| Common Name: | LIQUID ROC 700+ - COMP. A, LIQUID ROC 700+ - COMP. B |
| Manufacturer: | MKT FASTENING |
| SDS Revision Date: | 5/25/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 35T286 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
MKT(R*)
... A SOLID CONNECTION
MKT FASTENING LLC
SAFETY DATA SHEET
ACCORDING TO 29 CFR 1910.1200(G)
LIQUID ROC 700+ - COMP. A
PRINT DATE: 25.05.2016
PRODUCT CODE: SDB0030US
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: LIQUID ROC 700+ - COMP. A
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE:
ADHESIVE MOTAR FOR FASTENING ELEMENTS A-COMPONENT (RESIN)
USES ADVISED AGAINST: NO RESTRICTION
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME: MKT FASTENING LLC
STREET: 1 GUNNEBO DRIVE
PLACE: USA LONOKE, AR 72086
TELEPHONE: +1(501) 676-2222
TELEFAX: +1(501) 676-2524
INTERNET: WWW.MKTFASTENING.COM
EMERGENCY PHONE NUMBER:
US CHEMTREC: +1 800 424-9300 (24H)
| 2. HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE CHEMICAL:
29 CFR PART 1910.1200:
HAZARD CATEGORIES:
RESPIRATORY OR SKIN SENSITIZATION: SKIN SENS. 1
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE: STOT SE 3
SPECIFIC TARGET ORGAN TOXICITY REPEATED OR PROLONGED EXPOSURE: STOT RE 1
HAZARD STATEMENTS:
MAY CAUSE RESPIRATORY IRRITATION
MAY CAUSE AN ALLERGIC SKIN REACTION
LABEL ELEMENTS:
29 CFR PART 1910.1200:
SIGNAL WORD: WARNING
PICTOGRAMS: EXCLAMATION MARK
HAZARD STATEMENTS:
MAY CAUSE RESPIRATORY IRRITATION
MAY CAUSE AN ALLERGIC SKIN REACTION
PRECAUTIONARY STATEMENTS:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORE LOCKED UP.
DISPOSE OF CONTENTS/CONTAINER TO TO IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATION.
HAZARDS NOT OTHERWISE CLASSIFIED: NO INFORMATION AVAILABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
HAZARDOUS COMPONENTS:
CAS NO COMPONENTS QUANTITY
97-90-5 ETHYLENE DIMETHACRYLATE 10 - <20%
27813-02-1 METHACRYLIC ACID, MONOESTER WITH PROPANE-1,2-DIOL 1 - <10%
14808-60-7 QUARTZ (<10 (MICRO)M) * 1 - <5%
38668-48-3 1,1'-(P-TOLYLIMINO)DIPROPAN-2-OL 0,1 - <1%
FURTHER INFORMATION:
* THIS MIXTURE INCLUDES A FINE FRACTION OF CRYSTALLINE QUARTZ. HOWEVER,
ALVEOLAR PERMEABILITY CAN BE RULED OUT AS THE QUARTZ IS IRREVERSIBLY BOUND
INTO THE PASTE-LIKE COMPONENT AND THEREFORE NOT FREELY AVAILABLE.
SUBSEQUENT DRILLING, GRINDING OR OTHER TREATMENT CAN ALSO NOT RESULT IN
THE FREE AVAILABILITY OF THIS ALVEOLAR PERMEABLE QUARTZ. PURSUANT TO
ARTICLE 6 OF CLP REGULATION 1272/2008/EU CLASSIFICATION AND LABELLING AS
SLOT RE 2 IS NOT REQUIRED.
SVHC LISTE (CANDIDATE LIST OF SUBSTANCES OF VERY HIGH CONCERN FOR
AUTHORIZATION): SUBSTANCES ARE NOT CONTAINED OR ARE BELOW 0,1%.
| 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
AFTER INHALATION:
PROVIDE FRESH AIR. WHEN IN DOUBT OR IF SYMPTOMS ARE OBSERVED, GET MEDICAL
ADVICE.
AFTER CONTACT WITH SKIN:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
MEDICAL TREATMENT NECESSARY.
AFTER CONTACT WITH EYES:
RINSE IMMEDIATELY CAREFULLY AND THOROUGHLY WITH EYE-BATH OR WATER. IN CASE
OF EYE IRRITATION CONSULT AN OPHTHALMOLOGIST.
AFTER INGESTION: RINSE MOUTH IMMEDIATELY AND DRINK PLENTY OF WATER.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ALLERGIC REACTIONS
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
EXTINGUISHING POWDER
WATER SPRAY JET
UNSUITABLE EXTINGUISHING MEDIA: FULL WATER JET
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
PYROLYSIS PRODUCTS, TOXIC
CARBON MONOXIDE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
WEAR A SELF-CONTAINED BREATHING APPARATUS AND CHEMICAL PROTECTIVE CLOTHING.
ADDITIONAL INFORMATION:
SUPPRESS GASES/VAPOURS/MISTS WITH WATER SPRAY JET. COLLECT CONTAMINATED
FIRE EXTINGUISHING WATER SEPARATELY. DO NOT ALLOW ENTERING DRAINS OR
SURFACE WATER.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PROVIDE ADEQUATE VENTILATION. DO NOT BREATHE GAS/FUMES/VAPOR/SPRAY. AVOID
CONTACT WITH SKIN, EYES AND CLOTHES. USE PERSONAL PROTECTION EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER INTO SURFACE WATER OR DRAINS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
TAKE UP MECHANICALLY. TREAT THE RECOVERED MATERIAL AS PRESCRIBED IN THE
SECTION ON WASTE DISPOSAL.
REFERENCE TO OTHER SECTIONS:
SAFE HANDLING: SEE SECTION 7
PERSONAL PROTECTION EQUIPMENT: SEE SECTION 8
DISPOSAL: SEE SECTION 13
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
WASH HANDS BEFORE BREAKS AND AFTER WORK.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
NO SPECIAL FIRE PROTECTION MEASURES ARE NECESSARY.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS FOR STORAGE ROOMS AND VESSELS:
KEEP CONTAINER TIGHTLY CLOSED.
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL-VENTILATED PLACE.
ADVICE ON STORAGE COMPATIBILITY:
DO NOT USE FOR PRODUCTS WHICH COME INTO CONTACT WITH THE FOOD STUFFS.
FURTHER INFORMATION ON STORAGE CONDITIONS:
STORAGE TEMPERATURE: 5-25 DEG. C (41-77 F)
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS:
CAS NO. SUBSTANCE PPM MG/M3 F/CC CATEGORY ORIGIN
14808-60-7 SILICA, CRYSTALLINE 0.05 TWA (8 H) REL
(AS RESPIRABLE DUST)
14808-60-7 SILICA, CRYSTALLINE - 0.025 TWA (8 H) TLV
ALPHA-QUARTZ
(RESPIRABLE FRACTION)
14808-60-7 SILICA, CRYSTALLINE (Z-3) (Z-3) TWA (8 H) PEL
QUARTZ, RESPIRABLE
DUST
EXPOSURE CONTROLS: GLOVES
PROTECTIVE AND HYGIENE MEASURES:
REMOVE CONTAMINATED, SATURATED CLOTHING IMMEDIATELY. DRAW UP AND OBSERVE
SKIN PROTECTION PROGRAM. WASH HANDS AND FACE BEFORE BREAKS AND AFTER WORK
AND TAKE A SHOWER IF NECESSARY. WHEN USING DO NOT EAT OR DRINK.
EYE/FACE PROTECTION: WEAR EYE/FACE PROTECTION.
HAND PROTECTION:
WHEN HANDLING WITH CHEMICAL SUBSTANCES, PROTECTIVE GLOVES MUST BE WORN
WITH THE CE-LABEL INCLUDING THE FOUR CONTROL DIGITS. THE QUALITY OF THE
PROTECTIVE GLOVES RESISTANT TO CHEMICALS MUST BE CHOSEN AS A FUNCTION OF
THE SPECIFIC WORKING PLACE CONCENTRATION AND QUANTITY OF HAZARDOUS
SUBSTANCES. FOR SPECIAL PURPOSES, IT IS RECOMMENDED TO CHECK THE RESISTANCE
TO CHEMICALS OF THE PROTECTIVE GLOVES MENTIONED ABOVE TOGETHER WITH THE
SUPPLIER OF THESE GLOVES.
WEARING TIME WITH OCCASIONAL CONTACT (SPLASHES):
0,4MM NBR (NITRILE RUBBER): >480 MIN (EN 374)
WEARING TIME WITH PERMANENT CONTACT 0,5MM NBR (NITRILE RUBBER):
>480 MIN (EN 374)
SKIN PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: PASTE
COLOR: LIGHT BEIGE
TEST METHOD
PH-VALUE: NOT DETERMINED
CHANGES IN THE PHYSICAL STATE:
MELTING POINT/FREEZING POINT: NOT DETERMINED
INITIAL BOILING POINT AND BOILING RANGE: NOT DETERMINED
FLASH POINT: NOT APPLICABLE
FLAMMABILITY:
SOLID: NOT DETERMINED
GAS: NOT APPLICABLE
LOWER EXPLOSION LIMITS: NOT DETERMINED
UPPER EXPLOSION LIMITS: NOT DETERMINED
AUTO-IGNITION TEMPERATURE:
SOLID: NOT DETERMINED
GAS: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NOT DETERMINED
OXIDIZING PROPERTIES: NOT OXIDIZING.
VAPOR PRESSURE: NOT DETERMINED
DENSITY (AT 20 DEG. C): 1,72 G/CM3
WATER SOLUBILITY: INSOLUBLE
SOLUBILITY IN OTHER SOLVENTS: NOT DETERMINED
PARTITION COEFFICIENT: NOT DETERMINED
VAPOUR DENSITY: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
OTHER INFORMATION:
SOLID CONTENT: NOT DETERMINED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO HAZARDOUS REACTION WHEN HANDLED AND STORED ACCORDING TO PROVISIONS.
CHEMICAL STABILITY:
THE PRODUCT IS STABLE UNDER STORAGE AT NORMAL AMBIENT TEMPERATURES.
POSSIBILITY OF HAZARDOUS REACTIONS: NO KNOWN HAZARDOUS REACTIONS.
CONDITIONS TO AVOID: NONE
INCOMPATIBLE MATERIALS: NO INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO KNOWN HAZARDOUS DECOMPOSITION PRODUCTS.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
CAS NO COMPONENTS
EXPOSURE ROUTE DOSE SPECIES SOURCE
27813-02-1 METHACRYLIC ACID, MONOESTER WITH PROPANE-1,2-DIOL
ORAL LD50: 11200 MG/KG RAT
DERMAL LD50: >5000 MG/KG RABBIT
38668-48-3 1,1'-(P-TOLYLIMINO)DIPROPAN-2-OL
ORAL LD50: 27,5 MG/KG RAT
ADDITIONAL INFORMATION ON TESTS:
THIS MIXTURE IS CLASSIFIED AS HAZARDOUS ACCORDING TO REGULATION (EC)
NO. 1272/2008 [CLP].
FURTHER INFORMATION:
THE TOXICITY DATA LISTED PERTAINING TO THE INGREDIENTS ARE INTENDED FOR
THOSE WORKING IN THE MEDICINAL PROFESSIONS, EXPERTS FOR OCCUPATIONAL HEALTH
AND SAFETY AND TOXICOLOGISTS. THE TOXICITY DATA PERTAINING TO THE
INGREDIENTS WERE SUPPLIED BY THE MANUFACTURERS OF RAW MATERIALS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT: ECOTOXIC.
PERSISTENCE AND DEGRADABILITY: THE PRODUCT HAS NOT BEEN TESTED.
BIOACCUMULATIVE POTENTIAL: THE PRODUCT HAS NOT BEEN TESTED.
MOBILITY IN SOIL: THE PRODUCT HAS NOT BEEN TESTED.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
FURTHER INFORMATION:
DO NOT ALLOW TO ENTER INTO SURFACE WATER OR DRAINS. DO NOT ALLOW TO ENTER
INTO SOIL/SUBSOIL.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
ADVICE ON DISPOSAL:
DO NOT ALLOW TO ENTER INTO SURFACE WATER OR DRAINS. DO NOT ALLOW TO ENTER
INTO SOIL/SUBSOIL. DISPOSE OF WASTE ACCORDING TO APPLICABLE LEGISLATION.
CONTAMINATED PACKAGING:
NON-CONTAMINATED PACKAGES MAY BE RECYCLED. HANDLE CONTAMINATED PACKAGES
IN THE SAME WAY AS THE SUBSTANCE ITSELF.
| 14. TRANSPORT INFORMATION | |
US DOT 49 CFR 172.101:
PROPER SHIPPING NAME:
NOT A HAZARDOUS MATERIAL WITH RESPECT TO THESE TRANSPORT REGULATIONS.
MARINE TRANSPORT (IMDG):
UN NUMBER: NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
UN PROPER SHIPPING NAME:
NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
TRANSPORT HAZARD CLASS(ES):
NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
PACKING GROUP: NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
AIR TRANSPORT (ICAO):
UN NUMBER: NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
UN PROPER SHIPPING NAME:
NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
TRANSPORT HAZARD CLASS(ES):
NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
PACKING GROUP: NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
ENVIRONMENTAL HAZARDS:
ENVIRONMENTALLY HAZARDOUS: NO
SPECIAL PRECAUTIONS FOR USER: NO INFORMATION AVAILABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
U.S. REGULATIONS:
NATIONAL REGULATORY INFORMATION:
SARA SECTION 311/312 HAZARDS:
ETHYLENE DIMETHACRYLATE (97-90-5): IMMEDIATE (ACUTE) HEALTH HAZARD
METHACRYLIC ACID, MONOESTER WITH PROPANE-1,2-DIOL (27813-02-1):
IMMEDIATE (ACUTE) HEALTH HAZARD
QUARTZ (<10 (MICRO)M) * (14808-60-7): DELAYED (CHRONIC) HEALTH HAZARD
1,1'-(P-TOLYLIMINO)DIPROPAN-2-OL (38668-48-3):
IMMEDIATE (ACUTE) HEALTH HAZARD
STATE REGULATIONS:
SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65,
STATE OF CALIFORNIA):
THIS PRODUCT CONTAINS NO CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| 16. OTHER INFORMATION | |
HAZARDOUS MATERIALS INFORMATION LABEL (HMIS):
HEALTH 2
FLAMMABILITY 2
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA HAZARD RATINGS:
HEALTH 2
FLAMMABILITY 2
REACTIVITY 1
UNIQUE HAZARD
CHANGES:
REVISION DATE: 25.05.2016
REVISION NO: 1,02,2
THIS DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN SECTION(S):
6,7,8.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE
LC50: LETHAL CONCENTRATION, 50%
LD50: LETHAL DOSE, 50%
OTHER DATA:
THE ABOVE INFORMATION DESCRIBES EXCLUSIVELY THE SAFETY REQUIREMENTS OF
THE PRODUCT AND IS BASED ON OUR PRESENT-DAY KNOWLEDGE. THE INFORMATION IS
INTENDED TO GIVE YOU ADVICE ABOUT THE SAFE HANDLING OF THE PRODUCT NAMED
IN THIS SAFETY DATA SHEET, FOR STORAGE, PROCESSING, TRANSPORT AND DISPOSAL.
THE INFORMATION CANNOT BE TRANSFERRED TO OTHER PRODUCTS. IN THE CASE OF
MIXING THE PRODUCT WITH OTHER PRODUCTS OR IN THE CASE OF PROCESSING, THE
INFORMATION ON THIS SAFETY DATA SHEET IS NOT NECESSARILY VALID FOR THE NEW
MADE-UP MATERIAL.
(THE DATA FOR THE HAZARDOUS INGREDIENTS WERE TAKEN RESPECTIVELY FROM THE
LAST VERSION OF THE SUB-CONTRACTOR'S SAFETY DATA SHEET.)
REPLACES VERSION: 1,01
USA - EN
MKT(R*)
... A SOLID CONNECTION
MKT FASTENING LLC
SAFETY DATA SHEET
ACCORDING TO 29 CFR 1910.1200(G)
LIQUID ROC 700+ - COMP. B
PRINT DATE: 25.05.2016
PRODUCT CODE: SDB0020US
| 1. IDENTIFICATION | |
PRODUCT IDENTIFIER: LIQUID ROC 700+ - COMP. B
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: COMPOUND MORTAR B-COMPONENT (HARDENER)
USES ADVISED AGAINST: NO RESTRICTION
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME: MKT FASTENING LLC
STREET: 1 GUNNEBO DRIVE
PLACE: USA LONOKE, AR 72086
TELEPHONE: +1(501) 676-2222
TELEFAX: +1(501) 676-2524
INTERNET: WWW.MKTFASTENING.COM
EMERGENCY PHONE NUMBER:
US CHEMTREC: +1 800 424-9300 (24H)
| 2. HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE CHEMICAL:
29 CFR PART 1910.1200:
HAZARD CATEGORIES:
SERIOUS EYE DAMAGE/EYE IRRITATION: EYE IRRIT. 2A
RESPIRATORY OR SKIN SENSITIZATION: SKIN SENS. 1
SPECIFIC TARGET ORGAN TOXICITY REPEATED OR PROLONGED EXPOSURE: STOT RE 1
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE AN ALLERGIC SKIN REACTION
LABEL ELEMENTS:
29 CFR PART 1910.1200:
SIGNAL WORD: WARNING
PICTOGRAMS: EXCLAMATION MARK
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE AN ALLERGIC SKIN REACTION
PRECAUTIONARY STATEMENTS:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
DISPOSE OF CONTENTS/CONTAINER TO TO IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATION.
HAZARDS NOT OTHERWISE CLASSIFIED:
THIS SUBSTANCE MEETS THE PBT CRITERIA OF REACH, ANNEX XIII.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
HAZARDOUS COMPONENTS:
CAS NO COMPONENTS QUANTITY
94-36-0 DIBENZOYL PEROXIDE; BENZOYL PEROXIDE 1-20%
REACTION MASS OF DIETHYLENE GLYCOLE DIBENZOATE, 1-5%
DIPROPYLENE GLYCOLE DIBENZOATE AND TRIETHYLENE
GLYCOL DIBENZOATE
5444-75-7 2-ETHYLHEXYL BENZOATE 1-5%
14808-60-7 QUARTZ (<10 (MICRO)M) * 1-5%
FURTHER INFORMATION:
* THIS MIXTURE INCLUDES A FINE FRACTION OF CRYSTALLINE QUARTZ. HOWEVER,
ALVEOLAR PERMEABILITY CAN BE RULED OUT AS THE QUARTZ IS IRREVERSIBLY
BOUND INTO THE PASTE-LIKE COMPONENT AND THEREFORE NOT FREELY AVAILABLE.
SUBSEQUENT DRILLING, GRINDING OR OTHER TREATMENT CAN ALSO NOT RESULT IN
THE FREE AVAILABILITY OF THIS ALVEOLAR PERMEABLE QUARTZ. PURSUANT TO
ARTICLE 6 OF CLP REGULATION 1272/2008/EU CLASSIFICATION AND LABELLING AS
SLOT RE 2 IS NOT REQUIRED.
SVHC LISTE (CANDIDATE LIST OF SUBSTANCES OF VERY HIGH CONCERN FOR
AUTHORIZATION): SUBSTANCES ARE NOT CONTAINED OR ARE BELOW 0,1%.
| 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION: CHANGE CONTAMINATED, SATURATED CLOTHING.
AFTER INHALATION:
PROVIDE FRESH AIR. WHEN IN DOUBT OR IF SYMPTOMS ARE OBSERVED, GET MEDICAL
ADVICE.
AFTER CONTACT WITH SKIN:
AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER AND SOAP.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
MEDICAL TREATMENT NECESSARY.
AFTER CONTACT WITH EYES:
AFTER CONTACT WITH THE EYES, RINSE WITH WATER WITH THE EYELIDS OPEN FOR A
SUFFICIENT LENGTH OF TIME, THEN CONSULT AN OPHTHALMOLOGIST IMMEDIATELY.
AFTER INGESTION: RINSE MOUTH IMMEDIATELY AND DRINK PLENTY OF WATER.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ALLERGIC REACTIONS
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CO-ORDINATE FIRE-FIGHTING MEASURES TO THE FIRE SURROUNDINGS.
EXTINGUISHING POWDER
WATER SPRAY JET
UNSUITABLE EXTINGUISHING MEDIA: FULL WATER JET
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
PYROLYSIS PRODUCTS, TOXIC
CARBON MONOXIDE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
WEAR A SELF-CONTAINED BREATHING APPARATUS AND CHEMICAL PROTECTIVE CLOTHING.
ADDITIONAL INFORMATION:
COLLECT CONTAMINATED FIRE EXTINGUISHING WATER SEPARATELY. DO NOT ALLOW
ENTERING DRAINS OR SURFACE WATER.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PROVIDE ADEQUATE VENTILATION.
USE PERSONAL PROTECTION EQUIPMENT.
SPECIAL DANGER OF SLIPPING BY LEAKING/SPILLING PRODUCT.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER INTO SURFACE WATER OR DRAINS.
IN CASE OF GAS ESCAPE OR OF ENTRY INTO WATERWAYS, SOIL OR DRAINS, INFORM
THE RESPONSIBLE AUTHORITIES.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
TAKE UP MECHANICALLY.
ABSORB WITH LIQUID-BINDING MATERIAL (E.G. SAND, DIATOMACEOUS EARTH,
ACID- OR UNIVERSAL BINDING AGENTS).
TREAT THE RECOVERED MATERIAL AS PRESCRIBED IN THE SECTION ON WASTE
DISPOSAL.
REFERENCE TO OTHER SECTIONS:
SAFE HANDLING: SEE SECTION 7
PERSONAL PROTECTION EQUIPMENT: SEE SECTION 8
DISPOSAL: SEE SECTION 13
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
USE PROTECTIVE SKIN CREAM BEFORE HANDLING THE PRODUCT.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
NO SPECIAL FIRE PROTECTION MEASURES ARE NECESSARY.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS FOR STORAGE ROOMS AND VESSELS:
KEEP CONTAINER TIGHTLY CLOSED.
KEEP/STORE ONLY IN ORIGINAL CONTAINER.
ADVICE ON STORAGE COMPATIBILITY:
DO NOT USE FOR PRODUCTS WHICH COME INTO CONTACT WITH THE FOOD STUFFS.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
FURTHER INFORMATION ON STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A COOL PLACE.
STORAGE TEMPERATURE 5-25 DEG. C (41-77 F)
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
CAS NO. SUBSTANCE PPM MG/M3 F/CC CATEGORY ORIGIN
94-36-0 BENZOYL PEROXIDE 5 TWA (8 H) PEL
5 TWA (8 H) REL
14808-60-7 SILICA, CRYSTALLINE 0.05 TWA (8 H) REL
(AS RESPIRABLE DUST)
14808-60-7 SILICA, CRYSTALLINE - 0.025 TWA (8 H) TLV
ALPHA-QUARTZ
(RESPIRABLE FRACTION)
14808-60-7 SILICA, CRYSTALLINE (Z-3) (Z-3) TWA (8 H) PEL
QUARTZ, RESPIRABLE
DUST
14808-60-7 SILICA, CRYSTALLINE (Z-3) TWA (8 H) PEL
QUARTZ, TOTAL DUST
EXPOSURE CONTROLS:
GLOVES
CHEMICAL GOGGLES
PROTECTIVE AND HYGIENE MEASURES:
REMOVE CONTAMINATED, SATURATED CLOTHING IMMEDIATELY. DRAW UP AND OBSERVE
SKIN PROTECTION PROGRAM. WASH HANDS AND FACE BEFORE BREAKS AND AFTER WORK
AND TAKE A SHOWER IF NECESSARY. WHEN USING DO NOT EAT OR DRINK.
EYE/FACE PROTECTION:
SUITABLE EYE PROTECTION: WEAR EYE/FACE PROTECTION.
HAND PROTECTION:
WHEN HANDLING WITH CHEMICAL SUBSTANCES, PROTECTIVE GLOVES MUST BE WORN
WITH THE CE-LABEL INCLUDING THE FOUR CONTROL DIGITS. THE QUALITY OF THE
PROTECTIVE GLOVES RESISTANT TO CHEMICALS MUST BE CHOSEN AS A FUNCTION OF
THE SPECIFIC WORKING PLACE CONCENTRATION AND QUANTITY OF HAZARDOUS
SUBSTANCES. FOR SPECIAL PURPOSES, IT IS RECOMMENDED TO CHECK THE RESISTANCE
TO CHEMICALS OF THE PROTECTIVE GLOVES MENTIONED ABOVE TOGETHER WITH THE
SUPPLIER OF THESE GLOVES.
WEARING TIME WITH OCCASIONAL CONTACT (SPLASHES):
0,4MM NBR (NITRILE RUBBER): >480 MIN (EN 374)
WEARING TIME WITH PERMANENT CONTACT 0,5MM NBR (NITRILE RUBBER):
>480 MIN (EN 374)
SKIN PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: PASTE
COLOR: BLACK
ODOR: CHARACTERISTIC
TEST METHOD
PH-VALUE: NOT APPLICABLE
CHANGES IN THE PHYSICAL STATE:
MELTING POINT/FREEZING POINT: NOT DETERMINED
INITIAL BOILING POINT AND BOILING RANGE: NOT DETERMINED
FLASH POINT: NOT APPLICABLE
FLAMMABILITY:
SOLID: NOT DETERMINED
GAS: NOT APPLICABLE
LOWER EXPLOSION LIMITS: NOT DETERMINED
UPPER EXPLOSION LIMITS: NOT DETERMINED
AUTO-IGNITION TEMPERATURE:
SOLID: NOT DETERMINED
GAS: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NOT DETERMINED
OXIDIZING PROPERTIES: NOT OXIDIZING.
AVAILABLE OXYGEN CONTENT (%) <1%: NO CLASSIFICATION
VAPOR PRESSURE: NOT DETERMINED
DENSITY (AT 20 DEG. C): 1,59 G/CM3
WATER SOLUBILITY: INSOLUBLE
SOLUBILITY IN OTHER SOLVENTS: NOT DETERMINED
PARTITION COEFFICIENT: NOT DETERMINED
VAPOUR DENSITY: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
OTHER INFORMATION:
SOLID CONTENT: NOT DETERMINED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: SEE SECTION 10.3
CHEMICAL STABILITY:
THE PRODUCT IS STABLE UNDER STORAGE AT NORMAL AMBIENT TEMPERATURES.
POSSIBILITY OF HAZARDOUS REACTIONS:
VIOLENT REACTION WITH: OXIDISING AGENT
CONDITIONS TO AVOID: SEE SECTION 7.2
INCOMPATIBLE MATERIALS: OXIDIZING AGENT, STRONG
HAZARDOUS DECOMPOSITION PRODUCTS:
NO KNOWN HAZARDOUS DECOMPOSITION PRODUCTS.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
CAS NO COMPONENTS
EXPOSURE ROUTE DOSE SPECIES SOURCE
5444-75-7 2-ETHYLHEXYL BENZOATE
ORAL LD50: >2000 MG/KG RAT
ADDITIONAL INFORMATION ON TESTS:
THIS MIXTURE IS CLASSIFIED AS HAZARDOUS ACCORDING TO REGULATION (EC)
NO. 1272/2008 [CLP].
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT: ECOTOXIC.
PERSISTENCE AND DEGRADABILITY: THE PRODUCT HAS NOT BEEN TESTED.
BIOACCUMULATIVE POTENTIAL: THE PRODUCT HAS NOT BEEN TESTED.
MOBILITY IN SOIL: THE PRODUCT HAS NOT BEEN TESTED.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
FURTHER INFORMATION:
DO NOT ALLOW TO ENTER INTO SURFACE WATER OR DRAINS. DO NOT ALLOW TO ENTER
INTO SOIL/SUBSOIL.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
ADVICE ON DISPOSAL:
DO NOT ALLOW TO ENTER INTO SURFACE WATER OR DRAINS. DO NOT ALLOW TO ENTER
INTO SOIL/SUBSOIL. DISPOSE OF WASTE ACCORDING TO APPLICABLE LEGISLATION.
CONTAMINATED PACKAGING:
NON-CONTAMINATED PACKAGES MAY BE RECYCLED. HANDLE CONTAMINATED PACKAGES
IN THE SAME WAY AS THE SUBSTANCE ITSELF.
| 14. TRANSPORT INFORMATION | |
US DOT 49 CFR 172.101:
PROPER SHIPPING NAME:
NOT A HAZARDOUS MATERIAL WITH RESPECT TO THESE TRANSPORT REGULATIONS.
MARINE TRANSPORT (IMDG):
UN NUMBER: NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
UN PROPER SHIPPING NAME:
NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
TRANSPORT HAZARD CLASS(ES):
NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
PACKING GROUP: NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
AIR TRANSPORT (ICAO):
UN NUMBER: NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
UN PROPER SHIPPING NAME:
NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
TRANSPORT HAZARD CLASS(ES):
NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
PACKING GROUP: NO DANGEROUS GOOD IN SENSE OF THIS TRANSPORT REGULATION.
ENVIRONMENTAL HAZARDS:
ENVIRONMENTALLY HAZARDOUS: NO
SPECIAL PRECAUTIONS FOR USER: NO INFORMATION AVAILABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
U.S. REGULATIONS:
NATIONAL REGULATORY INFORMATION:
SARA SECTION 311/312 HAZARDS:
BENZOYL PEROXIDE (94-36-0): REACTIVE, IMMEDIATE (ACUTE) HEALTH HAZARD
QUARTZ (<10 (MICRO)M) * (14808-60-7): DELAYED (CHRONIC) HEALTH HAZARD
SARA SECTION 313 TOXIC RELEASE INVENTORY:
BENZOYL PEROXIDE (94-36-0):
DE MINIMIS LIMIT: 1.0%, REPORTABLE THRESHOLD = STANDARD
STATE REGULATIONS:
SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65,
STATE OF CALIFORNIA):
THIS PRODUCT CONTAINS NO CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| 16. OTHER INFORMATION | |
HAZARDOUS MATERIALS INFORMATION LABEL (HMIS):
HEALTH 2
FLAMMABILITY 2
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA HAZARD RATINGS:
HEALTH 2
FLAMMABILITY 2
REACTIVITY 1
UNIQUE HAZARD
CHANGES:
REVISION DATE: 25.05.2016
REVISION NO: 1,02,2
THIS DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN SECTION(S):
7,8,10.
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE
LC50: LETHAL CONCENTRATION, 50%
LD50: LETHAL DOSE, 50%
OTHER DATA:
THE ABOVE INFORMATION DESCRIBES EXCLUSIVELY THE SAFETY REQUIREMENTS OF
THE PRODUCT AND IS BASED ON OUR PRESENT-DAY KNOWLEDGE. THE INFORMATION IS
INTENDED TO GIVE YOU ADVICE ABOUT THE SAFE HANDLING OF THE PRODUCT NAMED
IN THIS SAFETY DATA SHEET, FOR STORAGE, PROCESSING, TRANSPORT AND DISPOSAL.
THE INFORMATION CANNOT BE TRANSFERRED TO OTHER PRODUCTS. IN THE CASE OF
MIXING THE PRODUCT WITH OTHER PRODUCTS OR IN THE CASE OF PROCESSING, THE
INFORMATION ON THIS SAFETY DATA SHEET IS NOT NECESSARILY VALID FOR THE NEW
MADE-UP MATERIAL.
(THE DATA FOR THE HAZARDOUS INGREDIENTS WERE TAKEN RESPECTIVELY FROM THE
LAST VERSION OF THE SUB-CONTRACTOR'S SAFETY DATA SHEET.)
REPLACES VERSION: 1,01
USA - EN