| Common Name: | NON-FLAMMABLE GAS MIXTURE, 50120MSA |
| Manufacturer: | AIR LIQUIDE |
| SDS Revision Date: | 10/17/2014 |
| SDS Format: | No Format Specified |
| Item Number(s): | 33RJ57 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
NON-FLAMMABLE GAS MIXTURE CONTAINING SULFUR DIOXIDE 0.0001%, HYDROGEN
SULFIDE 0.001-0.025%, PENTANE 0.0-0.75%, OXYGEN 0.0-23.5% IN NITROGEN
BALANCE
MSA
THE SAFETY COMPANY
SAFETY DATA SHEET
50120MSA
| SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
PRODUCT NAME:
NON-FLAMMABLE GAS MIXTURE CONTAINING SULFUR DIOXIDE 0.0001%, HYDROGEN
SULFIDE 0.001-0.025%, PENTANE 0.0-0.75%, OXYGEN 0.0-23.5% IN NITROGEN
BALANCE
MSA P/N: 10153806, 10153807, 10153808, 10154996
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RELEVANT IDENTIFIED USE(S):
CALIBRATION OF MONITORING AND RESEARCH EQUIPMENT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
AIR LIQUIDE
2700 POST OAK BLVD.
HOUSTON, TX 77056
UNITED STATES
WWW.US.AIRLIQUIDE.COM
SDS@AIRLIQUIDE.COM
U.S. SUPPLIER:
MINE SAFETY APPLIANCES COMPANY
100 CRANBERRY WOODS DRIVE
CRANBERRY TOWNSHIP
PENNSYLVANIA U.S.A. 16066
1-800-MSA-2222
WWW.MSANET.COM/PRISM
TELEPHONE (TECHNICAL): 713-896-2896
TELEPHONE (TECHNICAL): 800-819-1704
1.4 EMERGENCY TELEPHONE NUMBER:
MANUFACTURER: 800-424-9300 - CHEMTREC
MANUFACTURER: +1 703-527-3887 - OUTSIDE UNITED STATES
| SECTION 2 - HAZARDS IDENTIFICATION | |
EU/EEC:
ACCORDING TO REGULATION (EC) NO 1272/2008 (CLP)/REACH 1907/2006 [AMENDED BY
453/2010] ACCORDING TO EU DIRECTIVE 67/548/EEC (DSD) OR 1999/45/EC (DPD):
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLP: COMPRESSED GAS - H280
DSD/DPD: NOT CLASSIFIED
2.2 LABEL ELEMENTS:
CLP: WARNING
GAS CYLINDER
HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
PRECAUTIONARY STATEMENTS:
STORAGE/DISPOSAL:
P403: STORE IN A WELL-VENTILATED PLACE.
DSD/DPD:
RISK PHRASES: NO LABEL ELEMENT(S) REQUIRED
2.3 OTHER HAZARDS:
CLP:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
ACCORDING TO REGULATION (EC) NO. 1272/2008 (CLP) THIS MATERIAL IS
CONSIDERED HAZARDOUS.
DSD/DPD:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
ACCORDING TO EUROPEAN DIRECTIVE 1999/45/EC THIS PREPARATION IS NOT
CONSIDERED DANGEROUS.
UNITED STATES (US):
ACCORDING TO OSHA 29 CFR 1910.1200 HCS:
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012:
COMPRESSED GAS -H280
SIMPLE ASPHYXIANT
2.2 LABEL ELEMENTS:
OSHA HCS 2012: WARNING
GAS CYLINDER
HAZARD STATEMENTS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED - H280 MAY DISPLACE
OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENTS:
STORAGE/DISPOSAL: STORE IN A WELL-VENTILATED PLACE. - P403
2.3 OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
CANADA:
ACCORDING TO WHMIS:
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
WHMIS: COMPRESSED GAS - A
2.2 LABEL ELEMENTS:
WHMIS: COMPRESSED GAS - A
2.3 OTHER HAZARDS:
WHMIS:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
IN CANADA, THE PRODUCT MENTIONED ABOVE IS CONSIDERED HAZARDOUS UNDER THE
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS).
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE IN ACCORDANCE WITH
REGULATION (EC) NO 1272/2008.
3.2 MIXTURES:
COMPOSITION:
CHEMICAL NAME IDENTIFIERS %
OXYGEN CAS: 7782-44-7 0% TO 23.5%
EC NUMBER: 231-956-9
EU INDEX: 008-001-00-8
PENTANE CAS: 109-66-0 0% TO 0.75
EC NUMBER: 203-692-4
EU INDEX: 601-006-00-1
HYDROGEN SULFIDE CAS: 7783-06-4 0.001% TO 0.025%
EC NUMBER: 231-977-3
EU INDEX: 016-001-00-4
SULFUR DIOXIDE CAS: 7446-09-5 0.0001%
EC NUMBER: 231-195-2
EU INDEX: 016-011-00-9
NITROGEN CAS: 7727-37-9 BALANCE
EINECS: 231-783-9
CHEMICAL LD50/LC50 CLASSIFICATIONS ACCORDING
NAME TO REGULATION/DIRECTIVE
OXYGEN NDA EU DSD/DPD: ANNEX VI, TABLE 3.2: O R8
EU CLP:
ANNEX VI, TABLE 3.1:
OX. GAS 1, H270; PRESS. GAS - COMP.,
H280
OSHA HCS 2012:
OX. GAS 1; PRESS. GAS - COMP.
PENTANE INHALATION- EU DSD/DPD:
RAT LC50: ANNEX VI, TABLE 3.2:
364 G/M3 F+ R12 N R51-53 XN R65 R66 R67
4 HOUR(S)
EU CLP:
INGESTION/ ANNEX VI, TABLE 3.1:
ORAL-RAT FLAM. LIQ. 1, H224; ASP. TOX. 1, H304;
LD50:
>2000 MG/KG STOT SE 3:
NARC., H336; AQUATIC CHRONIC 2, H411;
EUH066
OSHA HCS 2012:
FLAM. LIQ. 1; ASP TOX. 1; EYE IRRIT.
2A; SKIN IRRIT. 2
STOT SE 3: NARC.
HYDROGEN SULFIDE INHALATION- EU DSD/DPD:
RAT LC50: ANNEX VI, TABLE 3.2:
700 MG/M3 F+ R12 T+ R26 N R50
4 HOUR(S)
EU CLP:
ANNEX VI, TABLE 3.1:
FLAM. GAS 1, H220; PRESS. GAS - COMP.,
H280
ACUTE TOX. 2 *H330:
AQUATIC ACUTE 1, H400
OSHA HCS 2012:
FLAM. GAS; PRESS. GAS - COMP.; ACUTE
TOX. 2 (INHL)
SULFUR DIOXIDE INHALATION- EU DSD/DPD:
RAT LC50: ANNEX VI, TABLE 3.2: T R23 C R34
2168 MG/M3
EU CLP:
ANNEX VI, TABLE 3.1:
PRESS. GAS - COMP., H280; ACUTE TOX.
3*, H331; SKIN CORR. 1B, H314
OSHA HCS 2012:
PRESS. GAS - COMP.; MUTA. 2; ACUTE
TOX. 3 (INHL); REPR. 2; SKIN CORR. 1B;
EYE DAM. 1
NITROGEN NDA EU DSD/DPD: NOT CLASSIFIED
EU CLP:
SELF CLASSIFIED:
PRESS. GAS - COMP. H280
OSHA HCS 2012:
PRESS. GAS - COMP.; SIMP. ASPHYX.
SEE SECTION 16 FOR FULL TEXT OF H-STATEMENTS AND R-PHRASES.
| SECTION 4 - FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL
RESPIRATION IF VICTIM IS NOT BREATHING. IF SIGNS/SYMPTOMS CONTINUE, GET
MEDICAL ATTENTION.
SKIN:
ALTHOUGH EXPOSURE IS UNLIKELY, IN CASE OF CONTACT IMMEDIATELY FLUSH SKIN
WITH RUNNING WATER. IF SKIN IRRITATION DEVELOPS GET MEDICAL
ADVICE/ATTENTION.
EYE:
FIRST AID IS NOT EXPECTED TO BE NECESSARY IF MATERIAL IS USED UNDER
ORDINARY CONDITIONS AND AS RECOMMENDED. IF IRRITATION DEVELOPS AND
PERSISTS, GET MEDICAL ATTENTION. INGESTION. INGESTION IS NOT CONSIDERED A
POTENTIAL ROUTE OF EXPOSURE.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED. A
POTENTIAL HEALTH HAZARD ASSOCIATED WITH THIS GAS IS ANOXIA.
4.4 OTHER INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. RESCUERS SHOULD NOT ATTEMPT TO
RETRIEVE VICTIMS OF EXPOSURE TO GASES WITHOUT ADEQUATE PERSONAL PROTECTIVE
EQUIPMENT. AT A MINIMUM, SELF-CONTAINED BREATHING APPARATUS MUST BE WORN.
VICTIM(S) WHO EXPERIENCE ANY ADVERSE EFFECT AFTER OVEREXPOSURE TO THIS GAS
MIXTURE MUST BE TAKEN FOR MEDICAL ATTENTION. RESCUERS SHOULD BE TAKEN FOR
MEDICAL ATTENTION IF NECESSARY. TAKE A COPY OF THE LABEL AND THE MSDS TO
PHYSICIAN OR OTHER HEALTH PROFESSIONAL WITH VICTIM(S).
| SECTION 5 - FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO DATA AVAILABLE
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN HEATED.
RUPTURED CYLINDERS MAY ROCKET.
HAZARDOUS COMBUSTION PRODUCTS: NO DATA AVAILABLE
5.3 ADVICE FOR FIREFIGHTERS:
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING PROVIDES LIMITED PROTECTION IN
FIRE SITUATIONS ONLY; IT IS NOT EFFECTIVE IN SPILL SITUATIONS WHERE DIRECT
CONTACT WITH THE SUBSTANCE IS POSSIBLE.
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK.
FIRE:
IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN A FIRE, ISOLATE FOR 800
METERS (1/2 MILE) IN ALL DIRECTIONS; ALSO, CONSIDER INITIAL EVACUATION FOR
800 METERS (1/2 MILE) IN ALL DIRECTIONS.
FIRE INVOLVING TANKS:
FIGHT FIRE FROM MAXIMUM DISTANCE OR USE UNMANNED HOSE HOLDERS OR MONITOR
NOZZLES.
FIRE INVOLVING TANKS:
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS
OUT.
FIRE INVOLVING TANKS:
DO NOT DIRECT WATER AT SOURCE OF LEAK OR SAFETY DEVICES; ICING MAY OCCUR.
FIRE INVOLVING TANKS:
WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICES OR
DISCOLORATION OF TANK.
FIRE INVOLVING TANKS: ALWAYS STAY AWAY FROM TANKS ENGULFED IN FIRE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
VENTILATE THE AREA BEFORE ENTRY. DO NOT WALK THROUGH SPILLED MATERIAL.
DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING
APPROPRIATE PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
KEEP UNAUTHORIZED PERSONNEL AWAY. KEEP OUT OF LOW AREAS. STAY UPWIND.
DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK.
LARGE SPILL:
CONSIDER INITIAL DOWNWIND EVACUATION FOR AT LEAST 500 METERS (1/3 MILE)
6.2 ENVIRONMENTAL PRECAUTIONS:
PREVENT SPREADING OF VAPORS THROUGH SEWERS, VENTILATION SYSTEMS AND
CONFINED AREAS.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
VENTILATE THE AREA.
ISOLATE AREA UNTIL GAS HAS DISPERSED.
USE WATER SPRAY TO REDUCE VAPORS; DO NOT PUT WATER DIRECTLY ON LEAK, SPILL
AREA OR INSIDE CONTAINER.
IF POSSIBLE, TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN
LIQUID.
6.4 REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION AND
SECTION 13 - DISPOSAL CONSIDERATIONS.
| SECTION 7 - HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. VENTILATE CLOSED SPACES BEFORE
ENTERING. BE AWARE OF ANY SIGNS OF DIZZINESS OR FATIGUE, ESPECIALLY IF WORK
IS DONE IN A POORLY VENTILATED AREA; EXPOSURES TO FATAL CONCENTRATIONS OF
THIS GAS MIXTURE COULD OCCUR WITHOUT ANY SIGNIFICANT WARNING SYMPTOMS, DUE
TO OLFACTORY FATIGUE OR OXYGEN DEFICIENCY. CYLINDERS SHOULD BE FIRMLY
SECURED TO PREVENT FALLING OR BEING KNOCKED-OVER. DO NOT ATTEMPT TO REPAIR,
ADJUST, OR IN ANY OTHER WAY MODIFY CYLINDERS. IF THERE IS A MALFUNCTION OR
ANOTHER TYPE OF OPERATIONAL PROBLEM, CONTACT NEAREST DISTRIBUTOR
IMMEDIATELY. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
DO NOT CUT, WELD, PUNCTURE OR INCINERATE CONTAINER.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
STORE IN A COOL, DRY, WELL-VENTILATED PLACE. PROTECT CYLINDERS AGAINST
PHYSICAL DAMAGE. CYLINDERS SHOULD BE FIRMLY SECURED TO PREVENT FALLING OR
BEING KNOCKED-OVER. DO NOT ALLOW AREA WHERE CYLINDERS ARE STORED TO EXCEED
52C (125F).
7.3 SPECIFIC END USE(S): REFER TO SECTION 1.2 - RELEVANT IDENTIFIED USES.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
EXPOSURE LIMITS/GUIDELINES:
RESULT ACGIH CANADA ONTARIO CANADA QUEBEC
PENTANE STELS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
(109-66-0)
TWAS 600 PPM TWA 600 PPM TWA 120 PPM TWAEV
(LISTED UNDER 350 MG/M3 TWAEV
PENTANE, ALL
ISOMERS)
SULFUR STELS 0.25 PPM STEL 5 PPM STEL 5 PPM STEV
DIOXIDE 10.4 MG/M3 STEL 13 MG/M3 STEV
(7446-09-5)
TWAS NOT ESTABLISHED 2 PPM TWA 2 PPM TWAEV
5.2 MG/M3 TWA 5.2 MG/M3 TWAEV
HYDROGEN CEILINGS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
SULFIDE
(7783-06-4) STELS 5 PPM STEL 15 PPM STEL 15 PPM STEV
21 MG/M3 STEV
TWAS 1 PPM TWA 10 PPM TWA 10 PPM TWAEV
14 MG/M3 TWAEV
RESULT CHINA CHINA HIGHLY TOXIC GOODS
PENTANE STELS 1000 MG/M3 STEL NOT ESTABLISHED
(LISTED UNDER PENTANE
(ALL ISOMERS))
TWAS 500 MG/M3 TWA NOT ESTABLISHED
(LISTED UNDER PENTANE
(ALL ISOMERS))
SULFUR STELS 10 MG/M3 STEL NOT ESTABLISHED
DIOXIDE
TWAS 5 MG/M3 TWA NOT ESTABLISHED
HYDROGEN CEILINGS 10 MG/M3 CEILING 10 MG/M3 CEILING
SULFIDE [MAC]
STELS NOT ESTABLISHED NOT ESTABLISHED
TWAS NOT ESTABLISHED NOT ESTABLISHED
RESULT EUROPE FRANCE GERMANY DFG
PENTANE TWAS 1000 PPM TWA 1000 PPM TWA NOT ESTABLISHED
(109-66-0) 3000 MG/M3 TWA [VME]
(RESTRICTIVE
LIMIT)
3000 MG/M3 TWA
[VME]
(RESTRICTIVE
LIMIT)
STELS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 2000 PPM PEAK
(LISTED UNDER
PENTANE)
6000 MG/M3 PEAK
(LISTED UNDER
PENTANE)
MAKS NOT ESTABLISHED NOT ESTABLISHED 1000 PPM TWA
MAK
3000 MG/M3 TWA
MAK
SULFUR STELS NOT ESTABLISHED 5 PPM STEL NOT ESTABLISHED
DIOXIDE [VLCT]
(7446-09-5)
10 MG/M3 STEL
[VLCT]
SULFUR TWAS NOT ESTABLISHED 2 PPM TWA [VME] NOT ESTABLISHED
DIOXIDE
(7446-09-5) 5 MG/M3 TWA
[VME]
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 1 PPM PEAK
(A CEILING
VALUE 1 ML/M3
OR 2.7 MG/M3
MUST NOT BE
EXCEEDED)
2.7 MG/M3 PEAK
(A CEILING
VALUE 1 ML/M3
OR 2.7 MG/M3
MUST NOT BE
EXCEEDED)
MAKS NOT ESTABLISHED NOT ESTABLISHED 1 PPM TWA MAK
2.7 MG/M3 TWA
MAK
HYDROGEN STELS NOT ESTABLISHED 10 PPM STEL NOT ESTABLISHED
SULFIDE [VLCT]
(7783-06-4)
14 MG/M3 STEL
[VLCT]
TWAS NOT ESTABLISHED 5 PPM TWA [VME] NOT ESTABLISHED
7 MG/M3 TWA
[VME]
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 10 PPM PEAK
14.2 MG/M3 PEAK
MAKS NOT ESTABLISHED NOT ESTABLISHED 5 PPM TWA MAK
7.1 MG/M3 TWA
MAK
RESULT GERMANY TRGS IRELAND
PENTANE TWAS 1000 PPM TWA AGW (THE RISK 1000 PPM TWA
OF DAMAGE TO THE EMBRYO OR 3000 MG/M3 TWA
FETUS CAN BE EXCLUDED WHEN
AGW AND BGW VALUES ARE
OBSERVED, EXPOSURE FACTOR 2)
3000 MG/M3 TWA AGW
(THE RISK OF DAMAGE TO THE
EMBRYO OR FETUS CAN BE
EXCLUDED WHEN AGW AND BGW
VALUES ARE OBSERVED,
EXPOSURE FACTOR 2)
STELS NOT ESTABLISHED 750 PPM STEL
2250 MG/M3 STEL
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
SULFUR STELS NOT ESTABLISHED 1 PPM STEL
DIOXIDE 2.6 MG/M3 STEL
TWAS 1 PPM TWA AGW (THE RISK OF 0.5 PPM TWA
DAMAGE TO THE EMBRYO OR FETUS 1.3 MG/M3 TWA
CAN BE EXCLUDED WHEN AGW AND
BGW VALUES ARE OBSERVED,
EXPOSURE FACTOR 1)
2.5 MG/M3 TWA AGW (THE RISK
OF DAMAGE TO THE EMBRYO OR
FETUS CAN BE EXCLUDED WHEN
AGW AND BGW VALUES ARE
OBSERVED, EXPOSURE FACTOR 1)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
HYDROGEN STELS NOT ESTABLISHED 10 PPM STEL
SULFIDE 14 MG/M3 STEL
TWAS 5 PPM TWA AGW (THE RISK OF 5 PPM TWA
DAMAGE TO THE EMBRYO OR FETUS 7 MG/M3 TWA
CAN BE EXCLUDED WHEN AGW AND
BGW VALUES ARE OBSERVED,
EXPOSURE FACTOR 2)
7.1 MG/M3 TWA AGW (THE RISK
OF DAMAGE TO THE EMBRYO OR
FETUS CAN BE EXCLUDED WHEN
AGW AND BGW VALUES ARE
OBSERVED, EXPOSURE FACTOR 2)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
RESULT ISRAEL ITALY NIOSH
PENTANE TWAS 600 PPM TWA 667 PPM TWA 120 PPM TWA
(109-66-0) (LISTED UNDER 2000 MG/M3 TWA 350 MG/M3 TWA
PENTANE, ALL
ISOMERS)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 610 PPM CEILING
(15 MIN)
1800 MG/M3
CEILING
(15 MIN)
STELS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
SULFUR STELS 0.25 PPM STEL NOT ESTABLISHED 5 PPM STEL
DIOXIDE 13 MG/M3 STEL
(7446-09-5)
TWAS NOT ESTABLISHED NOT ESTABLISHED 2 PPM TWA
5 MG/M3 TWA
HYDROGEN STELS 5 PPM STEL NOT ESTABLISHED NOT ESTABLISHED
SULFIDE
(7783-06-4) TWAS 1 PPM TWA NOT ESTABLISHED NOT ESTABLISHED
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 10 PPM CEILING
(10 MIN)
15 MG/M3
CEILING
(10 MIN)
RESULT OSHA OSHA VACATED
PENTANE TWAS 1000 PPM TWA 600 PPM TWA
2950 MG/M3 TWA 1800 MG/M3 TWA
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
STELS NOT ESTABLISHED 750 PPM STEL
2250 MG/M3 STEL
SULFUR STELS NOT ESTABLISHED 5 PPM STEL
DIOXIDE 15 MG/M3 STEL
TWAS 5 PPM TWA 2 PPM TWA
13 MG/M3 TWA 5 MG/M3 TWA
HYDROGEN STELS NOT ESTABLISHED 15 PPM STEL
SULFIDE 21 MG/M3 STEL
TWAS NOT ESTABLISHED 10 PPM TWA
14 MG/M3 TWA
CEILINGS 20 PPM CEILING NOT ESTABLISHED
RESULT PORTUGAL SPAIN SWEDEN
PENTANE TWAS 600 PPM TWA 1000 PPM TWA 600 PPM LLV
(109-66-0) [VLE-MP] [VLA-E[D] VALUE) 1800 MG/M3 LLV
3000 MG/M3 TWA
[VLA-ED]
(INDICATIVE LIMIT
VALUE)
STELS NOT ESTABLISHED NOT ESTABLISHED 750 PPM STV
2000 MG/M3 STV
SULFUR STELS 5 PPM STEL 2 PPM STEL NOT ESTABLISHED
DIOXIDE [VLE-CD] [VLA-EC]
(7446-09-5)
5.28 MG/M3 STEL
[VLA-EC]
TWAS 2 PPM TWA 1 PPM TWA 2 PPM LLV
[VLE-MP] [VLA-ED] 5 MG/M3 LLV
(IT IS PROHIBITED
THE PARTIAL OR
COMPLETE
COMMERCIALIZATION
OR USE OF THIS
SUBSTANCE AS A
PHYTOSANITARY OR
BIOCIDE COMPOUND)
2.64 MG/M3 TWA
[VLA-ED] (IT IS
PROHIBITED THE
PARTIAL OR
COMPLETE
COMMERCIALIZATION
OR USE OF THIS
SUBSTANCE AS A
PHYTOSANITARY OR
BIOCIDE COMPOUND)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 5 PPM CLV
13 MG/M3 CLV
HYDROGEN STELS 15 PPM STEL 10 PPM STEL NOT ESTABLISHED
SULFIDE [VLE-CD] [VLA-EC]
(7783-06-4)
14 MG/M3 STEL
[VLA-EC]
TWAS 10 PPM TWA 5 PPM TWA 10 PPM LLV
[VLE-MP] [VLA-ED] 14 MG/M3 LLV
7 MG/M3 TWA
[VLA-ED]
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 15 PPM CLV
20 MG/M3 CLV
EXPOSURE CONTROL NOTATIONS:
PORTUGAL:
SULFUR DIOXIDE (7446-09-5):
CARCINOGENS: (A4 - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN)
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (SIMPLE ASPHYXIANT)
IRELAND:
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (ASPHYXIANT)
SPAIN:
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (SIMPLE ASPHYXIANT)
GERMANY DFG:
SULFUR DIOXIDE (7446-09-5):
PREGNANCY: (NO RISK TO EMBRYO/FETUS IF EXPOSURE LIMITS ADHERED TO)
HYDROGEN SULFIDE (7783-06-4):
PREGNANCY: (NO RISK TO EMBRYO/FETUS IF EXPOSURE LIMITS ADHERED TO)
PENTANE (109-66-0):
PREGNANCY: (NO RISK TO EMBRYO/FETUS IF EXPOSURE LIMITS ADHERED TO)
EXPOSURE LIMITS SUPPLEMENTAL:
SPAIN:
SULFUR DIOXIDE (7446-09-5):
UNDER REVIEW:
(0.5 PPM VLA-ED; 1 PPM VLA-EC; IT IS PROHIBITED THE PARTIAL OR COMPLETE
COMMERCIALIZATION OR USE OF THIS SUBSTANCE AS A PHYTOSANITARY O BIOCIDE
COMPOUND)
8.2 EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS
BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN
ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN
STANDARD EN 149. USE A NIOSH/MSHA OR EUROPEAN STANDARD EN 149 APPROVED
RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS ARE EXPERIENCED.
EYE/FACE: WEAR SAFETY GLASSES.
SKIN/BODY: WEAR LEATHER GLOVES WHEN HANDLING CYLINDERS.
ENVIRONMENTAL EXPOSURE CONTROLS:
FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF WASTE. CONTROLS
SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT, INCLUDING
PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO WATERWAYS.
KEY TO ABBREVIATIONS:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
LLV: LIMIT LEVEL VALUE IS THE EXPOSURE LIMIT FOR 8-HOUR WORK DAY
MAK:
MAXIMALE ARBEITSPLATZ KONZENTRATION IS THE MAXIMUM PERMISSIBLE
CONCENTRATION
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
STEL: SHORT TERM EXPOSURE LIMITS ARE BASED ON 15-MINUTE EXPOSURES
STEV: SHORT TERM EXPOSURE VALUE
TWAEV: TIME-WEIGHTED AVERAGE EXPOSURE VALUE
TWA: TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: GAS
APPEARANCE/DESCRIPTION: COLORLESS GAS WITH ROTTEN EGG ODOR.
COLOR: COLORLESS
ODOR: ROTTEN-EGG
ODOR THRESHOLD: 013 PPM (HYDROGEN SULFIDE)
GENERAL PROPERTIES:
BOILING POINT: -195.8 C (-320.44 F) (NITROGEN)
MELTING POINT: -210 C (-346 F) (NITROGEN)
DECOMPOSITION TEMPERATURE: DATA LACKING
PH: NOT RELEVANT
SPECIFIC GRAVITY/RELATIVE DENSITY: 0.906 WATER=1 (NITROGEN)
DENSITY: 0.072 LB(S)/FT3 @ 0 C(32 F) (NITROGEN)
WATER SOLUBILITY: DATA LACKING
VISCOSITY: DATA LACKING
EXPLOSIVE PROPERTIES: DATA LACKING
OXIDIZING PROPERTIES: DATA LACKING
VOLATILITY:
VAPOR PRESSURE: DATA LACKING
VAPOR DENSITY: DATA LACKING
EVAPORATION RATE: DATA LACKING
FLAMMABILITY:
FLASH POINT: NOT RELEVANT
UEL: NOT RELEVANT
LEL: NOT RELEVANT
AUTOIGNITION: DATA LACKING
FLAMMABILITY (SOLID, GAS): NONFLAMMABLE GAS.
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: DATA LACKING
9.2 OTHER INFORMATION:
NO ADDITIONAL PHYSICAL AND CHEMICAL PARAMETERS NOTED.
| SECTION 10 - STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.2 CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4 CONDITIONS TO AVOID: EXCESS HEAT.
10.5 INCOMPATIBLE MATERIALS:
TITANIUM WILL BURN IN NITROGEN (THE MAIN COMPONENT OF THIS GAS MIXTURE).
LITHIUM REACTS SLOWLY WITH NITROGEN AT AMBIENT TEMPERATURES. DUE TO THE
PRESENCE OF PENTANE AND HYDROGEN SULFIDE, THIS GAS MIXTURE MAY BE
INCOMPATIBLE WITH STRONG OXIDIZERS. HYDROGEN SULFIDE IS CORROSIVE TO MOST
METALS DUE TO REACTION WITH METALS TO FORM METAL SULFIDES. PENTANE IS
INCOMPATIBLE WITH HALOGENS.
THE TRACE SULFUR DIOXIDE COMPONENT IS INCOMPATIBLE WITH THE FOLLOWING
MATERIALS:
CHLORATES, FLUORINE, INTERHALOGENS, SODIUM HYDRIDE, SODIUM, BASES, SILVER
AZIDE, BARIUM PEROXIDE, DIETHYL ZINC, NITRYL CHLORIDE, POWDERED METALS,
POTASSIUM, ACROLEIN, LITHIUM NITRATE AND PROPENE, MONOLITHIUM
ACETYLIDE-AMMONIA (LITHIUM ACETYLENE CARBIDE DIAMMINO), CESIUM AZIDE, METAL
OXIDES, METAL ACETYLIDES, AND CARBIDE. ALTHOUGH THE SULFUR DIOXIDE
COMPONENT IS IN LOW CONCENTRATION AND SIGNIFICANT REACTION IS NOT EXPECTED,
CAUTION SHOULD BE USED IF CONTACT WITH THIS GAS MIXTURE AND THESE MATERIALS
CAN OCCUR.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
COMBUSTION: SULFUR OXIDES, CARBON OXIDES.
HYDROLYSIS: SULFUROUS ACID.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
COMPONENTS:
SULFUR DIOXIDE 7446-09-05 ACUTE TOXICITY:
INHALATION-RAT LC50: 2520 PPM 1 HOUR(S)
IRRITATION:
EYE-RABBIT:
6 PPM 32 DAY(S)
MILD IRRITATION
MUTAGEN:
CYTOGENETIC ANALYSIS:
INHALATION-MOUSE:
14 (MICRO)G/L 4 HOUR(S) 7 DAY(S)
MICRONUCLEUS TEST:
INHALATION-MOUSE:
28 (MICRO)G/L 5 DAY(S)-INTERMITTENT
DNA ADDUCT:
INHALATION-RAT:
72 MG/KG 300 DAY(S)-INTERMITTENT
REPRODUCTIVE:
INHALATION-MOUSE TCLO:
25 PPM 7 HOUR(S)(6-15D PREG)
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES:
MUSCULOSKELETAL SYSTEM
INHALATION-RABBIT TCLO:
70 PPM 7 HOUR(S)(6-18D PREG)
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES:
MUSCULOSKELETAL SYSTEM
HYDROGEN SULFIDE 7783-06-4 ACUTE TOXICITY:
(0.001% TO 0.025%) INHALATION-RAT LC50: 700 MG/M3 4 HOUR(S)
IRRITATION:
EYE-HUMAN: 0.000125 PPM 5 HOUR(S)
REPRODUCTIVE:
INHALATION-RAT TCLO:
10 MG/M3 (48D PRE/1-22D PREG)
REPRODUCTIVE EFFECTS:
EFFECTS ON FERTILITY.
PRE-IMPLANTATION MORTALITY
REPRODUCTIVE EFFECTS:
EFFECTS ON FERTILITY:
POST-IMPLANTATION MORTALITY
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES:
UROGENITAL SYSTEM
PENTANE 109-66-0 ACUTE TOXICITY:
(0% TO 0.75%) INGESTION/ORAL-RAT LD50: >2000 MG/KG
INHALATION-RAT LC50: 364 G/M3 4 HOUR(S)
OXYGEN 7782-44-7 REPRODUCTIVE:
(0% TO 23.5%) INHALATION-RAT TCLO:
10 PPH 9 HOUR(S)(22D PREG)
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES:
RESPIRATORY SYSTEM
REPRODUCTIVE EFFECTS:
EFFECTS ON NEWBORN: PHYSICAL
GHS PROPERTIES CLASSIFICATION
ACUTE TOXICITY EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
ASPIRATION HAZARD EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
CARCINOGENICITY EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
GERM CELL MUTAGENICITY EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SKIN CORROSION/IRRITATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SKIN SENSITIZATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
STOT-RE EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
STOT-SE EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
TOXICITY FOR REPRODUCTION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
RESPIRATORY SENSITIZATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
SERIOUS EYE DAMAGE/IRRITATION EU/CLP: DATA LACKING
OSHA HCS 2012: DATA LACKING
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE):
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES. IF THIS MATERIAL IS
RELEASED IN A SMALL, POORLY VENTILATED AREA (I.E. AN ENCLOSED OR CONFINED
SPACE), AN OXYGEN-DEFICIENT ENVIRONMENT MAY OCCUR. INDIVIDUALS BREATHING
SUCH AN ATMOSPHERE MAY EXPERIENCE SYMPTOMS WHICH INCLUDE HEADACHES, RINGING
IN EARS, DIZZINESS, DROWSINESS, UNCONSCIOUSNESS, NAUSEA, VOMITING, AND
DEPRESSION OF ALL THE SENSES. UNDER SOME CIRCUMSTANCES OF OVER-EXPOSURE,
DEATH MAY OCCUR. THE FOLLOWING EFFECTS ASSOCIATED WITH DECREASED LEVELS OF
OXYGEN: INCREASE IN BREATHING AND PULSE RATE, EMOTIONAL UPSET, ABNORMAL
FATIGUE, NAUSEA, VOMITING, COLLAPSE, LOSS OF CONSCIOUSNESS, CONVULSIVE
MOVEMENTS, RESPIRATORY COLLAPSE AND DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE
SKIN:
ACUTE (IMMEDIATE):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
CHRONIC (DELAYED):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
EYE:
ACUTE (IMMEDIATE):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
CHRONIC (DELAYED):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
INGESTION:
ACUTE (IMMEDIATE):
INGESTION IS NOT ANTICIPATED TO BE A LIKELY ROUTE OF EXPOSURE TO THIS
PRODUCT.
CHRONIC (DELAYED):
INGESTION IS NOT ANTICIPATED TO BE A LIKELY ROUTE OF EXPOSURE TO THIS
PRODUCT.
KEY TO ABBREVIATIONS:
LC = LETHAL CONCENTRATION
LD = LETHAL DOSE
TC = TOXIC CONCENTRATION
| SECTION 12 - ECOLOGICAL INFORMATION | |
12.1 TOXICITY: MATERIAL DATA LACKING.
12.2 PERSISTENCE AND DEGRADABILITY: MATERIAL DATA LACKING.
12.3 BIOACCUMULATIVE POTENTIAL: MATERIAL DATA LACKING.
12.4 MOBILITY IN SOIL: MATERIAL DATA LACKING.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT AND VPVB ASSESSMENT HAS NOT BEEN CONDUCTED FOR THIS MATERIAL.
12.6 OTHER ADVERSE EFFECTS: NO STUDIES HAVE BEEN FOUND.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
14.1 UN 14.2 UN PROPER 14.3 14.4 14.5
NUMBER SHIPPING NAME TRANSPORT PACKING ENVIRONMENTAL
HAZARDS GROUP HAZARD
CLASS(ES)
DOT UN1956 COMPRESSED GASES, 2.2 NDA NDA
N.O.S. (NITROGEN,
OXYGEN)
TDG UN1956 COMPRESSED GASES, 2.2 NDA NDA
N.O.S. (NITROGEN,
OXYGEN)
IMO/IMDG UN1956 COMPRESSED GASES, 2.2 NDA NDA
N.O.S. (NITROGEN,
OXYGEN)
IATA/ICAO UN1956 COMPRESSED GASES, 2.2 NDA NDA
N.O.S. (NITROGEN,
OXYGEN)
14.6 SPECIAL PRECAUTIONS FOR USER:
CYLINDERS SHOULD BE TRANSPORTED IN A SECURE POSITION, IN A WELL-VENTILATED
VEHICLE. THE TRANSPORTATION OF COMPRESSED GAS CYLINDERS IN AUTOMOBILES OR
IN CLOSED-BODY VEHICLES CAN PRESENT SERIOUS SAFETY HAZARDS. IF TRANSPORTING
THESE CYLINDERS IN VEHICLES, ENSURE THESE CYLINDERS ARE NOT EXPOSED TO
EXTREMELY HIGH TEMPERATURES (AS MAY OCCUR IN AN ENCLOSED VEHICLE ON A HOT
DAY). ADDITIONALLY, THE VEHICLE SHOULD BE WELL-VENTILATED DURING
TRANSPORTATION.
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: DATA LACKING.
| SECTION 15 - REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: PRESSURE(SUDDEN RELEASE OF), ACUTE
STATE RIGHT TO KNOW:
COMPONENT CAS MA NJ PA
HYDROGEN SULFIDE 7783-06-4 YES YES YES
NITROGEN 7727-37-9 YES YES YES
OXYGEN 7782-44-7 YES YES YES
PENTANE 109-66-0 YES YES YES
SULFUR DIOXIDE 7446-09-5 YES YES YES
INVENTORY:
COMPONENT CAS CANADA DSL CANADA NDSL CHINA EU EINECS EU ELNICS
HYDROGEN 7783-06-4 YES NO YES YES NO
SULFIDE
NITROGEN 7727-37-9 YES NO YES YES NO
OXYGEN 7782-44-7 YES NO YES YES NO
PENTANE 109-66-0 YES NO YES YES NO
SULFUR 7446-09-5 YES NO YES YES NO
DIOXIDE
COMPONENT CAS TSCA
HYDROGEN SULFIDE 7783-06-4 YES
NITROGEN 7727-37-9 YES
OXYGEN 7782-44-7 YES
PENTANE 109-66-0 YES
SULFUR DIOXIDE 7446-09-5 YES
CANADA:
LABOR:
CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES:
HYDROGEN SULFIDE 7783-06-4 A, B1, D1 A, D2B
PENTANE 109-66-0 B2
OXYGEN 7782-44-7 A, C
SULFUR DIOXIDE 7446-09-5 A, D1A, D2B, E
NITROGEN 7727-37-9 A
CANADA - WHMIS - INGREDIENT DISCLOSURE LIST:
HYDROGEN SULFIDE 7783-06-4 1%
PENTANE 109-66-0 1%
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 1%
NITROGEN 7727-37-9 NOT LISTED
ENVIRONMENT:
CANADA - CEPA - PRIORITY SUBSTANCES LIST:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA:
ENVIRONMENT:
CHINA - OZONE DEPLETING SUBSTANCES - FIRST SCHEDULE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - OZONE DEPLETING SUBSTANCES - SECOND SCHEDULE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - OZONE DEPLETING SUBSTANCES - THIRD SCHEDULE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
CHINA - ANNEX I & II - CONTROLLED CHEMICALS LISTS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - DANGEROUS GOODS LIST:
HYDROGEN SULFIDE 7783-06-4
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 (COMPRESSED OR
REFRIGERATED
LIQUID)
SULFUR DIOXIDE 7446-09-5
NITROGEN 7727-37-9 (COMPRESSED OR
REFRIGERATED
LIQUID)
CHINA - EXPORT CONTROL LIST - PART I CHEMICALS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
EUROPE:
OTHER:
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - CLASSIFICATION:
HYDROGEN SULFIDE 7783-06-4 F+; R12 T+;
R26 N; R50
PENTANE 109-66-0 F+; R12 N; R51-53
XN; R65 R66 R67
OXYGEN 7782-44-7 O; R8
SULFUR DIOXIDE 7446-09-5 T; R23 C; R34
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - CONCENTRATION LIMITS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 20% <=C: T;
R: 23
5% <=C<20%: XN;
R: 20
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - LABELING:
HYDROGEN SULFIDE 7783-06-4 F+ T+ N R:
12-26-50
S:
(1/2)-9-16-
36-38-45-61
PENTANE 109-66-0 F+ XN N
R:
12-51/53-65-66-67
S:
(2)-9-16-29-
33-61-62
OXYGEN 7782-44-7 O R: 8
S: (2)-17
SULFUR DIOXIDE 7446-09-5 T R: 23-34
S:
(1/2)-9-26-
36/37/39-45
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - NOTES - SUBSTANCES AND
PREPARATIONS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 C
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 5
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - SAFETY PHRASES:
HYDROGEN SULFIDE 7783-06-4 S:
(1/2)-9-16-36-
38-45-61
PENTANE 109-66-0 S:
(2)-9-16-29-
33-61-62
OXYGEN 7782-44-7 S: (2)-17
SULFUR DIOXIDE 7446-09-5 S:
(1/2)-9-26-
36/37/39-45
NITROGEN 7727-37-9 NOT LISTED
GERMANY:
ENVIRONMENT:
GERMANY - TA LUFT - TYPES AND CLASSES:
HYDROGEN SULFIDE 7783-06-4 INORGANIC GAS
SUBSTANCE:
5.2.4, CLASS II
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 INORGANIC GAS
SUBSTANCE:
5.2.4, CLASS IV
NITROGEN 7727-37-9 NOT LISTED
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 1:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 ID NUMBER 743,
NOT CONSIDERED
HAZARDOUS TO
WATER
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 ID NUMBER 1351,
NOT CONSIDERED
HAZARDOUS TO
WATER
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 2 - WATER HAZARD CLASSES:
HYDROGEN SULFIDE 7783-06-4 ID NUMBER 283,
HAZARD CLASS 2 -
HAZARD TO WATERS
PENTANE 109-66-0 ID NUMBER 452,
HAZARD CLASS 2 -
HAZARD TO WATERS
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 ID NUMBER 416,
HAZARD CLASS 1 -
LOW HAZARD TO
WATERS
(FOOTNOTE 8)
NITROGEN 7727-37-9 NOT LISTED
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 3:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
GERMANY - SPECIFICALLY REGULATED CHEMICALS IN TRGS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
PORTUGAL:
OTHER:
PORTUGAL - PROHIBITED SUBSTANCES:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED KINGDOM:
ENVIRONMENT:
UNITED KINGDOM - POLLUTION INVENTORY - SCHEDULE 1 - THRESHOLDS FOR RELEASES
TO AIR:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
UNITED KINGDOM - WORKPLACE EXPOSURE LIMITS (WELS) - SUBSTANCES IN REVIEW:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED KINGDOM - LIST OF DANGEROUS SUBSTANCES IN WATER:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
HYDROGEN SULFIDE 7783-06-4 1500 LB TQ
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 1000 LB TQ
(LIQUID)
NITROGEN 7727-37-9 NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
HYDROGEN SULFIDE 7783-06-4 100 LB FINAL RQ
45.4 KG FINAL RQ
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - RADIONUCLIDES AND THEIR REPORTABLE QUANTITIES:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
HYDROGEN SULFIDE 7783-06-4 100 LB EPCRA RQ
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 500 LB EPCRA RQ
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
HYDROGEN SULFIDE 7783-06-4 500 LB TPQ
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 500 LB TPQ
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING:
HYDROGEN SULFIDE 7783-06-4 1.0 % DE MINIMIS
CONCENTRATION
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - RCRA (RESOURCE CONSERVATION & RECOVERY ACT) - HAZARDOUS
CONSTITUENTS - APPENDIX VIII TO 40 CFR 261:
HYDROGEN SULFIDE 7783-06-4 WASTE NUMBER U135
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - RCRA (RESOURCE CONSERVATION & RECOVERY ACT) - U SERIES WASTES -
ACUTELY TOXIC WASTES & OTHER HAZARDOUS CHARACTERISTICS:
HYDROGEN SULFIDE 7783-06-4 WASTE NUMBER U135
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES - CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 DEVELOPMENTAL
TOXICITY, INITIAL
DATE 7/29/11
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES - PENNSYLVANIA:
LABOR:
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST:
HYDROGEN SULFIDE 7783-06-4
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5
NITROGEN 7727-37-9 NOT LISTED
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - SPECIAL HAZARDOUS SUBSTANCES:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
SULFUR DIOXIDE 7446-09-5 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
15.2 CHEMICAL SAFETY ASSESSMENT:
NO CHEMICAL SAFETY ASSESSMENT HAS BEEN CARRIED OUT.
15.3 OTHER INFORMATION:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
RELEVANT PHRASES (CODE & FULL TEXT):
H220: EXTREMELY FLAMMABLE GAS
H224: EXTREMELY FLAMMABLE LIQUID AND VAPOUR
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDIZER
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H330: FATAL IF INHALED
H331: TOXIC IF INHALED
H400: VERY TOXIC TO AQUATIC LIFE
R8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
R12: EXTREMELY FLAMMABLE.
R23: TOXIC BY INHALATION.
R26: VERY TOXIC BY INHALATION.
R34: CAUSES BURNS.
R50: VERY TOXIC TO AQUATIC ORGANISMS.
R51: TOXIC TO AQUATIC ORGANISMS.
R53: MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
R65:
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
R66: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
R67: VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
LAST REVISION DATE: 17/OCTOBER/2014
PREPARATION DATE: 17/OCTOBER/2014
DISCLAIMER/STATEMENT OF LIABILITY:
TO THE BEST OF AIR LIQUIDE'S KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS
RELIABLE AND ACCURATE AS OF THIS DATE; HOWEVER, ACCURACY, SUITABILITY OR
COMPLETENESS ARE NOT GUARANTEED AND NO WARRANTIES OF ANY TYPE, EITHER
EXPRESS OR IMPLIED, ARE PROVIDED. THE INFORMATION CONTAINED HEREIN RELATES
ONLY TO THIS SPECIFIC PRODUCT. IF THIS GAS MIXTURE IS COMBINED WITH OTHER
MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED. DATA MAY BE CHANGED
FROM TIME TO TIME. BE SURE TO CONSULT THE LATEST EDITION.
KEY TO ABBREVIATIONS:
NDA = NO DATA AVAILABLE
REVISION DATE: 17/OCTOBER/2014
FORMAT: EU CLP/REACH
LANGUAGE: ENGLISH (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012