| Common Name: | STAIN-SORB |
| Manufacturer: | TOTAL SOLUTIONS |
| SDS Revision Date: | 3/27/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 32HC94, 32HC95 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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TOTAL SOLUTIONS(TM)
STAIN-SORB
SAFETY DATA SHEET
| SECTION 1: PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: STAIN-SORB
USE OF THE SUBSTANCE/MIXTURE: ABSORBENT
PRODUCT CODE: 0159
COMPANY:
TOTAL SOLUTIONS
P.O. BOX 240014
MILWAUKEE, WI 53224
USA
T: (414) 354-6417
EMERGENCY NUMBER:
CHEMTREC: (800) 424-9300
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
EYE IRRIT. 2B H320
SKIN SENS. 1 H317
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
MAY CAUSE AN ALLERGIC SKIN REACTION
CAUSES EYE IRRITATION
PRECAUTIONARY STATEMENTS (GHS-US):
AVOID BREATHING SPRAY
WASH THOROUGHLY AFTER HANDLING
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE
WEAR EYE PROTECTION, PROTECTIVE CLOTHING, PROTECTIVE GLOVES
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
FULL TEXT OF H-PHRASES: SEE SECTION 16
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION (GHS-US)
SILICA/SURFACTANT (CAS NO): PROPRIETARY 10-30 EYE IRRIT. 2B, H320
BLEND
(+)-LIMONENE (CAS NO): 5989-27-5 0.1-1 FLAM. LIQ. 3, H226
SKIN IRRIT. 2, H315
SKIN SENS. 1, H317
ASP. TOX. 1, H304
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION: REMOVE THE VICTIM INTO FRESH AIR.
FIRST-AID MEASURES AFTER SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE. WASH WITH PLENTY
OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. DO NOT INDUCE VOMITING.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
SYMPTOMS/INJURIES AFTER INHALATION: NONE UNDER NORMAL USE.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
GASTROINTESTINAL COMPLAINTS. DIARRHOEA. CRAMPS/UNCONTROLLED MUSCULAR
CONTRACTIONS. HEADACHE. VOMITING.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: TREAT SYMPTOMATICALLY.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: ALL EXTINGUISHING MEDIA ALLOWED.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
REACTIVITY:
THERMAL DECOMPOSITION MAY PRODUCE OXIDES OF CARBON AND NITROGEN. HYDROGEN
CHLORIDE. METHYL CHLORIDE.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE. USE WATER SPRAY OR FOG
FOR COOLING EXPOSED CONTAINERS. TAKE ACCOUNT OF ENVIRONMENTALLY HAZARDOUS
FIREFIGHTING WATER.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES: ISOLATE FROM FIRE, IF POSSIBLE, WITHOUT UNNECESSARY RISK.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: PROTECTIVE GOGGLES. GLOVES. PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
EVACUATE UNNECESSARY PERSONNEL. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
VENTILATE SPILLAGE AREA.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES:
STOP LEAK IF SAFE TO DO SO. STOP RELEASE. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT ENTRY TO SEWERS AND PUBLIC
WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS.
METHODS FOR CLEANING UP:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY, AND AS
PER LOCAL LEGISLATION.
6.4. REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
COMPLY WITH THE LEGAL REQUIREMENTS. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. HANDLE AND OPEN THE CONTAINER
WITH CARE.
HYGIENE MEASURES:
WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE
ALLOWED OUT OF THE WORKPLACE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS: STORE IN ORIGINAL CONTAINER.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS.
STORAGE AREA:
MEET THE LEGAL REQUIREMENTS. STORE IN A COOL AREA. STORE IN A
WELL-VENTILATED PLACE.
SPECIAL RULES ON PACKAGING: MEET THE LEGAL REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS: NO ADDITIONAL INFORMATION AVAILABLE
8.2. EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING. USE APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT WHEN RISK ASSESSMENT INDICATES THIS IS NECESSARY.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: OPAQUE. OFF-WHITE. LIQUID.
ODOR: MILD
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 9 - 11
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: >200 DEG. F
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 1.04 G/ML
SOLUBILITY: SOLUBLE IN WATER
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VOC CONTENT: <1%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THERMAL DECOMPOSITION MAY PRODUCE OXIDES OF CARBON AND NITROGEN. HYDROGEN
CHLORIDE. METHYL CHLORIDE.
10.2. CHEMICAL STABILITY: NO ADDITIONAL INFORMATION AVAILABLE
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REFER TO SECTION 10.1 ON REACTIVITY.
10.4. CONDITIONS TO AVOID: NO ADDITIONAL INFORMATION AVAILABLE
10.5. INCOMPATIBLE MATERIALS: OXIDIZING AGENTS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
(+)-LIMONENE (5989-27-5):
LD50 ORAL RAT:
4400 MG/KG BODY WEIGHT (RAT; OECD 423: ACUTE ORAL TOXICITY - ACUTE TOXIC
CLASS METHOD; LITERATURE STUDY; >2000 MG/KG BODYWEIGHT; RAT; READ-ACROSS)
LD50 DERMAL RABBIT:
>5000 MG/KG BODY WEIGHT (RABBIT; WEIGHT OF EVIDENCE; EQUIVALENT OR SIMILAR
TO OECD 402)
ATE CLP (ORAL): 4400.000 MG/KG BODY WEIGHT
SILICA/SURFACTANT BLEND (PROPRIETARY):
LD50 ORAL RAT: >2000 MG/KG
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 9 - 11
SERIOUS EYE DAMAGE/IRRITATION: CAUSES EYE IRRITATION.
PH: 9 - 11
RESPIRATORY OR SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
(+)-LIMONENE (5989-27-5):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION: NONE UNDER NORMAL USE.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
GASTROINTESTINAL COMPLAINTS. DIARRHOEA. CRAMPS/UNCONTROLLED MUSCULAR
CONTRACTIONS. HEADACHE. VOMITING.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
(+)-LIMONENE (5989-27-5):
LC50 FISH 1: 720 (MICRO)G/L (96 H; PIMEPHALES PROMELAS; LETHAL)
EC50 DAPHNIA 1: 0.36 MG/L (48 H; DAPHNIA MAGNA; GLP)
LC50 FISH 2: 702 (MICRO)G/L (96 H; PIMEPHALES PROMELAS)
THRESHOLD LIMIT ALGAE 1: 150 MG/L (72 H; DESMODESMUS SUBSPICATUS; GLP)
THRESHOLD LIMIT ALGAE 2: 2.62 MG/L (72 H; DESMODESMUS SUBSPICATUS)
12.2. PERSISTENCE AND DEGRADABILITY:
(+)-LIMONENE (5989-27-5)
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. FORMING SEDIMENTS IN WATER. ADSORBS INTO
THE SOIL.
THOD: 3.29 G O/G SUBSTANCE
12.3. BIOACCUMULATIVE POTENTIAL:
(+)-LIMONENE (5989-27-5):
BCF FISH 1: 864.8 - 1022 (PISCES; FRESH WEIGHT)
LOG POW:
4.38 (EXPERIMENTAL VALUE; OECD 117: PARTITION COEFFICIENT
(N-OCTANOL/WATER), HPLC METHOD; 37 DEG. C)
BIOACCUMULATIVE POTENTIAL:
POTENTIAL FOR BIOACCUMULATION (4 >/= LOG KOW </=5).
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT: NOT REGULATED FOR TRANSPORT
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
ADR: NO ADDITIONAL INFORMATION AVAILABLE
TRANSPORT BY SEA: NO ADDITIONAL INFORMATION AVAILABLE
AIR TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY.
THIS PRODUCT OR MIXTURE DOES NOT CONTAIN A TOXIC CHEMICAL OR CHEMICALS IN
EXCESS OF THE APPLICABLE DE MINIMIS CONCENTRATION AS SPECIFIED IN
40 CFR SUBSECTION 372.38(A) SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 AND 40 CFR PART 372.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER AND/OR REPRODUCTIVE TOXICITY.
| SECTION 16: OTHER INFORMATION | |
TRAINING ADVICE:
NORMAL USE OF THIS PRODUCT SHALL IMPLY USE IN ACCORDANCE WITH THE
INSTRUCTIONS ON THE PACKAGING.
FULL TEXT OF H-PHRASES:
ASP. TOX. 1: ASPIRATION HAZARD CATEGORY 1
EYE IRRIT. 2B: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2B
FLAM. LIQ. 3: FLAMMABLE LIQUIDS CATEGORY 3
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION CATEGORY 2
SKIN SENS. 1: SKIN SENSITIZATION CATEGORY 1
H226: FLAMMABLE LIQUID AND VAPOR
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H320: CAUSES EYE IRRITATION
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
PREPARED BY: TECHNICAL DEPARTMENT
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT. NO WARRANTY IS EXPRESSED OR IMPLIED
REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS OBTAINED FROM THE USE
THEREOF. OUR COMPANY ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR
PROPERTY DAMAGE TO THE VENDEE, USERS OR THIRD PARTIES CAUSED BY THE
MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF
THIS MATERIAL.
DATE OF ISSUE: 7/2/2015
REVISION DATE: 03/27/2015
VERSION: 1.0
P GHS SDS