| Common Name: | MR. CLEAN PROFESSIONAL NO-RINSE FLOOR CLEANER - CONCENTRATE |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 5/14/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 33NU14 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G PROFESSIONAL(TM)
SAFETY DATA SHEET
ISSUING DATE: 09-FEB-2015
REVISION DATE: 14-MAY-2018
VERSION: 2.01
| 1. IDENTIFICATION |  |
PRODUCT NAME:
MR. CLEAN PROFESSIONAL(TM) NO-RINSE FLOOR CLEANER - CONCENTRATE
PRODUCT CODE(S): 4-70
PRODUCT IDENTIFIER: 98980785_PROF_NG
PRODUCT TYPE: FINISHED PRODUCT - PROFESSIONAL USE ONLY
RECOMMENDED USE: FLOOR CARE.
RESTRICTIONS ON USE: USE ONLY AS DIRECTED ON LABEL.
DETAILS OF THE SUPPLIER OF THE SAFETY SDATA SHEET
PROCTER & GAMBLE PROFESSIONAL
1 P&G PLAZA
CINCINNATI, OHIO 45202
PROCTER & GAMBLE INC.
P.O. BOX 355, STATION A
TORONTO, ON M5W 1C5
1-800-332-7787
E-MAIL ADDRESS: PGSDS.IM@PG.COM
EMERGENCY TELEPHONE:
TRANSPORTATION (24 HR):
CHEMTREC: 1-800-424-9300
(U.S./ CANADA) OR: 1-703-527-3887
MEXICO TOLL FREE IN COUNTRY: 800-681-9531
| 2. HAZARD IDENTIFICATION | |
THIS PRODUCT IS CLASSIFIED UNDER 29CFR 1910.1200(D) AND THE CANADIAN
HAZARDOUS PRODUCTS REGULATION AS FOLLOWS:
HAZARD CATEGORY:
ACUTE TOXICITY - ORAL: CATEGORY 4
EYE DAMAGE / IRRITATION: CATEGORY 2A
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION
HARMFUL IF SWALLOWED
HAZARD PICTOGRAMS: EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
WASH HANDS THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF SWALLOWED:
RINSE WITH PLENTY OF WATER
DRINK 1 OR 2 GLASSES OF WATER
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL: NONE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS ARE LISTED ACCORDING TO 29CFR 1910.1200 APPENDIX D AND THE
CANADIAN HAZARDOUS PRODUCTS REGULATION:
CHEMICAL NAME SYNONYMS TRADE SECRET CAS-NO WEIGHT-%
ALCOHOLS, C12-16, ALCOHOLS, YES 68551-12-2 1 - 5
ETHOXYLATED C12-16,
ETHOXYLATED
OXIRANE, 2-METHYL-, OXIRANE, 2- YES 166736-08-9 1 - 5
POLYMER WITH METHYL-,
OXIRANE, MONO(2- POLYMER WITH
PROPYLHEPTYL) ETHER OXIRANE,
MONO(2-
PROPYLHEPTYL)
ETHER
BENZENESULFONIC BENZENESULFONIC YES 28348-53-0 0.5 - 1.5
ACID, (1-METHYL- ACID, (1-
ETHYL)-, SODIUM METHYLETHYL)-,
SALT (1:1) SODIUM SALT
(1:1)
SULFURIC ACID, SULFURIC ACID, YES 68585-47-7 0.5 - 1.5
MONO-C10-16-ALKYL MONO-C10-16-
ESTERS, SODIUM ALKYL ESTERS,
SALTS SODIUM SALTS
CITRUS AURANTIUM ORANGE OIL, YES 8008-57-9 0.1 - 1
DULCIS OIL EXPRESSED
LIMONENE CYCLOHEXENE, YES 5989-27-5 0.1 - 1
1-METHYL-4-
(1-METHYL-
ETHENYL)-,
(4R)-
ADDITIONAL INFORMATION:
ACTUAL CONCENTRATIONS WITHHELD AS TRADE SECRET IN ACCORDANCE WITH CANADIAN
HPR
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES FOR DIFFERENT EXPOSURE ROUTES:
EYE CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IMMEDIATELY IF IRRITATION
PERSISTS.
SKIN CONTACT:
RINSE WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS
AND PERSISTS.
INGESTION:
RINSE MOUTH. DRINK 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. GET
MEDICAL ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NONE UNDER NORMAL USE CONDITIONS.
F. INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
SPECIAL HAZARD: NONE KNOWN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
ADVICE FOR EMERGENCY RESPONDERS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT MATERIAL,
(E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. KEEP CONTAINER CLOSED WHEN
NOT IN USE.
NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE. KEEP OUT OF THE
REACH OF CHILDREN.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES: NO EXPOSURE LIMITS NOTED FOR INGREDIENT(S).
EXPOSURE CONTROLS:
ENGINEERING MEASURES:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
ENSURE ADEQUATE VENTILATION
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WHERE REASONABLY PRACTICABLE THIS SHOULD BE ACHIEVED BY THE USE OF LOCAL
EXHAUST VENTILATION AND GOOD GENERAL EXTRACTION
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
USE APPROPRIATE EYE PROTECTION
HAND PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
PROTECTIVE GLOVES
SKIN AND BODY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
DISTRIBUTION, WORKPLACE AND HOUSEHOLD SETTINGS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED
PRODUCT MANUFACTURING PLANT (NEEDED AT PRODUCT-PRODUCING PLANT ONLY):
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE @ 20 DEG. C: LIQUID
APPEARANCE: LIGHT YELLOW
ODOR: LEMON
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES NOTE
PH VALUE 10.35
MELTING POINT / FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT / BOILING RANGE NO INFORMATION AVAILABLE
FLASH POINT >93.3 DEG. C / >200 DEG. F
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
RELATIVE DENSITY 1.019
WATER SOLUBILITY 100%
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE
VISCOSITY NO INFORMATION AVAILABLE
VOC CONTENT (%) PRODUCTS COMPLY WITH US STATE AND
FEDERAL REGULATIONS FOR VOC CONTENT IN
CONSUMER PRODUCTS.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE UNDER NORMAL USE CONDITIONS.
STABILITY: STABLE UNDER NORMAL CONDITIONS.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE UNDER NORMAL PROCESSING.
INCOMPATIBLE MATERIALS: NONE IN PARTICULAR.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL USE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: NO KNOWN EFFECT.
SKIN CONTACT: NO KNOWN EFFECT.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
ACUTE TOXICITY: MAY BE HARMFUL IF SWALLOWED.
SKIN CORROSION/IRRITATION: NO KNOWN EFFECT.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
SKIN SENSITIZATION: NO KNOWN EFFECT.
RESPIRATORY SENSITIZATION: NO KNOWN EFFECT.
GERM CELL MUTAGENICITY: NO KNOWN EFFECT.
NEUROLOGICAL EFFECTS: NO KNOWN EFFECT.
REPRODUCTIVE TOXICITY: NO KNOWN EFFECT.
DEVELOPMENTAL TOXICITY: NO KNOWN EFFECT.
TERATOGENICITY: NO KNOWN EFFECT.
STOT - SINGLE EXPOSURE: NO KNOWN EFFECT.
STOT - REPEATED EXPOSURE: NO KNOWN EFFECT.
TARGET ORGAN EFFECTS: NO KNOWN EFFECT.
ASPIRATION HAZARD: NO KNOWN EFFECT.
CARCINOGENICITY: NO KNOWN EFFECT.
COMPONENT INFORMATION:
CHEMICAL NAME CAS-NO ORAL LD50 DERMAL LD50 INHALATION LC50
BENZENESULFONIC 28348-53-0 >7000 MG/KG >2000 MG/KG >6.41 MG/L AIR
ACID, (1- BW (OECD BW (//OECD
METHYLETHYL)-, 401) 402)
SODIUM SALT
(1:1)
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
WASTE FROM RESIDUES/UNUSED PRODUCTS:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES (NON-HOUSEHOLD SETTING): 331
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
IMDG: NOT REGULATED
IATA: NOT REGULATED
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL.
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS HAZARDOUS AIR
POLLUTANTS (HAPS) UNDER SECTION 112 OF THE CLEAN AIR ACT AMENDMENTS OF
1990.
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT SUBJECT TO WARNING LABELING UNDER CALIFORNIA
PROPOSITION 65.
U.S. STATE REGULATIONS (RTK):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED BY STATE
RIGHT-TO-KNOW REGULATIONS.
INTERNATIONAL INVENTORIES:
UNITED STATES:
ALL INTENTIONALLY-ADDED COMPONENTS OF THIS PRODUCT(S) ARE LISTED ON THE US
TSCA INVENTORY.
CANADA: THIS PRODUCT IS IN COMPLIANCE WITH CEPA FOR IMPORT BY P&G.
LEGEND:
UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY (TSCA)
CEPA: CANADIAN ENVIRONMENTAL PROTECTION ACT
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH HAZARD 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH HAZARD 2
FLAMMABILITY 1
INSTABILITY 0
ISSUING DATE: 09-FEB-2015
REVISION DATE: 14-MAY-2018
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT