| Common Name: | TRESEMME TRES TWO NON-AEROSOL HAIR SPRAY (PUMP) -ALL VARIANTS, EXTRA HOLD, ULTRA |
| Manufacturer: | UNILEVER |
| SDS Revision Date: | 9/22/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 32GN22 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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U
UNILEVER
SAFETY DATA SHEET
TRESEMME TRES TWO NON-AEROSOL HAIR SPRAY (PUMP) - ALL VARIANTS
EXTRA HOLD, ULTRA FINE MIST
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME:
TRESEMME TRES TWO NON-AEROSOL HAIR SPRAY (PUMP) -ALL VARIANTS
EXTRA HOLD, ULTRA FINE MIST
PRODUCT TYPE: NON-AEROSOL HAIRSPRAY
UPC CODE: 022400643366, 022400000206. 022400652290
INTERNAL PRODUCT CODE: M_ 20001501, M20005784
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES:
INDUSTRIAL USES:
USES OF SUBSTANCES AS SUCH OR IN PREPARATIONS AT INDUSTRIAL SITES
CONSUMER USES: PRIVATE HOUSEHOLDS (= GENERAL PUBLIC = CONSUMERS)
PROFESSIONAL USES:
PUBLIC DOMAIN (ADMINISTRATION, EDUCATION, ENTERTAINMENT, SERVICES,
CRAFTSMEN)
SUPPLIER'S DETAILS:
UNILEVER
700 SYLVAN AVENUE
ENGLEWOOD CLIFFS NJ 07632
USA
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
PHONE #: 800-761-3683 MONDAY THRU FRIDAY (8:30 AM - 5:00 PM EST)
EMERGENCY #: 800-745-9269 (24 HOURS)
POISON CONTROL #: 800-949-7866 (24 HOURS)
CHEMTREC #: 800-424-9300(24 HOURS, TRANSPORTATION EMERGENCIES)
CONSUMER INFORMATION:
FOR INFORMATION REGARDING THE USE OF THIS PRODUCT BY A CONSUMER, PLEASE
REFER DIRECTLY TO THE PRODUCT LABEL. THIS INDUSTRIAL MSDS IS PROVIDED FOR
WORKPLACE EMPLOYEES, PER US OSHA REGULATIONS. IT CONTAINS RECOMMENDATIONS
FOR HANDLING OF THIS PRODUCT IN AN OCCUPATIONAL, OR WORKPLACE, SETTING.
ANY FIRST AID OR WARNINGS THAT ARE APPLICABLE TO CONSUMER USE ARE STATED
DIRECTLY ON THE PRODUCT LABEL, IN ACCORDANCE WITH ALL APPLICABLE GOVERNMENT
REGULATIONS.
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 2
SERIOUS EYE DAMAGE/ EYE IRRITATION: CATEGORY 2B
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: FLAME
SIGNAL WORD: DANGER.
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
WEAR EYE OR FACE PROTECTION. WEAR PROTECTIVE GLOVES. KEEP AWAY FROM HEAT,
SPARKS, OPEN FLAMES AND HOT SURFACES. - NO SMOKING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF USED UP CONTAINER IN ACCORDANCE WITH LOCAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS: NONE KNOWN.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: SUBSTANCE
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % CAS NUMBER
ALCOHOL 45 - 55 64-17-5
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST-AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
KYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. GET
MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND
THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK.
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: MAY BE IRRITATING TO MOUTH, THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
NFPA 30B CLASSIFICATION: NOT AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS: NO SPECIFIC DATA.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILT MATERIAL. PUT
ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILT MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. PREVENT ENTRY
INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH SPILLAGES
INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN AND COLLECT
SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND, EARTH,
VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR DISPOSAL
ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A LICENSED
WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELLED CONTAINERS. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
ALCOHOL OSHA PEL 1989 1989-03-01 TWA:
1,900 MG/M3
1,000 PPM
FORM:
OSHA PEL 1993-06-30 TWA:
1,900 MG/M3
1,000 PPM
FORM:
NIOSH REL 1994-06-01 TWA:
1,900 MG/M3
1,000 PPM
FORM:
ACGIH TLV 2008-11-24 STEL:
1,000 PPM
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. IF USER OPERATIONS GENERATE DUST,
FUMES, GAS, VAPOUR OR MIST, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID
COLOUR: COLOURLESS
ODOUR: PERFUMED
ODOUR THRESHOLD: NOT AVAILABLE.
PH: 5.0
MELTING POINT: NOT APPLICABLE
BOILING POINT: NOT AVAILABLE.
FLASH POINT: 23.9 DEG. C (75.02 DEG. F)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: NOT AVAILABLE.
UPPER: NOT AVAILABLE.
VAPOUR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
DYNAMIC: NOT AVAILABLE.
KINEMATIC: NOT AVAILABLE.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED. UNDER NORMAL CONDITIONS OF STORAGE
AND USE, HAZARDOUS DECOMPOSITION PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
CONCLUSION/SUMMARY: VERY LOW TOXICITY TO HUMANS OR ANIMALS.
IRRITATION/CORROSION:
CONCLUSION/SUMMARY:
SKIN: THE MIXTURE IS NOT AN IRRITANT FOR THE SKIN.
EYES: CAUSES EYE IRRITATION.
RESPIRATORY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SENSITISATION:
CONCLUSION/SUMMARY:
SKIN: BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
RESPIRATORY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
MUTAGENICITY:
CONCLUSION/SUMMARY: NOT APPLICABLE.
CARCINOGENICITY:
CONCLUSION/SUMMARY:
NOT CLASSIFIED OR LISTED BY IARC, NTP, OSHA, EU AND ACGIH.
REPRODUCTIVE TOXICITY:
CONCLUSION/SUMMARY: NOT APPLICABLE.
TERATOGENICITY:
CONCLUSION/SUMMARY: NOT APPLICABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: MAY BE IRRITATING TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS:
CONCLUSION/SUMMARY: VERY LOW TOXICITY TO HUMANS OR ANIMALS.
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL >5,000 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
CONCLUSION/SUMMARY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
PERSISTENCE AND DEGRADABILITY:
CONCLUSION/SUMMARY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMISED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL
TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE
DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE
OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY
BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS
CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF SPILT MATERIAL AND
RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
RCRA CLASSIFICATION: D001 (IGNITABLE)
UNITED STATES - RCRA ACUTE HAZARDOUS WASTE "P" LIST: NOT LISTED
UNITED STATES - RCRA TOXIC HAZARDOUS WASTE "U" LIST: NOT LISTED
| SECTION 14. TRANSPORT INFORMATION | |
FOR SHIPMENT IN CONSUMER GROUND WATER AIR
PACKAGING
PROPER SHIPPING NAME ETHANOL ETHANOL ETHANOL
SOLUTION SOLUTION SOLUTION
HAZARD CLASS 3 3 3
UN/ID # UN1170 UN1170 UN1170
PACKING GROUP III III III
REQUIRED MARKINGS LIMITED LIMITED LIMITED QUANTITY
AND/OR LABELS QUANTITY FOR QUANTITY FOR MARKING FOR
PACKAGES NOT PACKAGES NOT PACKAGES
PREPARED FOR PREPARED FOR PREPARED FOR
AIR TRANSPORT AIR TRANSPORT AIR TRANSPORT
CLASS 3,
FLAMMABLE
LIQUIDS
UN1170
ETHANOL SOLUTION
MARKINGS AND/OR LIMITED LIMITED LIMITED
LABEL TYPES QUANTITY QUANTITY QUANTITY,
FLAMMABLE
LIQUID
ADDITIONAL ERG #127 ERG #127 ERG #127
NFORMATION: MARINE PROPER SHIPPING
POLLUTANT: NAME & UN # MUST
NOT REGULATED BE SHOWN ON THE
PACKAGE.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES: ALWAYS TRANSPORT IN CLOSED CONTAINERS
THAT ARE UPRIGHT AND SECURE. ENSURE THAT PERSONS TRANSPORTING THE PRODUCT
HAVE BEEN TRAINED IN THE EVENT OF AN ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX IT OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES - TSCA 12(B) - CHEMICAL EXPORT NOTIFICATION:
NONE OF THE COMPONENTS ARE LISTED.
UNITED STATES - TSCA 4(A) - FINAL TEST RULES: NOT LISTED
UNITED STATES - TSCA 4(A) - ITC PRIORITY LIST: NOT LISTED
UNITED STATES - TSCA 4(A) - PROPOSED TEST RULES: NOT LISTED
UNITED STATES - TSCA 4(F) - PRIORITY RISK REVIEW: NOT LISTED
UNITED STATES - TSCA 5(A)2 - FINAL SIGNIFICANT NEW USE RULES: NOT LISTED
UNITED STATES - TSCA 5(A)2 - PROPOSED SIGNIFICANT NEW USE RULES: NOT LISTED
UNITED STATES - TSCA 5(E) - SUBSTANCES CONSENT ORDER: NOT LISTED
UNITED STATES - TSCA 6 - FINAL RISK MANAGEMENT: NOT LISTED
UNITED STATES - TSCA 6 - PROPOSED RISK MANAGEMENT: NOT LISTED
UNITED STATES - TSCA 8(A) - CHEMICAL RISK RULES: NOT LISTED
UNITED STATES - TSCA 8(A) - DIOXIN/FURAN PRECURSOR: NOT LISTED
UNITED STATES - TSCA 8(A) - CHEMICAL DATA REPORTING (CDR): NOT DETERMINED
UNITED STATES - TSCA 8(A) - PRELIMINARY ASSESSMENT REPORT (PAIR):
NOT LISTED
UNITED STATES - TSCA 8(C) - SIGNIFICANT ADVERSE REACTION (SAR): NOT LISTED
UNITED STATES - TSCA 8(D) - HEALTH AND SAFETY STUDIES: NOT LISTED
UNITED STATES - EPA CLEAN WATER ACT (CWA) SECTION 307 - PRIORITY
POLLUTANTS:
NOT LISTED
UNITED STATES - EPA CLEAN WATER ACT (CWA) SECTION 311 - HAZARDOUS
SUBSTANCES:
NOT LISTED
UNITED STATES - EPA CLEAN AIR ACT (CAA) SECTION 112 - ACCIDENTAL RELEASE
PREVENTION - FLAMMABLE SUBSTANCES: NOT LISTED
UNITED STATES - EPA CLEAN AIR ACT (CAA) SECTION 112 - ACCIDENTAL RELEASE
PREVENTION - TOXIC SUBSTANCES: NOT LISTED
UNITED STATES - DEPARTMENT OF COMMERCE - PRECURSOR CHEMICAL: NOT LISTED
CLEAN AIR ACT SECTION 112(B) HAZARDOUS AIR POLLUTANTS (HAPS): NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % EHS SARA 302/304
ALCOHOL 45 - 55 YES. SARA 304 RQ: 100 LB/LBS
SARA 304 RQ: 188.2 LBS
SARA 311/312:
CLASSIFICATION:
DELAYED (CHRONIC) HEALTH HAZARD.
FIRE HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % CLASSIFICATION
ALCOHOL 45 - 55 F, CH
SARA 313: NONE OF THE COMPONENTS ARE LISTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: ALCOHOL
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
ALCOHOL
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED:
ALCOHOL
US CALIFORNIA 22CCR APPENDIX X SUBSTANCES: ALCOHOL
CALIFORNIA PROP. 65: NOT APPLICABLE.
UNITED STATES INVENTORY (TSCA 8B): EXEMPTED
CANADA INVENTORY: NOT DETERMINED.
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): NOT DETERMINED.
TAIWAN INVENTORY (CSNN): NOT DETERMINED.
MALAYSIA INVENTORY (EHS REGISTER): NOT DETERMINED.
JAPAN INVENTORY: NOT DETERMINED.
CHINA INVENTORY (IECSC): NOT DETERMINED.
KOREA INVENTORY: NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE I CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE II CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE III CHEMICALS: NOT LISTED
| SECTION 16. OTHER INFORMATION | |
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE HAZARDS
OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL FIRE
PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS NOT
THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
HISTORY:
DATE OF PRINTING: 09.22.2016
DATE OF ISSUE/DATE OF REVISION: 09.22.2016
DATE OF PREVIOUS ISSUE: 11.23.2015
VERSION: 1.2
PREPARED BY:
GLOBAL PRODUCT COMPLIANCE
UNILEVER REGULATORY AFFAIRS
40 MERRITT BLVD
TRUMBULL, CT 06611
USA
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL & INDUSTRIAL HYGIENISTS
AH: ACUTE HAZARD
BCF: BIOCONCENTRATION FACTOR
CAA: CLEAN AIR ACT
CARB: CALIFORNIA AIR RESOURCES BOARD
CCR: CALIFORNIA CODE OF REGULATIONS
CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION & LIABILITY ACT
CFR: CODE OF FEDERAL REGULATIONS
CH: CHRONIC HAZARD
CWA: CLEAN WATER ACT
DEA: DRUG ENFORCEMENT ADMINISTRATION
DOT: DEPARTMENT OF TRANSPORTATION
EC: EUROPEAN COMMISSION
EPCRA: EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW ACT
EST: EASTERN STANDARD TIME
F: FIRE
HAPS: HAZARDOUS AIR POLLUTANTS
HCS: HAZARD COMMUNICATION STANDARD
HMIS: HAZARDOUS MATERIALS INFORMATION SYSTEM
HVOC: HIGH VOLATILE ORGANIC COMPOUND
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IARC: INTERNATIONAL AGENCY FOR THE RESEARCH OF CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
ITC: INTERAGENCY TESTING COMMITTEE (TSCA)
KOC: ORGANIC CARBON/WATER PARTITION CONSTANT
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
LVOC: LOW VOLATILE ORGANIC COMPOUND
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
MPPCF: MILLION PARTICLES PER CUBIC FOOT
N/A: NOT APPLICABLE
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NOEC: NO OBSERVABLE EFFECT CONCENTRATION
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: OCCUPATION SAFETY & HEALTH ADMINISTRATION
PEL: PERMISSIBLE EXPOSURE LIMIT
RCRA: RESOURCE CONSERVATION & RECOVERY ACT
RQ: REPORTABLE QUANTITY
RTK: RIGHT-TO-KNOW
SARA: SUPERFUND AMENDMENTS & REAUTHORIZATION ACT
STEL: SHORT-TERM EXPOSURE LIMIT
TBD: TO BE DETERMINED
TCC: TAGLIABUE CLOSED CUP
TCLP: TOXICITY CHARACTERISTIC LEACHING PROCEDURE
TDG: TRANSPORT OF DANGEROUS GOODS
TLV: THRESHOLD LIMIT VALUE
TSCA: TOXIC SUBSTANCES CONTROL ACT
TWA: TIME WEIGHTED AVERAGE
UN: UNITED NATIONS
REFERENCES:
EVALUATION METHOD USED FOR MIXTURE CLASSIFICATION: CALCULATION METHOD.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVENAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN. FINAL DETERMINATION OF SUITABILITY OF ANY
MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS
ARE DESCRIBED HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.