| Common Name: | LOCTITE SUPERBONDER 414 KNOWN AS (LOCTITE 414 INSTANT ADHESIVE) |
| Manufacturer: | HENKEL AUSTRALIA |
| SDS Revision Date: | 4/13/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 32PK21 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
LOCTITE SUPERBONDER 414 KNOWN AS (LOCTITE 414 INSTANT ADHESIVE)
MSDS-NO.: 153532
V001.2
DATE OF ISSUE: 13.04.2015
| SECTION 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME:
LOCTITE SUPERBONDER 414 KNOWN AS (LOCTITE 414 INSTANT ADHESIVE)
INTENDED USE: CYANOACRYLATE
SUPPLIER:
HENKEL AUSTRALIA PTY LTD
135-141 CANTERBURY ROAD
KILSYTH, VICTORIA, 3137
AUSTRALIA
PHONE: +61 (3)9724 6444
EMERGENCY INFORMATION:
24 HOUR EMERGENCY CONTACT NUMBER: 03 9724 6556
| SECTION 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
HAZARDOUS ACCORDING TO THE CRITERIA OF SAFE WORK AUSTRALIA.
GHS CLASSIFICATION:
HAZARD CLASS HAZARD CATEGORY TARGET ORGAN
FLAMMABLE LIQUIDS CATEGORY 4
SKIN IRRITATION CATEGORY 2
SERIOUS EYE IRRITATION CATEGORY 2A
TARGET ORGAN SYSTEMIC TOXICANT - CATEGORY 3 RESPIRATORY TRACT
SINGLE EXPOSURE IRRITATION
HAZARD PICTOGRAM: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENT(S):
H227: COMBUSTIBLE LIQUID.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENT(S):
PREVENTION:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR PROTECTIVE GLOVES/EYE PROTECTION.
RESPONSE:
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P340+P312:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING.
P370+P378:
IN CASE OF FIRE:
USE WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROPRIATE TREATMENT AND DISPOSAL
FACILITY IN ACCORDANCE WITH APPLICABLE LAWS AND REGULATIONS, AND PRODUCT
CHARACTERISTICS AT TIME OF DISPOSAL.
CLASSIFICATION OF MATERIAL XI - IRRITANT
RISK PHRASES:
R36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
SAFETY PHRASES:
S23: DO NOT BREATHE VAPOUR.
S24/25: AVOID CONTACT WITH SKIN AND EYES.
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S36/37/39:
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION.
S46:
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR
LABEL.
DANGEROUS GOODS INFORMATION:
NOT CLASSIFIED AS DANGEROUS GOODS ACCORDING TO THE CRITERIA OF THE
AUSTRALIAN CODE FOR THE TRANSPORT OF DANGEROUS GOODS BY ROAD AND RAIL
(ADG CODE).
| SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
GENERAL CHEMICAL DESCRIPTION: MIXTURE
IDENTITY OF INGREDIENTS:
CHEMICAL INGREDIENTS CAS-NO. PROPORTION
ETHYL 2-CYANOACRYLATE 7085-85-0 60 - <=100%
NON HAZARDOUS INGREDIENTS <10%
| SECTION 4. FIRST AID MEASURES | |
INGESTION:
ENSURE THAT BREATHING PASSAGES ARE NOT OBSTRUCTED. THE PRODUCT WILL
POLYMERISE IMMEDIATELY IN THE MOUTH MAKING IT ALMOST IMPOSSIBLE TO SWALLOW.
SALIVA WILL SLOWLY SEPARATE THE SOLIDIFIED PRODUCT FROM THE MOUTH
(SEVERAL HOURS).
SKIN:
DO NOT PULL BONDED SKIN APART. IT MAY BE GENTLY PEELED APART USING A BLUNT
OBJECT SUCH AS A SPOON, PREFERABLY AFTER SOAKING IN WARM SOAPY WATER.
CYANOACRYLATES GIVE OFF HEAT ON SOLIDIFICATION. IN RARE CASES A LARGE DROP
WILL GENERATE ENOUGH HEAT TO CAUSE A BURN.
BURNS SHOULD BE TREATED NORMALLY AFTER THE ADHESIVE HAS BEEN REMOVED FROM
THE SKIN. IF LIPS ARE ACCIDENTALLY STUCK TOGETHER APPLY WARM WATER TO THE
LIPS AND ENCOURAGE MAXIMUM WETTING AND PRESSURE FROM SALIVA INSIDE THE
MOUTH. PEEL OR ROLL LIPS APART. DO NOT TRY TO PULL THE LIPS APART WITH
DIRECT OPPOSING ACTION.
EYES:
IF THE EYE IS BONDED CLOSED, RELEASE EYELASHES WITH WARM WATER BY COVERING
WITH WET PAD. CYANOACRYLATE WILL BOND TO EYE PROTEIN AND WILL CAUSE PERIODS
OF WEEPING WHICH WILL HELP TO DEBOND THE ADHESIVE.
KEEP EYE COVERED UNTIL DEBONDING IS COMPLETE, USUALLY WITHIN 1-3 DAYS.
DO NOT FORCE EYE OPEN. MEDICAL ADVICE SHOULD BE SOUGHT IN CASE SOLID
PARTICLES OF CYANOACRYLATE TRAPPED BEHIND THE EYELID CAUSE ANY ABRASIVE
DAMAGE.
INHALATION: MOVE TO FRESH AIR, CONSULT DOCTOR IF COMPLAINT PERSISTS.
FIRST AID FACILITIES:
EYE WASH AND SAFETY SHOWER
NORMAL WASHROOM FACILITIES
MEDICAL ATTENTION AND SPECIAL TREATMENT: TREAT SYMPTOMATICALLY.
SURGERY IS NOT NECESSARY TO SEPARATE ACCIDENTALLY BONDED TISSUES.
EXPERIENCE HAS SHOWN THAT BONDED TISSUES ARE BEST TREATED BY PASSIVE,
NON-SURGICAL FIRST AID. IF RAPID CURING HAS CAUSED THERMAL BURNS THEY
SHOULD BE TREATED SYMPTOMATICALLY AFTER ADHESIVE IS REMOVED.
| SECTION 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
FOAM, EXTINGUISHING POWDER, CARBON DIOXIDE.
FINE WATER SPRAY
IMPROPER EXTINGUISHING MEDIA: HIGH PRESSURE WATERJET
COMBUSTION BEHAVIOUR:
COMBUSTIBLE LIQUID
KEEP AWAY FROM HEAT, SPARK, AND OPEN FLAMES.
DECOMPOSITION PRODUCTS IN CASE OF FIRE:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPORS.
CARBON MONOXIDE CARBON DIOXIDE.
OXIDES OF NITROGEN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
WEAR FULL PROTECTIVE CLOTHING.
FIRE FIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS (SCBA).
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION.
AVOID SKIN AND EYE CONTACT.
WEAR PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS: DO NOT LET PRODUCT ENTER DRAINS.
CLEAN-UP METHODS:
DO NOT USE CLOTHS FOR MOPPING UP. FLOOD WITH WATER TO COMPLETE
POLYMERIZATION AND SCRAPE OFF THE FLOOR. CURED MATERIAL CAN BE DISPOSED OF
AS NON-HAZARDOUS WASTE. DISPOSE OF CONTAMINATED MATERIAL AS WASTE ACCORDING
TO SECTION 13.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING.
AVOID CONTACT WITH FABRIC OR PAPER GOODS. CONTACT WITH THESE MATERIALS MAY
CAUSE RAPID POLYMERIZATION WHICH CAN GENERATE SMOKE AND STRONG IRRITATING
VAPORS, AND CAUSE THERMAL BURNS.
CONDITIONS FOR SAFE STORAGE:
STORE IN A COOL PLACE IN CLOSED ORIGINAL CONTAINER.
FOR OPTIMUM SHELF LIFE STORE IN ORIGINAL CONTAINERS UNDER REFRIGERATED
CONDITIONS AT 2 - 8 DEG. C (35.6 - 46.4 DEG. F)
| SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
NATIONAL EXPOSURE STANDARDS: NONE
ENGINEERING CONTROLS: ENSURE GOOD VENTILATION/EXTRACTION.
EYE PROTECTION: WEAR PROTECTIVE GLASSES.
SKIN PROTECTION:
PROTECTIVE CLOTHING THAT COVERS ARMS AND LEGS.
THE USE OF CHEMICAL RESISTANT GLOVES SUCH AS NITRILE IS RECOMMENDED.
POLYETHYLENE OR POLYPROPYLENE GLOVES ARE RECOMMENDED WHEN USING LARGE
VOLUMES.
DO NOT USE PVC, RUBBER OR NYLON GLOVES.
PLEASE NOTE THAT IN PRACTICE THE WORKING LIFE OF CHEMICAL RESISTANT GLOVES
MAY BE CONSIDERABLY REDUCED AS A RESULT OF MANY INFLUENCING FACTORS (E.G.
TEMPERATURE). SUITABLE RISK ASSESSMENT SHOULD BE CARRIED OUT BY THE END
USER. IF SIGNS OF WEAR AND TEAR ARE NOTICED THEN THE GLOVES SHOULD BE
REPLACED.
RESPIRATORY PROTECTION:
IF INHALATION RISK EXISTS, WEAR A RESPIRATOR OR AIR SUPPLIED MASK COMPLYING
WITH THE REQUIREMENTS OF AS/NZS 1715 AND AS/NZS 1716.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORLESS LIQUID
ODOR: IRRITATING
ODOR THRESHOLD (CA): 1 - 2 PPM
SPECIFIC GRAVITY: 1.06
BOILING POINT: >149 DEG. C (>300.2 DEG. F)
FLASH POINT: 80 - 93 DEG. C (176 - 199.4 DEG. F)
VAPOR PRESSURE: <60.0000000 PA (25 DEG. C (77 DEG. F))
DENSITY: 1.1 G/CM3
AUTO IGNITION: 485 DEG. C
DECOMPOSITION TEMPERATURE:
| SECTION 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: KEEP AWAY FROM SOURCES OF IGNITION AND NAKED FLAMES.
INCOMPATIBLE MATERIALS:
RAPID EXOTHERMIC POLYMERIZATION WILL OCCUR IN THE PRESENCE OF WATER,
AMINES, ALKALIS AND ALCOHOLS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPORS.
CARBON MONOXIDE
CARBON DIOXIDE.
OXIDES OF NITROGEN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
HEALTH EFFECTS:
INGESTION:
NOT EXPECTED TO BE HARMFUL BY INGESTION. RAPIDLY POLYMERIZES (SOLIDIFIES)
AND BONDS IN MOUTH. IT IS ALMOST IMPOSSIBLE TO SWALLOW.
SKIN:
THIS PRODUCT IS IRRITATING TO THE SKIN.
BONDS SKIN IN SECONDS.
CYANOACRYLATES GENERATE HEAT ON SOLIDIFICATION. IN RARE CIRCUMSTANCES A
LARGE DROP WILL BURN THE SKIN. CURED ADHESIVE DOES NOT PRESENT A HEALTH
HAZARD EVEN IF BONDED TO THE SKIN.
EYES: IRRITATING TO EYES. CAUSES EXCESSIVE TEARING. EYELIDS MAY BOND.
INHALATION:
EXPOSURE TO VAPORS ABOVE THE ESTABLISHED EXPOSURE LIMIT RESULTS IN
RESPIRATORY IRRITATION, WHICH MAY LEAD TO DIFFICULTY IN BREATHING AND
TIGHTNESS IN THE CHEST.
ACUTE TOXICITY:
HAZARDOUS COMPONENTS CAS-NO. VALUE TYPE VALUE
ETHYL 2-CYANOACRYLATE 7085-85-0 LD50 >5,000 MG/KG
LD50 >2,000 MG/KG
HAZARDOUS COMPONENTS ROUTE OF EXPOSURE SPECIES METHOD
APPLICATION TIME
ETHYL 2-CYANOACRYLATE ORAL RAT OECD GUIDELINE
RABBIT 401 (ACUTE ORAL
TOXICITY)
DERMAL OECD GUIDELINE
402 (ACUTE DERMAL
TOXICITY)
SKIN CORROSION/IRRITATION:
HAZARDOUS CAS-NO. RESULT EXPOSURE SPECIES METHOD
COMPONENTS TIME
ETHYL 7085-85-0 SLIGHTLY 24 H RABBIT OECD
2-CYANOACRYLATE IRRITATING GUIDELINE
404 (ACUTE
DERMAL
IRRITATION /
CORROSION)
SERIOUS EYE DAMAGE/IRRITATION:
HAZARDOUS CAS-NO. RESULT EXPOSURE SPECIES METHOD
COMPONENTS TIME
ETHYL 7085-85-0 IRRITATING 72 H RABBIT OECD
2-CYANOACRYLATE GUIDELINE 405
(ACUTE EYE
IRRITATION /
CORROSION)
RESPIRATORY OR SKIN SENSITIZATION:
HAZARDOUS CAS-NO. RESULT TEST TYPE SPECIES METHOD
COMPONENTS
ETHYL 7085-85-0 NOT GUINEA
2-CYANOACRYLATE SENSITISING PIG
GERM CELL MUTAGENICITY:
HAZARDOUS CAS-NO. RESULT TYPE OF STUDY / METABOLIC
COMPONENTS ADMINISTRATION ACTIVATION /
EXPOSURE TIME
ETHYL 7085-85-0 NEGATIVE BACTERIAL REVERSE WITH AND WITHOUT
2-CYANOACRYLATE NEGATIVE MUTATION ASSAY WITH AND WITHOUT
NEGATIVE (E.G AMES TEST)
MAMMALIAN CELL
GENE MUTATION
ASSAY IN VITRO
MAMMALIAN
CHROMOSOME
ABERRATION TEST
HAZARDOUS COMPONENTS SPECIES METHOD
ETHYL 2-CYANOACRYLATE OECD GUIDELINE 471 (BACTERIAL
REVERSE MUTATION ASSAY)
OECD GUIDELINE 476 (IN VITRO
MAMMALIAN CELL GENE MUTATION TEST)
OECD GUIDELINE 473 (IN VITRO
MAMMALIAN CHROMOSOME ABERRATION TEST)
| SECTION 12. ECOLOGICAL INFORMATION | |
GENERAL ECOLOGICAL INFORMATION:
DO NOT EMPTY INTO DRAINS / SURFACE WATER / GROUND WATER.
PERSISTENCE AND DEGRADABILITY:
HAZARDOUS CAS-NO. RESULT ROUTE OF DEGRADABILITY METHOD
COMPONENTS APPLICATION
ETHYL 7085-85-0 AEROBIC 57% OECD
2-CYANOACRYLATE GUIDELINE
301 D
(READY
BIODEGRADA-
BILITY:
CLOSED
BOTTLE
TEST)
BIOACCUMULATIVE POTENTIAL / MOBILITY IN SOIL:
HAZARDOUS COMPONENTS CAS-NO. LOGKOW BIOCONCENTRATION EXPOSURE
FACTOR (BCF) TIME
ETHYL 2-CYANOACRYLATE 7085-85-0 0.776
HAZARDOUS COMPONENTS SPECIES TEMPERATURE METHOD
ETHYL 2-CYANOACRYLATE 22 DEG. C EU METHOD A.8 (PARTITION
COEFFICIENT)
| SECTION 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL OF PRODUCT:
CURED ADHESIVE:
DISPOSE OF AS WATER INSOLUBLE NON-TOXIC SOLID CHEMICAL IN AUTHORISED
LANDFILL OR INCINERATE UNDER CONTROLLED CONDITIONS. DISPOSE OF IN
ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONTRIBUTION OF THIS PRODUCT TO WASTE IS VERY INSIGNIFICANT IN COMPARISON
TO ARTICLE IN WHICH IT IS USED
DISPOSAL FOR UNCLEANED PACKAGE:
AFTER USE, TUBES, CARTONS AND BOTTLES CONTAINING RESIDUAL PRODUCT SHOULD BE
DISPOSED OF AS CHEMICALLY CONTAMINATED WASTE IN AN AUTHORISED LEGAL LAND
FILL SITE OR INCINERATED. DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL
REGULATIONS.
| SECTION 14. TRANSPORT INFORMATION | |
ROAD AND RAIL TRANSPORT:
DANGEROUS GOODS INFORMATION:
NOT CLASSIFIED AS DANGEROUS GOODS ACCORDING TO THE CRITERIA OF THE
AUSTRALIAN CODE FOR THE TRANSPORT OF DANGEROUS GOODS BY ROAD AND RAIL
(ADG CODE).
MARINE TRANSPORT IMDG: NOT DANGEROUS GOODS
AIR TRANSPORT IATA:
UN NO.: 3334
PROPER SHIPPING NAME:
AVIATION REGULATED LIQUID, N.O.S. (CYANOACRYLATE ESTER)
CLASS OR DIVISION: 9
PACKING GROUP: III
PACKING INSTRUCTIONS (PASSENGER): 964
PACKING INSTRUCTIONS (CARGO): 964
ADDITIONAL INFORMATION:
PRIMARY PACKS CONTAINING LESS THAN 500ML ARE UNREGULATED BY THIS MODE OF
TRANSPORT AND MAY BE SHIPPED UNRESTRICTED.
| SECTION 15. REGULATORY INFORMATION | |
SUSMP POISONS SCHEDULE: NONE
AICS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE AUSTRALIAN
INVENTORY OF CHEMICAL SUBSTANCES (AICS).
| SECTION 16. OTHER INFORMATION | |
ABBREVIATIONS/ACRONYMS:
ADGC: AUSTRALIAN DANGEROUS GOODS CODE
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS CODE
IATA-DGR:
INTERNATIONAL AIR TRANSPORT ASSOCIATION - DANGEROUS GOODS REGULATIONS
REASON FOR ISSUE:
REVIEWED SDS. REISSUED WITH NEW DATE. INVOLVED CHAPTERS: 1 - 16
DATE OF PREVIOUS ISSUE: 21.06.2010
DISCLAIMER:
THE PERCENTAGE WEIGHT (% W/W) OF INGREDIENTS IS NOT TO BE TAKEN AS A
SPECIFICATION GUARANTEED BY HENKEL AUSTRALIA PTY. LIMITED, BUT ONLY AS AN
APPROXIMATE GUIDE TO THE CONTENT OF HAZARDOUS INGREDIENTS IN THE MATERIAL.
THE INFORMATION CONTAINED HEREIN DOES NOT CONSTITUTE A GUARANTEE BY HENKEL
AUSTRALIA PTY. LIMITED CONCERNING THE PROPERTIES OF THE MATERIAL. THE
INFORMATION CONTAINED IN THE SAFETY DATA SHEET IS OFFERED IN GOOD FAITH AND
HAS BEEN DEVELOPED FROM WHAT IS BELIEVED TO BE ACCURATE AND RELIABLE
SOURCES. THE INFORMATION IS OFFERED WITHOUT WARRANTY, REPRESENTATION,
INDUCEMENT OR LICENCE AND HENKEL AUSTRALIA PTY. LIMITED ASSUMES NO LEGAL
RESPONSIBILITY FOR RELIANCE UPON SAME. HENKEL AUSTRALIA PTY. LIMITED
DISCLAIMS ANY LIABILITY FOR LOSS, INJURY OR DAMAGE INCURRED IN CONNECTION
WITH THE USE OF THE MATERIAL OR ITS ASSOCIATED SAFETY DATA SHEET. THIS
INFORMATION IS NOT TO BE CONSTRUED AS A REPRESENTATION THAT THE MATERIAL IS
SUITABLE FOR ANY PARTICULAR PURPOSE OR USE EXCEPT THOSE CONDITIONS AND
WARRANTIES IMPLIED BY EITHER COMMONWEALTH OR STATE STATUTES. CUSTOMERS ARE
ENCOURAGED TO MAKE THEIR OWN ENQUIRIES AS TO THE MATERIAL'S CHARACTERISTICS
AND, WHERE APPROPRIATE, TO CONDUCT THEIR OWN TESTS IN THE SPECIFIC CONTEXT
OF THE MATERIAL'S INTENDED USE.