| Common Name: | PREMIUM GEAR OIL ( MP ), SAE 85W-140 |
| Manufacturer: | CITGO PETROLEUM |
| SDS Revision Date: | 8/29/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 33ME39 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CITGO(R*)
SAFETY DATA SHEET
CITGO PREMIUM GEAR OIL (MP), SAE 85W-140
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: CITGO PREMIUM GEAR OIL (MP), SAE 85W-140
SYNONYMS: GEAR OIL
MATERIAL USES: GEAR OIL
CODE: 631320001
SUPPLIER'S DETAILS:
CITGO PETROLEUM CORPORATION
P.O. BOX 4689
HOUSTON, TX 77210
SDSVEND@CITGO.COM
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
TECHNICAL CONTACT: (800) 248-4684
MEDICAL EMERGENCY: (832) 486-4700
CHEMTREC EMERGENCY (UNITED STATES ONLY): (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN SENSITIZATION: CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS: MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
GENERAL:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. THOROUGHLY WASH EXPOSED AREAS
AND CLOTHING WITH SOAP AND WATER.
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
IF SWALLOWED:
DO NOT INDUCE VOMITING. IF YOU FEEL UNWELL, SEEK MEDICAL ATTENTION AND
SHOW THE LABEL WHEN POSSIBLE. KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
WEAR PROTECTIVE GLOVES. AVOID BREATHING VAPOR. CONTAMINATED WORK CLOTHING
MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
STORAGE:
STORE IN A DRY PLACE AND/OR IN CLOSED CONTAINER. STORE IN ACCORDANCE WITH
ALL LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: GEAR OIL
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
RESIDUAL OILS (PETROLEUM), SOLVENT-DEWAXED >/=75 - </=90 64742-62-7
DISTILLATES (PETROLEUM), HYDROTREATED </=5 64742-54-7
HEAVY PARAFFINIC
2,5-BIS(TERT-NONYLDITHIO)-1,3,4-THIADIAZOLE </=0.3 89347-09-1
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS
DUE TO PROCESS VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. IN THE EVENT OF ANY COMPLAINTS OR SYMPTOMS, AVOID FURTHER
EXPOSURE. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. DO NOT INDUCE
VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF VOMITING OCCURS,
THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. GET
MEDICAL ATTENTION IF ADVERSE HEALTH EFFECTS PERSIST OR ARE SEVERE. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH
WATER BEFORE REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SULFUR OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NONEMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS
OR CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR
PROCEED AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE,
ABSORBENT MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH
AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS
(SEE SECTION 13). DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
CONTAMINATED ABSORBENT MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED
PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN
ANY PROCESS IN WHICH THIS PRODUCT IS USED. DO NOT GET IN EYES OR ON SKIN
OR CLOTHING. DO NOT INGEST. AVOID BREATHING VAPOR OR MIST. KEEP IN THE
ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE
MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK.
KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS
THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE
CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR
INCOMPATIBLE MATERIALS BEFORE HANDLING OR USE.
BULK STORAGE CONDITIONS:
MAINTAIN ALL STORAGE TANKS IN ACCORDANCE WITH APPLICABLE REGULATIONS. USE
NECESSARY CONTROLS TO MONITOR TANK INVENTORIES. INSPECT ALL STORAGE TANKS
ON A PERIODIC BASIS. TEST TANKS AND ASSOCIATED PIPING FOR TIGHTNESS.
MAINTAIN THE AUTOMATIC LEAK DETECTION DEVICES TO ASSURE PROPER WORKING
CONDITION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
RESIDUAL OILS (PETROLEUM), ACGIH TLV (UNITED STATES, 6/2013).
SOLVENT-DEWAXED TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
NIOSH REL (UNITED STATES, 4/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
DISTILLATES (PETROLEUM), ACGIH TLV (UNITED STATES, 3/2018).
HYDROTREATED HEAVY PARAFFINIC TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
NIOSH REL (UNITED STATES, 10/2016).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
OSHA PEL (UNITED STATES, 5/2018).
TWA: 5 MG/M3 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE
TO AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, VAPOR CONTROLS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY GLASSES EQUIPPED WITH SIDE SHIELDS ARE RECOMMENDED AS MINIMUM
PROTECTION IN INDUSTRIAL SETTINGS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION:
CHEMICAL SPLASH GOGGLES. SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD
SHOULD BE USED WHEN A RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID
EXPOSURE TO LIQUID SPLASHES, MISTS, GASES OR DUSTS. IF INHALATION HAZARDS
EXIST, A FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
AVOID SKIN CONTACT WITH LIQUID. CHEMICAL-RESISTANT GLOVES COMPLYING WITH
AN APPROVED STANDARD SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL
PRODUCTS IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE
PARAMETERS SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE
GLOVES ARE STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED
THAT THE TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR
DIFFERENT GLOVE MANUFACTURERS. LEATHER GLOVES ARE NOT PROTECTIVE FOR LIQUID
CONTACT.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON
THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED
BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
AVOID SKIN CONTACT WITH LIQUID. APPROPRIATE FOOTWEAR AND ANY ADDITIONAL
SKIN PROTECTION MEASURES SHOULD BE SELECTED BASED ON THE TASK BEING
PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A SPECIALIST
BEFORE HANDLING THIS PRODUCT. LEATHER BOOTS ARE NOT PROTECTIVE FOR LIQUID
CONTACT.
RESPIRATORY PROTECTION:
AVOID INHALATION OF GASES, VAPORS, MISTS OR DUSTS. USE A PROPERLY FITTED,
AIR-PURIFYING OR SUPPLIED-AIR RESPIRATOR COMPLYING WITH AN APPROVED
STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY. RESPIRATOR
SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS, THE
HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: AMBER TO DARK AMBER
ODOR: PETROLEUM.
PH: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: 170 DEG. C (338 DEG. F) [PENSKY-MARTENS [ASTM D-93]]
OPEN CUP: 248 DEG. C (478.4 DEG. F) [CLEVELAND.]
EVAPORATION RATE: <1 (BUTYL ACETATE = 1)
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1%
UPPER: 7%
VAPOR PRESSURE: <0.0013 KPA (<0.01 MMHg) [ROOM TEMPERATURE]
VAPOR DENSITY: >1 [AIR = 1]
RELATIVE DENSITY: 0.9
DENSITY LBS/GAL: 7.5 LBS/GAL
DENSITY GM/CM3: NOT AVAILABLE.
GRAVITY, DEG. API: 26 @ 60 F
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
AUTO-IGNITION TEMPERATURE: 400 DEG. C (752 DEG. F)
FLOW TIME (ISO 2431): NOT AVAILABLE.
VISCOSITY:
KINEMATIC (ROOM TEMPERATURE): 3.61 CM2/S (361 CST)
KINEMATIC (40 DEG. C (104 DEG. F)): 3.48 CM2/S (348 CST)
VISCOSITY SUS: 2010 SUS @ 100 F
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NOT EXPECTED TO BE EXPLOSIVE, SELF-REACTIVE, SELF-HEATING, OR AN ORGANIC
PEROXIDE UNDER US GHS DEFINITION(S).
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
DISTILLATES (PETROLEUM), LD50 DERMAL RAT >5000 MG/KG
HYDROTREATED HEAVY LD50 ORAL RAT >5000 MG/KG
PARAFFINIC
2,5-BIS(TERT-NONYLDITHIO)- LD50 ORAL RAT >10 G/KG
1,3,4-THIADIAZOLE
CONCLUSION/SUMMARY:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE
LOW ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF MINERAL
OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED NO
SIGNIFICANT TOXICOLOGICAL EFFECTS.
IRRITATION/CORROSION: NOT AVAILABLE.
SKIN: NO ADDITIONAL INFORMATION.
EYES: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
SENSITIZATION: NOT AVAILABLE.
SKIN: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
MUTAGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
CARCINOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
TERATOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: DERMAL.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL:
ONCE SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
CONCLUSION/SUMMARY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NOT AVAILABLE.
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL
TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE
DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS.
DISPOSE OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE
DISPOSAL CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE
SEWER UNLESS FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES
WITH JURISDICTION. WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR
LANDFILL SHOULD ONLY BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS
MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD
BE TAKEN WHEN HANDLING EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR
RINSED OUT. EMPTY CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES.
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING
NAME
TRANSPORT HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
OIL:
THE PRODUCT(S) REPRESENTED BY THIS SDS IS (ARE) REGULATED AS "OIL" UNDER
49 CFR PART 130. SHIPMENTS BY RAIL OR HIGHWAY IN PACKAGING HAVING A
CAPACITY OF 3500 GALLONS OR MORE OR IN A QUANTITY GREATER 42,000 GALLONS
ARE SUBJECT TO THESE REQUIREMENTS. IN ADDITION, MIXTURES CONTAINING 10% OR
MORE OF THIS PRODUCT MAY BE SUBJECT TO THESE REQUIREMENTS.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
THIS MATERIAL IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN WATER
ACT (CWA) AND THE OIL POLLUTION ACT OF 1990 (OPA). DISCHARGES OR SPILLS
WHICH PRODUCE A VISIBLE SHEEN ON WATERS OF THE UNITED STATES, THEIR
ADJOINING SHORELINES, OR INTO CONDUITS LEADING TO SURFACE WATERS MUST
BE REPORTED TO THE EPA'S NATIONAL RESPONSE CENTER AT (800) 424-8802.
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: SKIN SENSITIZATION - CATEGORY 1
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % CLASSIFICATION
2,5-BIS(TERT-NONYLDITHIO)- </=0.3 ACUTE TOXICITY
1,3,4-THIADIAZOLE (INHALATION) - CATEGORY 4
SKIN IRRITATION - CATEGORY 2
EYE IRRITATION - CATEGORY 2A
SKIN SENSITIZATION - CATEGORY 1
STATE REGULATIONS:
MASSACHUSETTS: NONE OF THE COMPONENTS ARE LISTED.
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY: NONE OF THE COMPONENTS ARE LISTED.
PENNSYLVANIA: NONE OF THE COMPONENTS ARE LISTED.
INTERNATIONAL REGULATIONS:
INVENTORY LIST:
UNITED STATES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
AUSTRALIA: NOT DETERMINED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: NOT DETERMINED.
EUROPE: NOT DETERMINED.
JAPAN:
JAPAN INVENTORY (ENCS): NOT DETERMINED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
MALAYSIA: NOT DETERMINED.
NEW ZEALAND: NOT DETERMINED.
PHILIPPINES: NOT DETERMINED.
REPUBLIC OF KOREA: NOT DETERMINED.
TAIWAN: NOT DETERMINED.
THAILAND: NOT DETERMINED.
TURKEY: NOT DETERMINED.
VIET NAM: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 0
FLAMMABILITY 1
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE
HAZARDS OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL
FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS
NOT THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
SKIN SENSITIZATION - CATEGORY 1 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 8/29/2019
DATE OF ISSUE/DATE OF REVISION: 8/29/2019
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION
VERSION: 0.01
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES
WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT
ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY.
SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES
OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A
COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE.
USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF
THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE
PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS
AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM
LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY
CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
CITGO IS A REGISTERED TRADEMARK OF CITGO PETROLEUM CORPORATION