| Common Name: | BEAD SEALER |
| Manufacturer: | 31 |
| SDS Revision Date: | 11/13/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 33K060, 63DX05 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
ACCORDING TO 1907/2006/EC (REACH), 1272/2008/EC (CLP), AND OSHA GHS
PRINTING DATE: 13.11.2015
REVISION: 13.11.2015
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: BEAD SEALER
ARTICLE NUMBER: 14-101, 14-101A, 14-101B, 14-104, 14-104A, 14-104B
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NO FURTHER RELEVANT INFORMATION AVAILABLE.
APPLICATION OF THE SUBSTANCE / THE MIXTURE: SEALANT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
31 INCORPORATED
100 ENTERPRISE DR.
NEWCOMERSTOWN, OH 43832
PHONE: (740) 498-8324
1.4 EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.: +1 (800)255-3924, +1 (813)248-0585
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE EU REGULATIONS
AND NOT THE US GHS REGULATION: H361D, H400, H410.
THE FOLLOWING CLASSIFICATIONS ARE APPLICABLE ONLY TO OSHA (USA) REGULATIONS
AND NOT THE SPECIFIC CLP REGULATION: H361.
HEALTH HAZARD
REPR. 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
FLAME
FLAM. LIQ. 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
HEALTH HAZARD
REPR. 2:
H361D: SUSPECTED OF DAMAGING THE UNBORN CHILD.
ROUTE OF EXPOSURE: INHALATION.
STOT RE 2:
H373:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE.
ROUTE OF EXPOSURE: INHALATION.
ENVIRONMENT
AQUATIC ACUTE 1:
H400: VERY TOXIC TO AQUATIC LIFE.
AQUATIC CHRONIC 1:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
EXCLAMATION MARK
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
STOT SE 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
ADDITIONAL INFORMATION:
0% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN TOXICITY.
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
2.2 LABEL ELEMENTS:
LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008:
THE SUBSTANCE IS CLASSIFIED AND LABELLED ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM WITHIN THE UNITED STATES (GHS).
THE PRODUCT IS CLASSIFIED AND LABELLED ACCORDING TO THE CLP REGULATION.
HAZARD PICTOGRAMS:
THE FOLLOWING PICTOGRAM(S) ARE ONLY FOR USE WITHIN EUROPE: GHS09.
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
GHS09: ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELLING:
TOLUENE
NATURAL RUBBER LATEX
HEPTANE
HAZARD STATEMENTS:
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE GENERAL GHS
REGULATIONS AND NOT THE SPECIFIC CLP REGULATION: H361.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE EU REGULATIONS
AND NOT THE US GHS REGULATION: H361D, H410.
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H361D:
SUSPECTED OF DAMAGING THE UNBORN CHILD.
ROUTE OF EXPOSURE: INHALATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H373:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE.
ROUTE OF EXPOSURE: INHALATION.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P260: DO NOT BREATHE MIST/VAPOURS/SPRAY.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P370+P378:
IN CASE OF FIRE: USE FOAM, POWDER, OR CARBON DIOXIDE FOR EXTINCTION.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NFPA RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 3
REACTIVITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 2*
FIRE 3
REACTIVITY 0
* - INDICATES A LONG TERM HEALTH HAZARD FROM REPEATED OR PROLONGED
EXPOSURES.
2.3 OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION:
MIXTURE OF SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
DANGEROUS COMPONENTS:
CAS: 108-88-3 TOLUENE 50-100%
EINECS: 203-625-9 FLAM. LIQ. 2, H225
INDEX NUMBER: 601-021-00-3 REPR. 2, H361D; STOT RE 2, H373;
ASP. TOX. 1, H304
SKIN IRRIT. 2, H315;
STOT SE 3, H336
CAS: 142-82-5 HEPTANE 25-50%
EINECS: 205-563-8 FLAM. LIQ. 2, H225
INDEX NUMBER: 601-008-00-2 ASP. TOX. 1, H304
AQUATIC ACUTE 1, H400;
AQUATIC CHRONIC 1, H410
SKIN IRRIT. 2, H315;
STOT SE 3, H336
CAS: 9006-04-6 NATURAL RUBBER LATEX <10%
EINECS: 232-689-0 SKIN SENS. 1B, H317
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS REFER TO SECTION 16.
FOR THE LISTED INGREDIENT(S), THE IDENTITY AND EXACT PERCENTAGES ARE BEING
WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE MEDICAL
OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF IRREGULAR BREATHING OR RESPIRATORY ARREST PROVIDE ARTIFICIAL
RESPIRATION.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION IS EXPERIENCED, CONSULT A DOCTOR.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
A PERSON VOMITING WHILE LAYING ON THEIR BACK SHOULD BE TURNED ONTO THEIR
SIDE.
DO NOT INDUCE VOMITING; CALL FOR MEDICAL HELP IMMEDIATELY.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
HEADACHE
DIZZINESS
COUGHING
CRAMP
NAUSEA
ALLERGIC REACTIONS
GASTRIC OR INTESTINAL DISORDERS WHEN INGESTED.
DISORIENTATION
HAZARDS:
DANGER OF CONVULSION.
DANGER OF IMPAIRED BREATHING.
DANGER OF DISTURBED CARDIAC RHYTHM.
CONDITION MAY DETERIORATE WITH ALCOHOL CONSUMPTION.
MAY BE HARMFUL IN CONTACT WITH SKIN.
MAY BE HARMFUL IF INHALED.
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: IF NECESSARY OXYGEN RESPIRATION TREATMENT.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
FOAM
ALCOHOL RESISTANT FOAM
FIRE-EXTINGUISHING POWDER
CARBON DIOXIDE
GASEOUS EXTINGUISHING AGENTS
WATER HAZE OR FOG
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: WATER
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION: ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
KEEP AWAY FROM IGNITION SOURCES.
PROTECT FROM HEAT.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
ABSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID BINDERS,
UNIVERSAL BINDERS, SAWDUST).
PICK UP MECHANICALLY.
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
DO NOT FLUSH WITH WATER OR AQUEOUS CLEANSING AGENTS
6.4 REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING: USE ONLY IN WELL VENTILATED AREAS.
INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PROTECT AGAINST ELECTROSTATIC CHARGES.
FLAMMABLE GAS-AIR MIXTURES MAY FORM IN EMPTY RECEPTACLES.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
PROVIDE VENTILATION FOR RECEPTACLES.
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDISING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
KEEP CONTAINER TIGHTLY SEALED.
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES:
NO FURTHER DATA; SEE SECTION 7.
8.1 CONTROL PARAMETERS:
INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
108-88-3 TOLUENE:
PEL (USA):
SHORT-TERM VALUE: C 300; 500* PPM
LONG-TERM VALUE: 200 PPM
*10-MIN PEAK PER 8-HR SHIFT
REL (USA):
SHORT-TERM VALUE: 560 MG/M3, 150 PPM
LONG-TERM VALUE: 375 MG/M3, 100 PPM
TLV (USA):
LONG-TERM VALUE: 75 MG/M3, 20 PPM
BEI
EL (CANADA):
LONG-TERM VALUE: 20 PPM
R
EV (CANADA):
LONG-TERM VALUE: 20 PPM
142-82-5 HEPTANE:
IOELV (EU):
LONG-TERM VALUE: 2085 MG/M3, 500 PPM
PEL (USA):
LONG-TERM VALUE: 2000 MG/M3, 500 PPM
REL (USA):
SHORT-TERM VALUE: C 1800* MG/M3, C 440* PPM
LONG-TERM VALUE: 350 MG/M3, 85 PPM
*15-MIN
TLV (USA):
SHORT-TERM VALUE: 2050 MG/M3, 500 PPM
LONG-TERM VALUE: 1640 MG/M3, 400 PPM
EL (CANADA):
SHORT-TERM VALUE: 500 PPM
LONG-TERM VALUE: 400 PPM
EV (CANADA):
SHORT-TERM VALUE: 2,045 MG/M3, 500 PPM
LONG-TERM VALUE: 1,635 MG/M3, 400 PPM
9006-04-6 NATURAL RUBBER LATEX:
TLV (USA):
LONG-TERM VALUE: 0,0001* MG/M3
SKIN; (SEN) NIC-DSEN, RSEN;* INH. FRACTION
EL (CANADA):
LONG-TERM VALUE: 0,001 MG/M3
INHALABLE, SKIN; S
EV (CANADA):
LONG-TERM VALUE: 0,001 MG/M3
AS TOTAL PROTEINS, INHALABLE, SKIN
DNELS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PNECS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
INGREDIENTS WITH BIOLOGICAL LIMIT VALUES:
108-88-3 TOLUENE:
BEI (USA):
0,02 MG/L
MEDIUM: BLOOD
TIME: PRIOR TO LAST SHIFT OF WORKWEEK
PARAMETER: TOLUENE
0,03 MG/L
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: TOLUENE
0,3 MG/G CREATININE
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: O-CRESOL WITH HYDROLYSIS (BACKGROUND)
8.2 EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES ARE TO BE ADHERED TO WHEN HANDLING
CHEMICALS.
PREGNANT WOMEN SHOULD STRICTLY AVOID INHALATION OR SKIN CONTACT.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
RESPIRATORY PROTECTION:
NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
FOR SPILLS, RESPIRATORY PROTECTION MAY BE ADVISABLE.
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE WHEN HIGH CONCENTRATIONS ARE
PRESENT.
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE WHEN AEROSOL OR MIST IS FORMED.
PROTECTION OF HANDS:
PROTECTIVE GLOVES:
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES:
SEE SECTION 7 FOR ADDITIONAL INFORMATION.
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: LIQUID
COLOUR: BLACK
ODOUR: SOLVENT-LIKE
ODOUR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: 99 DEG. C (210 DEG. F)
FLASH POINT: -9 DEG. C (16 DEG. F) (TCC D56)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO/SELF-IGNITION TEMPERATURE: 215 DEG. C (419 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
SELF-IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOUR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: 1,1 VOL %
UPPER: 7,0 VOL %
OXIDISING PROPERTIES: NOT DETERMINED.
VAPOUR PRESSURE AT 20 DEG. C (68 DEG. F): 48 HPA (36 MMHg)
DENSITY AT 20 DEG. C (68 DEG. F): 0,87 G/CM3 (7,26 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT DETERMINED.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC AT 20 DEG. C (68 DEG. F): 721 MM2/S (CONVERTED FROM 5 ZAHN)
VOC CONTENT: 89,1%
VOC (CALIFORNIA): 75-90% WT
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.2 CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
USED EMPTY CONTAINERS MAY CONTAIN PRODUCT GASES WHICH FORM EXPLOSIVE
MIXTURES WITH AIR.
FLAMMABLE.
REACTS VIOLENTLY WITH OXIDISING AGENTS.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR WHEN
SPRAYED OR ATOMISED.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
10.4 CONDITIONS TO AVOID:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
STORE AWAY FROM OXIDISING AGENTS.
10.5 INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE
CARBON MONOXIDE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
LD/LC50 VALUES RELEVANT FOR CLASSIFICATION:
108-88-3 TOLUENE:
ORAL:
LD50: 5000 MG/KG (RAT)
DERMAL:
LD50: 12124 MG/KG (RABBIT)
INHALATIVE:
LC50/4 H: 5320 MG/L (MOUSE)
142-82-5 HEPTANE:
ORAL:
LD50: >5000 MG/KG (RAT) (ESTIMATE)
INHALATIVE:
LC50/4 H: 103 MG/L (RAT)
1333-86-4 CARBON BLACK:
ORAL:
LD50: 10000 MG/KG (RAT)
PRIMARY IRRITANT EFFECT:
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/IRRITATION:
SLIGHT IRRITANT EFFECT ON EYES.
CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITISATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
CAUSES SKIN AND EYE IRRITATION.
VAPOURS HAVE NARCOTIC EFFECT.
REPEATED DOSE TOXICITY:
REPEATED EXPOSURES MAY RESULT IN SKIN AND/OR RESPIRATORY SENSITIVITY.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING THE UNBORN CHILD. ROUTE OF EXPOSURE: INHALATION.
STOT-SINGLE EXPOSURE: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE.
ROUTE OF EXPOSURE: INHALATION.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY: TOXIC FOR AQUATIC ORGANISMS
12.2 PERSISTENCE AND DEGRADABILITY:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.3 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
AVOID TRANSFER INTO THE ENVIRONMENT.
DUE TO AVAILABLE DATA ON ELIMINABILITY/DECOMPOSITION AND BIOACCUMULATION
POTENTIAL PROLONGED TERM DAMAGE OF THE ENVIRONMENT CAN NOT BE EXCLUDED.
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
DANGER TO DRINKING WATER IF EVEN SMALL QUANTITIES LEAK INTO THE GROUND.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION:
CONTACT WASTE PROCESSORS FOR RECYCLING INFORMATION.
MUST NOT BE DISPOSED TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW PRODUCT
TO REACH SEWAGE SYSTEM.
CAN BE BURNED WITH HOUSEHOLD GARBAGE AFTER CONSULTING WITH THE WASTE
DISPOSAL FACILITY OPERATOR AND THE PERTINENT AUTHORITIES AND ADHERING TO
THE NECESSARY TECHNICAL REGULATIONS.
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED
MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL,
STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND
DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. RESIDUAL MATERIALS SHOULD
BE TREATED AS HAZARDOUS.
UNCLEANED PACKAGING:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
DOT, ADR, IMDG, IATA: UN1133
14.2 UN PROPER SHIPPING NAME:
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG (66 LB) AND INNER PACKAGINGS
LESS THAN 5 L (1.3 GAL).
DOT: ADHESIVES
ADR: 1133 ADHESIVES, ENVIRONMENTALLY HAZARDOUS
IMDG: ADHESIVES, MARINE POLLUTANT
IATA: ADHESIVES
14.3 TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
CLASS: 3 FLAMMABLE LIQUIDS.
LABEL: 3
ADR:
CLASS 3, FLAMMABLE LIQUIDS
ENVIRONMENT
CLASS: 3 (F1) FLAMMABLE LIQUIDS.
LABEL: 3
IMDG:
CLASS 3 - FLAMMABLE LIQUIDS
ENVIRONMENT
CLASS: 3 FLAMMABLE LIQUIDS.
LABEL: 3
IATA: CLASS 3, FLAMMABLE LIQUIDS
CLASS: 3 FLAMMABLE LIQUIDS.
LABEL: 3
14.4 PACKING GROUP:
DOT, ADR, IMDG, IATA: II
14.5 ENVIRONMENTAL HAZARDS:
PRODUCT CONTAINS ENVIRONMENTALLY HAZARDOUS SUBSTANCES: HEPTANE
MARINE POLLUTANT:
YES
SYMBOL (FISH AND TREE)
SPECIAL MARKING (ADR): SYMBOL (FISH AND TREE)
14.6 SPECIAL PRECAUTIONS FOR USER:
WARNING: FLAMMABLE LIQUIDS.
DANGER CODE (KEMLER): 33
EMS NUMBER: F-E, S-E
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
ADR:
TRANSPORT CATEGORY: 2
TUNNEL RESTRICTION CODE: D/E
IATA:
LIMITED QUANTITY BY AIR: 1L
UN "MODEL REGULATION": UN 1133 ADHESIVES, 3, II
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
108-88-3 TOLUENE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER:
REFERENCES TO CHEMICAL COMPONENTS LISTED BELOW ARE BASED ON UNBOUND
RESPIRABLE PARTICLES AND ARE NOT GENERALLY APPLICABLE TO PRODUCT AS
SUPPLIED.
1333-86-4 CARBON BLACK
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
108-88-3 TOLUENE
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
108-88-3 TOLUENE
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
108-88-3 TOLUENE II
142-82-5 HEPTANE D
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
1333-86-4 CARBON BLACK 2B
990001-01-0 TOLUENE 3
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
1333-86-4 CARBON BLACK
CANADA:
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 0.1%):
NONE OF THE INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 1%):
108-88-3 TOLUENE
142-82-5 HEPTANE
DIRECTIVE 2012/18/EU:
NAMED DANGEROUS SUBSTANCES - ANNEX I: NONE OF THE INGREDIENTS ARE LISTED.
OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS:
SUBSTANCES OF VERY HIGH CONCERN (SVHC) ACCORDING TO REACH, ARTICLE 57:
NONE OF THE INGREDIENTS ARE LISTED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| SECTION 16: OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL NOT
CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL NOT
ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H361D: SUSPECTED OF DAMAGING THE UNBORN CHILD.
ROUTE OF EXPOSURE: INHALATION.
H373:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE.
ROUTE OF EXPOSURE: INHALATION.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONISED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
SVHC: SUBSTANCES OF VERY HIGH CONCERN
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
FLAM. LIQ. 2: FLAMMABLE LIQUIDS, HAZARD CATEGORY 2
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
SKIN SENS. 1: SENSITISATION - SKIN, HAZARD CATEGORY 1
SKIN SENS. 1B: SENSITISATION - SKIN, HAZARD CATEGORY 1B
REPR. 2: REPRODUCTIVE TOXICITY, HAZARD CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
STOT RE 2:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 2
ASP. TOX. 1: ASPIRATION HAZARD, HAZARD CATEGORY 1
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTEHAZARD, CATEGORY 1
AQUATIC CHRONIC 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 1
SOURCES:
SDS PREPARED BY:
CHEMTEL INC.
1305 NORTH FLORIDA AVENUE
TAMPA, FLORIDA 33602-2902
USA
TOLL FREE NORTH AMERICA: 1-888-255-3924
INTL.: +01 813-248-0573
WEBSITE: WWW.CHEMTELINC.COM