| Common Name: | POLYSTYRENE FOAM INSULATION 78 ET CYLINDER SPRAY ADHESIVE (CLEAR OR GREEN) |
| Manufacturer: | 3M |
| SDS Revision Date: | 2/12/2020 |
| SDS Format: | GHS-US |
| Item Number(s): | 356XD1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) POLYSTYRENE FOAM INSULATION 78 ET CYLINDER SPRAY ADHESIVE
(CLEAR OR GREEN)
02/12/20
3M
SAFETY DATA SHEET
COPYRIGHT, 2020, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 22-1632-3
VERSION NUMBER: 4.02
ISSUE DATE: 02/12/20
SUPERCEDES DATE: 12/16/19
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) POLYSTYRENE FOAM INSULATION 78 ET CYLINDER SPRAY ADHESIVE
(CLEAR OR GREEN)
PRODUCT IDENTIFICATION NUMBERS:
62-4984-8030-0, 62-4984-8150-6, 62-4984-8300-7, 62-4986-8030-5,
62-4986-8150-1, 62-4986-8300-2 7100138815, 7010366510, 7000046605,
7010309902, 7100138682, 7010366511
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: INDUSTRIAL USE
RESTRICTIONS ON USE: ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 2.
SIMPLE ASPHYXIANT.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE LIQUID AND VAPOR.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
SUPPLEMENTAL INFORMATION:
INTENTIONAL CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
DIMETHYL ETHER 115-10-6 40 - 50 TRADE SECRET *
N-HEXANE 110-54-3 30 - 40 TRADE SECRET *
NON-HAZARDOUS COMPONENTS (NJTS REG. TRADE SECRET* 10 - 20 TRADE SECRET *
NO. 04499600-6892)
ACETONE 67-64-1 1 - 5 TRADE SECRET *
METHYLCYCLOPENTANE 96-37-7 1 - 5 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
HYDROCARBONS DURING COMBUSTION
FORMALDEHYDE DURING COMBUSTION
METHANE DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
KETONES DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE. WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED,
POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND
PANTS, BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE
COVERING FOR EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES
OR VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN
APPROPRIATE AQUEOUS FILM FORMING FOAM (AFFF) IS RECOMMENDED. WORKING FROM
AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR
COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT
ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES
NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF
THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL/OCCUPATIONAL USE ONLY. NOT FOR CONSUMER SALE OR USE. DO NOT
HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP
AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY
NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. AVOID
CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) WEAR LOW
STATIC OR PROPERLY GROUNDED SHOES. USE PERSONAL PROTECTIVE EQUIPMENT
(GLOVES, RESPIRATORS, ETC.) AS REQUIRED. TO MINIMIZE THE RISK OF IGNITION,
DETERMINE APPLICABLE ELECTRICAL CLASSIFICATIONS FOR THE PROCESS USING THIS
PRODUCT AND SELECT SPECIFIC LOCAL EXHAUST VENTILATION EQUIPMENT TO AVOID
FLAMMABLE VAPOR ACCUMULATION. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
IF THERE IS POTENTIAL FOR STATIC ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
N-HEXANE 110-54-3 ACGIH TWA: 50 PPM DANGER OF
CUTANEOUS
ABSORPTION
N-HEXANE 110-54-3 OSHA TWA:
1800 MG/M3(500 PPM)
DIMETHYL ETHER 115-10-6 AIHA TWA:
1880 MG/M3(1000 PPM)
ACETONE 67-64-1 ACGIH TWA: 250 PPM A4:
STEL: 500 PPM NOT CLASS. AS
HUMAN CARCIN
ACETONE 67-64-1 OSHA TWA:
2400 MG/M3(1000 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
DO NOT REMAIN IN AREA WHERE AVAILABLE OXYGEN MAY BE REDUCED. USE GENERAL
DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: SAFETY GLASSES WITH SIDE SHIELDS
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
FLUOROELASTOMER
NITRILE RUBBER
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
ORGANIC VAPOR RESPIRATORS MAY HAVE SHORT SERVICE LIFE.
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
PHYSICAL STATE: LIQUID
COLOR: BLUE
ODOR: FRUITY ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: -137 DEG. F [DETAILS: PROPELLANT]
EVAPORATION RATE: 1.9 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: 2.97 [REF STD: AIR=1]
DENSITY: 0.73 - 0.77 G/ML
SPECIFIC GRAVITY: 0.73 - 0.77 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
HAZARDOUS AIR POLLUTANTS: 30 - 40% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
</=624 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: LOW
SOLIDS]
SOLIDS CONTENT: 10 - 20%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
SIMPLE ASPHYXIATION:
SIGNS/SYMPTOMS MAY INCLUDE INCREASED HEART RATE, RAPID RESPIRATIONS,
DROWSINESS, HEADACHE, INCOORDINATION, ALTERED JUDGMENT, NAUSEA, VOMITING,
LETHARGY, SEIZURES, COMA, AND MAY BE FATAL.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PERIPHERAL NEUROPATHY:
SIGNS/SYMPTOMS MAY INCLUDE TINGLING OR NUMBNESS OF THE EXTREMITIES,
INCOORDINATION, WEAKNESS OF THE HANDS AND FEET, TREMORS AND MUSCLE ATROPHY.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED
ATE >5,000 MG/KG
N-HEXANE DERMAL RABBIT LD50: >2,000 MG/KG
N-HEXANE INHALATION- RAT LC50: 170 MG/L
VAPOR (4
HOURS)
N-HEXANE INGESTION RAT LD50: >28,700 MG/KG
DIMETHYL ETHER INHALATION-GAS RAT LC50: 164,000 PPM
(4 HOURS)
METHYLCYCLOPENTANE DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
METHYLCYCLOPENTANE INGESTION RAT LD50: >5,000 MG/KG
NON-HAZARDOUS DERMAL NOT LD50: >2,000 MG/KG
COMPONENTS (NJTS AVAILABLE
REG. NO. 04499600-
6892)
NON-HAZARDOUS INGESTION NOT LD50: >2,000 MG/KG
COMPONENTS (NJTS AVAILABLE
REG. NO. 04499600-
6892)
ACETONE DERMAL RABBIT LD50: >15,688 MG/KG
ACETONE INHALATION- RAT LC50: 76 MG/L
VAPOR (4
HOURS)
ACETONE INGESTION RAT LD50: 5,800 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
N-HEXANE HUMAN AND MILD IRRITANT
ANIMAL
METHYLCYCLOPENTANE SIMILAR MINIMAL IRRITATION
COMPOUNDS
NON-HAZARDOUS COMPONENTS (NJTS PROFESSIONAL NO SIGNIFICANT IRRITATION
REG. NO. 04499600-6892) JUDGMENT
ACETONE MOUSE MINIMAL IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
N-HEXANE RABBIT MILD IRRITANT
METHYLCYCLOPENTANE SIMILAR MILD IRRITANT
COMPOUNDS
NON-HAZARDOUS COMPONENTS PROFESSIONAL NO SIGNIFICANT IRRITATION
(NJTS REG. NO. 04499600-6892) JUDGMENT
ACETONE RABBIT SEVERE IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
N-HEXANE HUMAN NOT CLASSIFIED
NON-HAZARDOUS COMPONENTS (NJTS REG. NO. NOT CLASSIFIED
04499600-6892)
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
N-HEXANE IN VITRO NOT MUTAGENIC
N-HEXANE IN VIVO NOT MUTAGENIC
DIMETHYL ETHER IN VITRO NOT MUTAGENIC
DIMETHYL ETHER IN VIVO NOT MUTAGENIC
ACETONE IN VIVO NOT MUTAGENIC
ACETONE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
N-HEXANE DERMAL MOUSE NOT CARCINOGENIC
N-HEXANE INHALATION MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL ETHER INHALATION RAT NOT CARCINOGENIC
ACETONE NOT MULTIPLE ANIMAL NOT CARCINOGENIC
SPECIFIED SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE DURATION
N-HEXANE INGESTION NOT MOUSE NOAEL: DURING
CLASSIFIED 2,200 ORGANOGENESIS
FOR MG/KG/DAY
DEVELOPMENT
N-HEXANE INHALATION NOT RAT NOAEL: DURING GESTATION
CLASSIFIED 0.7 MG/L
FOR
DEVELOPMENT
N-HEXANE INGESTION TOXIC TO RAT NOAEL: 90 DAYS
MALE 1,140
REPRODUCTION MG/KG/DAY
N-HEXANE INHALATION TOXIC TO RAT LOAEL: 28 DAYS
MALE 3.52 MG/L
REPRODUCTION
DIMETHYL INHALATION NOT RAT NOAEL: DURING
ETHER CLASSIFIED 40,000 PPM ORGANOGENESIS
FOR
DEVELOPMENT
ACETONE INGESTION NOT RAT NOAEL: 13 WEEKS
CLASSIFIED 1,700
FOR MALE MG/KG/DAY
REPRODUCTION
ACETONE INHALATION NOT RAT NOAEL: DURING
CLASSIFIED 5.2 MG/L ORGANOGENESIS
FOR
DEVELOPMENT
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
N-HEXANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
N-HEXANE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION RESPIRATORY NOT CLASSIFIED
SYSTEM
DIMETHYL ETHER INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
DIMETHYL ETHER INHALATION CARDIAC SOME POSITIVE DATA
SENSITIZATION EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYLCYCLOPENTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
METHYLCYCLOPENTANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ACETONE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ACETONE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
ACETONE INHALATION LIVER NOT CLASSIFIED
ACETONE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE
DURATION
N-HEXANE HUMAN NOAEL NOT AVAILABLE NOT AVAILABLE
N-HEXANE RABBIT NOAEL: NOT AVAILABLE 8 HOURS
N-HEXANE RAT NOAEL: 24.6 MG/L 8 HOURS
DIMETHYL ETHER RAT LOAEL: 10,000 PPM 30 MINUTES
DIMETHYL ETHER DOG NOAEL: 100,000 PPM 5 MINUTES
METHYLCYCLOPENTANE SIMILAR COMPOUNDS NOAEL: NOT AVAILABLE
METHYLCYCLOPENTANE PROFESSIONAL NOAEL: NOT AVAILABLE
JUDGMENT
ACETONE HUMAN NOAEL: NOT AVAILABLE
ACETONE HUMAN NOAEL: NOT AVAILABLE
ACETONE HUMAN NOAEL: 1.19 MG/L 6 HOURS
ACETONE GUINEA PIG NOAEL: NOT AVAILABLE
ACETONE HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
N-HEXANE INHALATION PERIPHERAL NERVOUS CAUSES DAMAGE TO ORGANS
SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
N-HEXANE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION LIVER NOT CLASSIFIED
N-HEXANE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
N-HEXANE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
N-HEXANE INHALATION AUDITORY SYSTEM | NOT CLASSIFIED
IMMUNE SYSTEM |
EYES
N-HEXANE INHALATION HEART | SKIN | NOT CLASSIFIED
ENDOCRINE SYSTEM
N-HEXANE INGESTION PERIPHERAL NERVOUS SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INGESTION ENDOCRINE SYSTEM | NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM | LIVER |
IMMUNE SYSTEM |
KIDNEY AND/OR
BLADDER
DIMETHYL ETHER INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
DIMETHYL ETHER INHALATION LIVER NOT CLASSIFIED
ACETONE DERMAL EYES NOT CLASSIFIED
ACETONE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
ACETONE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
ACETONE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
ACETONE INHALATION HEART | LIVER NOT CLASSIFIED
ACETONE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
ACETONE INGESTION HEART NOT CLASSIFIED
ACETONE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
ACETONE INGESTION LIVER NOT CLASSIFIED
ACETONE INGESTION EYES NOT CLASSIFIED
ACETONE INGESTION RESPIRATORY SYSTEM NOT CLASSIFIED
ACETONE INGESTION MUSCLES NOT CLASSIFIED
ACETONE INGESTION SKIN | BONE, NOT CLASSIFIED
TEETH, NAILS,
AND/OR HAIR
NAME SPECIES TEST RESULT EXPOSURE DURATION
N-HEXANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
N-HEXANE MOUSE LOAEL: 1.76 MG/L 13 WEEKS
N-HEXANE RAT NOAEL: NOT AVAILABLE 6 MONTHS
N-HEXANE RAT LOAEL: 1.76 MG/L 6 MONTHS
N-HEXANE MOUSE NOAEL: 35.2 MG/L 13 WEEKS
N-HEXANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
N-HEXANE RAT NOAEL: 1.76 MG/L 6 MONTHS
N-HEXANE RAT NOAEL: 1,140 MG/KG/DAY 90 DAYS
N-HEXANE RAT NOAEL: NOT AVAILABLE 13 WEEKS
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 20,000 PPM 30 WEEKS
ACETONE GUINEA PIG NOAEL: NOT AVAILABLE 3 WEEKS
ACETONE HUMAN NOAEL: 3 MG/L 6 WEEKS
ACETONE HUMAN NOAEL: 1.19 MG/L 6 DAYS
ACETONE GUINEA PIG NOAEL: 119 MG/L NOT AVAILABLE
ACETONE RAT NOAEL: 45 MG/L 8 WEEKS
ACETONE RAT NOAEL: 900 MG/KG/DAY 13 WEEKS
ACETONE RAT NOAEL: 2,500 MG/KG/DAY 13 WEEKS
ACETONE RAT NOAEL: 200 MG/KG/DAY 13 WEEKS
ACETONE MOUSE NOAEL: 3,896 MG/KG/DAY 14 DAYS
ACETONE RAT NOAEL: 3,400 MG/KG/DAY 13 WEEKS
ACETONE RAT NOAEL: 2,500 MG/KG/DAY 13 WEEKS
ACETONE RAT NOAEL: 2,500 MG/KG 13 WEEKS
ACETONE MOUSE NOAEL: 11,298 MG/KG/DAY 13 WEEKS
ASPIRATION HAZARD:
NAME VALUE
N-HEXANE ASPIRATION HAZARD
METHYLCYCLOPENTANE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. AS A
DISPOSAL ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL
FACILITY. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D001 (IGNITABLE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
SIMPLE ASPHYXIANT
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
N-HEXANE 110-54-3 TRADE SECRET 30 - 40
N-HEXANE (HEXANE) 110-54-3 30 - 40
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 1
FLAMMABILITY 4
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 22-1632-3
VERSION NUMBER: 4.02
ISSUE DATE: 02/12/20
SUPERCEDES DATE: 12/16/19
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THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
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INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M.
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