| Common Name: | SP SMOKE MATCH |
| Manufacturer: | SUPERIOR SIGNAL |
| SDS Revision Date: | 4/23/2018 |
| SDS Format: | GHS-EU |
| Item Number(s): | 35LX66 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SP SMOKE MATCH
SAFETY DATA SHEET
REVISION DATE: APRIL 23, 2018
REPLACES ALL PREVIOUS EDITIONS
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE / MIXTURE |  |
AND OF THE COMPANY / UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: SP SMOKE MATCH
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE:
A SMOKE GENERATION MATCH FOR THE MARKING OF AIRFLOWS, AND FOR THEATRICAL
OR SPECIAL EFFECTS - FOR PROFESSIONAL USE ONLY.
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER:
SUPERIOR SIGNAL COMPANY LLC
P.O. BOX 96
SPOTSWOOD, NJ
USA
PHONE: 732-251-0800
FAX: 732-251-9442
EMAIL: INFO@SUPERIORSIGNAL.COM
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER: 732-251-0800
| SECTION 2: HAZARD IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008 ON
CLASSIFICATION, LABELLING AND PACKAGING OF SUBSTANCES AND MIXTURES,
AS AMENDED.
FLAMMABLE SOLIDS: CATEGORY 2
ACUTE TOXICITY - ORAL: CATEGORY 4
ACUTE TOXICITY - DERMAL: CATEGORY 5
ACUTE TOXICITY - INHALATION: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 3
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2B.
HAZARD TO THE AQUATIC ENVIRONMENT-CHRONIC HAZARD: CATEGORY 2
CLASSIFICATION ACCORDIND TO EU DIRECTIVES 67/548/EEC OR 1999/45/EC:
F: FLAMMABLE SOLID
XN: HARMFUL, R20/22
2.2 LABEL ELEMENTS:
LABELLING IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008
ON CLASSIFICATION, LABELLING AND PACKAGING OF SUBSTANCES AND
MIXTURES, AS AMENDED.
HAZARD LABEL FOR SUPPLY/USE REQUIRED:
HAZARDOUS COMPONENTS WHICH MUST BE LISTED ON THE LABEL:
POTASSIUM CHLORATE
EXCLAMATION MARK
FLAME
H228: FLAMMABLE SOLID
H302 & H332: HARMFUL IF SWALLOWED OR IF INHALED
H313: MAY BE HARMFUL IN CONTACT WITH SKIN
H316: CAUSES MILD SKIN IRRITATION
H320: CAUSES EYE IRRITATION
H401: TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING
P305 + P351:
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
2.3 OTHER HAZARDS:
IGNITES READILY, BURNS WITHOUT FLAMING, GIVING DENSE WHITE SMOKE. THE
COMBUSTION OF LARGE QUANTITIES OF THE PRODUCT GIVES RISE TO SIGNIFICANT
QUANTITIES OF SMOKE WITH FLAMES.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
CHEMICAL NATURE: SAFETY MATCH
HAZARDOUS COMPONENTS:
R-PHRASE(S) ACCORDING TO EC DIRECTIVE 67/548/EEC
HAZARD STATEMENTS ACCORDING TO REGULATION (EC) NO. 1907/2006
NAME CAS-NO. / EC DIRECTIVE REGULATION (EC) NO CONCENTRATION
EC-NO. 67/548/EEC 1272/2008 [%]
POTASSIUM 3811-04-9 O; R 9 N; R51/53 >2.50 - <25.00
CHLORATE 223-289-7 XN; R20/22 OX. SOL. 1, H271
ACUTE TOX. 4, H332
ACUTE TOX. 4, H302
AQUATIC CHRONIC 2,
H411
FURTHER INFORMATION:
FOR THE FULL TEXT OF THE R-PHRASES/ HAZARD STATEMENTS MENTIONED IN THIS
SECTION, SEE SECTION 16.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
CONSULT A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE.
INHALATION OF COMBUSTION PRODUCT:
IN SEVERE CASES REMOVE PATIENT FROM EXPOSURE. IF RECOVERY IS NOT RAPID
OR COMPLETE SEEK MEDICAL ATTENTION.
THE FOLLOWING APPLIES TO THE UNBURNED PRODUCT:
INGESTION:
IF SWALLOWED, RINSE MOUTH WITH WATER. SEEK MEDICAL ATTENTION AND SHOW THIS
DATA SHEET IF POSSIBLE.
SKIN CONTACT:
WASH SKIN WITH WATER, FOLLOWED BY SOAP AND WATER. IF IRRITATION ARISES SEEK
MEDICAL ATTENTION.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELLING (SEE SECTION 2.2) AND/OR IN SECTION 11
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NO DATA AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGEROUS GASES ARE EVOLVED IN THE EVENT OF A FIRE.
CONTAINS POTASSIUM CHLORATE WHICH IS CLASSIFIED AS AN OXIDISING AGENT.
5.3 ADVICE FOR FIREFIGHTERS:
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
FURTHER INFORMATION:
REMOVE PRODUCT FROM AREAS OF FIRE, OR OTHERWISE COOL CONTAINERS WITH
WATER IN ORDER TO AVOID PRESSURE BEING BUILT UP DUE TO HEAT.
WHENEVER POSSIBLE, CONTAIN FIRE-FIGHTING WATER BY DIKING AREA WITH SAND
OR EARTH.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK.
AVOID CONTACT WITH SPILLED PRODUCT OR CONTAMINATED SURFACES.
WHEN DEALING WITH A SPILLAGE DO NOT EAT, DRINK OR SMOKE.
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO GET INTO SURFACE WATER, DRAINS AND GROUND WATER.
IF SPILLAGE ENTERS DRAINS LEADING TO SEWAGE WORKS INFORM LOCAL WATER
COMPANY IMMEDIATELY.
IF SPILLAGE ENTERS RIVERS OR WATERCOURSES, NORIFY AUTHORITIES.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
COVER SPILLAGE WITH MOIST SAND OR SOIL. TRANSFER TO A CONTAINER FOR
DISPOSAL. WASH THE SPILLAGE AREA WITH WATER. WASHINGS MUST BE PREVENTED
FROM ENTERING SURFACE WATER DRAINS.
ADDITIONAL ADVICE: CHECK ALSO FOR ANY LOCAL SITE PROCEDURES.
6.4 REFERENCE TO OTHER SECTIONS:
INFORMATION REGARDING SAFE HANDLING, SEE SECTION 7.
INFORMATION REGARDING PERSONAL PROTECTIVE EQUIPMENT, SEE SECTION 8.
INFORMATION REGARDING WASTE DISPOSAL, SEE SECTION 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
NO SPECIFIC PRECAUTIONS REQUIRED WHEN HANDLING UNOPENED PACKS/CONTAINERS;
FOLLOW RELEVANT MANUAL HANDLING ADVICE.
AVOID DUST FORMATION.
ENSURE ADEQUATE VENTILATION.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
DUST MAY FORM EXPLOSIVE MIXTURE IN AIR.
HYGIENE MEASURES:
WHEN USING, DO NOT EAT, DRINK OR SMOKE.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WASH HANDS THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND BEFORE
EATING, DRINKING, CHEWING GUM, USING TOBACCO, USING THE TOILET OR
APPLYING COSMETICS.
WASH HANDS IMMEDIATELY AFTER WORK, IF NECESSARY TAKE A SHOWER.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
STORE IN A PLACE ACCESSIBLE BY AUTHORIZED PERSONS ONLY.
KEEP AWAY FROM DIRECT SUNLIGHT.
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
ADVICE ON COMMON STORAGE:
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
SUITABLE MATERIALS: CARDBOARD MATCH BOXES, OR PLASTIC POTS.
7.3 SPECIFIC END USES: REFER TO THE LABEL AND/OR LEAFLET.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENT CAS-NO. VALUE CONTROL PARAMETERS BASIS
AMMONIUM 12125-02-9 TWA 10 MG/M3 UK. EH40 WEL -
CHLORIDE WORKPLACE
EXPOSURE LIMITS
8.2 EXPOSURE CONTROLS:
EXPOSURE CONTROLS:
OCCUPATIONAL EXPOSURE LIMITS; HAZARDOUS INGREDIENTS; NOT APPLICABLE TO
FIELD USE
SMOKING AGENT MANUFACTURERS STANDARD, 8 HR TWA, 19 MG/M3.
PERSONAL PROTECTION:
SHOULD IT BE NECESSARY TO ENTER A HEAVILY SMOKE LADEN AREA, PROTECTIVE
RESPIRATORY EQUIPMENT AND EYE PROTECTION MUST BE USED (SE HSE GUIDANCE
BOOKLET (HS) G 53 : RESPIRATORY PROTECTIVE EQUIPMENT - A PRACTICAL GUIDE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
COLOUR: BLACK MAIN COMPOSITION, WITH RED IGNITION TIP.
ODOUR: ODOURLESS
MELTING POINT: NOT APPLICABLE.
BOILING POINT: NOT APPLICABLE.
FLASH-POINT: DOES NOT FLASH.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
MINIMUM IGNITION TEMP.: >130 DEG. C
MINIMUM IGNITION: NOT AVAILABLE
OXIDIZING PROPERTIES: OXIDISING AGENT; MAY ASSIST COMBUSTION.
ENERGY EXPLOSIVE PROPERTIES: NOT APPLICABLE
VAPOUR PRESSURE: NOT AVAILABLE.
SOLUBILITY: PARTLY SOLUBLE IN/WITH WATER.
PH-VALUE (QUANT.): NOT AVAILABLE.
PARTITION COEFF. (N-OCTANOL/WATER): NOT APPLICABLE
DENSITY: NOT AVAILABLE.
9.2 OTHER INFORMATION:
FURTHER SAFETY RELATED PHYSICAL-CHEMICAL DATA ARE NOT KNOWN
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: STABLE UNDER NORMAL CONDITIONS.
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
NO HAZARDOUS REACTIONS WHEN STORED AND HANDLED ACCORDING TO PRESCRIBED
INSTRUCTIONS.
10.4 CONDITIONS TO AVOID:
EXTREMES OF TEMPERATURE AND DIRECT SUNLIGHT.
HEAT, FLAMES AND SPARKS.
10.5 INCOMPATIBLE MATERIALS: STORE ONLY IN THE ORIGINAL CONTAINER.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
NO DECOMPOSITION PRODUCTS EXPECTED UNDER NORMAL CONDITIONS OF USE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD50 ORAL - RAT: 730 MG/KG
REMARKS:
BEHAVIOURAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX).
BEHAVIOURAL: MUSCLE CONTRACTION OR SPASTICITY.
BEHAVIOURAL: IRRITABILITY.
SKIN CORROSION/IRRITATION:
SKIN - RABBIT
RESULT: MILD SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION: MODERATE EYE IRRITATION
RESPIRATORY OR SKIN SENSITISATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
INHALATION - MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: NOT AVAILABLE
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY: UN-BURNED COMPOSITION IS NON-SELECTIVELY TOXIC TO PLANTS
12.2 PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE
12.3 BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED
12.6 OTHER ADVERSE EFFECTS: HARMFUL TO AQUATIC ORGANISMS
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
IN ACCORDANCE WITH CURRENT REGULATIONS MAY BE TAKEN TO WASTE DISPOSAL SITE
OR INCINERATION PLANT, AFTER CONSULTATION WITH SITE OPERATOR AND/OR WITH
THE RESPONSIBLE AUTHORITY.
CAN BE LAND FILLED OR INCINERATED, WHEN IN COMPLIANCE WITH LOCAL
REGULATIONS.
ADVICE MAY BE OBTAINED FROM LOCAL WASTE REGULATION AUTHORITY
(PART OF THE ENVIRONMENT AGENCY IN THE UK)
CONTAMINATED PACKAGING:
PACKAGING THAT CANNOT BE CLEANED SHOULD BE DISPOSED OF AS PRODUCT WASTE.
EMPTY CONTAINERS CAN BE LAND FILLED AFTER CLEANING, WHEN IN COMPLIANCE
WITH THE ENVIRONMENTAL PROTECTION (DUTY OF CARE) REGULATIONS 1991.
| SECTION 14: TRANSPORT INFORMATION | |
RAIL / ROAD (RID / ADR) CLASS UN PACKAGING KEMMLER INDEX
NUMBER GROUP
4.1 1944 III
PROPER SHIPPING NAME MATCHES, SAFETY (BOOK, CARD, OR STRIKE ON BOX)
SEA (IMDG-CODE) CLASS UN PACKAGING EMS MFAG
NUMBER GROUP
4.1 1944 III
PROPER SHIPPING NAME MATCHES, SAFETY (BOOK, CARD, OR STRIKE ON BOX)
MARINE POLLUTANT NO
AIR (ICAO / IATA) CLASS UN PACKAGING
NUMBER GROUP
4.1 1944 III
PROPER SHIPPING NAME MATCHES, SAFETY (BOOK, CARD, OR STRIKE ON BOX)
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
NOT APPLICABLE
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT IS NOT REQUIRED FOR THIS SUBSTANCE.
| SECTION 16: OTHER INFORMATION | |
FURTHER INFORMATION:
TEXT OF R-PHRASES MENTIONED IN SECTION 3:
R20/22: HARMFUL BY INHALATION AND IF SWALLOWED.
TEXT OF THE HAZARD STATEMENTS MENTIONED IN SECTION 3:
H228: FLAMMABLE SOLID
H302 & H332: HARMFUL IF SWALLOWED OR IF INHALED
H313: MAY BE HARMFUL IN CONTACT WITH SKIN
H316: CAUSES MILD SKIN IRRITATION
H320: CAUSES EYE IRRITATION
H401: TOXIC TO AQUATIC LIFE
THE ABOVE INFORMATION IS INTENDED TO GIVE GENERAL HEALTH AND SAFETY
GUIDANCE ON THE STORAGE AND TRANSPORT OF THE PRODUCT.
THE INFORMATION CONTAINED HEREIN IS BASED ON THE PRESENT STATE OF OUR
KNOWLEDGE AND IS INTENDED TO DESCRIBE OUR PRODUCTS FROM THE POINT OF
VIEW OF SAFETY REQUIREMENTS. IT SHOULD NOT THEREFORE BE CONSTRUED AS
GUARANTEEING SPECIFIC PROPERTIES.