| Common Name: | PLASTIC AND GLASS CLEANER |
| Manufacturer: | TECHSPRAY |
| SDS Revision Date: | 5/5/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 32LE93 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
TECHSPRAY
PLASTIC AND GLASS CLEANER
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: PLASTIC AND GLASS CLEANER
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: AEROSOL.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
SUPPLIER'S DETAILS:
MANUFACTURER:
TECHSPRAY
8125 COBB CENTER DRIVE
KENNESAW, GA 30152
TEL:
800-858-4043
1 703-527-3887
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
CHEMTREC: 1-800-858-4043
CANTUC (CANADIAN TRANSPORTATION): (613) 996-6666
EMERGENCY PHONE: (800) 858-4043 24/7
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
WHILE THIS MATERIAL IS NOT CONSIDERED HAZARDOUS BY THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200), THIS SDS CONTAINS VALUABLE
INFORMATION CRITICAL TO THE SAFE HANDLING AND PROPER USE OF THE PRODUCT.
THIS SDS SHOULD BE RETAINED AND AVAILABLE FOR EMPLOYEES AND OTHER USERS
OF THIS PRODUCT.
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: GASES UNDER PRESSURE
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: GAS CYLINDER
SIGNAL WORD: WARNING
HAZARD STATEMENTS: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
PRECAUTIONARY STATEMENTS:
PREVENTION: NOT APPLICABLE.
RESPONSE: NOT APPLICABLE.
STORAGE: PROTECT FROM SUNLIGHT. STORE IN COOL/WELL-VENTILATED PLACE.
DISPOSAL: NOT APPLICABLE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
PRODUCT CODE: 1625-18S
INGREDIENT NAME % CAS NUMBER
ETHYL ALCOHOL 1 - 5 64-17-5
ETHYLENE GLYCOL MONOBUTYL ETHER 0.5 - 1.5 111-76-2
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. GET
MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND
THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK.
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: MAY CAUSE EYE IRRITATION.
INHALATION: MAY BE IRRITATING TO EYES, SKIN AND RESPIRATORY SYSTEM.
SKIN CONTACT: MAY CAUSE EYE IRRITATION.
INGESTION:
DO NOT INGEST. IF SWALLOWED THEN SEEK IMMEDIATE MEDICAL ASSISTANCE.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
STOMACH PAINS
NAUSEA OR VOMITING
INGESTION SEEK MEDICAL ATTENTION.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST. BURSTING AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT
HIGH SPEED.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE
AREA IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. IN THE CASE OF AEROSOLS BEING RUPTURED, CARE
SHOULD BE TAKEN DUE TO THE RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND
PROPELLANT. IF A LARGE NUMBER OF CONTAINERS ARE RUPTURED, TREAT AS A BULK
MATERIAL SPILLAGE ACCORDING TO THE INSTRUCTIONS IN THE CLEAN-UP SECTION.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. PUT ON APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. PREVENT ENTRY
INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH SPILLAGES
INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN AND
COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF
VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. AVOID BREATHING
GAS. AVOID BREATHING VAPOR OR MIST.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS
AND FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED
CLOTHING AND PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE
ALSO SECTION 8 FOR ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE AWAY FROM DIRECT
SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
ETHYL ALCOHOL ACGIH TLV (UNITED STATES, 4/2014).
STEL: 1000 PPM 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 1900 MG/M3 10 HOURS.
TWA: 1000 PPM 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 1900 MG/M3 8 HOURS.
TWA: 1000 PPM 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 1900 MG/M3 8 HOURS.
TWA: 1000 PPM 8 HOURS.
ETHYLENE GLYCOL ACGIH TLV (UNITED STATES, 4/2014).
MONOBUTYL ETHER TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
ABSORBED THROUGH SKIN.
TWA: 24 MG/M3 10 HOURS.
TWA: 5 PPM 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
ABSORBED THROUGH SKIN.
TWA: 240 MG/M3 8 HOURS.
TWA: 50 PPM 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
ABSORBED THROUGH SKIN.
TWA: 120 MG/M3 8 HOURS.
TWA: 25 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. IF USER OPERATIONS GENERATE DUST,
FUMES, GAS, VAPOR OR MIST, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL
PRODUCTS, BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE
END OF THE WORKING PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO
REMOVE POTENTIALLY CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING
BEFORE REUSING. ENSURE THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE
CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN
A RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON
THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED
BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE
LEVELS, THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE
SELECTED RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: CLEAR. COLORLESS.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 10.3
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 100 DEG. C (212 DEG. F)
FLASH POINT:
CLOSED CUP: NOT APPLICABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 2.026 KJ/G
IGNITION DISTANCE: 0 CM
ENCLOSED SPACE IGNITION - TIME EQUIVALENT: 301 S/M3
ENCLOSED SPACE IGNITION - DEFLAGRATION DENSITY: 301 G/M3
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
ETHYL ALCOHOL LC50 INHALATION RAT 124700 MG/M3 4 HOURS
VAPOR
LD50 ORAL RAT 7 G/KG
ETHYLENE GLYCOL LC50 INHALATION RAT 450 PPM 4 HOURS
MONOBUTYL ETHER GAS.
LD50 DERMAL RABBIT 220 MG/KG
LD50 ORAL RAT 250 MG/KG
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
ETHYL ALCOHOL EYES: RABBIT 24 HOURS
MILD 500
IRRITANT MILLIGRAMS
EYES: RABBIT 0.066666667
MODERATE MINUTES
IRRITANT 100
MILLIGRAMS
EYES: RABBIT 100
MODERATE MICROLITERS
IRRITANT
EYES: RABBIT 500
SEVERE MILLIGRAMS
IRRITANT
SKIN: RABBIT 400
MILD MILLIGRAMS
IRRITANT
SKIN: RABBIT 24 HOURS
MODERATE 20
IRRITANT MILLIGRAMS
ETHYLENE GLYCOL EYES: RABBIT 24 HOURS
MONOBUTYL ETHER MODERATE 100
IRRITANT MILLIGRAMS
EYES: RABBIT 100
SEVERE MILLIGRAMS
IRRITANT
SKIN: RABBIT 500
MILD MILLIGRAMS
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
ETHYL ALCOHOL 1
ETHYLENE GLYCOL MONOBUTYL ETHER 3
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: MAY CAUSE EYE IRRITATION.
INHALATION: MAY BE IRRITATING TO EYES, SKIN AND RESPIRATORY SYSTEM.
SKIN CONTACT: MAY CAUSE EYE IRRITATION.
INGESTION:
DO NOT INGEST. IF SWALLOWED THEN SEEK IMMEDIATE MEDICAL ASSISTANCE.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
STOMACH PAINS
NAUSEA OR VOMITING
INGESTION SEEK MEDICAL ATTENTION.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
DERMAL 110000 MG/KG
INHALATION (VAPORS) 1100 MG/L
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
ETHYL ALCOHOL ACUTE EC50: ALGAE - ULVA 96 HOURS
17.921 MG/L PERTUSA
MARINE WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2000 (MICRO)G/L MAGNA
FRESH WATER
ACUTE LC50: CRUSTACEANS - ARTEMIA 48 HOURS
25500 (MICRO)G/L FRANCISCANA - LARVAE
MARINE WATER
ACUTE LC50: FISH - ONCORHYNCHUS 4 DAYS
42000 (MICRO)G/L MYKISS
FRESH WATER
CHRONIC NOEC: ALGAE - ULVA PERTUSA 96 HOURS
4.995 MG/L
MARINE WATER
CHRONIC NOEC: FISH - GAMBUSIA 12 WEEKS
0.375 UL/L HOLBROOKI - LARVAE
FRESH WATER
ETHYLENE GLYCOL ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
MONOBUTYL ETHER >1000 MG/L MAGNA
FRESH WATER
ACUTE LC50: CRUSTACEANS - 48 HOURS
1000 MG/L CHAETOGAMMARUS
MARINE WATER MARINUS - YOUNG
ACUTE LC50: FISH - MENIDIA 96 HOURS
1250000 (MICRO)G/L BERYLLINA
MARINE WATER
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
ETHYL ALCOHOL -0.35 LOW
ETHYLENE GLYCOL MONOBUTYL ETHER 0.81 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL
TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE
DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS.
DISPOSE OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE
DISPOSAL CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE
SEWER UNLESS FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES
WITH JURISDICTION. WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR
LANDFILL SHOULD ONLY BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS
MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. DO NOT PUNCTURE
OR INCINERATE CONTAINER.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER
UN PROPER CONSUMER CONSUMER CONSUMER
SHIPPING NAME COMMODITY ORM-D COMMODITY ORM-D COMMODITY ORM-D
TRANSPORT ORM-D ORM-D ORM-D
HAZARD CLASS(ES) CLASS 2.2, CLASS 2.2,
NON-FLAMMABLE NON-FLAMMABLE
AND NON-TOXIC AND NON-TOXIC
GASES GASES
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL
INFORMATION
ADR/RID IMDG IATA
UN NUMBER UN1950 UN1950 ID8000
UN PROPER AEROSOLS IN AEROSOLS IN CONSUMER
SHIPPING NAME LIMITED QUANTITIES LIMITED COMMODITY
OF CLASS 2 QUANTITIES ID8000
(PROPANE) OF CLASS 2
TRANSPORT 2 2.2 9
HAZARD CLASS(ES) CLASS 2.2, CLASS 2.2 - CLASS 9,
NON-FLAMMABLE NON-FLAMMABLE MISCELLANEOUS
AND NON-TOXIC GASES PRODUCTS,
GASES SUBSTANCES, OR
ORGANISMSCLASS
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL
INFORMATION
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN AIR ACT (CAA) 112 REGULATED FLAMMABLE SUBSTANCES: ISOBUTANE
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
ETHYL 1 - 5 YES. NO. NO. YES. NO.
ALCOHOL
ETHYLENE 0.5 - 1.5 NO. NO. NO. YES. NO.
GLYCOL
MONOBUTYL
ETHER
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING 2-BUTOXYETHANOL 111-76-2 0.5 - 1.5
REQUIREMENTS
SUPPLIER NOTIFICATION 2-BUTOXYETHANOL 111-76-2 0.5 - 1.5
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED:
ETHYL ALCOHOL; ISOBUTANE; 2-BUTOXYETHANOL
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
ETHYL ALCOHOL; ALCOHOL; ISOBUTANE; PROPANE, 2-METHYL-; 2-BUTOXY ETHANOL;
BUTYL CELLOSOLVE
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED:
DENATURED ALCOHOL; PROPANE, 2-METHYL-; ETHANOL, 2-BUTOXY-
INTERNATIONAL REGULATIONS:
CHEMICAL WEAPON CONVENTION LIST SCHEDULES I, II & III CHEMICALS:
NOT LISTED.
MONTREAL PROTOCOL (ANNEXES A, B, C, E): NOT LISTED.
STOCKHOLM CONVENTION ON PERSISTENT ORGANIC POLLUTANTS: NOT LISTED.
ROTTERDAM CONVENTION ON PRIOR INFORM CONSENT (PIC): NOT LISTED.
UNECE AARHUS PROTOCOL ON POPS AND HEAVY METALS: NOT LISTED.
INTERNATIONAL LISTS:
NATIONAL INVENTORY:
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN: ALL COMPONENTS ARE LISTED OR EXEMPTED.
MALAYSIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
NEW ZEALAND: ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
REPUBLIC OF KOREA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN: ALL COMPONENTS ARE LISTED OR EXEMPTED.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.
1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO
BE USED WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A
REGISTERED MARK OF THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA).
HMIS(R*) MATERIALS MAY BE PURCHASED EXCLUSIVELY FROM J. J. KELLER
(800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS
MATERIAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 1
FLAMMABILITY 0
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE
HAZARDS OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL
FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL
IS NOT THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER
OF CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325,
WHICH WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE
CLASSIFIED BY NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY
CHEMICALS DOES SO AT THEIR OWN RISK.
HISTORY:
DATE OF PRINTING: 5/5/2015.
DATE OF ISSUE/DATE OF REVISION: 5/5/2015.
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION.
VERSION: 1
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS
ACCURATE. HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS
SUBSIDIARIES, ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR
COMPLETENESS OF THE INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN
HAZARDS AND SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS
ARE DESCRIBED HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY
HAZARDS THAT EXIST.