| Common Name: | OXYGEN (</=21.5%), METHANE (</=2.5%), NITROGEN (BALANCE) |
| Manufacturer: | AIR LIQUIDE |
| SDS Revision Date: | 9/9/2013 |
| SDS Format: | GHS-US |
| Item Number(s): | 34WK16 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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OXYGEN (= 21.5%), METHANE (= 2.5%), NITROGEN (BALANCE)
MSA
THE SAFETY COMPANY
SAFETY DATA SHEET
50013MSA
| SECTION 1 - IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: OXYGEN (</=21.5%), METHANE (</=2.5%), NITROGEN (BALANCE)
SUPPLIER P/N:
96329, 476302, 478192, 479857, 493580, 710776, 815307, 815308, 10028022,
10028028, 10028032
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RECOMMENDED USE: CALIBRATION STANDARD
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
AIR LIQUIDE
2700 POST OAK BLVD.
HOUSTON, TX 77056
UNITED STATES
WWW.US.AIRLIQUIDE.COM
SDS@AIRLIQUIDE.COM
TELEPHONE (TECHNICAL): 713-896-2896
TELEPHONE (TECHNICAL): 800-819-1704
U.S. SUPPLIER:
MINE SAFETY APPLIANCES COMPANY
CRANBERRY TOWNSHIP
PENNSYLVANIA 16066
U.S.A.
WWW.MSANET.COM/PRISM
1-800-MSA-2222
EMERGENCY TELEPHONE NUMBER:
MANUFACTURER: 800-424-9300 - CHEMTREC
MANUFACTURER: +1 703-527-3887 - OUTSIDE UNITED STATES
| SECTION 2 - HAZARD IDENTIFICATION | |
UNITED STATES (US): ACCORDING TO OSHA 29 CFR 1910.1200 HCS
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012:
COMPRESSED GAS - H280
SIMPLE ASPHYXIANT
LABEL ELEMENTS:
OSHA HCS 2012: WARNING
GAS CYLINDER
HAZARD STATEMENTS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED - H280
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENTS:
STORAGE/DISPOSAL: STORE IN A WELL-VENTILATED PLACE. - P403
OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
CANADA: ACCORDING TO WHMIS
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
WHMIS: COMPRESSED GAS - A
LABEL ELEMENTS:
WHMIS: COMPRESSED GAS - A
OTHER HAZARDS:
WHMIS:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
IN CANADA, THE PRODUCT MENTIONED ABOVE IS CONSIDERED HAZARDOUS UNDER THE
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS).
OTHER INFORMATION:
NFPA:
HEALTH 1
FIRE 0
INSTABILITY 0
SPECIAL
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCES: MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE.
MIXTURES:
COMPOSITION:
CHEMICAL NAME IDENTIFIERS % CLASSIFICATIONS ACCORDING
TO REGULATION/DIRECTIVE
OXYGEN CAS: 7782-44-7 <=21.5% OSHA HCS 2012:
OX. GAS 1; PRESS GAS. - COMP.
METHANE CAS: 74-82-8 <=2.5% OSHA HCS 2012:
FLAM. GAS 1; PRESS. GAS - COMP;
SIMP. ASPHYX.
NITROGEN CAS: 7727-37-9 BALANCE OSHA HCS 2012:
PRESS. GAS - COMP. SIMP. ASPHYX.
| SECTION 4 - FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL
RESPIRATION IF VICTIM IS NOT BREATHING. IF SIGNS/SYMPTOMS CONTINUE, GET
MEDICAL ATTENTION.
SKIN:
ALTHOUGH EXPOSURE IS UNLIKELY, IN CASE OF CONTACT IMMEDIATELY FLUSH SKIN
WITH RUNNING WATER. IF SKIN IRRITATION DEVELOPS GET MEDICAL
ADVICE/ATTENTION.
EYE:
FIRST AID IS NOT EXPECTED TO BE NECESSARY IF MATERIAL IS USED UNDER
ORDINARY CONDITIONS AND AS RECOMMENDED. IF IRRITATION DEVELOPS AND
PERSISTS, GET MEDICAL ATTENTION.
INGESTION: INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED.
A POTENTIAL HEALTH HAZARD ASSOCIATED WITH THIS GAS IS ANOXIA.
OTHER INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. RESCUERS SHOULD NOT ATTEMPT TO
RETRIEVE VICTIMS OF EXPOSURE TO GASES WITHOUT ADEQUATE PERSONAL PROTECTIVE
EQUIPMENT. AT A MINIMUM, SELF-CONTAINED BREATHING APPARATUS MUST BE WORN.
VICTIM(S) WHO EXPERIENCE ANY ADVERSE EFFECT AFTER OVER - EXPOSURE TO THIS
GAS MIXTURE MUST BE TAKEN FOR MEDICAL ATTENTION. RESCUERS SHOULD BE TAKEN
FOR MEDICAL ATTENTION IF NECESSARY. TAKE A COPY OF THE LABEL AND THE MSDS
TO PHYSICIAN OR OTHER HEALTH PROFESSIONAL WITH VICTIM(S).
| SECTION 5 - FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO DATA AVAILABLE
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN HEATED.
RUPTURED CYLINDERS MAY ROCKET.
HAZARDOUS COMBUSTION PRODUCTS: NO DATA AVAILABLE
ADVICE FOR FIREFIGHTERS:
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING PROVIDES LIMITED PROTECTION
IN FIRE SITUATIONS ONLY; IT IS NOT EFFECTIVE IN SPILL SITUATIONS WHERE
DIRECT CONTACT WITH THE SUBSTANCE IS POSSIBLE.
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK.
FIRE:
IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN A FIRE, ISOLATE FOR
800 METERS (1/2 MILE) IN ALL DIRECTIONS; ALSO, CONSIDER INITIAL EVACUATION
FOR 800 METERS (1/2 MILE) IN ALL DIRECTIONS.
FIRE INVOLVING TANKS:
FIGHT FIRE FROM MAXIMUM DISTANCE OR USE UNMANNED HOSE HOLDERS OR MONITOR
NOZZLES.
FIRE INVOLVING TANKS:
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE
IS OUT.
FIRE INVOLVING TANKS:
DO NOT DIRECT WATER AT SOURCE OF LEAK OR SAFETY DEVICES; ICING MAY OCCUR.
FIRE INVOLVING TANKS:
WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICES
OR DISCOLORATION OF TANK.
FIRE INVOLVING TANKS: ALWAYS STAY AWAY FROM TANKS ENGULFED IN FIRE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
AVOID BREATHING GAS. VENTILATE THE AREA BEFORE ENTRY. IN CASE OF
INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT. DO NOT
TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP UNAUTHORIZED PERSONNEL AWAY. AS AN IMMEDIATE
PRECAUTIONARY MEASURE, ISOLATE SPILL OR LEAK AREA FOR AT LEAST 100 METERS
(330 FEET) IN ALL DIRECTIONS. ELIMINATE ALL IGNITION SOURCES (NO SMOKING,
FLARES, SPARKS OR FLAMES IN IMMEDIATE AREA)
ENVIRONMENTAL PRECAUTIONS: NO SPECIAL ENVIRONMENTAL PRECAUTIONS NECESSARY.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK.
USE WATER SPRAY TO REDUCE VAPORS; DO NOT PUT WATER DIRECTLY ON LEAK,
SPILL AREA OR INSIDE CONTAINER.
IF POSSIBLE, TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN
LIQUID.
ISOLATE AREA UNTIL GAS HAS DISPERSED.
VENTILATE THE AREA.
ALLOW SUBSTANCE TO EVAPORATE.
REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION AND
SECTION 13 - DISPOSAL CONSIDERATIONS.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. VENTILATE CLOSED SPACES BEFORE
ENTERING. BE AWARE OF ANY SIGNS OF DIZZINESS OR FATIGUE, ESPECIALLY IF
WORK IS DONE IN A POORLY VENTILATED AREA; EXPOSURES TO FATAL CONCENTRATIONS
OF THIS GAS MIXTURE COULD OCCUR WITHOUT ANY SIGNIFICANT WARNING SYMPTOMS,
DUE TO OLFACTORY FATIGUE OR OXYGEN DEFICIENCY. CYLINDERS SHOULD BE FIRMLY
SECURED TO PREVENT FALLING OR BEING KNOCKED - OVER. DO NOT ATTEMPT TO
REPAIR, ADJUST, OR IN ANY OTHER WAY MODIFY CYLINDERS. IF THERE IS A
MALFUNCTION OR ANOTHER TYPE OF OPERATIONAL PROBLEM, CONTACT NEAREST
DISTRIBUTOR IMMEDIATELY. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND
CAN BE HAZARDOUS. DO NOT CUT, WELD, PUNCTURE OR INCINERATE CONTAINER.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
STORE IN A COOL, DRY, WELL-VENTILATED PLACE. PROTECT CYLINDERS AGAINST
PHYSICAL DAMAGE. CYLINDERS SHOULD BE FIRMLY SECURED TO PREVENT FALLING OR
BEING KNOCKED - OVER.
SPECIFIC END USE(S): REFER TO SECTION 1.2 - RELEVANT IDENTIFIED USES.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS/GUIDELINES:
RESULT ACGIH CANADA ONTARIO
METHANE TWAS 1000 PPM TWA (LISTED UNDER 1000 PPM TWA
(74-82-8) ALIPHATIC HYDROCARBON GASES:
ALKANE C1-4)
EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN
ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. USE A
NIOSH/MSHA APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS
ARE EXPERIENCED.
EYE/FACE: WEAR SAFETY GLASSES.
SKIN/BODY: WEAR LEATHER GLOVES WHEN HANDLING CYLINDERS.
ENVIRONMENTAL EXPOSURE CONTROLS:
FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF WASTE. CONTROLS
SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT, INCLUDING
PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO WATERWAYS.
KEY TO ABBREVIATIONS:
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
TWA = TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: GAS
APPEARANCE/DESCRIPTION: COLORLESS GAS WITH NO ODOR.
COLOR: COLORLESS
ODOR: ODORLESS
ODOR THRESHOLD: NO DATA AVAILABLE
GENERAL PROPERTIES:
BOILING POINT: -196 C (-320.8 F) NITROGEN
MELTING POINT: -210 C (-346 F) NITROGEN
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
SPECIFIC GRAVITY/RELATIVE DENSITY: 0.967 WATER=1 NITROGEN
WATER SOLUBILITY: MODERATELY SOLUBLE
VISCOSITY: NO DATA AVAILABLE
VOLATILITY:
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: 0.97 AIR=1 NITROGEN
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY:
FLASH POINT: NO DATA AVAILABLE
UEL: NO DATA AVAILABLE
LEL: NO DATA AVAILABLE
AUTOIGNITION: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NONFLAMMABLE GAS.
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: NO DATA AVAILABLE
| SECTION 10 - STABILITY AND REACTIVITY | |
REACTIVITY: NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
CONDITIONS TO AVOID: EXCESS HEAT.
INCOMPATIBLE MATERIALS: NO DATA AVAILABLE
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
COMPONENT NAME CAS DATA
OXYGEN (<=21.5%) 7782-44-7 REPRODUCTIVE:
IHL-RAT TCLO: 10 PPH/9H (22D PREG)
GHS PROPERTIES CLASSIFICATION
ACUTE TOXICITY OSHA HCS 2012: NO DATA AVAILABLE
ASPIRATION HAZARD OSHA HCS 2012: NO DATA AVAILABLE
CARCINOGENICITY OSHA HCS 2012: NO DATA AVAILABLE
GERM CELL MUTAGENICITY OSHA HCS 2012: NO DATA AVAILABLE
SKIN CORROSION/IRRITATION OSHA HCS 2012: NO DATA AVAILABLE
SKIN SENSITIZATION OSHA HCS 2012: NO DATA AVAILABLE
STOT-RE OSHA HCS 2012: NO DATA AVAILABLE
STOT-SE OSHA HCS 2012: NO DATA AVAILABLE
TOXICITY FOR REPRODUCTION OSHA HCS 2012: NO DATA AVAILABLE
RESPIRATORY SENSITIZATION OSHA HCS 2012: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/IRRITATION OSHA HCS 2012: NO DATA AVAILABLE
ROUTE(S) OF ENTRY/EXPOSURE: INHALATION, SKIN, EYE, INGESTION
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE):
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES. IF THIS MATERIAL
IS RELEASED IN A SMALL, POORLY VENTILATED AREA (I.E. AN ENCLOSED OR
CONFINED SPACE), AN OXYGEN - DEFICIENT ENVIRONMENT MAY OCCUR. INDIVIDUALS
BREATHING SUCH AN ATMOSPHERE MAY EXPERIENCE SYMPTOMS WHICH INCLUDE
HEADACHES, RINGING IN EARS, DIZZINESS, DROWSINESS, UNCONSCIOUSNESS,
NAUSEA, VOMITING, AND DEPRESSION OF ALL THE SENSES. UNDER SOME
CIRCUMSTANCES OF OVER-EXPOSURE, DEATH MAY OCCUR. THE FOLLOWING EFFECTS
ASSOCIATED WITH DECREASED LEVELS OF OXYGEN: INCREASE IN BREATHING AND
PULSE RATE, EMOTIONAL UPSET, ABNORMAL FATIGUE, NAUSEA, VOMITING, COLLAPSE,
LOSS OF CONSCIOUSNESS, CONVULSIVE MOVEMENTS, RESPIRATORY COLLAPSE AND
DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE
SKIN:
ACUTE (IMMEDIATE):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
CHRONIC (DELAYED): NO DATA AVAILABLE
EYE:
ACUTE (IMMEDIATE):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
CHRONIC (DELAYED): NO DATA AVAILABLE
INGESTION:
ACUTE (IMMEDIATE):
INGESTION WILL NOT OCCUR DUE TO THE PHYSICAL FORM OF THIS PRODUCT.
CHRONIC (DELAYED): NO DATA AVAILABLE
CARCINOGENIC EFFECTS:
THE COMPONENTS OF THIS MATERIAL ARE NOT FOUND ON THE FOLLOWING LISTS:
NTP AND IARC; THEREFORE, THEY ARE NOT CONSIDERED TO BE, NOR SUSPECTED
TO BE, CANCER -CAUSING AGENTS BY THESE AGENCIES.
KEY TO ABBREVIATIONS:
TC = TOXIC CONCENTRATION
| SECTION 12 - ECOLOGICAL INFORMATION | |
TOXICITY: MATERIAL DATA LACKING.
PERSISTENCE AND DEGRADABILITY: MATERIAL DATA LACKING.
BIOACCUMULATIVE POTENTIAL: MATERIAL DATA LACKING.
MOBILITY IN SOIL: MATERIAL DATA LACKING.
OTHER ADVERSE EFFECTS: NO ADVERSE ECOLOGICAL EFFECTS ARE EXPECTED.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
14.1 UN 14.2 UN PROPER 14.3 14.4 14.5
NUMBER SHIPPING NAME TRANSPORT PACKING ENVIRONMENTAL
HAZARD GROUP HAZARDS
CLASS(ES)
DOT UN1956 COMPRESSED GAS, 2.2 NDA NDA
N.O.S.
(NITROGEN,
OXYGEN)
TDG UN1956 COMPRESSED GAS, 2.2 NDA NDA
N.O.S.
(NITROGEN,
OXYGEN)
IMO/IMDG UN1956 COMPRESSED GAS, 2.2 NDA NDA
N.O.S.
(NITROGEN,
OXYGEN)
IATA/ICAO UN1956 COMPRESSED GAS, 2.2 NDA NDA
N.O.S.
(NITROGEN,
OXYGEN)
SPECIAL PRECAUTIONS FOR USER:
CYLINDERS SHOULD BE TRANSPORTED IN A SECURE POSITION, IN A WELL-VENTILATED
VEHICLE. THE TRANSPORTATION OF COMPRESSED GAS CYLINDERS IN AUTOMOBILES OR
IN CLOSED-BODY VEHICLES CAN PRESENT SERIOUS SAFETY HAZARDS. IF TRANSPORTING
THESE CYLINDERS IN VEHICLES, ENSURE THESE CYLINDERS ARE NOT EXPOSED TO
EXTREMELY HIGH TEMPERATURES (AS MAY OCCUR IN AN ENCLOSED VEHICLE ON A HOT
DAY). ADDITIONALLY, THE VEHICLE SHOULD BE WELL-VENTILATED DURING
TRANSPORTATION.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT RELEVANT.
| SECTION 15 - REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: PRESSURE (SUDDEN RELEASE OF)
STATE RIGHT TO KNOW:
COMPONENT CAS MA NJ PA
METHANE 74-82-8 YES YES YES
NITROGEN 7727-37-9 YES YES YES
OXYGEN 7782-44-7 YES YES YES
INVENTORY:
COMPONENT CAS CANADA DSL CANADA NDSL TSCA
METHANE 74-82-8 YES NO YES
NITROGEN 7727-37-9 YES NO YES
OXYGEN 7782-44-7 YES NO YES
CANADA:
LABOR:
CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES:
OXYGEN 7782-44-7 A, C
NITROGEN 7727-37-9 A
METHANE 74-82-8 A, B1
CANADA - WHMIS - INGREDIENT DISCLOSURE LIST:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
ENVIRONMENT:
CANADA - CEPA - PRIORITY SUBSTANCES LIST:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CERCLA/SARA - RADIONUCLIDES AND THEIR REPORTABLE QUANTITIES:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
UNITED STATES - CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
UNITED STATES - PENNSYLVANIA:
LABOR:
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - SPECIAL HAZARDOUS SUBSTANCES:
OXYGEN 7782-44-7 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
METHANE 74-82-8 NOT LISTED
| SECTION 16 - OTHER INFORMATION | |
LAST REVISION DATE: 09/SEPTEMBER/2013
PREPARATION DATE: 13/NOVEMBER/2012
DISCLAIMER/STATEMENT OF LIABILITY:
TO THE BEST OF AIR LIQUIDE'S KNOWLEDGE, THE INFORMATION CONTAINED HEREIN
IS RELIABLE AND ACCURATE AS OF THIS DATE; HOWEVER, ACCURACY, SUITABILITY
OR COMPLETENESS ARE NOT GUARANTEED AND NO WARRANTIES OF ANY TYPE, EITHER
EXPRESS OR IMPLIED, ARE PROVIDED. THE INFORMATION CONTAINED HEREIN RELATES
ONLY TO THIS SPECIFIC PRODUCT. IF THIS GAS MIXTURE IS COMBINED WITH OTHER
MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED. DATA MAY BE CHANGED
FROM TIME TO TIME. BE SURE TO CONSULT THE LATEST EDITION.
KEY TO ABBREVIATIONS:
NDA = NO DATA AVAILABLE
REVISION DATE: 09/SEPTEMBER/2013
FORMAT: GHS
LANGUAGE: ENGLISH (US)
WHMIS, OSHA HCS 2012