| Common Name: | TRUFUEL 50 FUEL 6/32 |
| Manufacturer: | CALUMET PACKAGING |
| SDS Revision Date: | 9/8/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 33GY44 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CALUMET
SPECIALTY PRODUCTS PARTNERS, L.P.
SAFETY DATA SHEET
TRUFUEL 50 FUEL 6/32
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: TRUFUEL 50 FUEL 6/32
PRODUCT CODE: 6525638
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES:
PETROCHEMICAL INDUSTRY: FUEL.
USES ADVISED AGAINST REASON
NOT AVAILABLE.
SUPPLIER'S DETAILS:
CALUMET PACKAGING
10411 HIGHWAY 1
SHREVEPORT, LA 71115
USA
318-795-3800
24HR. CHEMTREC: 1-800-424-9300 / INTERNATIONAL 1-703-527-3887
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 1
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
CARCINOGENICITY: CATEGORY 2
TOXIC TO REPRODUCTION (FERTILITY): CATEGORY 2
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
AQUATIC HAZARD (ACUTE): CATEGORY 2
AQUATIC HAZARD (LONG-TERM): CATEGORY 3
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS AND DIZZINESS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
TOXIC TO AQUATIC LIFE.
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION.
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING. USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING
AND ALL MATERIAL-HANDLING EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. KEEP CONTAINER TIGHTLY
CLOSED. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. AVOID RELEASE TO
THE ENVIRONMENT. DO NOT BREATHE VAPOR. WASH HANDS THOROUGHLY AFTER
HANDLING.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF CONTAMINATED CLOTHING.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
AVOID CONTACT WITH SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.
HAZARDS NOT OTHERWISE CLASSIFIED:
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
NAPHTHA (PETROLEUM), FULL-RANGE ALKYLATE, >/=50 - <75 68527-27-5
BUTANE-CONTG.
ISOPENTANE >/=11 - <25 78-78-4
TOLUENE >/=10.1 - <25 108-88-3
XYLENE >/=10 - <25 1330-20-7
ETHYLBENZENE >/=1.1 - <3 100-41-4
N-HEXANE >/=0.1 - <0.3 110-54-3
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
WASH SKIN THOROUGHLY WITH SOAP AND WATER OR USE RECOGNIZED SKIN CLEANSER.
REMOVE CONTAMINATED CLOTHING AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10
MINUTES. GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES
THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH AIR
AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS
BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES
OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE
DANGEROUS. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE
DAMAGE. DO NOT INDUCE VOMITING. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT
LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS AND
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. DEFATTING TO THE SKIN.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
DRYNESS
CRACKING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE LIQUID AND VAPOR. IN A FIRE OR IF HEATED, A PRESSURE
INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A
SUBSEQUENT EXPLOSION. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
THIS MATERIAL IS TOXIC TO AQUATIC LIFE. THIS MATERIAL IS HARMFUL TO AQUATIC
LIFE WITH LONG LASTING EFFECTS. FIRE WATER CONTAMINATED WITH THIS MATERIAL
MUST BE CONTAINED AND PREVENTED FROM BEING DISCHARGED TO ANY WATERWAY,
SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR). WATER POLLUTING MATERIAL. MAY BE HARMFUL TO THE ENVIRONMENT IF
RELEASED IN LARGE QUANTITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). AVOID
EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING
PREGNANCY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR
OR MIST. DO NOT SWALLOW. AVOID RELEASE TO THE ENVIRONMENT. USE ONLY WITH
ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS
INADEQUATE. DO NOT ENTER STORAGE AREAS AND CONFINED SPACES UNLESS
ADEQUATELY VENTILATED. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED
ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT
IN USE. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER
IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND
MATERIAL HANDLING) EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST ELECTROSTATIC DISCHARGES. EMPTY CONTAINERS
RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. STORE LOCKED UP. ELIMINATE ALL
IGNITION SOURCES. SEPARATE FROM OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED
MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT
STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
NAPHTHA (PETROLEUM), FULL-RANGE ACGIH TLV (UNITED STATES).
ALKYLATE, BUTANE-CONTG. TWA: 200 PPM 8 HOURS.
ISOPENTANE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 1000 PPM 8 HOURS.
TOLUENE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 20 PPM 8 HOURS.
OSHA PEL Z2 (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
CEIL: 300 PPM
AMP: 500 PPM 10 MINUTES.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 100 PPM 8 HOURS.
TWA: 375 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 560 MG/M3 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 375 MG/M3 10 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 560 MG/M3 15 MINUTES.
XYLENE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 100 PPM 8 HOURS.
TWA: 434 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 651 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 655 MG/M3 15 MINUTES.
ETHYLBENZENE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 20 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 435 MG/M3 10 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
N-HEXANE ACGIH TLV (UNITED STATES, 4/2014).
ABSORBED THROUGH SKIN.
TWA: 50 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 500 PPM 8 HOURS.
TWA: 1800 MG/M3 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 50 PPM 8 HOURS.
TWA: 180 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 50 PPM 10 HOURS.
TWA: 180 MG/M3 10 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: CLEAR. AMBER.
ODOR: CHARACTERISTIC. HYDROCARBON.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 34.722 DEG. C (94.5 DEG. F)
FLASH POINT:
CLOSED CUP: <-20 DEG. C (<-4 DEG. F)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 0.7228
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): <0.205 CM2/S (<20.5 CST)
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
NAPHTHA LD50 ORAL RAT >5000 MG/KG
(PETROLEUM),
FULL-RANGE
ALKYLATE,
BUTANE-CONTG.
ISOPENTANE LC50 INHALATION VAPOR RAT 280000 MG/M3 4 HOURS
TOLUENE LC50 INHALATION VAPOR RAT 49 G/M3 4 HOURS
LD50 ORAL RAT 636 MG/KG
XYLENE LC50 INHALATION GAS. RAT 6670 PPM 4 HOURS
LC50 INHALATION VAPOR RAT 5000 PPM 4 HOURS
LD50 ORAL RAT 4300 MG/KG
ETHYLBENZENE LC50 INHALATION GAS. RAT 4000 PPM 4 HOURS
LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 3500 MG/KG
N-HEXANE LC50 INHALATION VAPOR RAT 48000 PPM 4 HOURS
LD50 ORAL RAT 15840 MG/KG
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
TOLUENE EYES: RABBIT 0.5 MINUTES
MILD IRRITANT 100 MILLIGRAMS
EYES: RABBIT 870 MICROGRAMS
MILD IRRITANT
EYES: RABBIT 24 HOURS
SEVERE 2 MILLIGRAMS
IRRITANT
SKIN: PIG 24 HOURS
MILD IRRITANT 250 MICROLITERS
SKIN: RABBIT 435 MILLIGRAMS
MILD IRRITANT
SKIN: RABBIT 24 HOURS
MODERATE 20 MILLIGRAMS
IRRITANT
SKIN: RABBIT 500 MILLIGRAMS
MODERATE
IRRITANT
XYLENE EYES: RABBIT 87 MILLIGRAMS
MILD IRRITANT
EYES: RABBIT 24 HOURS
SEVERE 5 MILLIGRAMS
IRRITANT
SKIN: RAT 8 HOURS
MILD IRRITANT 60 MICROLITERS
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
SKIN: RABBIT 100 PERCENT
MODERATE
IRRITANT
ETHYL- EYES: RABBIT 500 MILLIGRAMS
BENZENE SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 15 MILLIGRAMS
N-HEXANE EYES: RABBIT 10 MILLIGRAMS
MILD IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
TOLUENE 3
XYLENE 3
ETHYLBENZENE 2B
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
NAPHTHA (PETROLEUM), CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
FULL-RANGE ALKYLATE,
BUTANE-CONTG.
ISOPENTANE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
TOLUENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
XYLENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
ETHYLBENZENE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
N-HEXANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
TOLUENE CATEGORY 2 NOT DETERMINED KIDNEYS AND LIVER
ETHYLBENZENE CATEGORY 2 NOT DETERMINED EARS
N-HEXANE CATEGORY 2 NOT DETERMINED PERIPHERAL NERVOUS
SYSTEM
ASPIRATION HAZARD:
NAME RESULT
NAPHTHA (PETROLEUM), FULL-RANGE ALKYLATE, ASPIRATION HAZARD - CATEGORY 1
BUTANE-CONTG.
ISOPENTANE ASPIRATION HAZARD - CATEGORY 1
TOLUENE ASPIRATION HAZARD - CATEGORY 1
XYLENE ASPIRATION HAZARD - CATEGORY 1
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
N-HEXANE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS AND
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. DEFATTING TO THE SKIN.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
DRYNESS
CRACKING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: SUSPECTED OF DAMAGING FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 5255.9 MG/KG
DERMAL 10856.4 MG/KG
INHALATION (GASES) 51549.2 PPM
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
ISOPENTANE ACUTE EC50: DAPHNIA - DAPHNIA MAGNA 48 HOURS
2.3 MG/L
TOLUENE ACUTE EC50: ALGAE - 72 HOURS
12500 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - GAMMARUS 48 HOURS
11600 (MICRO)G/L PSEUDOLIMNAEUS - ADULT
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
6000 (MICRO)G/L MAGNA - JUVENILE
FRESH WATER (FLEDGLING, HATCHLING,
WEANLING)
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
5500 (MICRO)G/L KISUTCH - FRY
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA MAGNA 21 DAYS
1000 (MICRO)G/L
FRESH WATER
XYLENE ACUTE LC50: CRUSTACEANS - 48 HOURS
8500 (MICRO)G/L PALAEMONETES PUGIO
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
13400 (MICRO)G/L PROMELAS
FRESH WATER
ETHYLBENZENE ACUTE EC50: ALGAE - 72 HOURS
4600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: ALGAE - 96 HOURS
3600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - ARTEMIA 48 HOURS
6530 (MICRO)G/L SP. - NAUPLII
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2930 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
4200 (MICRO)G/L MYKISS
FRESH WATER
N-HEXANE ACUTE LC50: FISH - PIMEPHALES 96 HOURS
2500 (MICRO)G/L PROMELAS
FRESH WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT TEST RESULT DOSE INOCULUM
NAME
ISOPENTANE 301F READY 71.43% - 28 DAYS
BIODEGRADABILITY -
MANOMETRIC
RESPIROMETRY
TEST
ETHYLBENZENE 301B READY 70 TO 80 % -
BIODEGRADABILITY - 28 DAYS
CO2 EVOLUTION
TEST
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
ISOPENTANE READILY
TOLUENE READILY
XYLENE READILY
ETHYLBENZENE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
NAPHTHA (PETROLEUM), FULL- 10 TO 2500 HIGH
RANGE ALKYLATE,
BUTANE-CONTG.
ISOPENTANE 3 171 LOW
TOLUENE 2.73 90 LOW
XYLENE 3.12 8.1 TO 25.9 LOW
ETHYLBENZENE 3.6 LOW
N-HEXANE 4 501.187 HIGH
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. VAPOR FROM PRODUCT
RESIDUES MAY CREATE A HIGHLY FLAMMABLE OR EXPLOSIVE ATMOSPHERE INSIDE THE
CONTAINER. DO NOT CUT, WELD OR GRIND USED CONTAINERS UNLESS THEY HAVE BEEN
CLEANED THOROUGHLY INTERNALLY. AVOID DISPERSAL OF SPILLED MATERIAL AND
RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
UNITED STATES - RCRA TOXIC HAZARDOUS WASTE "U" LIST:
INGREDIENT CAS # STATUS REFERENCE
NUMBER
XYLENE 1330-20-7 LISTED U239
TOLUENE; BENZENE, METHYL- 108-88-3 LISTED U220
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG IMDG IATA
CLASSIFICATION CLASSIFICATION
UN NUMBER 1203 1203 1203 1203
UN PROPER GASOLINE GASOLINE GASOLINE GASOLINE
SHIPPING NAME
TRANSPORT 3 3 3 3
HAZARD
CLASS(ES) FLAMMABLE CLASS 3, CLASS 3 - CLASS 3,
LIQUID, CLASS/ FLAMMABLE FLAMMABLE FLAMMABLE
DIVISION 3.1, LIQUIDS LIQUIDS LIQUIDS
3.2, 3.3
ENVIRONMENT
PACKING GROUP II II II II
ENVIRONMENTAL NO. NO. YES. NO.
HAZARDS
ADDITIONAL REPORTABLE THE MARINE THE
INFORMATION QUANTITY: POLLUTANT ENVIRONMENTALLY
986.95 LBS / MARK IS NOT HAZARDOUS
448.08 KG REQUIRED SUBSTANCE MARK
[163.76 GAL / WHEN MAY APPEAR IF
619.92 L] TRANSPORTED REQUIRED BY
PACKAGE SIZES IN SIZES OF OTHER
SHIPPED IN </=5 L OR TRANSPORTATION
QUANTITIES </=5 KG. REGULATIONS.
LESS THAN
THE PRODUCT
REPORTABLE
QUANTITY ARE
NOT SUBJECT
TO THE RQ
(REPORTABLE
QUANTITY)
TRANSPORTATION
REQUIREMENTS.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) PAIR: NAPHTHALENE
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN WATER ACT (CWA) 307: TOLUENE; ETHYLBENZENE; NAPHTHALENE; BENZENE
CLEAN WATER ACT (CWA) 311:
XYLENE; TOLUENE; ETHYLBENZENE; NAPHTHALENE; BENZENE
CLEAN AIR ACT (CAA) 112 REGULATED FLAMMABLE SUBSTANCES: ISOPENTANE
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE (ACUTE) (CHRONIC)
OF HEALTH HEALTH
PRESSURE HAZARD HAZARD
NAPHTHA >/=50 - <75 YES. NO. NO. YES. NO.
(PETRO-
LEUM),
FULL-
RANGE
ALKYLATE,
BUTANE-
CONTG.
ISOPE- >/=11 - <25 YES. NO. NO. YES. NO.
NTANE
TOLUENE >/=10.1 - <25 YES. NO. NO. YES. YES.
XYLENE >/=10 - <25 YES. NO. NO. YES. YES.
ETHYL- >/=1.1 - <3 YES. NO. NO. YES. YES.
BENZENE
N-HEXANE >/=0.1 - <0.3 YES. NO. NO. YES. YES.
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING REQUIREMENTS:
TOLUENE 108-88-3 >/=10.1 - <25
XYLENE 1330-20-7 >/=10 - <25
ETHYLBENZENE 100-41-4 >/=1.1 - <3
SUPPLIER NOTIFICATION:
TOLUENE 108-88-3 >/=10.1 - <25
XYLENE 1330-20-7 >/=10 - <25
ETHYLBENZENE 100-41-4 >/=1.1 - <3
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED:
ISOPENTANE; XYLENE; TOLUENE; ETHYL BENZENE
NEW YORK:
THE FOLLOWING COMPONENTS ARE LISTED: XYLENE (MIXED); TOLUENE; ETHYLBENZENE
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
ISOPENTANE; BUTANE, 2-METHYL-; XYLENES; BENZENE, DIMETHYL-; TOLUENE;
BENZENE, METHYL-; ETHYL BENZENE; BENZENE, ETHYL-
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED:
BUTANE, 2-METHYL-; BENZENE, DIMETHYL-; BENZENE, METHYL-; BENZENE, ETHYL-
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INGREDIENT NAME CANCER REPRODUCTIVE NO SIGNIFICANT MAXIMUM ACCEPTABLE
RISK LEVEL DOSAGE LEVEL
TOLUENE NO. YES. NO. 7000 (MICRO)G/DAY
(INGESTION)
ETHYLBENZENE YES. NO. 41 (MICRO)G/DAY NO.
(INGESTION)
54 (MICRO)G/DAY
(INHALATION)
INTERNATIONAL LISTS:
NATIONAL INVENTORY:
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: NOT DETERMINED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN: NOT DETERMINED.
MALAYSIA: NOT DETERMINED.
NEW ZEALAND: NOT DETERMINED.
PHILIPPINES: NOT DETERMINED.
REPUBLIC OF KOREA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN: ALL COMPONENTS ARE LISTED OR EXEMPTED.
| SECTION 16. OTHER INFORMATION | |
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAM. LIQ. 1, H224 ON BASIS OF TEST DATA
SKIN IRRIT. 2, H315 CALCULATION METHOD
EYE IRRIT. 2A, H319 CALCULATION METHOD
CARC. 2, H351 CALCULATION METHOD
REPR. 2, H361 (FERTILITY) CALCULATION METHOD
REPR. 2, H361 (UNBORN CHILD) CALCULATION METHOD
STOT SE 3, H335 CALCULATION METHOD
STOT SE 3, H336 CALCULATION METHOD
STOT RE 2, H373 CALCULATION METHOD
ASP. TOX. 1, H304 CALCULATION METHOD
AQUATIC ACUTE 2, H401 CALCULATION METHOD
AQUATIC CHRONIC 3, H412 CALCULATION METHOD
HISTORY:
DATE OF ISSUE/DATE OF REVISION: 09/08/2015
VERSION: 1
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.