| Common Name: | ALUMINUM FLUX PASTE |
| Manufacturer: | LA-CO INDUSTRIES |
| SDS Revision Date: | 10/15/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 31ME57 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
LA-CO INDUSTRIES, INC.
ALUMINUM FLUX PASTE
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH
26, 2012 / RULES AND REGULATIONS
ACCORDING TO CANADIAN HAZARDOUS PRODUCTS REGULATIONS (HPR)
DATE OF ISSUE: 09/07/2011
REVISION DATE: 10/15/2015
SUPERSEDES: 08/31/2015
VERSION: 3.1
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
TRADE NAME: ALUMINUM FLUX PASTE
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: SOLDERING FLUX
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LA-CO INDUSTRIES, INC.
1201 PRATT BOULEVARD
ELK GROVE VILLAGE, IL. 60007-5746
PHONE: (847) 956-7600
FAX: (847) 956-9885
E-MAIL: CUSTOMER_SERVICE@LACO.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
24-HOUR EMERGENCY:
CHEMTREC - U.S.: 1-800-424-9300
INTERNATIONAL: +1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION IN ACCORDANCE WITH THE GLOBALLY HARMONIZED STANDARD:
ACUTE TOX. 4 (ORAL): H302
ACUTE TOX. 4 (INHALATION: DUST,MIST): H332
SKIN CORR. 1B: H314
SKIN SENS. 1: H317
MUTA. 2: H341
REPR. 2: H361
STOT SE 3: H335
STOT RE 2: H373
AQUATIC CHRONIC 2: H411
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
2.2 LABEL ELEMENTS:
GHS-US LABELLING:
HAZARD PICTOGRAMS (GHS-US):
GHS05: CORROSION
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
GHS09: ENVIRONMENT
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H302+H332: HARMFUL IF SWALLOWED OR IF INHALED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H335: MAY CAUSE RESPIRATORY IRRITATION
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P260: DO NOT BREATHE FUME, SPRAY
P264: WASH HANDS THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P272:
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE
P273: AVOID RELEASE TO THE ENVIRONMENT
P280:
WEAR EYE PROTECTION, FACE SHIELD, PROTECTIVE CLOTHING, PROTECTIVE GLOVES
P301+P312:
IF SWALLOWED: CALL A POISON CENTER, A DOCTOR IF YOU FEEL UNWELL
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P304+P340:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P310: IMMEDIATELY CALL A DOCTOR, A POISON CENTER
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL
P321: SPECIFIC TREATMENT (SEE FIRST AID MEASURES ON THIS LABEL)
P330: RINSE MOUTH
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P391: COLLECT SPILLAGE
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
P405: STORE LOCKED UP
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT % (W/W) GHS-US CLASSIFICATION
IDENTIFIER
2-AMINOETHANOL (CAS NO) 56.6 FLAM. LIQ. 4, H227
141-43-5 ACUTE TOX. 4 (ORAL),
H302
ACUTE TOX. 4 (DERMAL),
H312
ACUTE TOX. 4
INHALATION: DUST,MIST),
H332
SKIN CORR. 1B, H314
STOT SE 3, H335
AMMONIUM (CAS NO) 17.92 - 18.87 ACUTE TOX. 3 (ORAL),
HYDROGENDIFLUORIDE 1341-49-7 H301
SKIN CORR. 1B, H314
TIN CHLORIDE (CAS NO) 13.16 - 14.62 ACUTE TOX. 4
7772-99-8 (INHALATION:
DUST,MIST), H332
SKIN CORR. 1C, H314
SKIN SENS. 1, H317
MUTA. 2, H341
REPR. 2, H361
STOT SE 3, H335
STOT RE 2, H373
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
ZINC CHLORIDE (CAS NO) 8.51 - 8.96 ACUTE TOX. 4 (ORAL),
7646-85-7 H302
SKIN CORR. 1B, H314
STOT SE 3, H335
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
AMMONIUM (CAS NO) 0.19 - 0.94 ACUTE TOX. 3 (ORAL),
FLUORIDE 12125-01-8 H301
ACUTE TOX. 3 (DERMAL),
H311
ACUTE TOX. 3
(INHALATION:
DUST,MIST), H331
FULL TEXT OF H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. WASH
WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET IMMEDIATE MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL
UNWELL. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
SUSPECTED OF CAUSING GENETIC DEFECTS. SUSPECTED OF DAMAGING FERTILITY OR
THE UNBORN CHILD. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
SYMPTOMS/INJURIES AFTER INHALATION:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. HARMFUL IF INHALED. MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN
REACTION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/INJURIES AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS
HEALTH HAZARD. HARMFUL IF SWALLOWED.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: CARBON DIOXIDE. DRY POWDER. FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: NO PARTICULAR FIRE OR EXPLOSION HAZARD.
REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPOURS.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE. DO NOT ALLOW RUN-OFF
FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES. COOL ADJACENT
STRUCTURES AND CONTAINERS WITH WATER SPRAY TO PROTECT AND PREVENT
IGNITION.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION. WEAR FIRE/FLAME RESISTANT/RETARDANT CLOTHING.
WEAR A SELF CONTAINED BREATHING APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
AVOID ALL EYE AND SKIN CONTACT AND DO NOT BREATHE VAPOUR AND MIST.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
CHEMICAL GOGGLES OR SAFETY GLASSES. WEAR SUITABLE GLOVES. FACE SHIELD.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
WEAR SUITABLE GLOVES. CHEMICAL GOGGLES OR SAFETY GLASSES. FACE SHIELD.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. DO NOT DISCHARGE INTO DRAINS OR THE
ENVIRONMENT. PREVENT ENTRY TO SEWERS AND PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK.
METHODS FOR CLEANING UP:
TAKE UP IN NON-COMBUSTIBLE ABSORBENT MATERIAL AND SHOVE INTO CONTAINER
FOR DISPOSAL.
6.4. REFERENCE TO OTHER SECTIONS:
SECTION 13: DISPOSAL INFORMATION.
SECTION 7: SAFE HANDLING.
SECTION 8: PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. DO NOT BREATHE FUME, SPRAY.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. USE PERSONAL PROTECTIVE EQUIPMENT
AS REQUIRED. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH HANDS AND OTHER
EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING
AND WHEN LEAVING WORK. WASH CONTAMINATED CLOTHING BEFORE REUSE.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS:
KEEP ONLY IN ORIGINAL CONTAINER. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: SODIUM NITRITE. HYDROGEN FLUORIDE.
PROHIBITIONS ON MIXED STORAGE: INCOMPATIBLE MATERIALS.
STORAGE AREA: STORE IN DRY, COOL, WELL-VENTILATED AREA.
7.3. SPECIFIC END USE(S): FLUX.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
ALUMINUM FLUX PASTE:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
2-AMINOETHANOL (141-43-5):
ACGIH:
ACGIH TWA (MG/M3): 7.5 MG/M3
ACGIH:
ACGIH TWA (PPM): 3 PPM
ACGIH:
ACGIH STEL (MG/M3): 15 MG/M3
ACGIH:
ACGIH STEL (PPM): 6 PPM
ACGIH:
REMARK (ACGIH): EYE & SKIN IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 6 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 3 PPM
CANADA (QUEBEC):
VECD (MG/M3): 15 MG/M3
CANADA (QUEBEC):
VECD (PPM): 6 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 7.5 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 3 PPM
TIN CHLORIDE (7772-99-8):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
ZINC CHLORIDE (7646-85-7):
ACGIH:
ACGIH TWA (MG/M3): 1 MG/M3
ACGIH:
ACGIH STEL (MG/M3): 2 MG/M3
ACGIH:
REMARK (ACGIH): LRT & URT IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 1 MG/M3
CANADA (QUEBEC):
VEMP (MG/M3): 1 MG/M3
AMMONIUM FLUORIDE (12125-01-8):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
AMMONIUM HYDROGENDIFLUORIDE (1341-49-7):
ACGIH: NOT APPLICABLE
OSHA:
OSHA PEL (TWA) (MG/M3): 2.5 MG/M3
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
AVOID CREATING MIST OR SPRAY. EMERGENCY SAFETY SHOWERS SHOULD BE AVAILABLE
IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. EYEWASH STATIONS.
EITHER LOCAL EXHAUST OR GENERAL ROOM VENTILATION IS USUALLY REQUIRED.
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION:
WEAR SUITABLE GLOVES RESISTANT TO CHEMICAL PENETRATION. USE RUBBER GLOVES.
EYE PROTECTION:
FACE SHIELD. CHEMICAL GOGGLES OR SAFETY GLASSES.
SKIN AND BODY PROTECTION:
WEAR SUITABLE PROTECTIVE CLOTHING. IMPERVIOUS CLOTHING.
RESPIRATORY PROTECTION:
WEAR APPROPRIATE MASK. USE AIR-PURIFYING RESPIRATOR EQUIPPED WITH
PARTICULATE FILTERING CARTRIDGES.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
COLOUR: LIGHT AMBER.
ODOUR: AMMONIA-LIKE.
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 6 - 8
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: >93.3 DEG. C
FLASH POINT: >93 DEG. C
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: 1.33
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDISING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 0 %
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPOURS.
10.2. CHEMICAL STABILITY:
STABLE AT AMBIENT TEMPERATURE AND UNDER NORMAL CONDITIONS OF USE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS. SODIUM NITRITE.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION GENERATES:
CORROSIVE VAPOURS. HYDROGEN FLUORIDE. AMMONIA. CARBON MONOXIDE. BURNING
PRODUCES IRRITATING, TOXIC AND NOXIOUS FUMES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL: HARMFUL IF SWALLOWED.
INHALATION: DUST
MIST: HARMFUL IF INHALED.
ALUMINUM FLUX PASTE:
LD50 ORAL RAT: 671 MG/KG
ATE CLP (ORAL): 671.000 MG/KG BODYWEIGHT
ATE CLP (DUST,MIST): 2.174 MG/L/4H
2-AMINOETHANOL (141-43-5):
LD50 ORAL RAT: 1515 MG/KG
LD50 DERMAL RABBIT: 1822 (1822 - 3451) MG/KG
LC50 INHALATION RAT (MG/L): >1.3 MG/L
ATE CLP (ORAL): 1515.000 MG/KG BODYWEIGHT
ATE CLP (DERMAL): 1822.000 MG/KG BODYWEIGHT
ATE CLP (DUST,MIST): 1.500 MG/L/4H
TIN CHLORIDE (7772-99-8):
LD50 ORAL RAT: 2274.6 MG/KG BODYWEIGHT
LC50 INHALATION RAT (MG/L): 2 MG/L/4H
ATE CLP (ORAL): 2274.600 MG/KG BODYWEIGHT
ATE CLP (VAPOURS): 2.000 MG/L/4H
ATE CLP (DUST,MIST): 2.000 MG/L/4H
ZINC CHLORIDE (7646-85-7):
LD50 ORAL RAT: 1100 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG NO EFFECTS WERE SEEN
LC50 INHALATION RAT (MG/L): 2000 MG/M3 CALCULATED
ATE CLP (ORAL): 1100.000 MG/KG BODYWEIGHT
AMMONIUM FLUORIDE (12125-01-8):
LD50 ORAL RAT: 200 (200 - 2000) MG/KG
LC50 INHALATION RAT (MG/L): 1 MG/L/4H READ-ACROSS NAF
ATE CLP (ORAL): 200.000 MG/KG BODYWEIGHT
ATE CLP (DERMAL): 300.000 MG/KG BODYWEIGHT
ATE CLP (VAPOURS): 1.000 MG/L/4H
ATE CLP (DUST,MIST): 1.000 MG/L/4H
AMMONIUM HYDROGENDIFLUORIDE (1341-49-7):
LD50 ORAL RAT: 130 MG/KG
ATE CLP (ORAL): 130.000 MG/KG BODYWEIGHT
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITISATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
SYMPTOMS/INJURIES AFTER INHALATION:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. HARMFUL IF INHALED. MAY CAUSE RESPIRATORY IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN
REACTION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/INJURIES AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS
HEALTH HAZARD. HARMFUL IF SWALLOWED.
LIKELY ROUTES OF EXPOSURE: SKIN AND EYE CONTACT;INHALATION
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
ECOLOGY - WATER: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
2-AMINOETHANOL (141-43-5):
LC50 FISH 1: 165 MG/L 48 H
EC50 DAPHNIA 1: 65 MG/L 48 H
TIN CHLORIDE (7772-99-8):
NOEC CHRONIC CRUSTACEA: 0.18 MG/L
ZINC CHLORIDE (7646-85-7):
LC50 FISH 1: 0.727 (0.727 - 1.65) MG/L ONCORHYNCHUS KISUTCH
EC50 DAPHNIA 1: 0.33 (0.33 - 0.66) MG/L
AMMONIUM FLUORIDE (12125-01-8):
LC50 FISH 1: 209 MG/L 96 H
EC50 OTHER AQUATIC ORGANISMS 1:
26 - 48 MG/L 96 H, TRICHOPTERA AQUATIC LARVAE
NOEC (ACUTE):
11.8 MG/L TEST MAT. ESTIMATED FROM NH3-N CONTENT ACCORDING
TO EPA-600/3-79-091
AMMONIUM HYDROGENDIFLUORIDE (1341-49-7):
LC50 FISH 1: 421.4 NM
EC50 DAPHNIA 1: 109 - 340 MG/L
12.2. PERSISTENCE AND DEGRADABILITY:
ALUMINUM FLUX PASTE:
PERSISTENCE AND DEGRADABILITY:
MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE ENVIRONMENT.
2-AMINOETHANOL (141-43-5):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
TIN CHLORIDE (7772-99-8):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
12.3. BIOACCUMULATIVE POTENTIAL:
2-AMINOETHANOL (141-43-5):
LOG POW: -1.31
TIN CHLORIDE (7772-99-8):
LOG POW: -2.1506
ZINC CHLORIDE (7646-85-7):
BIOACCUMULATIVE POTENTIAL: NOT EXPECTED TO BIOACCUMULATE.
12.4. MOBILITY IN SOIL:
NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
SEWAGE DISPOSAL RECOMMENDATIONS: DO NOT DISPOSE OF WASTE INTO SEWER.
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT AND TDG:
TRANSPORT DOCUMENT DESCRIPTION:
UN1759 CORROSIVE SOLIDS, N.O.S. (2-AMINOETHANOL, AMMONIUM
DIHYDROGENFLUORIDE), 8, II
UN-NO.(DOT): UN1759
PROPER SHIPPING NAME (DOT):
CORROSIVE SOLIDS, N.O.S. (2-AMINOETHANOL, AMMONIUM DIHYDROGENFLUORIDE)
TRANSPORT HAZARD CLASS(ES) (DOT): 8 - CORROSIVE
PACKING GROUP (DOT): II - MEDIUM DANGER
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
ADR:
TRANSPORT DOCUMENT DESCRIPTION:
UN 1759 CORROSIVE SOLID, N.O.S. (2-AMINOETHANOL, AMMONIUM
DIHYDROGENFLUORIDE), 8, II, (E)
PROPER SHIPPING NAME (ADR):
CORROSIVE SOLID, N.O.S. (2-AMINOETHANOL, AMMONIUM DIHYDROGENFLUORIDE)
PACKING GROUP (ADR): II
TRANSPORT HAZARD CLASS(ES) (ADR): 8
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
TRANSPORT BY SEA:
UN-NO. (IMDG): UN 1759
PROPER SHIPPING NAME (IMDG):
CORROSIVE SOLID, N.O.S. (2-AMINOETHANOL,
AMMONIUM DIHYDROGENFLUORIDE)
TRANSPORT HAZARD CLASS(ES) (IMDG): 8
PACKING GROUP (IMDG): II
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
AIR TRANSPORT:
UN-NO. (IATA): UN 1759
PROPER SHIPPING NAME (IATA):
CORROSIVE SOLID, N.O.S. (2-AMINOETHANOL, AMMONIUM DIHYDROGENFLUORIDE)
TRANSPORT HAZARD CLASS(ES) (IATA): 8
PACKING GROUP (IATA): II
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
2-AMINOETHANOL (141-43-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
TIN CHLORIDE (7772-99-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
ZINC CHLORIDE (7646-85-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
AMMONIUM FLUORIDE (12125-01-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 100 LB
AMMONIUM HYDROGENDIFLUORIDE (1341-49-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 100 LB
15.2. INTERNATIONAL REGULATIONS:
CANADA:
2-AMINOETHANOL (141-43-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
TIN CHLORIDE (7772-99-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
ZINC CHLORIDE (7646-85-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
AMMONIUM FLUORIDE (12125-01-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
AMMONIUM HYDROGENDIFLUORIDE (1341-49-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
EU-REGULATIONS:
2-AMINOETHANOL (141-43-5):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
TIN CHLORIDE (7772-99-8):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
ZINC CHLORIDE (7646-85-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
AMMONIUM FLUORIDE (12125-01-8):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
AMMONIUM HYDROGENDIFLUORIDE (1341-49-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NATIONAL REGULATIONS:
ALUMINUM FLUX PASTE:
ALL COMPONENTS ARE LISTED ON THE EEC INVENTORY EUROPEAN INVENTORY OF
EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS).
ALL INGREDIENTS ARE LISTED IN THE TOXIC SUBSTANCES CONTROL ACT (TSCA).
ALL INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST (DSL)
OR NON-DOMESTIC SUBSTANCES LIST (NDSL).
15.3. US STATE REGULATIONS:
2-AMINOETHANOL (141-43-5):
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
TIN CHLORIDE (7772-99-8):
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK - RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
AMMONIUM FLUORIDE (12125-01-8):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
AMMONIUM HYDROGENDIFLUORIDE (1341-49-7):
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES: TRANSPORT INFORMATION.
DATA SOURCES:
CANADIAN CENTRE FOR OCCUPATIONAL HEALTH AND SAFETY. ACCESSED AT:
HTTP://WWW.CCOHS.CA/OSHANSWERS/LEGISL/WHMIS_CLASSIFI.HTML.
ESIS (EUROPEAN CHEMINCAL SUBSTANCES INFORMATION SYSTEM; ACCESSED AT:
HTTP://ESIS.JRC.EC.EUROPA.EU/INDEX.PHP?PGM=CLA.
EUROPEAN CHEMICALS AGENCY (ECHA) REGISTERED SUBSTANCES LIST. ACCESSED AT
HTTP://ECHA.EUROPA.EU/. KRISTER FORSBERG AND S.Z. MANSDORF, "QUICK
SELECTION GUIDE TO CHEMICAL PROTECTIVE CLOTHING", FIFTH EDITION.
NATIONAL FIRE PROTECTION ASSOCIATION; FIRE PROTECTION GUIDE TO HAZARDOUS
MATERIALS; 10TH EDITION.
OSHA 29CFR 1910.1200 HAZARD COMMUNICATION STANDARD.
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELLING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006.
TSCA CHEMICAL SUBSTANCE INVENTORY. ACCESSED AT
HTTP://WWW.EPA.GOV/OPPT/EXISTINGCHEMICALS/PUBS/TSCAINVENTORY/HOWTO.HTML.
ABBREVIATIONS AND ACRONYMS:
ACGIH: (AMERICAN CONFERENCE OF GOVERNEMENT INDUSTRIAL HYGIENISTS).
ATE: ACUTE TOXICITY ESTIMATE.
CAS: (CHEMICAL ABSTRACTS SERVICE) NUMBER.
CLP: CLASSIFICATION, LABELLING, PACKAGING.
EC50:
ENVIRONMENTAL CONCENTRATION ASSOCIATED WITH A RESPONSE BY 50% OF THE TEST
POPULATION.
GHS:
GLOBALLY HARMONIZED SYSTEM (OF CLASSIFICATION AND LABELING OF CHEMICALS).
LD50: LETHAL DOSE FOR 50% OF THE TEST POPULATION.
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION.
PBT: PERSISTENT, BIOACCUMULATIVE, TOXIC.
STEL: SHORT TERM EXPOSURE LIMITS.
TSCA: TOXIC SUBSTANCES CONTROL ACT.
TWA: TIME WEIGHT AVERAGE.
OTHER INFORMATION: NONE.
NFPA HEALTH HAZARD 3 - SHORT EXPOSURE COULD CAUSE SERIOUS TEMPORARY OR
RESIDUAL INJURY EVEN THOUGH PROMPT MEDICAL
ATTENTION WAS GIVEN.
NFPA FIRE HAZARD 1 - MUST BE PREHEATED BEFORE IGNITION CAN OCCUR.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND NOT REACTIVE WITH WATER.
FULL TEXT OF H-STATEMENTS:
ACUTE TOX. 3 (DERMAL): ACUTE TOXICITY (DERMAL), CATEGORY 3
ACUTE TOX. 3 (INHALATION: DUST,MIST):
ACUTE TOXICITY (INHALATION: DUST,MIST) CATEGORY 3
ACUTE TOX. 3 (ORAL): ACUTE TOXICITY (ORAL), CATEGORY 3
ACUTE TOX. 4 (DERMAL): ACUTE TOXICITY (DERMAL), CATEGORY 4
ACUTE TOX. 4 (INHALATION: DUST,MIST):
ACUTE TOXICITY (INHALATION: DUST,MIST) CATEGORY 4
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL), CATEGORY 4
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD, CATEGORY 1
AQUATIC CHRONIC 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 1
AQUATIC CHRONIC 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 2
FLAM. LIQ. 4: FLAMMABLE LIQUIDS, CATEGORY 4
MUTA. 2: GERM CELL MUTAGENICITY, CATEGORY 2
REPR. 2: REPRODUCTIVE TOXICITY, CATEGORY 2
SKIN CORR. 1B: SKIN CORROSION/IRRITATION, CATEGORY 1B
SKIN CORR. 1C: SKIN CORROSION/IRRITATION, CATEGORY 1C
SKIN SENS. 1: SENSITISATION - SKIN, CATEGORY 1
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, RESPIRATORY
TRACT IRRITATION
H227: COMBUSTIBLE LIQUID
H301: TOXIC IF SWALLOWED
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H312: HARMFUL IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H331: TOXIC IF INHALED
H332: HARMFUL IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H400: VERY TOXIC TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
SDS PREPARED BY:
THE REDSTONE GROUP, LLC
6077 FRANTZ RD.
SUITE 206
DUBLIN, OH 43016
USA
T: 614-923-7472
WWW.REDSTONEGRP.COM
LACO NA GHS SDS
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING
ANY SPECIFIC PROPERTY OF THE PRODUCT
EN (ENGLISH)
SDS REF.: LACO1412011