| Common Name: | COMET DISINFECTING SANITIZING BATHROOM CLEANER |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 4/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 33NT92, 33NT93, 392C19 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G PROFESSIONAL(TM)
SAFETY DATA SHEET
ISSUING DATE: 12-FEB-2015
REVISION DATE: 07-APR-2015
VERSION: 2
| 1. IDENTIFICATION |  |
PRODUCT NAME: COMET(R*) DISINFECTING SANITIZING BATHROOM CLEANER
PRODUCT CODE(S): 3-20
PRODUCT ID: 15154320_PROF_NG
PRODUCT TYPE: FINISHED PRODUCT - PROFESSIONAL USE ONLY
RECOMMENDED USE: DISINFECTANT
RESTRICTIONS ON USE:
DO NOT MIX WITH OTHER CLEANING PRODUCTS OR CHEMICALS AS IRRITATING FUMES
MAY BE FORMED.
MANUFACTURER:
PROCTER & GAMBLE PROFESSIONAL
2 P&G PLAZA
CINCINNATI, OHIO 45202
PROCTER & GAMBLE INC.
P.O. BOX 355, STATION A
TORONTO, ON M5W 1C5
1-800-332-7787
E-MAIL ADDRESS: PGSDS.IM@PG.COM
EMERGENCY TELEPHONE:
TRANSPORTATION (24 HR):
CHEMTREC: 1-800-424-9300
(U.S./ CANADA) OR: 1-703-527-3887
MEXICO TOLL FREE IN COUNTRY: 800-681-9531
| 2. HAZARD IDENTIFICATION | |
THIS PRODUCT IS CLASSIFIED UNDER 29CFR 1910.1200(D) AND THE CANADIAN
HAZARDOUS PRODUCTS REGULATION AS FOLLOWS:
HAZARD CATEGORY:
ACUTE TOXICITY - ORAL: CATEGORY 4
EYE DAMAGE / IRRITATION: CATEGORY 2B
CORROSIVE TO METALS: CATEGORY 1
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES EYE IRRITATION
HARMFUL IF SWALLOWED
MAY BE CORROSIVE TO METALS
HAZARD PICTOGRAMS:
EXCLAMATION MARK
CORROSION
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH HANDS THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
KEEP ONLY IN ORIGINAL CONTAINER
DO NOT MIX WITH OTHER CLEANING PRODUCTS OR CHEMICALS AS IRRITATING FUMES
MAY BE FORMED
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF SWALLOWED:
RINSE WITH PLENTY OF WATER
DRINK 1 OR 2 GLASSES OF WATER
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE
PRECAUTIONARY STATEMENTS - STORAGE: STORE IN CORROSIVE RESISTANT CONTAINER
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL REGULATION
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS ARE LISTED ACCORDING TO 29 CFR 1910.1200 APPENDIX D AND THE
CANADIAN HAZARDOUS PRODUCTS REGULATION:
CHEMICAL NAME SYNONYMS TRADE SECRET CAS-NO WEIGHT %
DIPROPYLENE GLYCOL NO 29911-28-2 5 - 10
BUTOXY ETHER
CITRIC ACID NO 77-92-9 1 - 5
1-PROPANAMINIUM, NO 68139-30-0 1 - 5
N-(3-AMINOPROPYL)-
2-HYDROXY-N,N-DIMETHYL-
3-SULFO-, N-COCO ACYL
DERIVS., INNER SALTS
BENZENESULFONIC ACID, NO 28348-53-0 1 - 5
(1-METHYLETHYL)-,
SODIUM SALT (1:1)
ALCOHOLS, C9-11, NO 68439-46-3 1 - 5
ETHOXYLATED
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES FOR DIFFERENT EXPOSURE ROUTES:
EYE CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IMMEDIATELY IF IRRITATION
PERSISTS.
SKIN CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
INGESTION:
RINSE MOUTH. DRINK 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. GET
MEDICAL ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NONE UNDER NORMAL USE CONDITIONS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
SPECIAL HAZARD: NONE KNOWN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
ADVICE FOR EMERGENCY RESPONDERS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT MATERIAL,
(E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. KEEP CONTAINER CLOSED WHEN
NOT IN USE. NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE. KEEP OUT
OF THE REACH OF CHILDREN.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
STORE IN CORROSIVE RESISTANT CONTAINER.
INCOMPATIBLE PRODUCTS:
DO NOT MIX WITH OTHER CLEANING PRODUCTS OR CHEMICALS AS IRRITATING FUMES
MAY BE FORMED.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES: NO EXPOSURE LIMITS NOTED FOR INGREDIENT(S).
EXPOSURE CONTROLS:
ENGINEERING MEASURES:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS: ENSURE ADEQUATE VENTILATION
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WHERE REASONABLY PRACTICABLE THIS SHOULD BE ACHIEVED BY THE USE OF LOCAL
EXHAUST VENTILATION AND GOOD GENERAL EXTRACTION
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
USE APPROPRIATE EYE PROTECTION
HAND PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
PROTECTIVE GLOVES
SKIN AND BODY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
IN CASE OF INSUFFICIENT VENTILATION WEAR SUITABLE RESPIRATORY EQUIPMENT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE @ 20 DEG. C: LIQUID
APPEARANCE: CLEAR
ODOR: SCENTED
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES NOTE
PH VALUE 3
MELTING/FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT/BOILING RANGE NO INFORMATION AVAILABLE
FLASH POINT >93.3 DEG. C / >200 DEG. F
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
RELATIVE DENSITY 1.042
WATER SOLUBILITY 100%
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE.
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE.
VISCOSITY OF PRODUCT <10 CPS
VOC CONTENT (%) PRODUCTS COMPLY WITH US
STATE AND FEDERAL
REGULATIONS FOR VOC
CONTENT IN CONSUMER
PRODUCTS.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE UNDER NORMAL USE CONDITIONS.
STABILITY: STABLE UNDER NORMAL CONDITIONS.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE UNDER NORMAL PROCESSING.
MATERIALS TO AVOID:
DO NOT MIX WITH OTHER CLEANING PRODUCTS OR CHEMICALS AS IRRITATING FUMES
MAY BE FORMED.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL USE.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: NO KNOWN EFFECT.
SKIN CONTACT: NO KNOWN EFFECT.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
EYE CONTACT: IRRITATING TO EYES.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
ACUTE TOXICITY: MAY BE HARMFUL IF SWALLOWED.
SKIN CORROSION/IRRITATION: NO KNOWN EFFECT.
SERIOUS EYE DAMAGE/EYE IRRITATION: IRRITATING TO EYES.
SKIN SENSITIZATION: NO KNOWN EFFECT.
RESPIRATORY SENSITIZATION: NO KNOWN EFFECT.
GERM CELL MUTAGENICITY: NO KNOWN EFFECT.
NEUROLOGICAL EFFECTS: NO KNOWN EFFECT.
REPRODUCTIVE TOXICITY: NO KNOWN EFFECT.
DEVELOPMENTAL TOXICITY: NO KNOWN EFFECT.
TERATOGENICITY: NO KNOWN EFFECT.
STOT - SINGLE EXPOSURE: NO KNOWN EFFECT.
STOT - REPEATED EXPOSURE: NO KNOWN EFFECT.
TARGET ORGAN EFFECTS: NO KNOWN EFFECT.
ASPIRATION HAZARD: NO KNOWN EFFECT.
CARCINOGENICITY: NO KNOWN EFFECT.
COMPONENT INFORMATION:
CHEMICAL NAME CAS-NO LD50 ORAL LD50 DERMAL LC50 INHALATION
DIPROPYLENE GLYCOL 29911-28-2 2610 MG/KG >2000 MG/KG >2.04 MG/L
BUTOXY ETHER BW (SIMILAR BW (OECD AIR (OECD
TO OECD 402; 403; STANDARD
401; STANDARD ACUTE METHOD;
STANDARD ACUTE RAT)
ACUTE METHOD; RAT)
METHOD;
RAT)
CITRIC ACID 77-92-9 5400 MG/KG >2000 MG/KG
BW (SIMILAR BW (OECD
TO OECD 402,
401; STANDARD
STANDARD ACUTE
ACUTE METHOD; RAT)
METHOD;
MOUSE)
BENZENESULFONIC 28348-53-0 5160.00
ACID, MG/KG (RAT)
(1-METHYLETHYL)-,
SODIUM SALT (1:1)
ALCOHOLS, C9-11, 68439-46-3 1600.00
ETHOXYLATED MG/KG (RAT)
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
PRODUCTS COVERED BY THIS MSDS, IN THEIR ORIGINAL FORM, WHEN DISPOSED AS
WASTE, ARE CORROSIVE HAZARDOUS WASTE, D002, ACCORDING TO FEDERAL RCRA
REGULATIONS (40 CFR 261). DISPOSAL SHOULD BE IN ACCORDANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES (NON-HOUSEHOLD SETTING): 331
| 14. TRANSPORT INFORMATION | |
DOT:
UN NO: UN1760
UN PROPER SHIPPING NAME: CORROSIVE LIQUIDS, N.O.S.
DESCRIPTION:
UN1760, CORROSIVE LIQUID, N.O.S , (CITRIC ACID), 8, III, LTD. QTY.
HAZARD CLASS: 8
PACKING GROUP: III
IMDG:
UN NUMBER: UN1760
UN PROPER SHIPPING NAME: CORROSIVE LIQUID, N.O.S.
DESCRIPTION:
UN1760, CORROSIVE LIQUID, N.O.S , (CITRIC ACID), 8, III, LTD. QTY.
TRANSPORT HAZARD CLASS(ES): 8
PACKING GROUP: III
IATA:
UN NO: UN1760
UN PROPER SHIPPING NAME: CORROSIVE LIQUID, N.O.S.
DESCRIPTION:
UN1760, CORROSIVE LIQUID, N.O.S, (CITRIC ACID), 8, III, LTD. QTY.
HAZARD CLASS: 8
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED
AS HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS HAZARDOUS AIR
POLLUTANTS (HAPS) UNDER SECTION 112 OF THE CLEAN AIR ACT AMENDMENTS OF
1990.
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO WARNING LABELING UNDER CALIFORNIA
PROPOSITION 65.
U.S. STATE REGULATIONS (RTK):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED BY STATE
RIGHT-TO-KNOW REGULATIONS
INTERNATIONAL INVENTORIES:
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT(S) ARE LISTED ON THE US
TSCA INVENTORY.
CANADA: THIS PRODUCT IS IN COMPLIANCE WITH CEPA FOR IMPORT BY P&G.
LEGEND:
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
CEPA - CANADIAN ENVIRONMENTAL PROTECTION ACT
FIFRA:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE UNITED STATES
ENVIRONMENTAL PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING
REQUIREMENTS UNDER FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM
THE CLASSIFICATION CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY
DATA SHEETS (SDS), AND FOR WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS. THE
HAZARD INFORMATION REQUIRED ON THE PESTICIDE LABEL IS REPRODUCED BELOW. THE
PESTICIDE LABEL ALSO INCLUDES OTHER IMPORTANT INFORMATION, INCLUDING
DIRECTIONS FOR USE.
EPA REGISTRATION NUMBER: 3573-54
CAUTION:
MAY BE HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH HAZARD 3
FLAMMABILITY 1
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH HAZARD 3
FLAMMABILITY 1
INSTABILITY 0
ISSUING DATE: 12-FEB-2015
REVISION DATE: 07-APR-2015
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT
15154320_PROF_NG - COMET(R*) DISINFECTING SANITIZING BATHROOM CLEANER