| Common Name: | LOCTITE LB 8012 MOLY PASTE KNOWN AS LOCTITE MOLY PASTE 12OZ AE EN, 1852755 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 4/10/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 33PK25, 45MY47 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 002.0
ISSUE DATE: 04/10/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE LB 8012 MOLY PASTE KNOWN AS LOCTITE MOLY PASTE 12OZ AE EN
PRODUCT TYPE: ANTISEIZE
IDH NUMBER: 1852755
ITEM NUMBER: 1852755
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CONTENTS UNDER PRESSURE.
FLAMMABLE AEROSOL.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE DAMAGE.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE AEROSOL. 2
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SPECIFIC TARGET ORGAN TOXICITY - 3
SINGLE EXPOSURE
PICTOGRAM(S):
FLAME
CORROSION
EXCLAMATION
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN,
EVEN AFTER USE. AVOID BREATHING MIST OR SPRAY. WASH AFFECTED AREA
THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IF SKIN IRRITATION OCCURS: GET
MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
N-HEPTANE 142-82-5 10 - 20
MOLYBDENUM DISULPHIDE 1317-33-5 10 - 20
METHYL ACETATE 79-20-9 10 - 20
ACETONE 67-64-1 10 - 20
PROPANE/ISOBUTANE 68476-86-8 10 - 20
CALCIUM DIHYDROXIDE 1305-62-0 1 - 5
DISTILLATES (PETROLEUM), 64742-52-5 1 - 5
HYDROTREATED HEAVY
NAPHTHENIC
DISTILLATES (PETROLEUM), 64742-53-6 1 - 5
HYDROTREATED LIGHT
NAPHTHENIC
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
SKIN CONTACT:
IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION. WASH AFFECTED AREA
IMMEDIATELY WITH SOAP AND WATER.
EYE CONTACT:
GET MEDICAL ATTENTION. IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
INGESTION:
DO NOT INDUCE VOMITING:
CONTAINS PETROLEUM DISTILLATES AND/OR AROMATIC SOLVENTS. ASPIRATION MAY
CAUSE PULMONARY EDEMA AND PNEUMONITIS. GET IMMEDIATE MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WATER SHOULD BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. WEAR A
SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE PIECE OPERATED IN
PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO
EXTREME HEAT. DO NOT PUNCTURE OR INCINERATE PRESSURIZED CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ELIMINATE IGNITION SOURCES INCLUDING SOURCES OF ELECTRICAL, STATIC OR
FRICTIONAL SPARKS. WIPE UP WITH ADSORBENT MATERIAL (E.G. CLOTH, FLEECE).
RINSE SPILL AREA WITH WATER. STORE IN A PARTLY FILLED, CLOSED CONTAINER
UNTIL DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP AWAY FROM HEAT, SPARK AND FLAME. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE GAS/FUMES/VAPOR/SPRAY.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA. STORE AWAY FROM HEAT, SPARKS, FLAMES,
OR OTHER SOURCES OF IGNITION. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT
WATER, AND OTHER HEAT SOURCES COULD CAUSE CONTAINER TO BURST.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS ACGIH TLV OSHA PEL AIHA OTHER
COMPONENT(S) WEEL
N-HEPTANE 400 PPM TWA 500 PPM NONE NONE
500 PPM STEL (2,000 MG/M3)
PEL
MOLYBDENUM 10 MG/M3 TWA 15 MG/M3 PEL NONE NONE
DISULPHIDE (AS Mo) (AS Mo) TOTAL
INHALABLE DUST.
FRACTION.
3 MG/M3 TWA
(AS Mo)
RESPIRABLE
FRACTION.
METHYL 200 PPM TWA 200 PPM NONE NONE
ACETATE 250 PPM STEL (610 MG/M3)
PEL
ACETONE 250 PPM TWA 1,000 PPM NONE NONE
500 PPM STEL (2,400 MG/M3)
PEL
PROPANE/ NONE NONE NONE NONE
ISOBUTANE
CALCIUM 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
DIHYDROXIDE RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
DISTILLATES EXPOSURE BY 500 PPM NONE NONE
(PETROLEUM), ALL ROUTES (2,000 MG/M3)
HYDROTREATED SHOULD BE PEL
HEAVY CAREFULLY 5 MG/M3 PEL
NAPHTHENIC CONTROLLED MIST.
TO LEVELS
AS LOW
AS POSSIBLE.
INCLUDED IN
THE
REGULATION
BUT WITH NO
DATA VALUES.
SEE
REGULATION
FOR FURTHER
DETAILS
DISTILLATES INCLUDED IN 5 MG/M3 TWA NONE NONE
(PETROLEUM), THE MIST
HYDROTREATED REGULATION 10 MG/M3
LIGHT BUT WITH NO TWA MIST
NAPHTHENIC DATA VALUES. 5 MG/M3 PEL
SEE MIST.
REGULATION 500 PPM
FOR FURTHER (2,000 MG/M3)
DETAILS PEL
EXPOSURE BY
ALL ROUTES
SHOULD BE
CAREFULLY
CONTROLLED
TO LEVELS AS
LOW AS
POSSIBLE.
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION.
RESPIRATORY PROTECTION:
WHEN WORKPLACE HAZARDS WARRANT THE USE OF A RESPIRATOR, APPROPRIATE
RESPIRATORS MUST BE USED, AND A PROGRAM THAT FOLLOWS 29 CFR 1910.134 MUST
BE FOLLOWED.
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION: CHEMICAL RESISTANT, IMPERMEABLE GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BLACK
ODOR: SOLVENT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: <-17 DEG. C (<1.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 45% (CALCULATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: NOT AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: EXTREMES OF TEMPERATURE AND DIRECT SUNLIGHT.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS WITH NAUSEA, DIZZINESS AND HEADACHE.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT:
CAUSES SERIOUS EYE DAMAGE. DIRECT SPRAY OR VAPORS WILL IRRITATE AND MAY
HARM EYES. DIRECT CONTACT WITH LIQUID MAY CAUSE CORNEAL DAMAGE AND VISUAL
IMPAIRMENT.
INGESTION:
NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. MAY CAUSE GASTROINTESTINAL
TRACT IRRITATION IF SWALLOWED.
HAZARDOUS LD50S AND LC50S IMMEDIATE AND DELAYED
COMPONENT(S) HEALTH EFFECTS
N-HEPTANE INHALATION LC50 CENTRAL NERVOUS
(RAT, 4 H): SYSTEM, IRRITANT
103 MG/L
MOLYBDENUM NONE NO TARGET ORGANS
DISULPHIDE
METHYL ACETATE ORAL LD50 BLOOD, CENTRAL NERVOUS
(RABBIT): SYSTEM, EYES, IRRITANT
3.7 G/KG
ACETONE ORAL LD50 CENTRAL NERVOUS SYSTEM,
(MOUSE): 5.2 G/KG IRRITANT
ORAL LD50 (MOUSE):
3,000 MG/KG
ORAL LD50 (RABBIT):
5,340 MG/KG
ORAL LD50 (RAT):
5,800 MG/KG
ORAL LD50 (RAT):
9,800 MG/KG
DERMAL LD50
(RABBIT):
20,000 MG/KG
INHALATION LC50
(RAT, 4 H): 76 MG/L
PROPANE/ NONE NO RECORDS
ISOBUTANE
CALCIUM ORAL LD50 (RAT): IRRITANT, CORROSIVE
DIHYDROXIDE 7,340 MG/KG
DISTILLATES NONE IRRITANT
(PETROLEUM),
HYDROTREATED
HEAVY
NAPHTHENIC
DISTILLATES NONE IRRITANT
(PETROLEUM),
HYDROTREATED
LIGHT
NAPHTHENIC
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED)
N-HEPTANE NO NO NO
MOLYBDENUM DISULPHIDE NO NO NO
METHYL ACETATE NO NO NO
ACETONE NO NO NO
PROPANE/ISOBUTANE NO NO NO
CALCIUM DIHYDROXIDE NO NO NO
DISTILLATES KNOWN TO GROUP 1 NO
(PETROLEUM), BE HUMAN
HYDROTREATED HEAVY CARCINOGEN.
NAPHTHENIC
DISTILLATES KNOWN TO GROUP 1 NO
(PETROLEUM), BE HUMAN
HYDROTREATED LIGHT CARCINOGEN.
NAPHTHENIC
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
DOT HAZARDOUS SUBSTANCE(S): ACETONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS (N-HEPTANE)
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
MARINE POLLUTANT: N-HEPTANE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: FIRE, PRESSURE, IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY:
N-HEPTANE (CAS# 142-82-5) 100 LBS. (45.4 KG)
METHYL ACETATE (CAS# 79-20-9) 100 LBS. (45.4 KG)
ACETONE (CAS# 67-64-1) 5,000 LBS. (2,270 KG)
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 04/10/2018
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.