| Common Name: | CLARION FOOD MACHINERY HT EP GREASE, NO. 2 |
| Manufacturer: | CITGO PETROLEUM |
| SDS Revision Date: | 4/19/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 33ME97 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CLARION(R*) LUBRICANTS
SAFETY DATA SHEET
CLARION(R*) FOOD MACHINERY HT EP GREASE, NO. 2
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: CLARION(R*) FOOD MACHINERY HT EP GREASE, NO. 2
SYNONYMS: LUBRICATING GREASE
CODE: 655700009
MSDS #: 655700009
SUPPLIER'S DETAILS:
CITGO PETROLEUM CORPORATION
P.O. BOX 4689
HOUSTON, TX 77210
SDSVEND@CITGO.COM
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
TECHNICAL CONTACT: (800) 248-4684
MEDICAL EMERGENCY: (832) 486-4700
CHEMTREC EMERGENCY: (800) 424-9300 (UNITED STATES ONLY)
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
AQUATIC HAZARD (ACUTE): CATEGORY 2
AQUATIC HAZARD (LONG-TERM): CATEGORY 2
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
EXCLAMATION MARK
ENVIRONMENT
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE.
INITIAL SYMPTOMS MAY BE MINOR.
PRECAUTIONARY STATEMENTS:
GENERAL:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.. IF IN EYES: RINSE CAUTIOUSLY
WITH WATER FOR SEVERAL MINUTES. IF SWALLOWED: DO NOT INDUCE VOMITING. AFTER
HANDLING, ALWAYS WASH HANDS THOROUGHLY WITH SOAP AND WATER. IF YOU FEEL
UNWELL, SEEK MEDICAL ATTENTION AND SHOW THE LABEL WHEN POSSIBLE. KEEP OUT
OF REACH OF CHILDREN.
PREVENTION:
WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION. AVOID RELEASE TO THE
ENVIRONMENT. WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE: COLLECT SPILLAGE.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF CONTAMINATED CLOTHING AND WASH
IT BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
STORE IN A DRY PLACE AND/OR IN CLOSED CONTAINER. STORE IN ACCORDANCE WITH
ALL LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED:
INJECTION OF PETROLEUM HYDROCARBONS REQUIRES IMMEDIATE MEDICAL ATTENTION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: LUBRICATING GREASE
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
WHITE MINERAL OIL (PETROLEUM) >/=50 - </=75 8042-47-5
CARBONIC ACID CALCIUM SALT >/=10 - </=25 471-34-1
ALUMINUM, BENZOATE HYDROGENATED </=10 68647-58-5
TALLOW FATTY ACID ISO-PR ALC. COMPLEXES
ZINC OXIDE </=3 1314-13-2
* = VARIOUS
** = MIXTURE
*** = PROPRIETARY
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO PROCESS VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. DO NOT INDUCE
VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF VOMITING OCCURS,
THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. GET
MEDICAL ATTENTION IF ADVERSE HEALTH EFFECTS PERSIST OR ARE SEVERE. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
CAUSES SKIN IRRITATION. INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE
SEVERE PERMANENT TISSUE DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN THE EVENT OF INJECTION IN UNDERLYING TISSUE, IMMEDIATE TREATMENT SHOULD
INCLUDE EXTENSIVE INCISION, DEBRIDEMENT AND SALINE IRRIGATION. INADEQUATE
TREATMENT CAN RESULT IN ISCHEMIA AND GANGRENE. EARLY SYMPTOMS MAY BE
MINIMAL.
SPECIFIC TREATMENTS: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THIS MATERIAL IS TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. FIRE
WATER CONTAMINATED WITH THIS MATERIAL MUST BE CONTAINED AND PREVENTED
FROM BEING DISCHARGED TO ANY WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
PHOSPHORUS OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR). WATER POLLUTING MATERIAL. MAY BE HARMFUL TO THE ENVIRONMENT IF
RELEASED IN LARGE QUANTITIES. COLLECT SPILLAGE.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
MOVE CONTAINERS FROM SPILL AREA. AVOID DUST GENERATION. USING A VACUUM
WITH HEPA FILTER WILL REDUCE DUST DISPERSAL. PLACE SPILLED MATERIAL IN
A DESIGNATED, LABELED WASTE CONTAINER. DISPOSE OF VIA A LICENSED WASTE
DISPOSAL CONTRACTOR.
LARGE SPILL:
MOVE CONTAINERS FROM SPILL AREA. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. AVOID DUST
GENERATION. DO NOT DRY SWEEP. VACUUM DUST WITH EQUIPMENT FITTED WITH A HEPA
FILTER AND PLACE IN A CLOSED, LABELED WASTE CONTAINER. DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
INGEST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID RELEASE TO THE
ENVIRONMENT. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE
MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE.
EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT
REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR INCOMPATIBLE
MATERIALS BEFORE HANDLING OR USE.
BULK STORAGE CONDITIONS:
DO NOT APPLY HEAT OR FLAME TO STOCKPILED MATERIAL. ROTATE STOCK TO REDUCE
THE POTENTIAL FOR HOT SPOTS. DO NOT STORE WITH OXIDIZERS. MINIMIZE DUST
CREATION BY KEEPING MATERIAL MOIST AND/OR COVERED.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
WHITE MINERAL OIL (PETROLEUM) ACGIH TLV (UNITED STATES, 3/2016).
TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
CALCIUM CARBONATE NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 10 MG/M3 10 HOURS.
FORM: TOTAL
ALUMINUM, BENZOATE ACGIH TLV (UNITED STATES).
HYDROGENATED TALLOW FATTY ACID TWA: 10 MG/M3 8 HOURS.
ISO-PR ALC. COMPLEXES
NIOSH REL (UNITED STATES, 10/2013).
TWA: 2 MG/M3, (AS Al) 10 HOURS.
ZINC OXIDE NIOSH REL (UNITED STATES, 10/2013).
CEIL: 15 MG/M3
FORM: DUST
TWA: 5 MG/M3 10 HOURS.
FORM: DUST AND FUMES
STEL: 10 MG/M3 15 MINUTES.
FORM: FUME
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
FORM: FUME
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ACGIH TLV (UNITED STATES).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE
ACGIH TLV (UNITED STATES, 3/2016).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
STEL: 10 MG/M3 15 MINUTES.
FORM: RESPIRABLE FRACTION
OSHA PEL (UNITED STATES).
NOTES: RESPIRABLE
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE DUST
OSHA PEL (UNITED STATES).
NOTES: TOTAL
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE
TO AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, VAPOR CONTROLS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY GLASSES EQUIPPED WITH SIDE SHIELDS ARE RECOMMENDED AS MINIMUM
PROTECTION IN INDUSTRIAL SETTINGS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES. SAFETY EYEWEAR COMPLYING WITH AN
APPROVED STANDARD SHOULD BE USED WHEN A RISK ASSESSMENT INDICATES THIS IS
NECESSARY TO AVOID EXPOSURE TO LIQUID SPLASHES, MISTS, GASES OR DUSTS. IF
INHALATION HAZARDS EXIST, A FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT GLOVES COMPLYING WITH AN APPROVED STANDARD SHOULD BE
WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK ASSESSMENT
INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS SPECIFIED BY THE
GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE STILL RETAINING
THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE TIME TO
BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT GLOVE
MANUFACTURERS.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
AVOID INHALATION OF GASES, VAPORS, MISTS OR DUSTS. USE A PROPERLY FITTED,
PARTICULATE FILTER RESPIRATOR COMPLYING WITH AN APPROVED STANDARD IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. RESPIRATOR SELECTION MUST BE BASED
ON KNOWN OR ANTICIPATED EXPOSURE LEVELS, THE HAZARDS OF THE PRODUCT AND THE
SAFE WORKING LIMITS OF THE SELECTED RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: SOLID. [SMOOTH TEXTURE]
COLOR: OFF-WHITE.
ODOR: MILD PETROLEUM ODOR
PH: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
OPEN CUP: >150 DEG. C (>302 DEG. F) [ESTIMATED]
EVAPORATION RATE: <1 (N-BUTYL ACETATE. = 1)
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1%
UPPER: 7%
VAPOR PRESSURE: <0.0013 KPA (<0.01 MM Hg) [ROOM TEMPERATURE]
VAPOR DENSITY: >10 [AIR = 1]
RELATIVE DENSITY: 0.98
DENSITY LBS/GAL: ESTIMATED 8.17 LBS/GAL
DENSITY GM/CM3: NOT AVAILABLE.
GRAVITY, DEG. API: ESTIMATED 13 @ 60 F
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
FLOW TIME (ISO 2431): NOT AVAILABLE.
NLGI GRADE: 2
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NOT EXPECTED TO BE EXPLOSIVE, SELF-REACTIVE, SELF-HEATING, OR AN ORGANIC
PEROXIDE UNDER US GHS DEFINITION(S).
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
CARBONIC ACID CALCIUM SALT LD50 ORAL RAT 6450 MG/KG
CONCLUSION/SUMMARY:
WHITE MINERAL OIL (PETROLEUM):
LOW-VISCOSITY AND HIGH-VISCOSITY WHITE MINERAL OILS: ^[25, 45, 50, 70]
DRAIZE EYE, ACUTE: NON-IRRITATING [RABBIT].
DRAIZE DERMAL, ACUTE: NON-IRRITATING [RABBIT].
BUEHLER, ACUTE: NON-SENSITIZING [GUINEA PIG].
28-DAY DERMAL, SUB-CHRONIC: NON-IRRITATING [RABBIT].
104-WEEK DERMAL, CHRONIC: NO SKIN TUMORS AT SITE OF APPLICATION [MOUSE].
MUTAGENICITY:
MODIFIED AMES ASSAY: NEGATIVE [SALMONELLA TYPHIMURIUM].
IN-VITRO LYMPHOMA ASSAY: NEGATIVE OR NO TOXICITY [MOUSE].
LIFETIME MOUSE SKIN PAINTING STUDIES INDICATED THAT WHITE MINERAL OILS ARE
NOT MUTAGENIC OR CARCINOGENIC. MINERAL OIL MISTS DERIVED FROM HIGHLY
REFINED OILS ARE REPORTED TO HAVE LOW ACUTE AND SUB-ACUTE TOXICITIES IN
ANIMALS. EFFECTS FROM SINGLE AND SHORT-TERM REPEATED EXPOSURES TO HIGH
CONCENTRATIONS OF MINERAL OIL MISTS WELL ABOVE APPLICABLE WORKPLACE
EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY REACTION, LIPOID GRANULOMA
FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND SUB-ACUTE STUDIES INVOLVING
EXPOSURES TO LOWER CONCENTRATIONS OF MINERAL OIL MISTS AT OR NEAR CURRENT
WORK PLACE EXPOSURE LEVELS PRODUCED NO SIGNIFICANT TOXICOLOGICAL EFFECTS.
IN LONG TERM STUDIES (UP TO TWO YEARS) NO CARCINOGENIC EFFECTS HAVE BEEN
REPORTED IN ANY ANIMAL SPECIES TESTED.
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVA-
NAME TION
CARBONIC ACID SKIN - MODERATE RABBIT 24 HOURS
CALCIUM SALT IRRITANT 500
MILLIGRAMS
EYES - MILD RABBIT
IRRITANT
RESPIRATORY - RABBIT
IRRITANT
ZINC OXIDE EYES - MILD RABBIT 24 HOURS
IRRITANT 500
MILLIGRAMS
SKIN - MILD RABBIT 24 HOURS
IRRITANT 500
MILLIGRAMS
SKIN: NO ADDITIONAL INFORMATION.
EYES: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
SENSITIZATION: NOT AVAILABLE.
SKIN: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
MUTAGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
CARCINOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY:
THIS GREASE PRODUCT CONTAINS CRYSTALLINE SILICA AT CONCENTRATIONS ABOVE
0.1%. IARC CONCLUDES THAT CRYSTALLINE SILICA IN THE FORM OF QUARTZ OR
CRISTOBALITE DUST IS CARCINOGENIC TO HUMANS (GROUP 1). IN ADDITION, IN THE
14TH REPORT ON CARCINOGENS, NTP INCLUDES SILICA, CRYSTALLINE (RESPIRABLE
SIZE) ON ITS LIST OF SUBSTANCES KNOWN TO BE HUMAN CARCINOGENS. INHALATION
EXPOSURES TO RESPIRABLE-SIZED SILICA DUST FROM A GREASE MATRIX ARE
UNLIKELY.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
TERATOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: DERMAL.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
CAUSES SKIN IRRITATION. INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE
SEVERE PERMANENT TISSUE DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
CARBONIC ACID ACUTE LC50: FISH - GAMBUSIA AFFINIS - 96 HOURS
CALCIUM SALT 56000 PPM FRESH ADULT
WATER
CHRONIC NOEC: FISH - ONCORHYNCHUS 28 DAYS
61 MG/G FRESH MYKISS - JUVENILE
WATER (FLEDGLING, HATCHLING,
WEANLING)
ZINC OXIDE ACUTE EC50: ALGAE - 72 HOURS
0.042 MG/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA - EXPONENTIAL
GROWTH PHASE
ACUTE LC50: DAPHNIA - DAPHNIA MAGNA - 48 HOURS
98 (MICRO)G/L NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS MYKISS 96 HOURS
1.1 PPM FRESH
WATER
CHRONIC NOEC: ALGAE - 72 HOURS
0.017 MG/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA - EXPONENTIAL
GROWTH PHASE
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
CONCLUSION/SUMMARY: NOT AVAILABLE.
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
WHITE MINERAL OIL NOT READILY
(PETROLEUM)
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
WHITE MINERAL OIL (PETROLEUM) >6 HIGH
ZINC OXIDE 60960 HIGH
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER
SHIPPING NAME
TRANSPORT
HAZARD CLASS(ES)
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN WATER ACT (CWA) 307: ZINC OXIDE
THIS MATERIAL IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN WATER
ACT (CWA) AND THE OIL POLLUTION ACT OF 1990 (OPA). DISCHARGES OR SPILLS
WHICH PRODUCE A VISIBLE SHEEN ON WATERS OF THE UNITED STATES, THEIR
ADJOINING SHORELINES, OR INTO CONDUITS LEADING TO SURFACE WATERS MUST BE
REPORTED TO THE EPA'S NATIONAL RESPONSE CENTER AT (800) 424-8802.
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION:
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % CLASSIFICATION
CALCIUM CARBONATE >/=10 - </=25 SKIN IRRITATION - CATEGORY 2
EYE IRRITATION - CATEGORY 2A
ZINC OXIDE <2.5 EYE IRRITATION - CATEGORY 2A
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING ZINC OXIDE 1314-13-2 <2
REQUIREMENTS
SUPPLIER NOTIFICATION ZINC OXIDE 1314-13-2 <2
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: ZINC OXIDE FUME
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED: ZINC OXIDE
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED:
ALUMINUM SOLUBLE SALTS; ZINC OXIDE (ZNO)
INTERNATIONAL REGULATIONS:
WHMIS (CANADA): NOT CONTROLLED UNDER WHMIS (CANADA).
INVENTORY LIST:
UNITED STATES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN:
JAPAN INVENTORY (ENCS): NOT DETERMINED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
MALAYSIA: NOT DETERMINED.
NEW ZEALAND: NOT DETERMINED.
PHILIPPINES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
REPUBLIC OF KOREA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN: NOT DETERMINED.
THAILAND: NOT DETERMINED.
TURKEY: NOT DETERMINED.
VIET NAM: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 1
FLAMMABILITY 1
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE HAZARDS
OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL FIRE
PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS NOT
THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
SKIN IRRITATION - CATEGORY 2 CALCULATION METHOD
EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
AQUATIC HAZARD (ACUTE) - CATEGORY 2 CALCULATION METHOD
AQUATIC HAZARD (LONG-TERM) - CATEGORY 2 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 4/19/2018
DATE OF ISSUE/DATE OF REVISION: 4/19/2018
DATE OF PREVIOUS ISSUE: 9/6/2017
VERSION: 2
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS,
1973 AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES
WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT
ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY.
SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES
OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A
COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE.
USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF
THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE
PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS
AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM
LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY
CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
CLARION IS A REGISTERED TRADEMARK OF CITGO PETROLEUM CORPORATION