| Common Name: | LITHOPLEX HM GREASE NO. 2 |
| Manufacturer: | CITGO PETROLEUM |
| SDS Revision Date: | 8/10/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 33ME83, 33ME84, 33ME85 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CITGO(R*)
SAFETY DATA SHEET
CITGO LITHOPLEX(R*) HM GREASE NO. 2
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: CITGO LITHOPLEX(R*) HM GREASE NO. 2
SYNONYMS:
LUBRICATING GREASE
CITGO(R*) MATERIAL CODE: 655357001
MATERIAL USES: LUBRICATING GREASE
CODE: 655357001
MSDS #: 655357001
SUPPLIER'S DETAILS:
CITGO PETROLEUM CORPORATION
P.O. BOX 4689
HOUSTON, TX 77210
SDSVEND@CITGO.COM
EMERGENCY TELEPHONE NUMBER:
TECHNICAL CONTACT: (800) 248-4684
MEDICAL EMERGENCY: (832) 486-4700
CHEMTREC EMERGENCY (UNITED STATES ONLY): (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SERIOUS EYE DAMAGE/ EYE IRRITATION: CATEGORY 2A
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
INJECTION UNDER THE SKIN CAN CAUSE SEVERE INJURY.
MOST DAMAGE OCCURS IN THE FIRST FEW HOURS.
INITIAL SYMPTOMS MAY BE MINIMAL.
PRECAUTIONARY STATEMENTS:
GENERAL:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
IF SWALLOWED:
DO NOT INDUCE VOMITING. AFTER HANDLING, ALWAYS WASH HANDS THOROUGHLY WITH
SOAP AND WATER. IF YOU FEEL UNWELL, SEEK MEDICAL ATTENTION AND SHOW THE
LABEL WHEN POSSIBLE. KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
WEAR EYE OR FACE PROTECTION. WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
STORE IN A DRY PLACE AND/OR IN CLOSED CONTAINER. STORE IN ACCORDANCE
WITH ALL LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED:
INJECTION OF PETROLEUM HYDROCARBONS REQUIRES IMMEDIATE MEDICAL ATTENTION
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION:
LUBRICATING GREASE
CITGO(R*) MATERIAL CODE: 655357001
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
MOLYBDENUM DISULFIDE 3 - 7 1317-33-5
ZINC AND ZINC COMPOUNDS 1 - 5 68649-42-3
* = VARIOUS
** = MIXTURE
*** = PROPRIETARY
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY
OR IS DUE TO PROCESS VARIATION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CLOTHING BEFORE
REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. DO NOT INDUCE
VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF VOMITING OCCURS,
THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. GET
MEDICAL ATTENTION IF ADVERSE HEALTH EFFECTS PERSIST OR ARE SEVERE. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: IRRITATING TO MOUTH, THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED, IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY
IF LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
NO SPECIFIC FIRE OR EXPLOSION HAZARD.
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SULFUR OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
MOVE CONTAINERS FROM SPILL AREA. AVOID DUST GENERATION. USING A VACUUM
WITH HEPA FILTER WILL REDUCE DUST DISPERSAL. PLACE SPILLED MATERIAL IN
A DESIGNATED, LABELED WASTE CONTAINER. DISPOSE OF VIA A LICENSED WASTE
DISPOSAL CONTRACTOR.
LARGE SPILL:
MOVE CONTAINERS FROM SPILL AREA. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. AVOID DUST
GENERATION. DO NOT DRY SWEEP. VACUUM DUST WITH EQUIPMENT FITTED WITH A HEPA
FILTER AND PLACE IN A CLOSED, LABELED WASTE CONTAINER. DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
INGEST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. KEEP IN THE ORIGINAL
CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL,
KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY CONTAINERS RETAIN PRODUCT
RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS
AND FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED
CLOTHING AND PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE
ALSO SECTION 8 FOR ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK.
KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS
THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE
CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
BULK STORAGE CONDITIONS:
DO NOT APPLY HEAT OR FLAME TO STOCKPILED MATERIAL. ROTATE STOCK TO REDUCE
THE POTENTIAL FOR HOT SPOTS. DO NOT STORE WITH OXIDIZERS. MINIMIZE DUST
CREATION BY KEEPING MATERIAL MOIST AND/OR COVERED.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
MOLYBDENUM DISULFIDE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 10 MG/M3, (AS Mo) 8 HOURS.
FORM: INHALABLE FRACTION
TWA: 3 MG/M3, (AS MO) 8 HOURS.
FORM: RESPIRABLE FRACTION
OSHA PEL (UNITED STATES, 2/2013).
TWA: 15 MG/M3, (AS MO) 8 HOURS.
FORM: TOTAL DUST
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE
TO AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, VAPOR CONTROLS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY GLASSES EQUIPPED WITH SIDE SHIELDS ARE RECOMMENDED AS MINIMUM
PROTECTION IN INDUSTRIAL SETTINGS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES. SAFETY GLASSES WITH SIDE SHIELDS.
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF INHALATION HAZARDS EXIST, A FULL-FACE
RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT GLOVES COMPLYING WITH AN APPROVED STANDARD SHOULD BE
WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK ASSESSMENT
INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS SPECIFIED BY THE
GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE STILL RETAINING
THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE TIME TO
BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT GLOVE
MANUFACTURERS.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
AVOID INHALATION OF GASES, VAPORS, MISTS OR DUSTS. USE A PROPERLY FITTED,
PARTICULATE FILTER RESPIRATOR COMPLYING WITH AN APPROVED STANDARD IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. RESPIRATOR SELECTION MUST BE BASED
ON KNOWN OR ANTICIPATED EXPOSURE LEVELS, THE HAZARDS OF THE PRODUCT AND THE
SAFE WORKING LIMITS OF THE SELECTED RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID. [SMOOTH TEXTURE]
COLOR: DARK GRAY TO BLACK
ODOR: MILD PETROLEUM ODOR
PH: NOT AVAILABLE.
BOILING POINT/BOILING RANGE: NOT AVAILABLE.
FLASH POINT:
OPEN CUP: >150 DEG. C (>302 DEG. F) [CLEVELAND.]
EVAPORATION RATE: <1 (BUTYL ACETATE = 1)
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: <0.013 KPA (<0.1 MM HG) [ROOM TEMPERATURE]
VAPOR DENSITY: >10 [AIR = 1]
RELATIVE DENSITY: 0.96
DENSITY LBS/GAL: ESTIMATED 16 @ 60 F
GRAVITY, DEG. API: ESTIMATED 8 LBS/GAL
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
NLGI GRADE: 2
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NOT EXPECTED TO BE EXPLOSIVE, SELF-REACTIVE, SELF-HEATING, OR AN
ORGANIC PEROXIDE UNDER US GHS DEFINITION(S).
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL
NOT OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
MOLYBDENUM DISULFIDE LD DERMAL RAT >2 G/KG
LD ORAL RAT >2 G/KG
LD50 ORAL RAT >6000 MG/KG
LDLO ORAL RAT 6 G/KG
ZINC AND ZINC COMPOUNDS LD50 DERMAL RABBIT 2000 MG/KG
LD50 ORAL RABBIT 2000 MG/KG
LD50 ORAL RAT 2890 MG/KG
CONCLUSION/SUMMARY:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE
LOW ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF MINERAL
OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED NO
SIGNIFICANT TOXICOLOGICAL EFFECTS.
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE
LOW ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF MINERAL
OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED NO
SIGNIFICANT TOXICOLOGICAL EFFECTS.
MOLYBDENUM DISULFIDE:
IN GENERAL, INSOLUBLE COMPOUNDS OF MOLYBDENUM, SUCH AS MOLYBDENUM
DISULFIDE, EXHIBIT A LOW ORDER OF TOXICITY.
ZINC AND ZINC COMPOUNDS:
INHALATION (LC50), ACUTE: > 1310 MG/L (RAT SCREEN LEVEL)(4 HOURS).
DRAIZE EYE, ACUTE: MODERATE TO SEVERE EYE IRRITANT. (RABBIT).
DRAIZE DERMAL, ACUTE: MILD TO MODERATE SKIN IRRITANT. (RABBIT).
BUEHLER DERMAL, ACUTE: NON-SENSITIZING. (GUINEA PIG).
28-DAY DERMAL, SUB-CHRONIC:
SEVERE SKIN IRRITANT. (RABBIT). REPORTED REDUCED FOOD CONSUMPTION RESULTING
IN WEIGHT LOSS AND TESTICULAR ATROPHY.
IRRITATION/CORROSION:
SKIN:
MOLYBDENUM DISULFIDE: MAY CAUSE SKIN IRRITATION.
EYES:
MOLYBDENUM DISULFIDE: MAY CAUSE EYE IRRITATION.
RESPIRATORY:
MOLYBDENUM DISULFIDE: MAY CAUSE RESPIRATORY IRRITATION.
SENSITIZATION:
SKIN: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
MUTAGENICITY:
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
CARCINOGENICITY:
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
REPRODUCTIVE TOXICITY:
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
TERATOGENICITY:
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
MOLYBDENUM DISULFIDE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: DERMAL.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: IRRITATING TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
CONCLUSION/SUMMARY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NOT AVAILABLE.
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING EMPTIED
CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY CONTAINERS OR
LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF SPILLED
MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER NOT REGULATED. NOT AVAILABLE. NOT AVAILABLE.
UN PROPER NOT AVAILABLE. NOT AVAILABLE.
SHIPPING NAME
TRANSPORT NOT AVAILABLE. NOT AVAILABLE.
HAZARD CLASS(ES)
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL
INFORMATION
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN WATER ACT (CWA) 307: ZINC AND ZINC COMPOUNDS
THIS MATERIAL IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN WATER
ACT (CWA) AND THE OIL POLLUTION ACT OF 1990 (OPA). DISCHARGES OR SPILLS
WHICH PRODUCE A VISIBLE SHEEN ON WATERS OF THE UNITED STATES, THEIR
ADJOINING SHORELINES, OR INTO CONDUITS LEADING TO SURFACE WATERS MUST BE
REPORTED TO THE EPA'S NATIONAL RESPONSE CENTER AT (800) 424-8802.
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: IMMEDIATE (ACUTE) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE (ACUTE) (CHRONIC)
OF HEALTH HEALTH
PRESSURE HAZARD HAZARD
MOLYBDENUM NO. NO. NO. YES. NO.
DISULFIDE
ZINC AND ZINC NO. NO. NO. YES. NO.
COMPOUNDS
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING ZINC AND ZINC COMPOUNDS 68649-42-3 <2
REQUIREMENTS
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: MOLYBDENUM DISULPHIDE; POLYMER
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED: ZINC COMPOUNDS; POLYMER
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED: ZINC COMPOUNDS; POLYMER
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA INVENTORY (IECSC): ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN INVENTORY: NOT DETERMINED.
KOREA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
MALAYSIA INVENTORY (EHS REGISTER): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC):
ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
TAIWAN INVENTORY (CSNN): NOT DETERMINED.
CANADA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EU INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
WHMIS (CANADA): NOT CONTROLLED UNDER WHMIS (CANADA).
| SECTION 16. OTHER INFORMATION | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 1
FLAMMABILITY 1
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE
HAZARDS OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL
FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL
IS NOT THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED
BY NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES
SO AT THEIR OWN RISK.
HISTORY:
DATE OF ISSUE/DATE OF REVISION: 8/10/2015.
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS,
1973 AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES
WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT
ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY.
SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES
OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A
COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE.
USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF
THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF
THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR
THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY
DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY
WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
CITGO IS A REGISTERED TRADEMARK OF CITGO PETROLEUM CORPORATION