| Common Name: | MYSTIK JT-6 HI-TEMP GREASE WITH MOLY, NLGI NO. 2 |
| Manufacturer: | CITGO PETROLEUM |
| SDS Revision Date: | 4/9/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 33MF17 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MYSTIK(R*) LUBRICANTS
SAFETY DATA SHEET
MYSTIK(R*) JT-6(R*) HI-TEMP GREASE WITH MOLY, NLGI NO 2
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER:
MYSTIK(R*) JT-6(R*) HI-TEMP GREASE WITH MOLY, NLGI NO. 2
SYNONYMS:
LUBRICATING GREASE; CITGO(R*) MATERIAL CODE: 665056002
FORMER NAME: MYSTIK(R*) TETRIMOLY(R*) EXTREME DUTY GREASE NLGI NO. 2
CODE: 665056002
MSDS #: 665056002
SUPPLIER'S DETAILS:
CITGO PETROLEUM CORPORATION
P.O. BOX 4689
HOUSTON, TX 77210
SDSVEND@CITGO.COM
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
TECHNICAL CONTACT: (800) 248-4684
MEDICAL EMERGENCY: (832) 486-4700
CHEMTREC EMERGENCY: (800) 424-9300
(UNITED STATES ONLY)
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
AQUATIC HAZARD (LONG-TERM) - CATEGORY 4
GHS LABEL ELEMENTS:
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
MAY CAUSE LONG LASTING HARMFUL EFFECTS TO AQUATIC LIFE.
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
PRECAUTIONARY STATEMENTS:
GENERAL:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING..
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
IF SWALLOWED:
DO NOT INDUCE VOMITING. AFTER HANDLING, ALWAYS WASH HANDS THOROUGHLY WITH
SOAP AND WATER. IF YOU FEEL UNWELL, SEEK MEDICAL ATTENTION AND SHOW THE
LABEL WHEN POSSIBLE. KEEP OUT OF REACH OF CHILDREN.
PREVENTION: AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE: NOT APPLICABLE.
STORAGE:
STORE IN A DRY PLACE AND/OR IN CLOSED CONTAINER. STORE IN ACCORDANCE WITH
ALL LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED:
INJECTION OF PETROLEUM HYDROCARBONS REQUIRES IMMEDIATE MEDICAL ATTENTION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION:
LUBRICATING GREASE; CITGO(R*) MATERIAL CODE: 665056002
FORMER NAME: MYSTIK(R*) TETRIMOLY(R*) EXTREME DUTY GREASE NLGI NO. 2
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
DISTILLATES (PETROLEUM), HYDROTREATED >/=10 - </=25 64742-52-5
HEAVY NAPHTHENIC
DISTILLATES (PETROLEUM), HYDROTREATED >/=10 - </=25 64742-54-7
HEAVY PARAFFINIC
RESIDUAL OILS (PETROLEUM), SOLVENT-DEWAXED </=10 64742-62-7
LITHIUM, 12-HYDROXYOCTADECANOATE SEBACATE </=10 68815-49-6
COMPLEXES
MOLYBDENUM DISULPHIDE </=5 1317-33-5
DISTILLATES (PETROLEUM), SOLVENT-REFINED </=3 64741-88-4
HEAVY PARAFFINIC
* = VARIOUS
** = MIXTURE
*** = PROPRIETARY
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO PROCESS VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CLOTHING BEFORE
REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. DO NOT INDUCE
VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF VOMITING OCCURS,
THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. GET
MEDICAL ATTENTION IF ADVERSE HEALTH EFFECTS PERSIST OR ARE SEVERE. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS. ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
IN THE EVENT OF INJECTION IN UNDERLYING TISSUE, IMMEDIATE TREATMENT SHOULD
INCLUDE EXTENSIVE INCISION, DEBRIDEMENT AND SALINE IRRIGATION. INADEQUATE
TREATMENT CAN RESULT IN ISCHEMIA AND GANGRENE. EARLY SYMPTOMS MAY BE
MINIMAL.
SPECIFIC TREATMENTS: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THIS MATERIAL MAY CAUSE LONG LASTING HARMFUL EFFECTS TO AQUATIC LIFE. FIRE
WATER CONTAMINATED WITH THIS MATERIAL MUST BE CONTAINED AND PREVENTED FROM
BEING DISCHARGED TO ANY WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SULFUR OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS.
SEE ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR). WATER POLLUTING MATERIAL. MAY BE HARMFUL TO THE ENVIRONMENT
IF RELEASED IN LARGE QUANTITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
MOVE CONTAINERS FROM SPILL AREA. VACUUM OR SWEEP UP MATERIAL AND PLACE
IN A DESIGNATED, LABELED WASTE CONTAINER. DISPOSE OF VIA A LICENSED WASTE
DISPOSAL CONTRACTOR.
LARGE SPILL:
MOVE CONTAINERS FROM SPILL AREA. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. VACUUM OR
SWEEP UP MATERIAL AND PLACE IN A DESIGNATED, LABELED WASTE CONTAINER.
DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
INGEST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID RELEASE TO THE
ENVIRONMENT. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE
FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY
CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE
CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR INCOMPATIBLE
MATERIALS BEFORE HANDLING OR USE.
BULK STORAGE CONDITIONS:
DO NOT APPLY HEAT OR FLAME TO STOCKPILED MATERIAL. ROTATE STOCK TO REDUCE
THE POTENTIAL FOR HOT SPOTS. DO NOT STORE WITH OXIDIZERS. MINIMIZE DUST
CREATION BY KEEPING MATERIAL MOIST AND/OR COVERED.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
DISTILLATES (PETROLEUM), HYDROTREATED ACGIH TLV (UNITED STATES, 3/2016).
HEAVY NAPHTHENIC TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
DISTILLATES (PETROLEUM), HYDROTREATED ACGIH TLV (UNITED STATES, 3/2016).
HEAVY PARAFFINIC TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
RESIDUAL OILS (PETROLEUM), ACGIH TLV (UNITED STATES, 6/2013).
SOLVENT-DEWAXED TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
NIOSH REL (UNITED STATES, 4/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
LITHIUM, 12-HYDROXYOCTADECANOATE ACGIH TLV (UNITED STATES).
SEBACATE COMPLEXES TWA: 10 MG/M3 8 HOURS.
MOLYBDENUM DISULPHIDE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 10 MG/M3, (AS Mo) 8 HOURS.
FORM: INHALABLE FRACTION
TWA: 3 MG/M3, (AS Mo) 8 HOURS.
FORM: RESPIRABLE FRACTION
OSHA PEL (UNITED STATES, 6/2016).
TWA: 15 MG/M3, (AS Mo) 8 HOURS.
FORM: TOTAL DUST
DISTILLATES (PETROLEUM), ACGIH TLV (UNITED STATES, 3/2016).
SOLVENT-REFINED HEAVY PARAFFINIC TWA: 5 MG/M3 8 HOURS.
FORM: INHALABLE FRACTION
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE
TO AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, VAPOR CONTROLS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD.
APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY CONTAMINATED
CLOTHING.
WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT EYEWASH STATIONS
AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY GLASSES EQUIPPED WITH SIDE SHIELDS ARE RECOMMENDED AS MINIMUM
PROTECTION IN INDUSTRIAL SETTINGS.
IF CONTACT IS POSSIBLE, THE FOLLOWING PROTECTION SHOULD BE WORN, UNLESS
THE ASSESSMENT INDICATES A HIGHER DEGREE OF PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF INHALATION HAZARDS EXIST, A FULL-FACE
RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT GLOVES COMPLYING WITH AN APPROVED STANDARD SHOULD BE
WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK ASSESSMENT
INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS SPECIFIED BY THE
GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE STILL RETAINING
THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE TIME TO
BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT GLOVE
MANUFACTURERS.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
AVOID INHALATION OF GASES, VAPORS, MISTS OR DUSTS. USE A PROPERLY FITTED,
PARTICULATE FILTER RESPIRATOR COMPLYING WITH AN APPROVED STANDARD IF A
RISK ASSESSMENT INDICATES THIS IS NECESSARY. RESPIRATOR SELECTION MUST BE
BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS, THE HAZARDS OF THE PRODUCT
AND THE SAFE WORKING LIMITS OF THE SELECTED RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: SOLID. [SMOOTH TEXTURE]
COLOR: DARK GRAY TO BLACK.
ODOR: MILD PETROLEUM ODOR
PH: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
OPEN CUP: >150 DEG. C (>302 DEG. F) [ESTIMATED]
EVAPORATION RATE: <1 (BUTYL ACETATE = 1)
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1%
UPPER: 7%
VAPOR PRESSURE: <0.0013 KPA (<0.01 MMHg) [ROOM TEMPERATURE]
VAPOR DENSITY: >1 [AIR = 1]
RELATIVE DENSITY: 0.94
DENSITY LBS/GAL: ESTIMATED 7.84 LBS/GAL
DENSITY GM/CM3: NOT AVAILABLE.
GRAVITY, DEG. API: ESTIMATED 19 @ 60 F
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
FLOW TIME (ISO 2431): NOT AVAILABLE.
NLGI GRADE: 2
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NOT EXPECTED TO BE EXPLOSIVE, SELF-REACTIVE, SELF-HEATING, OR AN ORGANIC
PEROXIDE UNDER US GHS DEFINITION(S).
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
DISTILLATES (PETROLEUM), LD50 ORAL RAT >5000 MG/KG
HYDROTREATED HEAVY LD50 ORAL RAT >5000 MG/KG
NAPHTHENIC
DISTILLATES (PETROLEUM), LD50 ORAL RAT >5000 MG/KG
HYDROTREATED HEAVY
PARAFFINIC
MOLYBDENUM DISULPHIDE LD DERMAL RAT >2 G/KG
LD ORAL RAT >2 G/KG
LD50 ORAL RAT >6000 MG/KG
LDLO ORAL RAT 6 G/KG
DISTILLATES (PETROLEUM), LD50 DERMAL RABBIT 2000 MG/KG
SOLVENT-REFINED HEAVY LD50 ORAL RAT 5000 MG/KG
PARAFFINIC
CONCLUSION/SUMMARY:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE
LOW ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF
MINERAL OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED
NO SIGNIFICANT TOXICOLOGICAL EFFECTS.
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE LOW
ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF
MINERAL OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED
NO SIGNIFICANT TOXICOLOGICAL EFFECTS.
MOLYBDENUM DISULPHIDE:
IN GENERAL, INSOLUBLE COMPOUNDS OF MOLYBDENUM, SUCH AS MOLYBDENUM
DISULFIDE, EXHIBIT A LOW ORDER OF TOXICITY.
DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY PARAFFINIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE LOW
ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF
MINERAL OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED
NO SIGNIFICANT TOXICOLOGICAL EFFECTS.
IRRITATION/CORROSION: NOT AVAILABLE.
SKIN:
MOLYBDENUM DISULPHIDE: MAY CAUSE SKIN IRRITATION.
EYES:
MOLYBDENUM DISULPHIDE: MAY CAUSE EYE IRRITATION.
RESPIRATORY:
MOLYBDENUM DISULPHIDE: MAY CAUSE RESPIRATORY IRRITATION.
SENSITIZATION: NOT AVAILABLE.
SKIN: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
MUTAGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
CARCINOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY:
DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY PARAFFINIC:
IN LONG TERM STUDIES (UP TO TWO YEARS) NO CARCINOGENIC EFFECTS HAVE BEEN
REPORTED IN ANY ANIMAL SPECIES TESTED.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
DISTILLATES (PETROLEUM), SOLVENT-REFINED 4
HEAVY PARAFFINIC
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
TERATOGENICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
MOLYBDENUM DISULPHIDE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: DERMAL.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
INJECTION OF PRESSURIZED HYDROCARBONS CAN CAUSE SEVERE PERMANENT TISSUE
DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY: NOT AVAILABLE.
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
CONCLUSION/SUMMARY: NOT AVAILABLE.
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
DISTILLATES (PETROLEUM), INHERENT
HYDROTREATED HEAVY
NAPHTHENIC
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
DISTILLATES (PETROLEUM), >6 HIGH
HYDROTREATED HEAVY
NAPHTHENIC
DISTILLATES (PETROLEUM), 3.9 TO 6 HIGH
SOLVENT-REFINED HEAVY
PARAFFINIC
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER NOT REGULATED. NOT AVAILABLE. NOT AVAILABLE.
UN PROPER SHIPPING NOT AVAILABLE. NOT AVAILABLE.
NAME
TRANSPORT HAZARD NOT AVAILABLE. NOT AVAILABLE.
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN WATER ACT (CWA) 307: ZINC BIS(DIPENTYLDITHIOCARBAMATE)
CLEAN WATER ACT (CWA) 311: XYLENE
THIS MATERIAL IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN WATER
ACT (CWA) AND THE OIL POLLUTION ACT OF 1990 (OPA). DISCHARGES OR SPILLS
WHICH PRODUCE A VISIBLE SHEEN ON WATERS OF THE UNITED STATES, THEIR
ADJOINING SHORELINES, OR INTO CONDUITS LEADING TO SURFACE WATERS MUST BE
REPORTED TO THE EPA'S NATIONAL RESPONSE CENTER AT (800) 424-8802.
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % CLASSIFICATION
MOLYBDENUM DISULPHIDE </=5 SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY
(SINGLE EXPOSURE) (RESPIRATORY
TRACT IRRITATION): CATEGORY 3
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: MOLYBDENUM DISULFIDE
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY: NONE OF THE COMPONENTS ARE LISTED.
PENNSYLVANIA: NONE OF THE COMPONENTS ARE LISTED.
CALIFORNIA PROP. 65 CLEAR AND REASONABLE WARNINGS (2018):
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CUMENE, WHICH IS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. FOR MORE INFORMATION GO TO
WWW.P65WARNINGS.CA.GOV.
INGREDIENT NAME % CANCER REPRODUCTIVE NO MAXIMUM
SIGNIFICANT ACCEPTABLE
RISK LEVEL DOSAGE
LEVEL
CUMENE <0.01 YES. NO.
INTERNATIONAL REGULATIONS:
WHMIS (CANADA): NOT CONTROLLED UNDER WHMIS (CANADA).
INVENTORY LIST:
UNITED STATES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN:
JAPAN INVENTORY (ENCS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
MALAYSIA: NOT DETERMINED.
NEW ZEALAND: ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
REPUBLIC OF KOREA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN: NOT DETERMINED.
THAILAND: NOT DETERMINED.
TURKEY: NOT DETERMINED.
VIET NAM: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 1
FLAMMABILITY 1
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE
HAZARDS OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL
FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS
NOT THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
AQUATIC HAZARD (LONG-TERM) - CATEGORY 4 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 4/9/2018
DATE OF ISSUE/DATE OF REVISION: 4/9/2018
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION
VERSION: 1
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES
WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT
ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY.
SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES
OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A
COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE.
USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF
THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE
PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS
AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM
LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY
CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
MYSTIK IS A REGISTERED TRADEMARK OF CITGO PETROLEUM CORPORATION