| Common Name: | PLEDGE MULTISURFACE II ANTIBACTERIAL (FRESH CITRUS) |
| Manufacturer: | S.C. JOHNSON |
| SDS Revision Date: | 2/25/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 32GM47 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SC JOHNSON
A FAMILY COMPANY
SAFETY DATA SHEET
ACCORDING TO HAZARD COMMUNICATION STANDARD; 29 CFR 1910.1200
PLEDGE(R*) MULTISURFACE II ANTIBACTERIAL (FRESH CITRUS)
VERSION: 1.1
PRINT DATE: 03/04/2015
REVISION DATE: 02/25/2015
SDS NUMBER: 350000021920
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT INFORMATION:
PRODUCT NAME: PLEDGE(R*) MULTISURFACE II ANTIBACTERIAL (FRESH CITRUS)
RECOMMENDED USE: DISINFECTANT
MANUFACTURER, IMPORTER, SUPPLIER:
S.C. JOHNSON & SON, INC.
1525 HOWE STREET
RACINE, WI 53403-2236
TELEPHONE: +18005585252
EMERGENCY TELEPHONE NUMBER:
24 HOUR MEDICAL EMERGENCY PHONE: (866) 231-5406
24 HOUR INTERNATIONAL EMERGENCY PHONE: (703) 527-3887
24 HOUR TRANSPORT EMERGENCY PHONE: (800) 424-9300
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GLOBALLY HARMONIZED SYSTEM (GHS) CLASSIFICATION:
HAZARD CLASSIFICATION HAZARD CATEGORY HAZARDS IDENTIFICATION
GASES UNDER PRESSURE COMPRESSED GAS CONTAINS GAS UNDER PRESSURE;
MAY EXPLODE IF HEATED.
LABELLING:
HAZARD SYMBOLS: GAS CYLINDER
SIGNAL WORD: WARNING
HAZARD STATEMENTS: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
PRECAUTIONARY STATEMENTS:
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
OTHER HAZARDS: NONE IDENTIFIED
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WEIGHT PERCENT
ISOPROPANOL 67-63-0 1.00 - 5.00
ALKYL ETHYLBENZALKONIUM 85409-23-0 0.0001 - 0.10
N-ALKYL DIMETHYL BENZYL AMMONIUM 53516-76-0 0.0001 - 0.10
CHLORIDE
THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
FOR ADDITIONAL INFORMATION ON PRODUCT INGREDIENTS, SEE
WWW.WHATSINSIDESCJOHNSON.COM.
| 4. FIRST AID MEASURES | |
EYE CONTACT: NO SPECIAL REQUIREMENTS
SKIN CONTACT: NO SPECIAL REQUIREMENTS
INHALATION: NO SPECIAL REQUIREMENTS.
INGESTION: NO SPECIAL REQUIREMENTS
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIFIC HAZARDS DURING FIREFIGHTING:
AEROSOL PRODUCT - CONTAINERS MAY ROCKET OR EXPLODE IN HEAT OF FIRE.
FURTHER INFORMATION:
FIGHT FIRE FROM MAXIMUM DISTANCE OR PROTECTED AREA. COOL AND USE CAUTION
WHEN APPROACHING OR HANDLING FIRE-EXPOSED CONTAINERS. WEAR FULL PROTECTIVE
CLOTHING AND POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS. IN CASE
OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION.
WASH THOROUGHLY AFTER HANDLING.
ENVIRONMENTAL PRECAUTIONS:
OUTSIDE OF NORMAL USE, AVOID RELEASE TO THE ENVIRONMENT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL.
CLEAN RESIDUE FROM SPILL SITE.
| 7. HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
FOR PERSONAL PROTECTION SEE SECTION 8.
KEEP OUT OF REACH OF CHILDREN AND PETS.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
NORMAL MEASURES FOR PREVENTIVE FIRE PROTECTION.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. MG/M3 PPM NON- BASIS
STANDARD
UNITS
ISOPROPANOL 67-63-0 980 MG/M3 400 PPM OSHA TWA
ISOPROPANOL 67-63-0 400 PPM ACGIH STEL
ISOPROPANOL 67-63-0 200 PPM ACGIH TWA
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION: NO SPECIAL REQUIREMENTS.
HAND PROTECTION: NO SPECIAL REQUIREMENTS.
EYE PROTECTION: NO SPECIAL REQUIREMENTS.
SKIN AND BODY PROTECTION: NO SPECIAL REQUIREMENTS.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WASH
THOROUGHLY AFTER HANDLING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
FORM:
AEROSOL
COMPRESSED GAS
COLOR: CLEAR
ODOR: PLEASANT
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 8.0 - 9.0 (UNDILUTED)
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
FLASH POINT: DOES NOT FLASH
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 0.99 G/CM3 AT 20 DEG. C
SOLUBILITY(IES): COMPLETELY SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS TOTAL VOC (WT. %)*:
1.7% - ADDITIONAL EXEMPTIONS MAY APPLY
*AS DEFINED BY US FEDERAL AND STATE CONSUMER PRODUCT REGULATIONS
OTHER INFORMATION: NONE IDENTIFIED
| 10. STABILITY AND REACTIVITY | |
POSSIBILITY OF HAZARDOUS REACTIONS:
IF ACCIDENTAL MIXING OCCURS AND TOXIC GAS IS FORMED, EXIT AREA IMMEDIATELY.
DO NOT RETURN UNTIL WELL VENTILATED.
CONDITIONS TO AVOID: DIRECT SOURCES OF HEAT.
INCOMPATIBLE MATERIALS:
DO NOT MIX WITH BLEACH OR ANY OTHER HOUSEHOLD CLEANERS.
STRONG BASES
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPOURS.
| 11. TOXICOLOGICAL INFORMATION | |
EMERGENCY OVERVIEW: WARNING
ACUTE ORAL TOXICITY:
LD50 MEASURED: >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 MEASURED: >5.11 MG/L
ACUTE DERMAL TOXICITY:
LD50 MEASURED: >5,000 MG/KG
GHS PROPERTIES CLASSIFICATION ROUTES OF ENTRY
ACUTE TOXICITY NO CLASSIFICATION PROPOSED
SKIN CORROSION/IRRITATION NO CLASSIFICATION PROPOSED
SERIOUS EYE DAMAGE/EYE NO CLASSIFICATION PROPOSED
IRRITATION
SKIN SENSITISATION NO CLASSIFICATION PROPOSED
RESPIRATORY SENSITISATION NO CLASSIFICATION PROPOSED
GERM CELL MUTAGENICITY NO CLASSIFICATION PROPOSED
CARCINOGENICITY NO CLASSIFICATION PROPOSED
REPRODUCTIVE TOXICITY NO CLASSIFICATION PROPOSED
SPECIFIC TARGET ORGAN NO CLASSIFICATION PROPOSED
TOXICITY - SINGLE
EXPOSURE
SPECIFIC TARGET ORGAN NO CLASSIFICATION PROPOSED
TOXICITY - REPEATED
EXPOSURE
ASPIRATION HAZARD NO CLASSIFICATION PROPOSED
AGGRAVATED MEDICAL CONDITION: NONE KNOWN.
| 12. ECOLOGICAL INFORMATION | |
PRODUCT: THE PRODUCT ITSELF HAS NOT BEEN TESTED.
TOXICITY:
THE INGREDIENTS IN THIS FORMULA HAVE BEEN REVIEWED AND NO ADVERSE IMPACT TO
THE ENVIRONMENT IS EXPECTED WHEN USED ACCORDING TO LABEL DIRECTIONS.
TOXICITY TO FISH:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
ISOPROPANOL LC50 PIMEPHALES PROMELAS 9,640 MG/L 96 H
(FATHEAD MINNOW)
ALKYL ETHYL- NO DATA
BENZALKONIUM AVAILABLE
N-ALKYL DIMETHYL NO DATA
BENZYL AMMONIUM AVAILABLE
CHLORIDE
TOXICITY TO AQUATIC INVERTEBRATES:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
ISOPROPANOL EC50 DAPHNIA MAGNA 13,299 48 H
(WATER FLEA) MG/L
ALKYL ETHYL- EC50: DAPHNIA (WATER 0.016 MG/L
BENZALKONIUM NO DATA FLEA)
AVAILABLE
N-ALKYL DIMETHYL NO DATA
BENZYL AMMONIUM AVAILABLE
CHLORIDE
TOXICITY TO AQUATIC PLANTS:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
ISOPROPANOL EC50 DESMODESMUS >1,000 72 H
SUBSPICATUS (GREEN MG/L
ALGAE)
ALKYL ETHYL- NO DATA
BENZALKONIUM AVAILABLE
N-ALKYL DIMETHYL NO DATA
BENZYL AMMONIUM AVAILABLE
CHLORIDE
PERSISTENCE AND DEGRADABILITY:
COMPONENT BIODEGRADATION EXPOSURE SUMMARY
TIME
ISOPROPANOL 53% 5 D READILY BIODEGRADABLE
ALKYL ETHYL- 60% 13 D READILY BIODEGRADABLE
BENZALKONIUM
N-ALKYL DIMETHYL NO DATA AVAILABLE
BENZYL AMMONIUM
CHLORIDE
BIOACCUMULATIVE POTENTIAL:
COMPONENT BIOCONCENTRATION PARTITION COEFFICIENT N-
FACTOR (BCF) OCTANOL/WATER (LOG)
ISOPROPANOL 0.96 ESTIMATED 0.05
ALKYL ETHYLBENZALKONIUM NO DATA AVAILABLE NO DATA AVAILABLE
N-ALKYL DIMETHYL BENZYL NO DATA AVAILABLE NO DATA AVAILABLE
AMMONIUM CHLORIDE
MOBILITY:
COMPONENT END POINT VALUE
ISOPROPANOL NO DATA AVAILABLE
ALKYL ETHYLBENZALKONIUM NO DATA AVAILABLE
N-ALKYL DIMETHYL BENZYL NO DATA AVAILABLE
AMMONIUM CHLORIDE
PBT AND VPVB ASSESSMENT:
COMPONENT RESULTS
ISOPROPANOL NOT FULFILLING PBT AND VPVB CRITERIA
ALKYL ETHYLBENZALKONIUM NOT FULFILLING PBT AND VPVB CRITERIA
N-ALKYL DIMETHYL BENZYL NOT FULFILLING PBT AND VPVB CRITERIA
AMMONIUM CHLORIDE
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
CONSUMER MAY DISCARD EMPTY CONTAINER IN TRASH, OR RECYCLE WHERE FACILITIES
EXIST.
| 14. TRANSPORT INFORMATION | |
PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP-TO-DATE
SHIPPING INFORMATION.
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT
UN NUMBER 1950 1950 1950
UN PROPER UN 1950 AEROSOLS, UN 1950 UN 1950 AEROSOLS,
SHIPPING NAME NON-FLAMMABLE, 2.2, AEROSOLS, NON- NON-FLAMMABLE,
LTD QTY FLAMMABLE, 2.2, 2.2, LTD QTY
LTD QTY
TRANSPORT 2.2 2 2.2
HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL
HAZARDS
SPECIAL LIMITED QUANTITIES LIMITED QUANTITIES LIMITED QUANTITIES
PRECAUTIONS DEROGATION MAY BE DEROGATION MAY BE DEROGATION MAY BE
FOR USER APPLICABLE TO THIS APPLICABLE TO THIS APPLICABLE TO THIS
PRODUCT, PLEASE PRODUCT, PLEASE PRODUCT, PLEASE
CHECK TRANSPORT CHECK TRANSPORT CHECK TRANSPORT
DOCUMENTS. DOCUMENTS. DOCUMENTS.
| 15. REGULATORY INFORMATION | |
FIFRA LABELING:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS, AND FOR
WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS.
FOLLOWING IS THE HAZARD INFORMATION AS REQUIRED ON THE PESTICIDE LABEL:
CONTENTS UNDER PRESSURE.
EXPOSURE TO TEMPERATURES ABOVE 130 DEG. F MAY CAUSE BURSTING.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON
THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT COMPLY WITH THE NEW SUBSTANCES NOTIFICATION
REQUIREMENTS UNDER THE CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA).
CALIFORNIA PROP. 65:
THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS UNDER
CALIFORNIA'S PROPOSITION 65.
REGISTRATION # / AGENCY: 4822-576/US/EPA
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
NFPA RATINGS:
HEALTH 1
FIRE 0
REACTIVITY 0
SPECIAL
THIS INFORMATION IS BEING PROVIDED IN ACCORDANCE WITH THE OCCUPATIONAL
SAFETY AND HEALTH ADMINISTRATION (OSHA) REGULATION (29 CFR 1910.1200). THE
INFORMATION SUPPLIED IS DESIGNED FOR WORKPLACES WHERE PRODUCT USE AND
FREQUENCY OF EXPOSURE EXCEEDS THAT ESTABLISHED FOR THE LABELED CONSUMER
USE.
FURTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED TO BE
TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESSED OR
IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED HEREIN. ACTUAL
CONDITIONS OF USE ARE BEYOND THE SELLER'S CONTROL. USER IS RESPONSIBLE TO
EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT FOR ANY PARTICULAR
USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND
REGULATIONS.
PREPARED BY:
SC JOHNSON GLOBAL SAFETY ASSESSMENT & REGULATORY AFFAIRS (GSARA)