| Common Name: | AEROSOL COP-GRAF ANTI-SEIZE COMPOUND |
| Manufacturer: | ANTI-SEIZE TECHNOLOGY |
| SDS Revision Date: | 11/1/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 34D498 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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A
ANTI-SEIZE TECHNOLOGY
A.S.T. INDUSTRIES, INC.
AEROSOL COP-GRAF(TM) ANTI-SEIZE COMPOUND
SAFETY DATA SHEET
| SECTION 1: IDENTIFICATION |  |
MANUFACTURER/SUPPLIER:
ANTI-SEIZE TECHNOLOGY
2345 N. 17TH AVE.
FRANKLIN PARK, IL 60131
PHONE: 847-455-2300
TOLL FREE: 800 991-1106
WEB: ANTISEIZE.COM
INFORMATION PHONE NUMBER:
EMERGENCY PHONE NUMBER:
INFOTRAC 24/7 PHONE:
1-800-535-5053 ( US & CANADA) OR 352-323-3500 ( INTERNATIONAL)
PRODUCT USE: ANTI-SEIZE COMPOUND
RESTRICTION ON USE: USE ONLY AS DIRECTED
SDS DATE OF PREPARATION: NOVEMBER 2017
| SECTION 2: HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION (HAZCOM 2012):
FLAMMABLE AEROSOL: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
ASPIRATION HAZARD: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CATEGORY 3 (NARCOTIC EFFECTS)
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD PHRASES:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY PHRASES:
PREVENTION:
WASH THOROUGHLY AFTER HANDLING.
WEAR PROTECTIVE GLOVES, EYE AND FACE PROTECTION.
AVOID BREATHING MIST OR SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES OR HOT SURFACES. NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR. DO NOT INDUCE VOMITING.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
STORAGE:
STORE IN A WELL-VENTILATED PLACE.
STORE LOCKED UP.
STORE AT TEMPERATURES NOT EXCEEDING 120 DEG. F
DISPOSAL:
DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL, REGIONAL AND NATIONAL
REGULATIONS.
OTHER HAZARDS: NONE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS# %
ACETONE 67-64-1 20-30
HEPTANE 142-82-5 15-25
DISTILLATES (PETROLEUM), SOLVENT- 64742-65-0 8-12
DEWAXED HEAVY PARAFFINIC
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 8-12
HEAVY NAPHTHENIC
PROPANE 74-98-6 5-15
BUTANE 106-97-8 5-15
COPPER 7440-50-8 5-8
GRAPHITE 7782-42-5 3-7
THE SPECIFIC IDENTITY AND/OR EXACT PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
EYE:
IMMEDIATELY FLUSH EYES WITH WATER, HOLDING THE EYELIDS APART. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
SKIN:
IN CASE OF CONTACT, WASH THOROUGHLY WITH PLENTY OF WATER. GET MEDICAL
ATTENTION IF IRRITATION PERSISTS.
INHALATION:
REMOVE TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IF IRRITATION
OCCURS, GET MEDICAL ATTENTION.
INGESTION:
ASPIRATION HAZARD. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
CAUSES EYE AND SKIN IRRITATION. PRODUCT IS AN ASPIRATION HAZARD. MAY ENTER
THE LUNGS DURING SWALLOWING OR VOMITING AND CAUSE LUNG DAMAGE. INHALATION
MAY CAUSE IRRITATION, HEADACHE, DIZZINESS AND DROWSINESS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IMMEDIATE MEDICAL ATTENTION REQUIRED FOR INGESTION.
| SECTION 5: FIRE-FIGHTING MEASURES | |
SUITABLE AND UNSUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY OR FOG, FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
SPECIAL HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE AEROSOL. KEEP AWAY FROM HEAT AND OPEN FLAMES. CONTAINER
MAY RUPTURE OR EXPLODE IN THE HEAT OF A FIRE. PROLONGED EXPOSURE TO
TEMPERATURES ABOVE 120 DEG. F MAY CAUSE CANS TO BURST. COMBUSTION MAY
PRODUCE CARBON DIOXIDE, CARBON MONOXIDE.
SPECIAL EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
WEAR NIOSH APPROVED POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS
AND FULL PROTECTIVE CLOTHING. COOL FIRE EXPOSED CONTAINERS WITH WATER.
PROTECT AGAINST BURSTING CANS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. ELIMINATE ALL SOURCES
OF IGNITION WITH EXPLOSION-PROOF EQUIPMENT. VENTILATE AREA.
ENVIRONMENTAL HAZARDS:
REPORT SPILLS AND RELEASES AS REQUIRED TO APPROPRIATE AUTHORITIES.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
PLACE LEAKING CONTAINER INTO A SUITABLE CONTAINER AND PLACE IN A
WELL-VENTILATED AREA UNTIL THE PROPELLANT HAS DISSIPATED. COLLECT LIQUID
SPILL WITH AN INERT ABSORBENT MATERIAL AND PLACE INTO A SUITABLE CONTAINER
FOR DISPOSAL.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES. AVOID BREATHING VAPORS AND MISTS. USE WITH
ADEQUATE VENTILATION. KEEP AWAY FROM HEAT SOURCES. CONTENTS UNDER PRESSURE.
DO NOT PUNCTURE OR INCINERATE CONTAINER. DO NOT SMOKE WHILE USING.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A COOL, WELL-VENTILATED AREA AT TEMPERATURES BELOW 120 DEG. F. DO
NOT STORE IN DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME EXPOSURE LIMITS
ACETONE 500 PPM TWA ACGIH TLV
750 PPM STEL ACGIH TLV
1000 PPM TWA OSHA PEL
HEPTANE 400 PPM TWA ACGIH TLV
500 PPM STEL ACGIH TLV
500 PPM TWA OSHA PEL
DISTILLATES (PETROLEUM), SOLVENT- 5 MG/M3 TWA ACGIH TLV (INHALATION)
DEWAXED HEAVY PARAFFINIC
DISTILLATES (PETROLEUM), NONE ESTABLISHED
HYDROTREATED HEAVY NAPHTHENIC
PROPANE 1000 PPM TWA OSHA PEL
BUTANE 1000 PPM STEL ACGIH TLV
COPPER, DUST OR FUME 1 MG/M3 TWA ACGIH TLV
1 MG/M3 TWA OSHA PEL
GRAPHITE 2 MG/M3 TWA ACGIH TLV RESPIRABLE
15 MG/M3 TWA OSHA PEL TOTAL DUST
5 MG/M3 TWA OSHA PEL RESPIRABLE
FRACTION
APPROPRIATE ENGINEERING CONTROLS:
USE WITH ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE
LEVELS BELOW THE EXPOSURE LIMITS.
INDIVIDUAL PROTECTION MEASURES:
RESPIRATORY PROTECTION:
IN OPERATIONS WHERE THE OCCUPATIONAL EXPOSURE LIMITS ARE EXCEEDED, A NIOSH
APPROVED RESPIRATOR WITH ORGANIC VAPOR/PARTICULATE CARTRIDGES OR SUPPLIED
AIR RESPIRATOR APPROPRIATE FOR THE FORM AND CONCENTRATION OF THE
CONTAMINANTS SHOULD BE USED. SELECTION AND USE OF RESPIRATORY EQUIPMENT
MUST BE IN ACCORDANCE WITH OSHA 1910.134 AND GOOD INDUSTRIAL HYGIENE
PRACTICE.
SKIN PROTECTION:
IMPERVIOUS GLOVES SUCH AS NITRILE RECOMMENDED WHERE NEEDED TO AVOID
PROLONGED SKIN CONTACT.
EYE PROTECTION:
SAFETY GOGGLES RECOMMENDED WHERE NEEDED TO AVOID EYE CONTACT.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: AEROSOL
VAPOR DENSITY (AIR = 1): >1
ODOR: MILD ODOR
SPECIFIC GRAVITY: 0.7
ODOR THRESHOLD: NOT ESTABLISHED
WATER SOLUBILITY: NOT SOLUBLE
PH: NOT AVAILABLE
OCTANOL/WATER PARTITION COEFFICIENT: NOT AVAILABLE
MELTING POINT/FREEZING POINT: NOT AVAILABLE
AUTOIGNITION TEMPERATURE: NOT AVAILABLE
BOILING POINT: -44 TO 208 DEG. F
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
FLASH POINT: -141 DEG. F (PROPELLANT)
VISCOSITY: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
EXPLOSION PROPERTIES: NONE
FLAMMABLE LIMITS:
LEL: NOT ESTABLISHED
UEL: NOT ESTABLISHED
OXIDIZING PROPERTIES: NOT OXIDIZING
VAPOR PRESSURE: NOT ESTABLISHED
AEROSOL FIRE PROTECTION LEVEL: LEVEL 2 AEROSOL (NFPA 30B)
VOC CONTENT: 39.81%
FLAMMABILITY (SOLID, GAS): PROPELLANT IS A FLAMMABLE GAS
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS OF USE.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE AND HANDLING CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, SPARKS, FLAMES AND OTHER SOURCES OF IGNITION. DROPPING
CONTAINERS MAY CAUSE BURSTING.
INCOMPATIBLE MATERIALS:
AVOID STRONG OXIDIZING AGENTS AND ACIDS. CONCENTRATED OXYGEN.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION MAY PRODUCE CARBON DIOXIDE, CARBON MONOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
POTENTIAL HEALTH EFFECTS:
EYE: CAUSES SERIOUS EYE IRRITATION.
SKIN: CONTACT MAY CAUSE IRRITATION AND DRYING OF THE SKIN.
INHALATION:
MIST OR VAPOR CAN IRRITATE THE THROAT AND LUNGS. HIGH CONCENTRATIONS MAY
CAUSE NASAL AND RESPIRATORY IRRITATION AND CENTRAL NERVOUS SYSTEM EFFECTS
SUCH AS HEADACHE, DIZZINESS AND NAUSEA. INTENTIONAL ABUSE MAY BE HARMFUL
OR FATAL.
INGESTION:
IF SWALLOWED, THIS MATERIAL MAY CAUSE IRRITATION OF THE MOUTH, THROAT AND
ESOPHAGUS. SWALLOWING MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA,
VOMITING, DIARRHEA, DIZZINESS, DROWSINESS AND OTHER CENTRAL NERVOUS SYSTEM
EFFECTS. THIS PRODUCT IS AN ASPIRATION HAZARD. IF SWALLOWED, CAN ENTER THE
LUNGS AND MAY CAUSE CHEMICAL PNEUMONITIS, SEVERE LUNG DAMAGE AND DEATH.
CHRONIC HAZARDS: NONE KNOWN.
CARCINOGEN STATUS:
NONE OF THE COMPONENTS OF THIS PRODUCT ARE LISTED AS CARCINOGENS BY IARC,
NTP OR OSHA.
ACUTE TOXICITY VALUES:
ACETONE:
ORAL RAT LD50: 5800 MG/KG
DERMAL RABBIT LD50: >7426 MG/KG AVAILABLE.
HEPTANE:
ORAL RAT LD50: >5000 MG/KG
INHALATION RAT LC50: >=29.29 MG/L
DERMAL RABBIT LD50: >2000 MG/KG
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC:
ORAL RAT LD50: >5000 MG/KG
INHALATION RAT LC50: 2.18 MG/L
DERMAL RABBIT LD50: >2000 MG/KG
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC:
ORAL RAT LD50: >5000 MG/KG
INHALATION RAT LC50: 1.8 MG/L
DERMAL RABBIT LD50: >2000 MG/KG
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ACETONE:
ACUTE:
ULVA PERTUSA:
EC50: 20.565 MG/L/96H
GAMMARUS PULEX: 6000 MG/L/48HR
DAPHNIA MAGNA: 10 MG/L/48HR
PIMEPHALES PROMELAS JUVENILE: 100 MG/L/96HR
CHRONIC:
ULVA PERTUSA:
NOEC: 4.95 MG/L/96HR
DAPHNIIDAE:
NOEC: 0.016 ML/L/21DAYS
DAPHNIA MAGNA:
NOEC: 0.1 ML/L/21DAYS
PERSISTENCE AND DEGRADABILITY:
ACETONE AND HEPTANE ARE READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
ACETONE IS NOT BIOACCUMULATIVE. HEPTANE MAY BIOACCUMULATE BASED ON A LOG
KOW OF 4.66
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NONE KNOWN
| SECTION 13: DISPOSAL CONSIDERATIONS | |
DISPOSE IN ACCORDANCE WITH ALL LOCAL, REGIONAL AND NATIONAL REGULATIONS. DO
NOT PUNCTURE OR INCINERATE CONTAINERS. WHEN CONTENTS ARE DEPLETED, CONTINUE
TO DEPRESS BUTTON UNTIL ALL GAS IS EXPELLED.
| SECTION 14: TRANSPORT INFORMATION | |
DOT PROPER SHIPPING NAME: UN1950, AEROSOLS, 2.1, LIMITED QUANTITY
DOT TECHNICAL NAME: NONE
DOT HAZARD CLASS: 2.1
UN NUMBER: UN1950
DOT LABELS REQUIRED (49CFR172.101): LTD QTY
IMDG SHIPPING DESCRIPTION:
UN1950, AEROSOLS, 2.1, FP -17 C, LIMITED QUANTITY, MARINE POLLUTANT
ID NUMBER: UN1950
HAZARD CLASS: 2.1
PACKING GROUP: NONE
LABELS REQUIRED: NONE
MARKING REQUIRED: LIMITED QUANTITY MARK
PLACARDS REQUIRED:
LIMITED QUANTITY AND MARINE POLLUTANT MARK ON TRANSPORT CONTAINERS
ICAO/IATA
PROPER SHIPPING NAME: AEROSOL, FLAMMABLE
HAZARD CLASS: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
| SECTION 15: REGULATORY INFORMATION | |
SAFETY, HEALTH, AND ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT IN
QUESTION.
CERCLA HAZARDOUS SUBSTANCES (SECTION 103)/RQ: THIS PRODUCT HAS AN RQ OF
16,666 LBS BASED ON THE RQ FOR ACETONE OF 5000 LBS. IN ADDITION, OIL SPILLS
ARE REPORTABLE TO THE NATIONAL RESPONSE CENTER UNDER THE CLEAN WATER ACT
AND MANY STATES HAVE MORE STRINGENT RELEASE REPORTING REQUIREMENTS. REPORT
SPILLS REQUIRED UNDER FEDERAL, STATE AND LOCAL REGULATIONS.
SARA HAZARD CATEGORY (311/312): FIRE HAZARD, PRESSURE HAZARD, ACUTE HEALTH
SARA 313:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS REGULATED UNDER SARA TITLE
III, SECTION 313: NONE
EPA TSCA INVENTORY:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT KNOWN TO CONTAIN LISTED CHEMICALS.
| SECTION 16: OTHER INFORMATION | |
REVISION SUMMARY: NEW FORMAT TO COMPLY WITH OSHA HAZCOM 2012
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN. FINAL DETERMINATION OF SUITABILITY OF ANY
MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS
ARE DESCRIBED HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.