| Common Name: | PREMIUM LITHIUM EP-2 GREASE |
| Manufacturer: | CITGO PETROLEUM |
| SDS Revision Date: | 2/10/2021 |
| SDS Format: | GHS-US |
| Item Number(s): | 33ME70, 33ME71 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CITCO(R*)
SAFETY DATA SHEET
CITGO PREMIUM LITHIUM EP-2 GREASE
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: CITGO PREMIUM LITHIUM EP-2 GREASE
OTHER MEANS OF IDENTIFICATION:
LUBRICATING GREASE;
CITGO(R*) MATERIAL CODE: 655212001
MATERIAL USES: LUBRICATING GREASE
PRODUCT CODE: 655212001
MSDS #: 655212001
SUPPLIER'S DETAILS:
CITGO PETROLEUM CORPORATION
P.O. BOX 4689
HOUSTON, TX 77210
SDSVEND@CITGO.COM
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
TECHNICAL CONTACT: (800) 248-4684
MEDICAL EMERGENCY: (832) 486-4700
CHEMTREC EMERGENCY: (800) 424-9300 (UNITED STATES ONLY)
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
WHILE THIS MATERIAL IS NOT CONSIDERED HAZARDOUS BY THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200), THIS SDS CONTAINS VALUABLE
INFORMATION CRITICAL TO THE SAFE HANDLING AND PROPER USE OF THE PRODUCT.
THIS SDS SHOULD BE RETAINED AND AVAILABLE FOR EMPLOYEES AND OTHER USERS
OF THIS PRODUCT.
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: NOT CLASSIFIED.
GHS LABEL ELEMENTS:
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
PRECAUTIONARY STATEMENTS:
PREVENTION: AVOID CONTACT WITH EYES, SKIN OR CLOTHING..
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERALMINUTES.
IF SWALLOWED:
DO NOT INDUCE VOMITING. AFTER HANDLING, ALWAYS WASH HANDS THOROUGHLY WITH
SOAP AND WATER. IF YOU FEEL UNWELL, SEEK MEDICAL ATTENTION AND SHOW THE
LABEL WHEN POSSIBLE. KEEP OUT OF REACH OF CHILDREN.
RESPONSE: NOT APPLICABLE.
STORAGE:
STORE IN A DRY PLACE AND/OR IN CLOSED CONTAINER. STORE IN ACCORDANCE WITH
ALL LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED:
INJECTION OF PETROLEUM HYDROCARBONS REQUIRES IMMEDIATE MEDICAL ATTENTION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION:
LUBRICATING GREASE;
CITGO(R*) MATERIAL CODE: 655212001
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER:
INGREDIENT NAME % CAS NUMBER
DISTILLATES (PETROLEUM), HYDROTREATED >/=25 - </=50 64742-54-7
HEAVY PARAFFINIC
DISTILLATES (PETROLEUM), HYDROTREATED >/=25 - </=50 64742-52-5
HEAVY NAPHTHENIC
RESIDUAL OILS (PETROLEUM), SOLVENT-DEWAXED >/=10 - </=25 64742-62-7
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS
DUE TO PROCESS VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. GET
MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING. DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO SO BY MEDICAL PERSONNEL. GET MEDICAL ATTENTION IF SYMPTOMS
OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
IN THE EVENT OF INJECTION IN UNDERLYING TISSUE, IMMEDIATE TREATMENT SHOULD
INCLUDE EXTENSIVE INCISION, DEBRIDEMENT AND SALINE IRRIGATION. INADEQUATE
TREATMENT CAN RESULT IN ISCHEMIA AND GANGRENE. EARLY SYMPTOMS MAY BE
MINIMAL.
SPECIFIC TREATMENTS: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
NO SPECIFIC FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS: NO SPECIFIC DATA.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
RAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NONEMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
MOVE CONTAINERS FROM SPILL AREA. VACUUM OR SWEEP UP MATERIAL AND PLACE IN
A DESIGNATED, LABELED WASTE CONTAINER. DISPOSE OF VIA A LICENSED WASTE
DISPOSAL CONTRACTOR.
LARGE SPILL:
MOVE CONTAINERS FROM SPILL AREA. PREVENT ENTRY INTO SEWERS, WATER COURSES,
BASEMENTS OR CONFINED AREAS. VACUUM OR SWEEP UP MATERIAL AND PLACE IN A
DESIGNATED, LABELED WASTE CONTAINER. DISPOSE OF VIA A LICENSED WASTE
DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR INCOMPATIBLE
MATERIALS BEFORE HANDLING OR USE.
BULK STORAGE CONDITIONS:
DO NOT APPLY HEAT OR FLAME TO STOCKPILED MATERIAL. ROTATE STOCK TO REDUCE
THE POTENTIAL FOR HOT SPOTS. DO NOT STORE WITH OXIDIZERS. MINIMIZE DUST
CREATION BY KEEPING MATERIAL MOIST AND/OR COVERED.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
DISTILLATES (PETROLEUM), ACGIH TLV (UNITED STATES, 3/2020).
HYDROTREATED HEAVY PARAFFINIC TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
OSHA PEL (UNITED STATES, 5/2018).
TWA: 5 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2016).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
DISTILLATES (PETROLEUM), ACGIH TLV (UNITED STATES, 3/2020).
HYDROTREATED HEAVY NAPHTHENIC TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
OSHA PEL (UNITED STATES, 5/2018).
TWA: 5 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2016).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
RESIDUAL OILS (PETROLEUM), ACGIH TLV (UNITED STATES, 6/2013).
SOLVENT-DEWAXED TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
NIOSH REL (UNITED STATES, 4/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
ACGIH TLV (UNITED STATES).
TWA: 5 MG/M3
STEL: 10 MG/M3
NIOSH REL (UNITED STATES).
TWA: 5 MG/M3
STEL: 10 MG/M3
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE
TO AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, VAPOR CONTROLS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE
WORKING PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE
POTENTIALLY CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE
REUSING. ENSURE THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE
WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY GLASSES EQUIPPED WITH SIDE SHIELDS ARE RECOMMENDED AS MINIMUM
PROTECTION IN INDUSTRIAL SETTINGS.
IF CONTACT IS POSSIBLE, THE FOLLOWING PROTECTION SHOULD BE WORN, UNLESS
THE ASSESSMENT INDICATES A HIGHER DEGREE OF PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN
A RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO
LIQUID SPLASHES, MISTS, GASES OR DUSTS. IF INHALATION HAZARDS EXIST, A
FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT GLOVES COMPLYING WITH AN APPROVED STANDARD SHOULD BE
WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK ASSESSMENT
INDICATES THIS IS NECESSARY.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON
THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED
BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
AVOID INHALATION OF GASES, VAPORS, MISTS OR DUSTS. USE A PROPERLY FITTED,
PARTICULATE FILTER RESPIRATOR COMPLYING WITH AN APPROVED STANDARD IF A
RISK ASSESSMENT INDICATES THIS IS NECESSARY. RESPIRATOR SELECTION MUST BE
BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS, THE HAZARDS OF THE PRODUCT
AND THE SAFE WORKING LIMITS OF THE SELECTED RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
THE CONDITIONS OF MEASUREMENT OF ALL PROPERTIES ARE AT STANDARD
TEMPERATURE AND PRESSURE UNLESS OTHERWISE INDICATED.
APPEARANCE:
PHYSICAL STATE: SOLID. [SMOOTH TEXTURE]
COLOR: DARK AMBER.
ODOR: MILD PETROLEUM ODOR
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT:
BOILING POINT, INITIAL BOILING POINT, AND BOILING RANGE: NOT AVAILABLE.
FLASH POINT:
OPEN CUP: >150 DEG. C (>302 DEG. F) [ESTIMATED]
EVAPORATION RATE: <1 (BUTYL ACETATE = 1)
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1%
UPPER: 7%
VAPOR PRESSURE: <0.013 KPA (<0.1 MM Hg)
RELATIVE VAPOR DENSITY: >10 [AIR = 1]
RELATIVE DENSITY: 0.91
DENSITY LBS/GAL: ESTIMATED 7.59 LBS/GAL
DENSITY GM/CM3: NOT AVAILABLE.
GRAVITY, DEG. API: ESTIMATED 24 @ 60 F
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE.
NLGI GRADE: 2
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): 1.7 CM2/S (170 CST)
VISCOSITY SUS: ESTIMATED 788 SUS @104 F
FLOW TIME (ISO 2431): NOT AVAILABLE.
PARTICLE CHARACTERISTICS:
MEDIAN PARTICLE SIZE: NOT AVAILABLE.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NOT EXPECTED TO BE EXPLOSIVE, SELF-REACTIVE, SELF-HEATING, OR AN ORGANIC
PEROXIDE UNDER US GHS DEFINITION(S).
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
DISTILLATES (PETROLEUM), LD50 DERMAL RAT >5000 MG/KG
HYDROTREATED HEAVY PARAFFINIC LD50 ORAL RAT >5000 MG/KG
DISTILLATES (PETROLEUM), LD50 ORAL RAT >5000 MG/KG
HYDROTREATED HEAVY LD50 ORAL RAT >5000 MG/KG
NAPHTHENIC
CONCLUSION/SUMMARY:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE
LOW ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL
MISTS WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG
INFLAMMATORY REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA.
IN ACUTE AND SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS
OF MINERAL OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS
PRODUCED NO SIGNIFICANT TOXICOLOGICAL EFFECTS.
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE
LOW ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF MINERAL
OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED NO
SIGNIFICANT TOXICOLOGICAL EFFECTS.
IRRITATION/CORROSION: NOT AVAILABLE.
SKIN: NO ADDITIONAL INFORMATION.
EYES: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
SENSITIZATION: NOT AVAILABLE.
SKIN: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
MUTAGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
CARCINOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
TERATOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: DERMAL.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES: N/A
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES EXPOSURE
DISTILLATES (PETROLEUM), ACUTE EC50: DAPHNIA - 48 HOURS
HYDROTREATED HEAVY >10000 MG/L DAPHNIA MAGNA
NAPHTHENIC FRESH WATER
ACUTE LC50: FISH - 96 HOURS
>100 MG/L PIMEPHALES
FRESH WATER PROMELAS
ACUTE NOEL: ALGAE - 72 HOURS
>100 MG/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
CONCLUSION/SUMMARY: NOT AVAILABLE.
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
DISTILLATES (PETROLEUM), INHERENT
HYDROTREATED HEAVY
NAPHTHENIC
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
DISTILLATES (PETROLEUM), >6 HIGH
HYDROTREATED HEAVY
NAPHTHENIC
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL
TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE
DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS.
DISPOSE OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE
DISPOSAL CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE
SEWER UNLESS FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES
WITH JURISDICTION. WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR
LANDFILL SHOULD ONLY BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS
MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
RCRA CLASSIFICATION: D018
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER
SHIPPING NAME
TRANSPORT
HAZARD CLASS(ES)
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO IMO INSTRUMENTS: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES INVENTORY (TSCA 8B): NOT DETERMINED.
CLEAN WATER ACT (CWA) 307:
PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS; TOLUENE;
ETHYLBENZENE; BENZENE; NAPHTHALENE
CLEAN WATER ACT (CWA) 311:
XYLENE; TOLUENE; ETHYLBENZENE; BENZENE; NAPHTHALENE UNITED STATES
INVENTORY (TSCA 8B): NOT DETERMINED.
THIS MATERIAL IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN WATER
ACT (CWA) AND THE OIL POLLUTION ACT OF 1990 (OPA). DISCHARGES OR SPILLS
WHICH PRODUCE A VISIBLE SHEEN ON WATERS OF THE UNITED STATES, THEIR
ADJOINING SHORELINES, OR INTO CONDUITS LEADING TO SURFACE WATERS MUST BE
REPORTED TO THE EPA'S NATIONAL RESPONSE CENTER AT (800) 424-8802.
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
STATE REGULATIONS:
MASSACHUSETTS: NONE OF THE COMPONENTS ARE LISTED.
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY: NONE OF THE COMPONENTS ARE LISTED.
PENNSYLVANIA: NONE OF THE COMPONENTS ARE LISTED.
CALIFORNIA PROP. 65 CLEAR AND REASONABLE WARNINGS (2018):
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING BENZENE, WHICH IS KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING
ETHYLBENZENE, NAPHTHALENE AND CUMENE, WHICH ARE KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, AND TOLUENE AND N-HEXANE, WHICH ARE KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
INGREDIENT NAME % CANCER REPRODUCTIVE NO SIGNIFICANT MAXIMUM
RISK LEVEL ACCEPTABLE
DOSAGE
LEVEL
TOLUENE <0.01 NO. YES. YES.
ETHYLBENZENE <0.001 YES. NO. YES.
BENZENE <0.001 YES. YES. YES. YES.
N-HEXANE <0.001 NO. YES. YES.
NAPHTHALENE <0.0001 YES. NO. YES.
CUMENE <0.0001 YES. NO.
INTERNATIONAL REGULATIONS:
ROTTERDAM CONVENTION ON PRIOR INFORMED CONSENT (PIC): NOT LISTED.
INVENTORY LIST:
UNITED STATES: NOT DETERMINED.
AUSTRALIA: NOT DETERMINED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN:
JAPAN INVENTORY (CSCL): AT LEAST ONE COMPONENT IS NOT LISTED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
MALAYSIA: NOT DETERMINED
NEW ZEALAND: ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
REPUBLIC OF KOREA: NOT DETERMINED.
TAIWAN: NOT DETERMINED.
THAILAND: NOT DETERMINED.
TURKEY: NOT DETERMINED.
VIET NAM: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 1
FLAMMABILITY 1
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE
HAZARDS OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL
FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS
NOT THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
NOT CLASSIFIED.
HISTORY:
DATE OF PRINTING: 2/10/2021
DATE OF ISSUE/DATE OF REVISION: 2/10/2021
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION
VERSION: 1
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES
WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED
WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR
ACCURACY. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM
SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS
PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED
AS A COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE
APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE
SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE
OR APPLICATION.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF
THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR
THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY
DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN
ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
CITGO IS A REGISTERED TRADEMARK OF CITGO PETROLEUM CORPORATION