| Common Name: | BATHROOM & SHOWER CLEANER CONCENTRATE (PRODUCT NO. 51, CHEMICAL MANAGEMENT SYSTE |
| Manufacturer: | 3M |
| SDS Revision Date: | 5/9/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 35YY77, 52EE50 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (PRODUCT NO. 51, 3M(TM)
CHEMICAL MANAGEMENT SYSTEMS)
05/09/16
3M
SAFETY DATA SHEET
COPYRIGHT, 2016, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 33-2740-0
ISSUE DATE: 05/09/16
VERSION NUMBER: 3.00
SUPERCEDES DATE: 10/07/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (PRODUCT NO. 51, 3M(TM)
CHEMICAL MANAGEMENT SYSTEMS)
PRODUCT IDENTIFICATION NUMBERS:
61-0000-6361-2, 61-0000-6396-8, 61-0000-6425-5, 70-0716-5994-3,
70-0716-8380-2, 70-0716-8381-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
FOR DAILY CLEANING OF SURFACES SUCH AS CERAMIC TILE, STAINLESS STEEL,
FIXTURES, FLOORS AND MORE. WILL NOT DAMAGE FLOOR FINISHES OR SEALERS. LOW
FLOW FOR USE IN FILLING BOTTLES., HARD SURFACE CLEANER
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
CORROSIVE TO METAL: CATEGORY 1.
ACUTE TOXICITY (ORAL): CATEGORY 4.
ACUTE TOXICITY (INHALATION): CATEGORY 4.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1B.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HAZARD STATEMENTS:
MAY BE CORROSIVE TO METALS.
HARMFUL IF SWALLOWED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
HARMFUL IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP ONLY IN ORIGINAL CONTAINER.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
STORAGE:
STORE IN A CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS. MAY CAUSE CHEMICAL RESPIRATORY
TRACT BURNS.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
WATER 7732-18-5 60 - 90 TRADE SECRET *
HYDROCHLORIC ACID 7647-01-0 10 - 30 TRADE SECRET *
ETHOXYLATED C9-11 ALCOHOLS 68439-46-3 0.1 - 1 TRADE SECRET *
BENZENE, ETHENYL-, HOMOPOLYMER 9003-53-6 0.1 - 0.5 TRADE SECRET *
BENZYL-C12-16-ALKYLDIMETHYL 68424-85-1 <0.1 TRADE SECRET *
AMMONIUM CHLORIDES
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
MATERIAL WILL NOT BURN. NON-COMBUSTIBLE. USE A FIRE FIGHTING AGENT SUITABLE
FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CHLORINE DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A METAL CONTAINER APPROVED FOR USE IN TRANSPORTATION BY
APPROPRIATE AUTHORITIES. THE CONTAINER MUST BE LINED WITH POLYETHYLENE
PLASTIC OR CONTAIN A PLASTIC DRUM LINER MADE OF POLYETHYLENE. CLEAN UP
RESIDUE WITH WATER. COVER, BUT DO NOT SEAL FOR 48 HOURS. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. THIS PRODUCT IS NOT INTENDED TO BE
USED WITHOUT PRIOR DILUTION AS SPECIFIED ON THE PRODUCT LABEL. GROUNDING OR
SAFETY SHOES WITH ELECTROSTATIC DISSIPATING SOLES (ESD) ARE NOT REQUIRED
WITH A CHEMICAL DISPENSING SYSTEM. KEEP OUT OF REACH OF CHILDREN. DO NOT
BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE. KEEP AWAY FROM REACTIVE METALS (EG.
ALUMINUM, ZINC ETC.) TO AVOID THE FORMATION OF HYDROGEN GAS THAT COULD
CREATE AN EXPLOSION HAZARD.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. KEEP ONLY
IN ORIGINAL CONTAINER. STORE IN A CORROSIVE RESISTANT CONTAINER WITH A
RESISTANT INNER LINER. STORE AWAY FROM ACIDS. STORE AWAY FROM STRONG BASES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
HYDROCHLORIC 7647-01-0 OSHA CEIL:
ACID 7 MG/M3 (5 PPM)
HYDROCHLORIC 7647-01-0 ACGIH CEIL: 2 PPM A4:
ACID NOT CLASS. AS HUMAN
CARCIN
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SPECIAL
VENTILATION IS NOT REQUIRED. USE GENERAL DILUTION VENTILATION AND/OR LOCAL
EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT
EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF
VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, EYE CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR. IF THE PRODUCT IS NOT USED WITH A
CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN ACCIDENTAL RELEASE, WEAR
PROTECTIVE EYE/FACE PROTECTION. SELECT AND USE EYE/FACE PROTECTION TO
PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SKIN CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
FLUOROELASTOMER
NEOPRENE
NATURAL RUBBER
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
SELECT AND USE BODY PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS OF
AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
APRON - NEOPRENE
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, RESPIRATORY
PROTECTION IS NOT REQUIRED.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR ACID
GASES
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: OPAQUE WHITE PUNGENT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: <1
MELTING POINT: NOT APPLICABLE
BOILING POINT: 210 DEG. F
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY: 1.112 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS: <0.01% WEIGHT
PERCENT VOLATILE: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NOT DETERMINED
10.5. INCOMPATIBLE MATERIALS: STRONG BASES
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
HARMFUL IF INHALED. RESPIRATORY TRACT CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE NASAL DISCHARGE, SEVERE NOSE AND THROAT PAIN,
CHEST TIGHTNESS AND PAIN, COUGHING UP BLOOD, WHEEZING, AND BREATHLESSNESS,
POSSIBLY PROGRESSING TO RESPIRATORY FAILURE.
SKIN CONTACT:
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION: HARMFUL IF SWALLOWED.
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE
CALCULATED ATE: >5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE
DUST/MIST CALCULATED ATE: 1 - 5 MG/L
(4 HR)
OVERALL PRODUCT INGESTION NO DATA AVAILABLE
CALCULATED ATE: 300 - 2,000 MG/KG
HYDROCHLORIC DERMAL RABBIT LD50: >5,010 MG/KG
ACID
HYDROCHLORIC INHALATION- RAT LC50: 1 MG/L
ACID DUST/MIST
(4 HOURS)
HYDROCHLORIC INGESTION RAT LD50: 238 MG/KG
ACID
ETHOXYLATED DERMAL RABBIT LD50: >2,000 MG/KG
C9-11 ALCOHOLS
ETHOXYLATED INGESTION RAT LD50: 1,378 MG/KG
C9-11 ALCOHOLS
BENZENE, DERMAL RABBIT LD50: >2,000 MG/KG
ETHENYL-,
HOMOPOLYMER
BENZENE, INGESTION RAT LD50: >5,000 MG/KG
ETHENYL-,
HOMOPOLYMER
BENZYL-C12-16- DERMAL RABBIT LD50: 645 MG/KG
ALKYLDIMETHYL
AMMONIUM
CHLORIDES
BENZYL-C12-16- INGESTION RAT LD50: 366 MG/KG
ALKYLDIMETHYL
AMMONIUM
CHLORIDES
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
HYDROCHLORIC ACID HUMAN CORROSIVE
ETHOXYLATED C9-11 ALCOHOLS RABBIT IRRITANT
BENZENE, ETHENYL-, HOMOPOLYMER PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
HYDROCHLORIC ACID RABBIT CORROSIVE
ETHOXYLATED C9-11 ALCOHOLS PROFESSIONAL CORROSIVE
JUDGEMENT
SKIN SENSITIZATION:
NAME SPECIES VALUE
HYDROCHLORIC ACID HUMAN NOT SENSITIZING
AND
ANIMAL
ETHOXYLATED C9-11 ALCOHOLS GUINEA NOT SENSITIZING
PIG
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
HYDROCHLORIC ACID IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
ETHOXYLATED C9-11 ALCOHOLS IN VITRO NOT MUTAGENIC
BENZENE, ETHENYL-, HOMOPOLYMER IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
HYDROCHLORIC ACID NOT HUMAN SOME POSITIVE DATA EXIST, BUT
SPECIFIED AND THE DATA ARE NOT SUFFICIENT
ANIMAL FOR CLASSIFICATION
BENZENE, ETHENYL-, NOT RAT SOME POSITIVE DATA EXIST, BUT
HOMOPOLYMER SPECIFIED THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
ETHOXYLATED C9-11 ALCOHOLS DERMAL NOT TOXIC TO FEMALE REPRODUCTION
ETHOXYLATED C9-11 ALCOHOLS DERMAL NOT TOXIC TO DEVELOPMENT
ETHOXYLATED C9-11 ALCOHOLS DERMAL SOME POSITIVE MALE REPRODUCTIVE
DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHOXYLATED C9-11 ALCOHOLS RAT NOAEL: 2 GENERATION
250 MG/KG/DAY
ETHOXYLATED C9-11 ALCOHOLS RAT NOAEL: 2 GENERATION
250 MG/KG/DAY
ETHOXYLATED C9-11 ALCOHOLS RAT NOAEL: 2 GENERATION
100 MG/KG/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
HYDROCHLORIC INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
ACID IRRITATION IRRITATION
ETHOXYLATED C9-11 INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
ALCOHOLS IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROCHLORIC ACID NOAEL:
NOT AVAILABLE
ETHOXYLATED C9-11 NOT NOAEL: NOT AVAILABLE
ALCOHOLS AVAILABLE NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ETHOXYLATED C9-11 DERMAL KIDNEY AND/OR SOME POSITIVE DATA EXIST,
ALCOHOLS BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ETHOXYLATED C9-11 DERMAL HEMATOPOIETIC ALL DATA ARE NEGATIVE
ALCOHOLS SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHOXYLATED C9-11 RAT NOAEL: 13 WEEKS
ALCOHOLS 125 MG/KG/DAY
ETHOXYLATED C9-11 RAT NOAEL: 13 WEEKS
ALCOHOLS 125 MG/KG/DAY
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY.
COMBUSTION PRODUCTS WILL INCLUDE HALOGEN ACID (HCl/HF/HBr). FACILITY MUST
BE CAPABLE OF HANDLING HALOGENATED MATERIALS. EMPTY DRUMS/BARRELS/
CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D002 (CORROSIVE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
HYDROCHLORIC ACID 7647-01-0 TRADE SECRET 10 - 30
15.2. STATE REGULATIONS:
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
JAPAN CHEMICAL SUBSTANCE CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
15.4. INTERNATIONAL REGULATIONS:
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS NONE
CORROSIVE: YES
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN COATINGS
ASSOCIATION (ACA).
DOCUMENT GROUP: 33-2740-0
VERSION NUMBER: 3.00
ISSUE DATE: 05/09/16
SUPERCEDES DATE: 10/07/15
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INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
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PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
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INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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