| Common Name: | LOCTITE LB 8507 NICK AS 12OZEN, 1852753 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 12/13/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 33PK29, 42MM72 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 12/13/2019
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE LB 8507 NICK AS 12OZEN
PRODUCT TYPE/USE: ANTISEIZE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1852753
ITEM NUMBER: 1852753
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CONTENTS UNDER PRESSURE.
FLAMMABLE AEROSOL.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF CAUSING CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE AEROSOL. 2
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
CARCINOGENICITY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
ASPIRATION HAZARD 1
PICTOGRAM(S):
FLAME
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT, SPARKS,
OPEN FLAMES, HOT SURFACES - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR
OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT
BREATHE MIST OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. DO NOT
EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE
PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION. DO NOT INDUCE VOMITING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
PETROLEUM DISTILLATES APPROX. 30 - 60
NICKEL 7440-02-0 10 - 30
GRAPHITE 7782-42-5 10 - 30
ALUMINUM NOT POWDER, DUST OR FUME 7429-90-5 1 - 5
N-HEPTANE 142-82-5 10 - 30
ACETONE 67-64-1 10 - 30
PROPANE/ISOBUTANE 68476-86-8 10 - 30
*EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH WITH SOAP AND WATER. IF
SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION. WASH CLOTHING BEFORE
REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING: CONTAINS PETROLEUM DISTILLATES AND/OR AROMATIC
SOLVENTS. ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET IMMEDIATE MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WATER SHOULD BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. WEAR A
SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE PIECE OPERATED IN
PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. IN CASE OF FIRE, KEEP
CONTAINERS COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CONTENTS UNDER PRESSURE. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT
OR OTHER SOURCES OF IGNITION. DO NOT PUNCTURE OR INCINERATE PRESSURIZED
CONTAINERS. CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE)
WHEN EXPOSED TO EXTREME HEAT. VAPOR ACCUMULATION CAN FLASH OR EXPLODE IF
IGNITED.
HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. REMOVE ALL SOURCES OF IGNITION. SOAK UP WITH
INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL
BINDER, SAWDUST). REMOVE THE ABSORBED MATERIAL, AND PLACE IN AN
APPROPRIATE CHEMICAL WASTE CONTAINER FOR DISPOSAL. RINSE SPILL AREA WITH
WATER.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP AWAY FROM HEAT, SPARK AND FLAME. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
VAPORS WILL ACCUMULATE READILY AND MAY IGNITE EXPLOSIVELY. REFER TO SECTION
8.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE. HEAT FROM SUNLIGHT,
RADIATORS, STOVES, HOT WATER, AND OTHER HEAT SOURCES COULD CAUSE CONTAINER
TO BURST.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
PETROLEUM DISTILLATES NONE NONE NONE NONE
APPROX.
NICKEL 1.5 MG/M3 1 MG/M3 NONE NONE
TWA PEL (AS NI)
INHALABLE
FRACTION.
GRAPHITE 2 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE RESPIRABLE
FRACTION. FRACTION.
15 MG/M3
PEL TOTAL
DUST.
ALUMINUM NOT POWDER, 1 MG/M3 TWA 5 MG/M3 PEL NONE NONE
DUST OR FUME RESPIRABLE (AS AL)
FRACTION. RESPIRABLE
FRACTION.
15 MPPCF
TWA
RESPIRABLE
FRACTION.
5 MG/M3
TWA
RESPIRABLE
FRACTION.
N-HEPTANE 400 PPM TWA 500 PPM NONE NONE
500 PPM (2,000 MG/M3)
STEL PEL
ACETONE 250 PPM TWA 1,000 PPM NONE NONE
500 PPM (2,400 MG/M3)
STEL PEL
PROPANE/ISOBUTANE NONE NONE NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED RESPIRATOR IF VENTILATION IS INADEQUATE.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: AEROSOL, LIQUID, OR, PASTE
COLOR: SILVER
ODOR: KETONE
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: <-17 DEG. C (<1.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 35.9%
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. EXTREMES
OF TEMPERATURE AND DIRECT SUNLIGHT.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS WITH NAUSEA, DIZZINESS AND HEADACHE.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. DIRECT SPRAY OR VAPORS WILL IRRITATE AND MAY
HARM EYES. DIRECT CONTACT WITH LIQUID MAY CAUSE CORNEAL DAMAGE AND VISUAL
IMPAIRMENT.
INGESTION:
PRINCIPAL HAZARD OF INGESTION IS ASPIRATION INTO THE LUNGS AND SUBSEQUENT
PNEUMONITIS.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
PETROLEUM DISTILLATES NONE NO DATA
APPROX.
NICKEL NONE ALLERGEN, CARCINOGEN, IRRITANT,
KIDNEY, MUTAGEN, REPRODUCTIVE,
RESPIRATORY
GRAPHITE INHALATION LC50 LUNG
(RAT, 4 H):
>2,000 MG/M3
INHALATION LC50
(RAT, 4 H):
>2,000 MG/M3
ALUMINUM NOT POWDER, NONE CENTRAL NERVOUS SYSTEM,
DUST OR FUME IRRITANT, LUNG
N-HEPTANE NONE CENTRAL NERVOUS SYSTEM, IRRITANT
ACETONE ORAL LD50 CENTRAL NERVOUS SYSTEM, IRRITANT
(MOUSE):
5.2 G/KG
ORAL LD50
(MOUSE):
3,000 MG/KG
ORAL LD50
(RABBIT):
5,340 MG/KG
ORAL LD50
(RAT):
5,800 MG/KG
ORAL LD50
(RAT):
9,800 MG/KG
DERMAL LD50
(RABBIT):
20,000 MG/KG
PROPANE/ISOBUTANE NONE NO RECORDS
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
PETROLEUM DISTILLATES NO NO NO
APPROX.
NICKEL REASONABLY GROUP 2B NO
ANTICIPATED TO
BE A HUMAN
CARCINOGEN.
GRAPHITE NO NO NO
ALUMINUM NOT POWDER, NO NO NO
DUST OR FUME
N-HEPTANE NO NO NO
ACETONE NO NO NO
PROPANE/ISOBUTANE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT AVAILABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
DOT HAZARDOUS SUBSTANCE(S): NICKEL, ACETONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS (N-HEPTANE)
HAZARD CLASS OR DIVISION: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
MARINE POLLUTANT: N-HEPTANE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312:
FIRE, PRESSURE, IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). NICKEL (CAS# 7440-02-0).
CERCLA REPORTABLE QUANTITY:
NICKEL (CAS# 7440-02-0) 100 LBS. (45.4 KG)
N-HEPTANE (CAS# 142-82-5) 100 LBS. (45.4 KG)
ACETONE (CAS# 67-64-1) 5,000 LBS. (2,270 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2, 15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 12/13/2019
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF ANY
KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY OTHER
JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.