| Common Name: | INNER LINER SEALER |
| Manufacturer: | 31 |
| SDS Revision Date: | 3/13/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 33K062, 63DW90 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
ACCORDING TO 1907/2006/EC (REACH), 1272/2008/EC (CLP), AND OSHA GHS
PRINTING DATE: 13.03.2015
REVISION: 13.03.2015
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/ UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: INNER LINER SEALER
ARTICLE NUMBER: 14-128
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NO FURTHER RELEVANT INFORMATION AVAILABLE.
APPLICATION OF THE SUBSTANCE / THE MIXTURE: CLEANER SOLVENT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
31 INCORPORATED
100 ENTERPRISE DR.
NEWCOMERSTOWN, OH 43832
PHONE: (740) 498-8324
1.4 EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.: (800)255-3924, +1 (813)248-0585
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE EU REGULATIONS
AND NOT THE US GHS REGULATION: H361F, H400, H410.
THE FOLLOWING CLASSIFICATIONS ARE APPLICABLE ONLY TO THE GENERAL GHS
REGULATIONS AND NOT THE SPECIFIC CLP REGULATION: H351, H361.
HEALTH HAZARD
REPR. 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
FLAME
FLAM. LIQ. 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
HEALTH HAZARD
REPR. 2:
H361F: SUSPECTED OF DAMAGING FERTILITY.
STOT RE 2:
H373:
MAY CAUSE DAMAGE TO THE NERVOUS SYSTEM THROUGH PROLONGED OR REPEATED
EXPOSURE.
ROUTE OF EXPOSURE: INHALATIVE.
ASP. TOX. 1:
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
ENVIRONMENT
AQUATIC ACUTE 1:
H400: VERY TOXIC TO AQUATIC LIFE.
AQUATIC CHRONIC 1:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
EXCLAMATION MARK
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2:
H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC:
XN; HARMFUL
R48/20-62-65:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION. POSSIBLE RISK OF IMPAIRED FERTILITY.
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
XI; IRRITANT
R38: IRRITATING TO SKIN.
F; HIGHLY FLAMMABLE
R11: HIGHLY FLAMMABLE.
N; DANGEROUS FOR THE ENVIRONMENT
R50/53:
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN
THE AQUATIC ENVIRONMENT.
R67: VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT:
THE PRODUCT HAS TO BE LABELLED DUE TO THE CALCULATION PROCEDURE OF THE
"GENERAL CLASSIFICATION GUIDELINE FOR PREPARATIONS OF THE EU" IN THE
LATEST VALID VERSION.
CLASSIFICATION SYSTEM:
THE CLASSIFICATION IS ACCORDING TO THE LATEST EDITIONS OF THE EU-LISTS,
AND EXTENDED BY COMPANY AND LITERATURE DATA.
THE CLASSIFICATION IS IN ACCORDANCE WITH THE LATEST EDITIONS OF
INTERNATIONAL SUBSTANCES LISTS, AND IS SUPPLEMENTED BY INFORMATION FROM
TECHNICAL LITERATURE AND BY INFORMATION PROVIDED BY THE COMPANY.
ADDITIONAL INFORMATION:
0 PERCENT OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN TOXICITY
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
2.2 LABEL ELEMENTS:
LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008:
THE PRODUCT IS CLASSIFIED AND LABELLED ACCORDING TO THE CLP REGULATION.
HAZARD PICTOGRAMS: ENVIRONMENT
THIS PICTOGRAM ONLY APPLICABLE FOR EU REGULATIONS. NOT FOR USE IN THE
UNITED STATES (OSHA GHS).
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
GHS09: ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELLING:
N-HEXANE
HEPTANE
HAZARD STATEMENTS:
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE EU REGULATIONS
AND NOT THE US GHS REGULATION: H361F, H410.
THE FOLLOWING HAZARD STATEMENTS ARE APPLICABLE ONLY TO THE GENERAL GHS
REGULATIONS AND NOT THE SPECIFIC CLP REGULATION: H351, H361.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H361F: SUSPECTED OF DAMAGING FERTILITY.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H373:
MAY CAUSE DAMAGE TO THE NERVOUS SYSTEM THROUGH PROLONGED OR REPEATED
EXPOSURE. ROUTE OF EXPOSURE: INHALATIVE.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P260: DO NOT BREATHE MIST/VAPOURS/SPRAY.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P264: WASH THOROUGHLY AFTER HANDLING.
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P370+P378:
IN CASE OF FIRE: USE FOAM, POWDER, OR CARBON DIOXIDE FOR EXTINCTION.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P331: DO NOT INDUCE VOMITING.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
EUH066: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
RESTRICTED TO PROFESSIONAL USERS.
HAZARD DESCRIPTION:
WHMIS-SYMBOLS:
B2 - FLAMMABLE LIQUID
D2A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS
NFPA RATINGS (SCALE 0-4):
HEALTH 1
FIRE 3
REACTIVITY 0
HMIS-RATINGS (SCALE 0-4):
HEALTH 1*
FIRE 3
REACTIVITY 0
* - INDICATES A LONG TERM HEALTH HAZARD FROM REPEATED OR PROLONGED
EXPOSURES.
HMIS LONG TERM HEALTH HAZARD SUBSTANCES:
110-54-3 N-HEXANE
2.3 OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION:
MIXTURE OF SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
DANGEROUS COMPONENTS:
CAS: 110-54-3 N-HEXANE 20-40%
EINECS: 203-777-6 XN R48/20-62-65; XI R38; F R11;
INDEX NUMBER: 601-037-00-0 N R51/53
R67
REPR. CAT. 3
FLAM. LIQ. 2. H225
REPR. 2, H361F; STOT RE 2, H373;
ASP. TOX. 1, H304
AQUATIC CHRONIC 2, H411
SKIN IRRIT. 2, H315; STOT SE 3, H336
CAS: 142-82-5 HEPTANE 20-40%
EINECS: 205-563-8 XN R65; XI R38; F R11; N R50/53
INDEX NUMBER: 601-008-00-2 R67
FLAM. LIQ. 2, H225
ASP. TOX. 1, H304
AQUATIC ACUTE 1, H400;
AQUATIC CHRONIC 1, H410
SKIN IRRIT. 2, H315; STOT SE 3, H336
CAS: 67-64-1 ACETONE 10-20%
EINECS: 200-662-2 XI R36; F R11
INDEX NUMBER: 606-001-00-8 R66-67
FLAM. LIQ. 2, H225
EYE IRRIT. 2, H319; STOT SE 3, H336
CAS: 14807-96-6 TALC 1-5%
EINECS: 238-877-9
DANGEROUS COMPONENTS (ALTERNATIVE CLASSIFICATIONS):
COMPONENT CLASSIFICATIONS RELEVANT TO THE USA AND GENERAL GHS.
CAS: 14807-96-6 TALC (Mg3H2(SiO3)4) XN R40 1-5%
EINECS: 238-877-9 CARC. 2, H351
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED RISK PHRASES REFER TO SECTION 16.
FOR THE LISTED INGREDIENTS, THE IDENTITY AND EXACT PERCENTAGES ARE BEING
WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE
MEDICAL OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF IRREGULAR BREATHING OR RESPIRATORY ARREST PROVIDE ARTIFICIAL
RESPIRATION.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; CALL FOR MEDICAL HELP IMMEDIATELY.
A PERSON VOMITING WHILE LAYING ON THEIR BACK SHOULD BE TURNED ONTO THEIR
SIDE.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
HEADACHE
BREATHING DIFFICULTY
DIZZINESS
COUGHING
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
IRRITANT TO EYES.
GASTRIC OR INTESTINAL DISORDERS WHEN INGESTED.
NAUSEA
DISORIENTATION
HAZARDS:
DANGER OF PULMONARY OEDEMA.
DANGER OF PNEUMONIA.
DANGER OF IMPAIRED BREATHING.
MAY BE HARMFUL IN CONTACT WITH SKIN.
MAY BE HARMFUL IF INHALED.
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
DANGER OF DISTURBED CARDIAC RHYTHM.
DANGER OF CONVULSION.
POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
IF SWALLOWED, GASTRIC IRRIGATION WITH ADDED, ACTIVATED CARBON.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
IF SWALLOWED OR IN CASE OF VOMITING, DANGER OF ENTERING THE LUNGS.
LATER OBSERVATION FOR PNEUMONIA AND PULMONARY OEDEMA.
VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, SAND, EXTINGUISHING POWDER. DO NOT USE WATER.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: WATER
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
USE LARGE QUANTITIES OF FOAM AS IT IS PARTIALLY DESTROYED BY THE PRODUCT.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
KEEP AWAY FROM IGNITION SOURCES.
PROTECT FROM HEAT.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO EVAPORATE.
ABSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID BINDERS,
UNIVERSAL BINDERS, SAWDUST).
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
ENSURE ADEQUATE VENTILATION.
DO NOT FLUSH WITH WATER OR AQUEOUS CLEANSING AGENTS
USED RAGS OR OTHER CLEANING MATERIALS SHOULD BE SOAKED WITH WATER AND
PLACED IN A SEALED CONTAINER.
6.4 REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
RAGS / METAL WOOLS / CUTTINGS / SHAVINGS AND WASTE PAPERS SOAKED WITH
PRODUCT MUST BE PLACED IN A SEALED, METAL CONTAINER RATED FOR FLAMMABLE
WASTE.
PREVENT FORMATION OF AEROSOLS.
AVOID SPLASHES OR SPRAY IN ENCLOSED AREAS.
USE ONLY IN WELL VENTILATED AREAS.
INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PROTECT AGAINST ELECTROSTATIC CHARGES.
FLAMMABLE GAS-AIR MIXTURES MAY FORM IN EMPTY RECEPTACLES.
FUMES CAN COMBINE WITH AIR TO FORM AN EXPLOSIVE MIXTURE.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
PROVIDE VENTILATION FOR RECEPTACLES.
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDISING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
KEEP CONTAINER TIGHTLY SEALED.
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES:
NO FURTHER DATA; SEE ITEM 7.
8.1 CONTROL PARAMETERS:
INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
110-54-3 N-HEXANE:
IOELV (EU):
LONG-TERM VALUE: 72 MG/M3, 20 PPM
PEL (USA):
LONG-TERM VALUE: 1800 MG/M3, 500 PPM
REL (USA):
LONG-TERM VALUE: 180 MG/M3, 50 PPM
TLV (USA):
LONG-TERM VALUE: 176 MG/M3, 50 PPM
SKIN; BEI
EL (CANADA):
LONG-TERM VALUE: 20 PPM
SKIN
EV (CANADA):
LONG-TERM VALUE: 176 MG/M3, 50 PPM
142-82-5 HEPTANE:
IOELV (EU):
LONG-TERM VALUE: 2085 MG/M3, 500 PPM
PEL (USA):
LONG-TERM VALUE: 2000 MG/M3, 500 PPM
REL (USA):
LONG-TERM VALUE: 350 MG/M3, 85 PPM
CEILING LIMIT: 1800* MG/M3, 440* PPM
*15-MIN
TLV (USA):
SHORT-TERM VALUE: 2050 MG/M3, 500 PPM
LONG-TERM VALUE: 1640 MG/M3, 400 PPM
EL (CANADA):
SHORT-TERM VALUE: 500 PPM
LONG-TERM VALUE: 400 PPM
EV (CANADA):
SHORT-TERM VALUE: 2,045 MG/M3, 500 PPM
LONG-TERM VALUE: 1,635 MG/M3, 400 PPM
67-64-1 ACETONE:
IOELV (EU):
LONG-TERM VALUE: 1210 MG/M3, 500 PPM
PEL (USA):
LONG-TERM VALUE: 2400 MG/M3, 1000 PPM
REL (USA):
LONG-TERM VALUE: 590 MG/M3, 250 PPM
TLV (USA):
SHORT-TERM VALUE: (1782) NIC-1187 MG/M3, (750) NIC-500 PPM
LONG-TERM VALUE: (1188) NIC-475 MG/M3, (500) NIC-200 PPM
BEI
EL (CANADA):
SHORT-TERM VALUE: 500 PPM
LONG-TERM VALUE: 250 PPM
EV (CANADA):
SHORT-TERM VALUE: 750 PPM
LONG-TERM VALUE: 500 PPM
546-93-0 MAGNESITE:
PEL (USA):
LONG-TERM VALUE: 15* 5** MG/M3
*TOTAL DUST
**RESPIRABLE FRACTION
REL (USA):
LONG-TERM VALUE: 10* 5** MG/M3
*TOTAL DUST
**RESPIRABLE FRACTION
TLV (USA): TLV WITHDRAWN
EL (CANADA):
LONG-TERM VALUE: 10 MG/M3
EV (CANADA):
LONG-TERM VALUE: 10 MG/M3
TOTAL DUST
1333-86-4 CARBON BLACK:
PEL (USA):
LONG-TERM VALUE: 3,5 MG/M3
REL (USA):
LONG-TERM VALUE: 3,5* MG/M3
*0,1 IN PRESENCE OF PAHS; SEE POCKET GUIDE APPS. A+C
TLV (USA):
LONG-TERM VALUE: 3* MG/M3
*INHALABLE FRACTION
EL (CANADA):
LONG-TERM VALUE: 3 MG/M3
IARC 2B
EV (CANADA):
LONG-TERM VALUE: 3,5 MG/M3
DNELS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PNECS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
INGREDIENTS WITH BIOLOGICAL LIMIT VALUES:
110-54-3 N-HEXANE:
BEI (USA): 0,4 MG/L
MEDIUM: URINE
TIME: END OF SHIFT AT END OF WORKWEEK
PARAMETER: 2,5-HEXANEDIONE WITHOUT HYDROLYSIS
67-64-1 ACETONE:
BEI (USA): 50 MG/L
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: ACETONE (NONSPECIFIC)
ADDITIONAL INFORMATION:
THE LISTS VALID DURING THE MAKING WERE USED AS BASIS.
8.2 EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES ARE TO BE ADHERED TO WHEN HANDLING
CHEMICALS.
PREGNANT WOMEN SHOULD STRICTLY AVOID INHALATION OR SKIN CONTACT.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
RESPIRATORY PROTECTION:
NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE WHEN HIGH CONCENTRATIONS ARE
PRESENT.
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE WHEN AEROSOL OR MIST IS FORMED.
FOR SPILLS, RESPIRATORY PROTECTION MAY BE ADVISABLE.
NIOSH OR EN APPROVED ORGANIC VAPOR RESPIRATOR EQUIPPED WITH A DUST/MIST
PREFILTER SHOULD BE USED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/THE
SUBSTANCE/THE PREPARATION. SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION
OF THE PENETRATION TIMES, RATES OF DIFFUSION AND THE DEGRADATION.
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: SOLVENT RESISTANT PROTECTIVE CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES:
SEE SECTION 7 FOR ADDITIONAL INFORMATION.
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: LIQUID
COLOUR: NOT DETERMINED.
ODOUR: SOLVENT-LIKE
ODOUR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE:
180 DEG. F / 82 DEG. C (356 DEG. F / 180 DEG. F)
FLASH POINT: 5 DEG. F / -15 DEG. C (41 DEG. F / -59 DEG. F)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO/SELF-IGNITION TEMPERATURE:
419 DEG. F / 215 DEG. C (786 DEG. F / 419 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
SELF-IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOUR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: 1,1 VOL %
UPPER: 13,0 VOL %
VAPOUR PRESSURE AT 20 DEG. C (68 DEG. F): 233 HPA (175 MMHg)
DENSITY: NOT DETERMINED.
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT DETERMINED.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
SOLVENT CONTENT:
VOC CONTENT: 84,5%
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
10.2 CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
FLAMMABLE.
REACTS VIOLENTLY WITH OXIDISING AGENTS.
USED EMPTY CONTAINERS MAY CONTAIN PRODUCT GASES WHICH FORM EXPLOSIVE
MIXTURES WITH AIR.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR WHEN
SPRAYED OR ATOMISED.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
10.4 CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
STORE AWAY FROM OXIDISING AGENTS.
10.5 INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE AND CARBON DIOXIDE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES RELEVANT FOR CLASSIFICATION:
142-82-5 HEPTANE:
ORAL:
LD50: >5000 MG/KG (RAT) (ESTIMATE)
INHALATIVE:
LC50/4H: 103 MG/L (RAT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITISATION: NO SENSITISING EFFECTS KNOWN.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO THE CALCULATION METHOD
OF THE GENERAL EU CLASSIFICATION GUIDELINES FOR PREPARATIONS AS ISSUED IN
THE LATEST VERSION:
IRRITANT
INHALATION OF CONCENTRATED VAPOURS AS WELL AS ORAL INTAKE WILL LEAD TO
ANAESTHESIA-LIKE CONDITIONS AND HEADACHE, DIZZINESS, ETC.
TOXIC AND/OR CORROSIVE EFFECTS MAY BE DELAYED UP TO 12 HOURS.
SUSPECTED OF CAUSING CANCER. ROUTE OF EXPOSURE: INHALATIVE.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
MAY BE HARMFUL IF SWALLOWED.
MAY BE HARMFUL IN CONTACT WITH SKIN.
MAY BE HARMFUL IF INHALED.
VAPOURS HAVE NARCOTIC EFFECT.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN AND EYE IRRITATION.
REPEATED DOSE TOXICITY:
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DAMAGE TO THE NERVOUS SYSTEM THROUGH PROLONGED OR REPEATED
EXPOSURE.
ROUTE OF EXPOSURE: INHALATIVE.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
REPR. 2
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY: TOXIC FOR AQUATIC ORGANISMS
12.2 PERSISTENCE AND DEGRADABILITY: EASILY BIODEGRADABLE
12.3 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ECOTOXICAL EFFECTS:
REMARK:
VERY TOXIC FOR FISH
THE PRODUCT IS OXYGEN-CONSUMING. THE DECLARED ACTION MAY BE PARTLY CAUSED
BY LACK OF OXYGEN.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
WATER HAZARD CLASS 2 (GERMAN REGULATION) (SELF-ASSESSMENT):
HAZARDOUS FOR WATER
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
DANGER TO DRINKING WATER IF EVEN SMALL QUANTITIES LEAK INTO THE GROUND.
ALSO POISONOUS FOR FISH AND PLANKTON IN WATER BODIES.
VERY TOXIC FOR AQUATIC ORGANISMS
DUE TO AVAILABLE DATA ON ELIMINABILITY/DECOMPOSITION AND BIOACCUMULATION
POTENTIAL PROLONGED TERM DAMAGE OF THE ENVIRONMENT CAN NOT BE EXCLUDED.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW PRODUCT
TO REACH SEWAGE SYSTEM. CAN BE BURNED WITH HOUSEHOLD GARBAGE AFTER
CONSULTING WITH THE WASTE DISPOSAL FACILITY OPERATOR AND THE PERTINENT
AUTHORITIES AND ADHERING TO THE NECESSARY TECHNICAL REGULATIONS.
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED
MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL,
STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND
DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. RESIDUAL MATERIALS
SHOULD BE TREATED AS HAZARDOUS.
UNCLEANED PACKAGING:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| SECTION 14: TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
DOT, ADR, IMDG, IATA: UN1993
14.2 UN PROPER SHIPPING NAME:
DOT: FLAMMABLE LIQUIDS, N.O.S. (HEXANES, HEPTANES)
ADR:
1993 FLAMMABLE LIQUID, N.O.S. (HEXANES, HEPTANES), ENVIRONMENTALLY
HAZARDOUS
IMDG, IATA: FLAMMABLE LIQUID, N.O.S. (HEXANES, HEPTANES)
14.3 TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
CLASS: 3 FLAMMABLE LIQUIDS.
LABEL: 3
ADR:
CLASS 3, FLAMMABLE LIQUID
ENVIRONMENT
CLASS: 3 (F1) FLAMMABLE LIQUIDS.
LABEL: 3
IMDG, IATA:
CLASS 3 - FLAMMABLE LIQUIDS
CLASS: 3 FLAMMABLE LIQUIDS.
LABEL: 3
14.4 PACKING GROUP:
DOT, ADR, IMDG, IATA: II
14.5 ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL MARKING (ADR): SYMBOL (FISH AND TREE)
14.6 SPECIAL PRECAUTIONS FOR USER:
WARNING: FLAMMABLE LIQUIDS.
DANGER CODE (KEMLER): 33
EMS NUMBER: F-E, S-E
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
ADR:
LIMITED QUANTITIES (LQ): 1L
TRANSPORT CATEGORY: 2
TUNNEL RESTRICTION CODE: D/E
UN "MODEL REGULATION":
UN1993, FLAMMABLE LIQUID, N.O.S. (HEXANES, HEPTANES), ENVIRONMENTALLY
HAZARDOUS, 3, II
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
110-54-3 N-HEXANE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER:
REFERENCES TO CHEMICAL COMPONENTS LISTED BELOW ARE BASED ON UNBOUND
RESPIRABLE PARTICLES AND ARE NOT GENERALLY APPLICABLE TO PRODUCT AS
SUPPLIED.
14807-96-6 TALC (Mg3H2(SiO3)4)
1333-86-4 CARBON BLACK
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS ARE LISTED.
CARCINOGENIC CATEGORIES
EPA (ENVIRONMENTAL PROTECTION AGENCY):
110-54-3 N-HEXANE II
142-82-5 HEPTANE D
67-64-1 ACETONE I
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
14807-96-61 TALC (Mg3H2(SiO3)4) 2B
1333-86-4 CARBON BLACK 2B
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
67-64-1 ACETONE A4
14807-96-6 TALC (Mg3H2(SiO3)4) A4
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS ARE LISTED.
CANADA:
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 0.1%):
NONE OF THE INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 1%):
110-54-3 N-HEXANE
142-82-5 HEPTANE
67-64-1 ACETONE
OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH HAZARD CRITERIA OF THE
CONTROLLED PRODUCTS REGULATIONS AND THE SDS CONTAINS ALL THE INFORMATION
REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
SUBSTANCES OF VERY HIGH CONCERN (SVHC) ACCORDING TO REACH, ARTICLE 57:
NONE OF THE INGREDIENTS ARE LISTED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| SECTION 16: OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H361F: SUSPECTED OF DAMAGING FERTILITY.
H373:
MAY CAUSE DAMAGE TO THE NERVOUS SYSTEM THROUGH PROLONGED OR REPEATED
EXPOSURE.
ROUTE OF EXPOSURE: INHALATIVE.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
R11: HIGHLY FLAMMABLE.
R36: IRRITATING TO EYES.
R38: IRRITATING TO SKIN.
R48/20:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
R50/53:
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN
THE AQUATIC ENVIRONMENT.
R51/53:
TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
R62: POSSIBLE RISK OF IMPAIRED FERTILITY.
R65:
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
R66: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
R67: VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONISED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (CANADA)
VOC: VOLATILE ORGANIC COMPOUNDS (USA, EU)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
FLAM. LIQ. 2: FLAMMABLE LIQUIDS, HAZARD CATEGORY 2
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
REPR. 2: REPRODUCTIVE TOXICITY, HAZARD CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
STOT RE 2:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 2
ASP. TOX. 1: ASPIRATION HAZARD, HAZARD CATEGORY 1
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTEHAZARD, CATEGORY 1
AQUATIC CHRONIC 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 1
AQUATIC CHRONIC 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 2
SOURCES:
SDS PREPARED BY:
CHEMTEL INC.
1305 NORTH FLORIDA AVENUE
TAMPA, FLORIDA 33602-2902
USA
TOLL FREE NORTH AMERICA: 1-888-255-3924
INTL.: +01 813-248-0573
WEBSITE: WWW.CHEMTELINC.COM