMERGENCY MEDICAL SERVICE. ENSURE THAT MEDICAL PERSONNEL ARE
AWARE OF THE MATERIAL(S) INVOLVED, TAKE PRECAUTIONS TO PROTECT THEMSELVES
AND PREVENT SPREAD OF CONTAMINATION.
| SECTION 5 - FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
LARGE FIRE: WATER SPRAY, FOG OR REGULAR FOAM.
SMALL FIRES: DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NO DATA AVAILABLE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
DUST DISPERSED IN AIR IN SUFFICIENT CONCENTRATIONS AND IN THE PRESENCE IF
AN IGNITION SOURCE IS AN EXPLOSION HAZARD.
HAZARDOUS COMBUSTION PRODUCTS:
ON BURNING, MAY RELEASE CARBON DIOXIDE AND CARBON MONOXIDE.
5.3 ADVICE FOR FIREFIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.
LARGE FIRES: MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK.
LARGE FIRES:
DO NOT SCATTER SPILLED MATERIAL WITH HIGH PRESSURE WATER STREAMS.
LARGE FIRES: DIKE FIRE-CONTROL WATER FOR LATER DISPOSAL.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH MATERIAL THAT GENERATES RESPIRABLE DUST UNLESS PROPER
PPE IS USED. DO NOT WALK THROUGH SPILLED MATERIAL.
EMERGENCY PROCEDURES:
USE NORMAL CLEAN UP PROCEDURES. VENTILATE CLOSED SPACES BEFORE ENTERING.
6.2 ENVIRONMENTAL PRECAUTIONS: AVOID RUN OFF TO WATERWAYS AND SEWERS.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
CAREFULLY SHOVEL OR SWEEP UP SPILLED MATERIAL AND PLACE IN SUITABLE
CONTAINER. AVOID GENERATING DUST.
6.4 REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION AND SECTION 13 -
DISPOSAL CONSIDERATIONS.
| SECTION 7 - HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. USE APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT (PPE) DO NOT BREATHE DUST. AVOID ACCUMULATION OF DUST. GOOD
HOUSEKEEPING PRACTICES SHOULD BE IN PLACE TO PREVENT ACCUMULATION OF DUSTS
ON SURFACES. IF DUSTS ARE GENERATED DURING PROCESSING ELIMINATE IGNITION
SOURCES. TAKE PRECAUTIONARY MEASURES AGAINST STATIC CHARGES. GRAPHITE IS
CONDUCTIVE AND CAN CAUSE SHORT CIRCUITS AND OTHER ELECTRICAL MALFUNCTIONS.
GRAPHITE CAUSES SLIPPERY CONDITIONS. WASH THOROUGHLY WITH SOAP AND WATER
AFTER HANDLING AND BEFORE EATING, DRINKING, OR USING TOBACCO.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE: VENTILATE ENCLOSED AREAS. KEEP CONTAINER CLOSED.
7.3 SPECIFIC END USE(S): REFER TO SECTION 1.2 - RELEVANT IDENTIFIED USES.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
EXPOSURE LIMITS/GUIDELINES:
RESULT ACGIH NIOSH OSHA
QUARTZ TWAS 0.025 MG/M3 TWA 0.05 MG/M3 TWA NOT ESTABLISHED
(14808-60-7) (RESPIRABLE (RESPIRABLE
FRACTION) DUST)
GRAPHITE AS TWAS 2 MG/M3 TWA 2.5 MG/M3 TWA 15 MG/M3 TWA
PARTICULATES (ALL FORMS (NATURAL, (SYNTHETIC,
NOT OTHERWISE EXCEPT GRAPHITE RESPIRABLE TOTAL DUST)
CLASSIFIED FIBERS, DUST)
(PNOC) RESPIRABLE 5 MG/M3 TWA
FRACTION) (SYNTHETIC,
RESPIRABLE
FRACTION)
TALC TWAS 2 MG/M3 TWA 2 MG/M3 TWA NOT ESTABLISHED
(14807-96-6) (PARTICULATE (CONTAINING NO
MATTER ASBESTOS AND
CONTAINING NO <1% QUARTZ,
ASBESTOS AND RESPIRABLE
<1% CRYSTALLINE DUST)
SILICA,
RESPIRABLE
FRACTION)
EXPOSURE LIMITS SUPPLEMENTAL:
OSHA:
GRAPHITE (7782-42-5):
MINERAL DUSTS: (15 MPPCF TWA (NATURAL))
TALC (14807-96-6):
MINERAL DUSTS: (20 MPPCF TWA (IF 1% QUARTZ OR MORE, USE QUARTZ LIMIT))
QUARTZ (14808-60-7):
MINERAL DUSTS:
((30)/(%SiO2 + 2) MG/M3 TWA, TOTAL DUST
(250)/(%SiO2 + 5) MPPCF TWA, RESPIRABLE FRACTION
(10)/(%SiO2 + 2) MG/M3 TWA, RESPIRABLE FRACTION)
8.2 EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
ADEQUATE VENTILATION SYSTEMS AS NEEDED TO CONTROL CONCENTRATIONS OF
AIRBORNE CONTAMINANTS BELOW APPLICABLE THRESHOLD LIMIT VALUES. ALL DUST
CONTROL EQUIPMENT SHOULD CONTAIN EXPLOSION RELIEF VENTS OR AN EXPLOSION
SUPRESSION SYSTEM OR AN OXYGEN-DEFICIENT ENVIRONMENT. MAKE SURE THAT DUST
HANDLING SYSTEMS ARE DESIGNED TO PREVENT ESCAPE OF DUST INTO THE WORK AREA
AND THAT THEY DO NOT LEAK.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
FOR LIMITED EXPOSURE USE AN N95 DUST MASK. FOR PROLONGED EXPOSURE USE AN
AIR-PURIFYING RESPIRATOR WITH HIGH EFFICIENCY PARTICULATE AIR (HEPA)
FILTERS. FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR
EUROPEAN STANDARD EN 149. USE A NIOSH/MSHA OR EUROPEAN STANDARD EN 149
APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS ARE
EXPERIENCED.
EYE/FACE:
WEAR PROTECTIVE EYEWEAR (GOGGLES, FACE SHIELD, OR SAFETY GLASSES). EYE WASH
STATION SHOULD BE AVAILABLE.
HANDS: WEAR PROTECTIVE GLOVES.
SKIN/BODY: WEAR LONG SLEEVES AND/OR PROTECTIVE COVERALLS.
ENVIRONMENTAL EXPOSURE CONTROLS:
FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF WASTE. CONTROLS
SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT, INCLUDING
PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO WATERWAYS.
KEY TO ABBREVIATIONS:
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
NIOSH = NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
TWA = TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: SOLID
APPEARANCE/DESCRIPTION: GRAY POWDER WITH NO ODOR.
COLOR: GRAY
ODOR: NONE
ODOR THRESHOLD: DATA LACKING
GENERAL PROPERTIES:
BOILING POINT: DATA LACKING
MELTING POINT: DATA LACKING
DECOMPOSITION TEMPERATURE: DATA LACKING
PH: DATA LACKING
SPECIFIC GRAVITY/RELATIVE DENSITY: =2.69
WATER SOLUBILITY: INSOLUBLE
VISCOSITY: DATA LACKING
EXPLOSIVE PROPERTIES: DATA LACKING
OXIDIZING PROPERTIES: DATA LACKING
VOLATILITY:
VAPOR PRESSURE: DATA LACKING
VAPOR DENSITY: DATA LACKING
EVAPORATION RATE: DATA LACKING
FLAMMABILITY:
FLASH POINT: DATA LACKING
UEL: DATA LACKING
LEL: DATA LACKING
AUTOIGNITION: DATA LACKING
FLAMMABILITY (SOLID, GAS): DATA LACKING
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: DATA LACKING
9.2 OTHER INFORMATION:
NO ADDITIONAL PHYSICAL AND CHEMICAL PARAMETERS NOTED.
| SECTION 10 - STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.2 CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: WILL NOT OCCUR.
10.4 CONDITIONS TO AVOID:
ACCUMULATION OF DUSTS - MIXTURES OF GRAPHITE DUST AND AIR ARE EXPLOSIVE
WHEN IGNITED.
10.5 INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS, ACIDS, AND ALKALIS.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
ON BURNING MAY RELEASE CARBON DIOXIDE AND CARBON MONOXIDE.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
COMPONENTS:
TALC (80%) 14807-96-6:
IRRITATION:
SKIN-HUMAN:
300 (MICRO)G 3 DAY(S)-INTERMITTENT
MILD IRRITATION
TUMORIGEN / CARCINOGEN:
INHALATION-RAT TCLO: 18 MG/M3 6 HOUR(S) 2 YEAR(S)-INTERMITTENT
TUMORIGENIC: CARCINOGENIC BY RTECS CRITERIA
LUNGS, THORAX, OR RESPIRATION: BRONCHIOGENIC CARCINOMA
ENDOCRINE: TUMORS
QUARTZ (<1%) 14808-60-7:
MULTI-DOSE TOXICITY:
INHALATION-HAMSTER TCLO: 3 MG/M3 6 HOUR(S) 78 WEEK(S)-INTERMITTENT
LUNGS, THORAX, OR RESPIRATION: FIBROSIS (INTERSTITIAL)
LUNGS, THORAX, OR RESPIRATION: CHANGES IN LUNG WEIGHT
INHALATION-RAT TCLO: 80 MG/M3 26 WEEK(S)-INTERMITTENT
LUNGS, THORAX, OR RESPIRATION: FIBROSIS, FOCAL (PNEUMOCONIOSIS)
BLOOD: CHANGES IN SPLEEN
IMMUNOLOGICAL INCLUDING ALLERGIC: DECREASE IN CELLULAR IMMUNE RESPONSE
TUMORIGEN / CARCINOGEN:
INHALATION RAT TCLO: 50 MG/M3 6 HOUR(S) 71 WEEK(S)-INTERMITTENT
TUMORIGENIC: CARCINOGENIC BY RTECS CRITERIA
LIVER: TUMORS
GHS PROPERTIES CLASSIFICATION
ACUTE TOXICITY EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
ASPIRATION HAZARD EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
CARCINOGENICITY EU/CLP: CARCINOGENICITY 1A
OSHA HCS 2012: CARCINOGENICITY 1A
GERM CELL MUTAGENICITY EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SKIN CORROSION/IRRITATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SKIN SENSITIZATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
STOT-RE EU/CLP:
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE
1
OSHA HCS 2012:
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE
1
STOT-SE EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
TOXICITY FOR REPRODUCTION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
RESPIRATORY SENSITIZATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SERIOUS EYE DAMAGE/ EU/CLP: DATA LACKING
IRRITATION OSHA HCS 2012: DATA LACKING
ROUTE(S) OF ENTRY/EXPOSURE: INHALATION, SKIN, EYE, INGESTION
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: DISORDERS OF THE LUNGS.
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE): EXPOSURE TO DUST MAY CAUSE IRRITATION.
CHRONIC (DELAYED):
REPEATED AND PROLONGED EXPOSURE TO DUST MAY CAUSE LUNG EFFECTS INCLUDING
PNEUMOCONIOSIS.
SKIN:
ACUTE (IMMEDIATE): EXPOSURE TO DUST MAY CAUSE MECHANICAL IRRITATION.
CHRONIC (DELAYED): NO DATA AVAILABLE.
EYE:
ACUTE (IMMEDIATE):
EXPOSURE TO DUST MAY CAUSE MECHANICAL IRRITATION. EXCESSIVE CONCENTRATIONS
OF NUISANCE DUST IN THE WORKPLACE MAY REDUCE VISIBILITY AND MAY CAUSE
UNPLEASANT DEPOSITS IN EYES.
CHRONIC (DELAYED): NO DATA AVAILABLE.
INGESTION:
ACUTE (IMMEDIATE):
EXCESSIVE CONCENTRATIONS OF NUISANCE DUST IN THE WORKPLACE MAY CAUSE
MECHANICAL IRRITATION TO MUCOUS MEMBRANES.
CHRONIC (DELAYED): NO DATA AVAILABLE.
CARCINOGENIC EFFECTS:
THIS PRODUCT CONTAINS CRYSTALLINE SILICA AS QUARTZ. CRYSTALLINE SILICA IS
CLASSIFIED AS A KNOWN CARCINOGEN ACCORDING TO NTP. REPEATED AND PROLONGED
EXPOSURE MAY CAUSE CANCER.
CARCINOGENIC EFFECTS:
CAS IARC NTP
QUARTZ 14808-60-7 GROUP 1-CARCINOGENIC KNOWN HUMAN CARCINOGEN
KEY TO ABBREVIATIONS:
TC = TOXIC CONCENTRATION
| SECTION 12 - ECOLOGICAL INFORMATION | |
12.1 TOXICITY: DATA LACKING.
12.2 PERSISTENCE AND DEGRADABILITY: DATA LACKING.
12.3 BIOACCUMULATIVE POTENTIAL: DATA LACKING.
12.4 MOBILITY IN SOIL: DATA LACKING.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT AND VPVB ASSESSMENT HAS NOT BEEN CONDUCTED FOR THIS MATERIAL.
12.6 OTHER ADVERSE EFFECTS: NO STUDIES HAVE BEEN FOUND.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
14.1 UN 14.2 UN 14.3 TRANSPORT 14.4 PACKING 14.5
NUMBER PROPER HAZARD GROUP ENVIRONMENTAL
SHIPPING CLASS(ES) HAZARDS
NAME
DOT NDA NOT REGULATED NDA NDA NDA
TDG NDA NOT REGULATED NDA NDA NDA
IMO/ NDA NOT REGULATED NDA NDA NDA
IMDG
IATA/ NDA NOT REGULATED NDA NDA NDA
ICAO
14.6 SPECIAL PRECAUTIONS FOR USER: NONE SPECIFIED.
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: DATA LACKING.
| SECTION 15 - REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: CHRONIC
INVENTORY:
COMPONENT CAS CANADA DSL CANADA NDSL EU EINECS EU ELNICS
GRAPHITE 7782-42-5 YES NO YES NO
QUARTZ 14808-60-7 YES NO YES NO
TALC 14807-96-6 YES NO YES NO
CANADA:
LABOR:
CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES:
TALC 14807-96-6 D2A
QUARTZ 14808-60-7 D2A (IN CERTAIN CASES, THIS
CLASSIFICATION DOES NOT APPLY.
FOR MORE INFORMATION, CONSULT THE
SECTION SUBSTANCE SPECIFIC
ISSUES - SILICA, CRYSTALLINE,
ENCAPSULATED ON HEALTH CANADA'S
WHMIS DIVISION WEBSITE.)
GRAPHITE 7782-42-5 D2A (NATURAL); D2B (SYNTHETIC)
CANADA - WHMIS - INGREDIENT DISCLOSURE LIST:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 1%
GRAPHITE 7782-42-5 NOT LISTED
ENVIRONMENT:
CANADA - CEPA - PRIORITY SUBSTANCES LIST:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
EUROPE:
OTHER:
EU - HAZARDOUS SUBSTANCES RESTRICTED OR PROHIBITED IN ELECTRICAL EQUIPMENT
(2011/65/EU) (ROHS):
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
JAPAN:
ENVIRONMENT:
INVENTORY - JAPAN - INDUSTRIAL SAFETY AND HEALTH LAW SUBSTANCES (ISHL):
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
OTHER:
JAPAN - CHEMICAL SUBSTANCE CONTROL LAW (CSCL) - MONITORING CHEMICAL
SUBSTANCES:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
JAPAN - POISONOUS AND DELETERIOUS SUBSTANCES - SUBSTANCES NOT CONSIDERED
DELETERIOUS:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
JAPAN - POISONOUS AND DELETERIOUS SUBSTANCES - SUBSTANCES NOT CONSIDERED
POISONOUS:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CERCLA/SARA - RADIONUCLIDES AND THEIR REPORTABLE QUANTITIES:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
UNITED STATES - CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 CARCINOGEN, INITIAL DATE 10/1/88
(AIRBORNE PARTICLES OF RESPIRABLE
SIZE)
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
TALC 14807-96-6 NOT LISTED
QUARTZ 14808-60-7 NOT LISTED
GRAPHITE 7782-42-5 NOT LISTED
15.2 CHEMICAL SAFETY ASSESSMENT:
NO CHEMICAL SAFETY ASSESSMENT HAS BEEN CARRIED OUT.
15.3 OTHER INFORMATION:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
| SECTION 16 - OTHER INFORMATION | |
RELEVANT PHRASES (CODE & FULL TEXT):
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
R48/20:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
LAST REVISION DATE: 27/MARCH/2015
PREPARATION DATE: 27/MARCH/2015
DISCLAIMER/STATEMENT OF LIABILITY:
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE. HOWEVER, NO
WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE
RESULTS OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED
HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO
RESPONSIBILITY FOR ITS USE.
KEY TO ABBREVIATIONS:
NDA = NO DATA AVAILABLE
REVISION DATE: 27/MARCH/2015
FORMAT: EU CLP/REACH
LANGUAGE: ENGLISH (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012