| Common Name: | NON-FLAMMABLE GAS MIXTURE, 50016 |
| Manufacturer: | AIR LIQUIDE |
| SDS Revision Date: | 1/21/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 36J501 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NON-FLAMMABLE GAS MIXTURE CONTAINING ONE OR MORE OF THE FOLLOWING
COMPONENTS IN A NITROGEN BALANCE GAS: OXYGEN, 0.0015-23.5%; PROPANE,
0-1.1%; CARBON MONOXIDE, 0.0005-1.0%; HYDROGEN SULFIDE, 0.001-0.025%
INDUSTRIAL SCIENTIFIC
1 LIFE WAY
PITTSBURGH, PA 15205-7500
PHONE: (412) 788-4353
TOLL-FREE: 800-DETECTS
FAX: (412) 788-8353
SAFETY DATA SHEET
(REPLACES ISC MSDS NO. 1810-6179, 1810-7219, 1810-9094, 1810-9177,
1810-9188, 1810-9197)
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
PRODUCT NAME:
NON-FLAMMABLE GAS MIXTURE CONTAINING ONE OR MORE OF THE FOLLOWING
COMPONENTS IN A NITROGEN BALANCE GAS: OXYGEN, 0.0015-23.5%; PROPANE,
0-1.1%; CARBON MONOXIDE, 0.0005-1.0%; HYDROGEN SULFIDE, 0.001-0.025%
DOCUMENT NO.: 50016
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES
ADVISED AGAINST:
RELEVANT IDENTIFIED USE(S):
CALIBRATION OF MONITORING AND RESEARCH EQUIPMENT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
AIR LIQUIDE
2700 POST OAK BLVD.
HOUSTON, TX 77056
UNITED STATES
WWW.US.AIRLIQUIDE.COM
SDS@AIRLIQUIDE.COM
TELEPHONE (TECHNICAL): 713-896-2896
TELEPHONE (TECHNICAL): 800-819-1704
1.4 EMERGENCY TELEPHONE NUMBER:
MANUFACTURER: 800-424-9300 - CHEMTREC
MANUFACTURER: +1 703-527-3887 - OUTSIDE UNITED STATES
| SECTION 2: HAZARDS IDENTIFICATION | |
EU/EEC:
ACCORDING TO REGULATION (EC) NO 1272/2008 (CLP)/REACH 1907/2006
[AMENDED BY 453/2010]
ACCORDING TO EU DIRECTIVE 67/548/EEC (DSD) OR 1999/45/EC (DPD)
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLP:
COMPRESSED GAS: H280
REPRODUCTIVE TOXICITY 1A: H360
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 2: H373
DSD/DPD:
HARMFUL (Xn)
SUBSTANCES TOXIC TO REPRODUCTION - CATEGORY 1
R20, R48/20, R61
2.2 LABEL ELEMENTS:
CLP: DANGER
GAS CYLINDER
HEALTH HAZARD
HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P260: DO NOT BREATHE GAS.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
RESPONSE:
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE/DISPOSAL:
P403: STORE IN A WELL-VENTILATED PLACE.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
DSD/DPD:
HARMFUL OR IRRITANT
TOXIC OR VERY TOXIC
RISK PHRASES:
R20: HARMFUL BY INHALATION.
R48/20:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
R61: MAY CAUSE HARM TO THE UNBORN CHILD.
SAFETY PHRASES:
S53: AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
2.3 OTHER HAZARDS:
CLP:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
ACCORDING TO REGULATION (EC) NO. 1272/2008 (CLP) THIS MATERIAL IS
CONSIDERED HAZARDOUS.
DSD/DPD:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
ACCORDING TO EUROPEAN DIRECTIVE 1999/45/EC THIS PREPARATION IS CONSIDERED
DANGEROUS.
UNITED STATES (US): ACCORDING TO OSHA 29 CFR 1910.1200 HCS
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012:
COMPRESSED GAS: H280
REPRODUCTIVE TOXICITY 1A: H360
SIMPLE ASPHYXIANT
2.2 LABEL ELEMENTS:
OSHA HCS 2012:
DANGER
GAS CYLINDER
HEALTH HAZARD
HAZARD STATEMENTS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED: H280
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.: H360
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.: P201
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.:
P202
DO NOT BREATHE GAS.: P260
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.:
P280
RESPONSE:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION.:
P308+P313
STORAGE/DISPOSAL:
STORE IN A WELL-VENTILATED PLACE.: P403
STORE LOCKED UP.: P405
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.:
P501
2.3 OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
CANADA:
ACCORDING TO WHMIS
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
WHMIS:
COMPRESSED GAS: A
VERY TOXIC: D1A
OTHER TOXIC EFFECTS: D2A
2.2 LABEL ELEMENTS:
WHMIS:
A - COMPRESSED GAS
D1 - MATERIALS CAUSING IMMEDIATE AND SERIOUS TOXIC EFFECTS
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
COMPRESSED GAS: A
VERY TOXIC: D1A
OTHER TOXIC EFFECTS: D2A
2.3 OTHER HAZARDS:
WHMIS:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
IN CANADA, THE PRODUCT MENTIONED ABOVE IS CONSIDERED HAZARDOUS UNDER THE
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS).
2.4 OTHER INFORMATION:
NFPA:
HEALTH 1
FIRE 0
INSTABILITY 0
SPECIAL
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE IN ACCORDANCE WITH
REGULATION (EC) NO 1272/2008.
3.2 MIXTURES:
COMPOSITION:
CHEMICAL IDENTIFIERS % LD50/LC50
NAME
OXYGEN CAS: 7782-44-7 0.0015% TO 23.5% NDA
EC NUMBER: 231-956-9
PROPANE CAS: 74-98-6 0% TO 1.1% NDA
EC NUMBER: 200-827-9
HYDROGEN CAS: 7783-06-4 0.001% TO 0.025% INHALATION-RAT
SULFIDE EC NUMBER: 231-977-3 LC50 - 444 PPM
CARBON CAS: 630-08-0 0.005% TO 1% INHALATION-RAT
MONOXIDE EC NUMBER: 211-128-3 LC50 - 1807 PPM
4 HOUR(S)
NITROGEN CAS: 7727-37-9 74.245% TO 99.997% NDA
EINECS: 231-783-9
CHEMICAL CLASSIFICATIONS ACCORDING TO REGULATION/DIRECTIVE
NAME
OXYGEN EU DSD/DPD: ANNEX I - O; R8
EU CLP: ANNEX VI - OX. GAS 1, H270; PRESS. GAS, H280
OSHA HCS 2012: OX. GAS 1; PRESS GAS. - COMP.
PROPANE EU DSD/DPD: ANNEX I - F+; R12
EU CLP: ANNEX VI - FLAM. GAS 1, H220; PRESS. GAS, H280
OSHA HCS 2012: FLAM. GAS 1; PRESS. GAS - COMP.; SIMP. ASPHYX.
HYDROGEN EU DSD/DPD: ANNEX I - F+; R12; T+; R26; N; R50
SULFIDE EU CLP: ANNEX VI - FLAM. GAS 1, H220; PRESS. GAS - LIQ., H280;
ACUTE TOX. 2 *, H330; AQUATIC ACUTE 1, H400
OSHA HCS 2012: FLAM. GAS 1; PRESS. GAS - LIQ.; ACUTE TOX 2
(INHL)
CARBON EU DSD/DPD: ANNEX I - F+; R12; REPR. CAT. 1; R61; T; R23-48/23
MONOXIDE EU CLP: ANNEX VI - FLAM. GAS 1, H220; PRESS. GAS, H280; REPR.
1A, H360D; ACUTE TOX. 3 *; H331; STOT RE 1, H372
OSHA HCS 2012: FLAM GAS; PRESS GAS; REPR 1A; ACUTE TOX 3
(INHL)
NITROGEN EU DSD/DPD: NONE
EU CLP: SELF CLASSIFIED - PRESS. GAS - COMP., H280
OSHA HCS 2012: PRESS. GAS - COMP.; SIMP. ASPHYX.
SEE SECTION 16 FOR FULL TEXT OF H-STATEMENTS AND R-PHRASES.
| SECTION 4 - FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL
RESPIRATION IF VICTIM IS NOT BREATHING. IF SIGNS/SYMPTOMS CONTINUE, GET
MEDICAL ATTENTION.
SKIN:
ALTHOUGH EXPOSURE IS UNLIKELY, IN CASE OF CONTACT IMMEDIATELY FLUSH SKIN
WITH RUNNING WATER. IF SKIN IRRITATION DEVELOPS GET MEDICAL
ADVICE/ATTENTION.
EYE:
FIRST AID IS NOT EXPECTED TO BE NECESSARY IF MATERIAL IS USED UNDER
ORDINARY CONDITIONS AND AS RECOMMENDED. IF IRRITATION DEVELOPS AND
PERSISTS, GET MEDICAL ATTENTION.
INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED.
A POTENTIAL HEALTH HAZARD ASSOCIATED WITH THIS GAS IS ANOXIA.
4.4 OTHER INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. RESCUERS SHOULD NOT ATTEMPT TO
RETRIEVE VICTIMS OF EXPOSURE TO GASES WITHOUT ADEQUATE PERSONAL PROTECTIVE
EQUIPMENT. AT A MINIMUM, SELF-CONTAINED BREATHING APPARATUS MUST BE WORN.
VICTIM(S) WHO EXPERIENCE ANY ADVERSE EFFECT AFTER OVER-EXPOSURE TO THIS GAS
MIXTURE MUST BE TAKEN FOR MEDICAL ATTENTION. RESCUERS SHOULD BE TAKEN FOR
MEDICAL ATTENTION IF NECESSARY. TAKE A COPY OF THE LABEL AND THE MSDS TO
PHYSICIAN OR OTHER HEALTH PROFESSIONAL WITH VICTIM(S).
| SECTION 5 - FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO DATA AVAILABLE
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN HEATED.
RUPTURED CYLINDERS MAY ROCKET.
HAZARDOUS COMBUSTION PRODUCTS: NO DATA AVAILABLE
5.3 ADVICE FOR FIREFIGHTERS:
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING PROVIDES LIMITED PROTECTION IN
FIRE SITUATIONS ONLY; IT IS NOT EFFECTIVE IN SPILL SITUATIONS WHERE DIRECT
CONTACT WITH THE SUBSTANCE IS POSSIBLE.
ALWAYS WEAR THERMAL PROTECTIVE CLOTHING WHEN HANDLING
REFRIGERATED/CRYOGENIC LIQUIDS.
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK.
FIRE:
IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN A FIRE, ISOLATE FOR 800
METERS (1/2 MILE) IN ALL DIRECTIONS; ALSO, CONSIDER INITIAL EVACUATION
FOR 800 METERS (1/2 MILE) IN ALL DIRECTIONS.
FIRE INVOLVING TANKS:
FIGHT FIRE FROM MAXIMUM DISTANCE OR USE UNMANNED HOSE HOLDERS OR MONITOR
NOZZLES.
FIRE INVOLVING TANKS:
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE
IS OUT.
FIRE INVOLVING TANKS:
DO NOT DIRECT WATER AT SOURCE OF LEAK OR SAFETY DEVICES; ICING MAY OCCUR.
FIRE INVOLVING TANKS:
WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICES
OR DISCOLORATION OF TANK.
FIRE INVOLVING TANKS: ALWAYS STAY AWAY FROM TANKS ENGULFED IN FIRE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING
APPROPRIATE PROTECTIVE CLOTHING. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. VENTILATE THE AREA BEFORE ENTRY.
EMERGENCY PROCEDURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. KEEP UNAUTHORIZED PERSONNEL AWAY.
KEEP OUT OF LOW AREAS. STAY UPWIND. DO NOT DIRECT WATER AT SPILL OR SOURCE
OF LEAK.
LARGE SPILL:
CONSIDER INITIAL DOWNWIND EVACUATION FOR AT LEAST 500 METERS (1/3 MILE)
6.2 ENVIRONMENTAL PRECAUTIONS:
PREVENT SPREADING OF VAPORS THROUGH SEWERS, VENTILATION SYSTEMS AND
CONFINED AREAS.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK.
USE WATER SPRAY TO REDUCE VAPORS; DO NOT PUT WATER DIRECTLY ON LEAK, SPILL
AREA OR INSIDE CONTAINER.
IF POSSIBLE, TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN
LIQUID.
ISOLATE AREA UNTIL GAS HAS DISPERSED.
VENTILATE THE AREA.
6.4 REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION AND
SECTION 13 - DISPOSAL CONSIDERATIONS.
| SECTION 7 - HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. VENTILATE CLOSED SPACES BEFORE
ENTERING. BE AWARE OF ANY SIGNS OF DIZZINESS OR FATIGUE, ESPECIALLY IF
WORK IS DONE IN A POORLY VENTILATED AREA; EXPOSURES TO FATAL
CONCENTRATIONS OF THIS GAS MIXTURE COULD OCCUR WITHOUT ANY SIGNIFICANT
WARNING SYMPTOMS, DUE TO OLFACTORY FATIGUE OR OXYGEN DEFICIENCY. CYLINDERS
SHOULD BE FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED-OVER. DO NOT
ATTEMPT TO REPAIR, ADJUST, OR IN ANY OTHER WAY MODIFY CYLINDERS. IF THERE
IS A MALFUNCTION OR ANOTHER TYPE OF OPERATIONAL PROBLEM, CONTACT NEAREST
DISTRIBUTOR IMMEDIATELY. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN
BE HAZARDOUS. DO NOT CUT, WELD, PUNCTURE OR INCINERATE CONTAINER.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
STORE IN A COOL, DRY, WELL-VENTILATED PLACE. PROTECT CYLINDERS AGAINST
PHYSICAL DAMAGE. CYLINDERS SHOULD BE FIRMLY SECURED TO PREVENT FALLING
OR BEING KNOCKED-OVER.
7.3 SPECIFIC END USE(S):
REFER TO SECTION 1.2 - RELEVANT IDENTIFIED USES.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
EXPOSURE LIMITS/GUIDELINES:
RESULT ACGIH CANADA ONTARIO CANADA QUEBEC
PROPANE TWAS 1000 PPM TWA 1000 PPM TWA 1000 PPM
(74-98-6) (LISTED UNDER 1800 MG/M3 TWAEV TWAEV;
ALIPHATIC
HYDROCARBON
GASES:
ALKANE C1-4)
HYDROGEN CEILINGS NOT NOT NOT
SULFIDE ESTABLISHED ESTABLISHED ESTABLISHED
(7783-06-4)
STELS 5 PPM STEL 15 PPM STEL 15 PPM STEV;
21 MG/M3 STEV
TWAS 1 PPM TWA 10 PPM TWA 10 PPM TWAEV;
14 MG/M3 TWAEV
CARBON CEILINGS NOT NOT NOT
MONOXIDE ESTABLISHED ESTABLISHED ESTABLISHED
(630-08-0)
STELS NOT NOT 200 PPM STEV;
ESTABLISHED ESTABLISHED 230 MG/M3 STEV
TWAS 25 PPM TWA 25 PPM TWA 35 PPM TWAEV;
40 MG/M3 TWAEV
RESULT CHINA CHINA HIGHLY TOXIC GOODS
PROPANE TWAS NOT ESTABLISHED NOT ESTABLISHED
HYDROGEN CEILINGS 10 MG/M3 CEILING 10 MG/M3 CEILING
SULFIDE [MAC]
STELS NOT ESTABLISHED NOT ESTABLISHED
TWAS NOT ESTABLISHED NOT ESTABLISHED
CARBON MONOXIDE CEILINGS 20 MG/M3 CEILING NOT ESTABLISHED
[MAC] (HIGH
ALTITUDE AREA,
2000-3000M);
15 MG/M3 CEILING
[MAC] (HIGH
ALTITUDE AREA,
>3000M)
STELS 30 MG/M3 STEL 30 MG/M3 STEL (NOT
(NOT IN HIGH IN HIGH ALTITUDE AREA)
ALTITUDE AREA)
TWAS 20 MG/M3 TWA (NOT 20 MG/M3 TWA (NOT IN
IN HIGH ALTITUDE HIGH ALTITUDE AREA)
AREA)
RESULT FRANCE GERMANY DFG GERMANY TRGS
PROPANE TWAS NOT NOT 1000 PPM TWA
ESTABLISHED ESTABLISHED AGW (EXPOSURE
FACTOR 4);
1800 MG/M3 TWA
AGW (EXPOSURE
FACTOR 4)
CEILINGS NOT 4000 PPM PEAK; NOT
ESTABLISHED 7200 MG/M3 PEAK ESTABLISHED
MAKS NOT 1000 PPM TWA MAK; NOT
ESTABLISHED 1800 MG/M3 TWA ESTABLISHED
MAK
HYDROGEN STELS 10 PPM STEL NOT ESTABLISHED NOT
SULFIDE [VLCT]; ESTABLISHED
14 MG/M3 STEL
[VLCT]
TWAS 5 PPM TWA NOT ESTABLISHED 5 PPM TWA AGW
[VME]; 7 (THE RISK OF
MG/M3 TWA DAMAGE TO THE
[VME] EMBRYO OR
FETUS CAN BE
EXCLUDED WHEN
AGW AND BGW
VALUES ARE
OBSERVED,
EXPOSURE
FACTOR 2);
7.1 MG/M3
TWA AGW (THE
RISK OF DAMAGE
TO THE EMBRYO
OR FETUS CAN
BE EXCLUDED
WHEN AGW AND
BGW VALUES ARE
OBSERVED,
EXPOSURE
FACTOR 2)
CEILINGS NOT 10 PPM PEAK; 14.2 NOT
ESTABLISHED MG/M3 PEAK ESTABLISHED
MAKS NOT 5 PPM TWA MAK; NOT
ESTABLISHED 7.1 MG/M3 TWA ESTABLISHED
MAK
CARBON TWAS 50 PPM TWA NOT ESTABLISHED 30 PPM TWA AGW
MONOXIDE [VME]; (THE RISK OF
) 55 MG/M3 TWA DAMAGE TO THE
[VME] EMBRYO OR
FETUS CANNOT
BE EXCLUDED
EVEN WHEN
AGW AND BGW
VALUES ARE
OBSERVED,
EXPOSURE
FACTOR 2);
35 MG/M3 TWA
AGW (THE RISK
OF DAMAGE TO
THE EMBRYO OR
FETUS CANNOT
BE EXCLUDED
EVEN WHEN
AGW AND BGW
VALUES ARE
OBSERVED,
EXPOSURE
FACTOR 2)
STELS NOT NOT ESTABLISHED NOT
ESTABLISHED ESTABLISHED
CEILINGS NOT 60 PPM PEAK; 70 NOT
ESTABLISHED MG/M3 PEAK ESTABLISHED
RESULT IRELAND ISRAEL
PROPANE TWAS 1000 PPM TWA 1000 PPM TWA (GAS)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
HYDROGEN STELS 10 PPM STEL; 5 PPM STEL
SULFIDE 14 MG/M3 STEL
TWAS 5 PPM TWA; 7 MG/M3 TWA 1 PPM TWA
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
CARBON MONOXIDE TWAS 20 PPM TWA; 23 25 PPM TWA
MG/M3 TWA
STELS 100 PPM STEL; 115 NOT ESTABLISHED
MG/M3 STEL
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
RESULT NIOSH OSHA PORTUGAL
PROPANE TWAS 1000 PPM TWA; 1000 PPM TWA; 1000 PPM TWA
1800 MG/M3 TWA 1800 MG/M3 TWA [VLE-MP]
HYDROGEN STELS NOT NOT ESTABLISHED 15 PPM STEL
SULFIDE ESTABLISHED [VLE-CD
TWAS NOT NOT ESTABLISHED 10 PPM TWA
ESTABLISHED [VLE-MP]
CEILINGS 10 PPM 20 PPM CEILING NOT
CEILING (10 ESTABLISHED
MIN);
15 MG/M3
CEILING
(10 MIN)
CARBON TWAS 35 PPM TWA; 50 PPM TWA; 55 25 PPM TWA
MONOXIDE 40 MG/M3 TWA MG/M3 TWA [VLE-MP]
BIOLOGI- NOT NOT ESTABLISHED NOT
CAL ESTABLISHED ESTABLISHED
LIMIT
VALUES
(BLV)
STELS NOT NOT NOT
ESTABLISHED ESTABLISHED ESTABLISHED
CEILINGS 200 PPM NOT ESTABLISHED NOT
CEILING; 229 ESTABLISHED
MG/M3 CEILING
RESULT SPAIN SWEDEN
PROPANE TWAS 1000 PPM TWA NOT ESTABLISHED
[VLA-ED]
HYDROGEN STELS 10 PPM STEL NOT ESTABLISHED
SULFIDE [VLA-EC];
14 MG/M3 STEL
[VLA-EC]
TWAS 5 PPM TWA 10 PPM LLV;
[VLA-ED]; 14 MG/M3 LLV
7 MG/M3 TWA
[VLA-ED]
CEILINGS NOT ESTABLISHED 15 PPM CLV; 20 MG/M3 CLV
CARBON MONOXIDE TWAS 25 PPM TWA 20 PPM LLV (REGULATED
[VLA-ED]; UNDER EXHAUST FUMES,
29 MG/M3 TWA LISTED UNDER EXHAUST
[VLA-ED] FUMES); 25 MG/M3 LLV
(REGULATED UNDER EXHAUST
FUMES, LISTED UNDER
EXHAUST FUMES); 35
PPM LLV; 40 MG/M3
LLV
BIOLOGI- 3.5 % OF NOT ESTABLISHED
CAL CARBOXYHEMOGLOBIN
LIMIT IN TOTAL
VALUES HEMOGLOBIN BLOOD
(BLV) END OF SHIFT
CARBOXYHEMOGLOBIN
(2,F,I); 20 PPM
ALVEOLAR AIR END
OF SHIFT CO
END-CUT OF EXHALED
AIR (2,F,I)
STELS NOT ESTABLISHED 100 PPM STV; 120
MG/M3 STV
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
EXPOSURE CONTROL NOTATIONS:
PORTUGAL:
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (SIMPLE ASPHYXIANT)
FRANCE:
CARBON MONOXIDE (630-08-0):
REPRODUCTIVE TOXINS: (REPRODUCTIVE TOXIN CATEGORY 1)
IRELAND:
PROPANE (74-98-6):
SIMPLE ASPHYXIANTS: (ASPHYXIANT)
CARBON MONOXIDE (630-08-0):
SUBSTANCES WITH POTENTIAL CHRONIC HEALTH EFFECTS: (REPR1A)
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (ASPHYXIANT)
SPAIN:
CARBON MONOXIDE (630-08-0):
REPRODUCTIVE TOXINS:
(KNOWN REPRODUCTIVE TOXINS WITH CLASSIFICATION FROM HUMAN DATA)
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (SIMPLE ASPHYXIANT)
SWEDEN:
CARBON MONOXIDE (630-08-0):
REPRODUCTIVE TOXINS: (CAUSES REPRODUCTIVE DISTURBANCES)
GERMANY DFG:
PROPANE (74-98-6):
PREGNANCY: (CLASSIFICATION NOT YET POSSIBLE)
HYDROGEN SULFIDE (7783-06-4):
PREGNANCY: (NO RISK TO EMBRYO/FETUS IF EXPOSURE LIMITS ADHERED TO)
CARBON MONOXIDE (630-08-0):
PREGNANCY: (RISK TO EMBRYO/FETUS PROBABLE)
8.2 EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT
BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN
STANDARD EN 149. USE A NIOSH/MSHA OR EUROPEAN STANDARD EN 149 APPROVED
RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS ARE EXPERIENCED.
EYE/FACE: WEAR SAFETY GLASSES.
SKIN/BODY: WEAR LEATHER GLOVES WHEN HANDLING CYLINDERS.
ENVIRONMENTAL EXPOSURE CONTROLS:
FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF WASTE. CONTROLS
SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT, INCLUDING
PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO WATERWAYS.
KEY TO ABBREVIATIONS:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
LLV: LIMIT LEVEL VALUE IS THE EXPOSURE LIMIT FOR 8-HOUR WORK DAY
TWAEV: TIME-WEIGHTED AVERAGE EXPOSURE VALUE
MAK:
MAXIMALE ARBEITSPLATZ KONZENTRATION IS THE MAXIMUM PERMISSIBLE
CONCENTRATION
TWA: TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: GAS
APPEARANCE/DESCRIPTION:
GAS MIXTURE, COLORLESS GAS, WHICH HAS A ROTTEN EGG-LIKE ODOR, DUE TO THE
PRESENCE OF HYDROGEN SULFIDE.
COLOR: COLORLESS
ODOR: ROTTEN EGG-LIKE ODOR, DUE TO THE PRESENCE OF HYDROGEN SULFIDE.
ODOR THRESHOLD: DATA LACKING
GENERAL PROPERTIES:
BOILING POINT: -195.8 C(-320.44 F) NITROGEN
MELTING POINT: -210 C(-346 F) NITROGEN
DECOMPOSITION TEMPERATURE: DATA LACKING
pH: DATA LACKING
SPECIFIC GRAVITY/RELATIVE DENSITY: DATA LACKING
DENSITY: 0.072 LB(S)/FT3 @ 0 C(32 F) NITROGEN
WATER SOLUBILITY: 0.023 % @ 0 C(32 F) NITROGEN
VISCOSITY: DATA LACKING
EXPLOSIVE PROPERTIES: DATA LACKING
OXIDIZING PROPERTIES: DATA LACKING
VOLATILITY:
VAPOR PRESSURE: DATA LACKING
VAPOR DENSITY: 0.906 AIR=1 NITROGEN
EVAPORATION RATE: NOT RELEVANT
FLAMMABILITY:
FLASH POINT: DATA LACKING
UEL: DATA LACKING
LEL: DATA LACKING
AUTOIGNITION: DATA LACKING
FLAMMABILITY (SOLID, GAS): NOT FLAMMABLE.
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: DATA LACKING
9.2 OTHER INFORMATION:
NO ADDITIONAL PHYSICAL AND CHEMICAL PARAMETERS NOTED.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.2 CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4 CONDITIONS TO AVOID: EXCESS HEAT.
10.5 INCOMPATIBLE MATERIALS: NO DATA AVAILABLE
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
COMPONENT NAME CAS DATA
HYDROGEN SULFIDE (0.001% TO 0.025%) 7783-06-4 ACUTE TOXICITY:
IHL-RAT LC50:700 MG/M3/4H;
IRRITATION:
EYE-HMN 0.000125 PPM/5H;
REPRODUCTIVE:
IHL-RAT TCLO:10 MG/M3 (48D
PRE/1-22D PREG)
CARBON MONOXIDE (0.005% TO 1%) 630-08-0 ACUTE TOXICITY:
IHL-RAT LC50:1807 PPM/4H;
REPRODUCTIVE:
IHL-RAT TCLO:150 PPM
(0-20D PREG)
GHS PROPERTIES CLASSIFICATION
ACUTE TOXICITY EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
ASPIRATION HAZARD EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
CARCINOGENICITY EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
GERM CELL EU/CLP: CLASSIFICATION CRITERIA NOT MET
MUTAGENICITY OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
SKIN CORROSION/ EU/CLP: CLASSIFICATION CRITERIA NOT MET
IRRITATION OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
SKIN SENSITIZATION EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
STOT-RE EU/CLP:
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 2
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
STOT-SE EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
TOXICITY FOR EU/CLP: TOXIC TO REPRODUCTION 1A
REPRODUCTION OSHA HCS 2012: TOXIC TO REPRODUCTION 1A
RESPIRATORY EU/CLP: CLASSIFICATION CRITERIA NOT MET
SENSITIZATION OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
SERIOUS EYE EU/CLP: CLASSIFICATION CRITERIA NOT MET
DAMAGE/IRRITATION OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
ROUTE(S) OF ENTRY/EXPOSURE: INHALATION, SKIN, EYE
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE):
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES. IF THIS MATERIAL IS
RELEASED IN A SMALL, POORLY VENTILATED AREA (I.E. AN ENCLOSED OR CONFINED
SPACE), AN OXYGEN-DEFICIENT ENVIRONMENT MAY OCCUR. INDIVIDUALS BREATHING
SUCH AN ATMOSPHERE MAY EXPERIENCE SYMPTOMS WHICH INCLUDE HEADACHES, RINGING
IN EARS, DIZZINESS, DROWSINESS, UNCONSCIOUSNESS, NAUSEA, VOMITING, AND
DEPRESSION OF ALL THE SENSES. UNDER SOME CIRCUMSTANCES OF OVER-EXPOSURE,
DEATH MAY OCCUR. THE FOLLOWING EFFECTS ASSOCIATED WITH DECREASED LEVELS
OF OXYGEN: INCREASE IN BREATHING AND PULSE RATE, EMOTIONAL UPSET, ABNORMAL
FATIGUE, NAUSEA, VOMITING, COLLAPSE, LOSS OF CONSCIOUSNESS, CONVULSIVE
MOVEMENTS, RESPIRATORY COLLAPSE AND DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE
SKIN:
ACUTE (IMMEDIATE):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
CHRONIC (DELAYED):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
EYE:
ACUTE (IMMEDIATE):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
CHRONIC (DELAYED):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
INGESTION:
ACUTE (IMMEDIATE):
INGESTION IS NOT ANTICIPATED TO BE A LIKELY ROUTE OF EXPOSURE TO THIS
PRODUCT.
CHRONIC (DELAYED):
INGESTION IS NOT ANTICIPATED TO BE A LIKELY ROUTE OF EXPOSURE TO THIS
PRODUCT.
OTHER:
CHRONIC (DELAYED):
THE TRANSPORT OF OXYGEN IN BLOOD ENSURED BY HAEMOGLOBIN WILL BE SLOWED
DOWN BECAUSE CARBOXYHAEMOGLOBIN INSTEAD OF OXYHAEMOGLOBIN WILL BE FORMED
IN LUNGS. THE AFFINITY OF HEAMOGLOBIN FOR CARBON MONOXIDE IS 200 TO 300
HIGHER THEN FOR OXYGEN. ALL RELATED HEALTH HAZARDS WIL BE CAUSED BY SLOW
RESPIRATION OF CELLS WHICH WILL DAMAGE THE CENTRAL NERVOUS SYSTEM, COLLAPSE
THE CARDIOVASCULAR SYSTEM, CAUSE KIDNEY INSUFFICIENCY, COMA, ETC.
CARCINOGENIC EFFECTS:
THE COMPONENTS OF THIS MATERIAL ARE NOT FOUND ON THE FOLLOWING LISTS:
FEDERAL OSHA Z LIST, NTP AND IARC; THEREFORE, THEY ARE NOT CONSIDERED
TO BE, NOR SUSPECTED TO BE, CANCER-CAUSING AGENTS BY THESE AGENCIES.
REPRODUCTIVE EFFECTS:
THE CARBON MONOXIDE COMPONENT OF THIS GAS MIXTURE CAN CAUSE TERATOGENIC
EFFECTS IN HUMANS. SEVERE EXPOSURE TO CARBON MONOXIDE DURING PREGNANCY
HAS CAUSED ADVERSE EFFECTS AND THE DEATH OF THE FETUS. IN GENERAL, MATERNAL
SYMPTOMS ARE AN INDICATOR OF THE POTENTIAL RISK TO THE FETUS SINCE CARBON
MONOXIDE IS TOXIC TO THE MOTHER BEFORE IT IS TOXIC TO THE FETUS.
| SECTION 12 - ECOLOGICAL INFORMATION | |
12.1 TOXICITY: MATERIAL DATA LACKING.
12.2 PERSISTENCE AND DEGRADABILITY: MATERIAL DATA LACKING.
12.3 BIOACCUMULATIVE POTENTIAL: MATERIAL DATA LACKING.
12.4 MOBILITY IN SOIL: MATERIAL DATA LACKING.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT AND VPVB ASSESSMENT HAS NOT BEEN CONDUCTED FOR THIS MATERIAL.
12.6 OTHER ADVERSE EFFECTS: NO STUDIES HAVE BEEN FOUND.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
14.1 UN 14.2 UN PROPER SHIPPING 14.3 TRANSPORT HAZARD
NUMBER NAME CLASS(ES)
DOT UN1956 COMPRESSED GAS, N.O.S. 2.2
(OXYGEN, NITROGEN)
TDG UN1956 COMPRESSED GAS, N.O.S. 2.2
(OXYGEN, NITROGEN)
IMO/IMDG UN1956 COMPRESSED GAS, N.O.S. 2.2
(OXYGEN, NITROGEN)
IATA/ICAO UN1956 COMPRESSED GAS, N.O.S. 2.2
(OXYGEN, NITROGEN)
14.4 PACKING GROUP 14.5 ENVIRONMENTAL HAZARDS
DOT NDA NDA
TDG NDA NDA
IMO/IMDG NDA NDA
IATA/ICAO NDA NDA
14.6 SPECIAL PRECAUTIONS FOR USER:
CYLINDERS SHOULD BE TRANSPORTED IN A SECURE POSITION, IN A WELL-VENTILATED
VEHICLE. THE TRANSPORTATION OF COMPRESSED GAS CYLINDERS IN AUTOMOBILES OR
IN CLOSED-BODY VEHICLES CAN PRESENT SERIOUS SAFETY HAZARDS. IF TRANSPORTING
THESE CYLINDERS IN VEHICLES, ENSURE THESE CYLINDERS ARE NOT EXPOSED TO
EXTREMELY HIGH TEMPERATURES (AS MAY OCCUR IN AN ENCLOSED VEHICLE ON A HOT
DAY). ADDITIONALLY, THE VEHICLE SHOULD BE WELL-VENTILATED DURING
TRANSPORTATION.
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE:
NOT RELEVANT.
14.8 OTHER INFORMATION:
DOT:
ACCORDING TO APPENDIX A TO 49 CFR 172.101 HYDROGEN SULFIDE H2S HAS A
REPORTABLE QUANTITY OF 100 LBS (45.4 KG)
| SECTION 15 - REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: ACUTE, PRESSURE(SUDDEN RELEASE OF)
STATE RIGHT TO KNOW:
COMPONENT CAS MA NJ PA
CARBON MONOXIDE 630-08-0 YES YES YES
HYDROGEN SULFIDE 7783-06-4 YES YES YES
NITROGEN 7727-37-9 YES YES YES
OXYGEN 7782-44-7 YES YES YES
PROPANE 74-98-6 YES YES YES
INVENTORY:
COMPONENT CAS CANADA CANADA CHINA EU EINECS EU ELNICS
DSL NDSL
CARBON 630-08-0 YES NO YES YES NO
MONOXIDE
HYDROGEN 7783-06-4 YES NO YES YES NO
SULFIDE
NITROGEN 7727-37-9 YES NO YES YES NO
OXYGEN 7782-44-7 YES NO YES YES NO
PROPANE 74-98-6 YES NO YES YES NO
COMPONENT CAS TSCA
CARBON MONOXIDE 630-08-0 YES
HYDROGEN SULFIDE 7783-06-4 YES
NITROGEN 7727-37-9 YES
OXYGEN 7782-44-7 YES
PROPANE 74-98-6 YES
CANADA:
LABOR:
CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES:
HYDROGEN SULFIDE 7783-06-4 A, B1, D1A, D2B
CARBON MONOXIDE 630-08-0 A, B1, D1A, D2A
OXYGEN 7782-44-7 A, C
PROPANE 74-98-6 A, B1
NITROGEN 7727-37-9 A
CANADA - WHMIS - INGREDIENT DISCLOSURE LIST:
HYDROGEN SULFIDE 7783-06-4 1 %
CARBON MONOXIDE 630-08-0 0.1 %
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
ENVIRONMENT:
CANADA - 2004 NPRI (NATIONAL POLLUTANT RELEASE INVENTORY):
HYDROGEN SULFIDE 7783-06-4 PART 1, GROUP 1
SUBSTANCE
CARBON MONOXIDE 630-08-0 PART 4 SUBSTANCE
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 PART 5 SUBSTANCE
NITROGEN 7727-37-9 NOT LISTED
CANADA - 2005 NPRI (NATIONAL POLLUTANT RELEASE INVENTORY):
HYDROGEN SULFIDE 7783-06-4 PART 1, GROUP 1
SUBSTANCE
CARBON MONOXIDE 630-08-0 PART 4 SUBSTANCE
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 PART 5 SUBSTANCE
NITROGEN 7727-37-9 NOT LISTED
CANADA - CEPA - GREENHOUSE GASES SUBJECT TO MANDATORY REPORTING:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CANADA - CEPA - PRIORITY SUBSTANCES LIST:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CANADA - DWQ (DRINKING WATER QUALITY) - IMACS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
CANADA - ACCELERATED REDUCTION/ELIMINATION OF TOXICS (ARET):
HYDROGEN SULFIDE 7783-06-4 B-3
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CANADA NEW BRUNSWICK:
ENVIRONMENT:
CANADA - NEW BRUNSWICK - OZONE DEPLETING SUBSTANCES - SCHEDULE A:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CANADA - NEW BRUNSWICK - OZONE DEPLETING SUBSTANCES - SCHEDULE B:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA:
ENVIRONMENT:
CHINA - OZONE DEPLETING SUBSTANCES - FIRST SCHEDULE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - OZONE DEPLETING SUBSTANCES - SECOND SCHEDULE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - OZONE DEPLETING SUBSTANCES - THIRD SCHEDULE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
CHINA - ANNEX I & II - CONTROLLED CHEMICALS LISTS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - DANGEROUS GOODS LIST:
HYDROGEN SULFIDE 7783-06-4
CARBON MONOXIDE 630-08-0
OXYGEN 7782-44-7 (COMPRESSED OR
REFRIGERATED LIQUID)
PROPANE 74-98-6
NITROGEN 7727-37-9 (COMPRESSED OR
REFRIGERATED LIQUID)
CHINA - EXPORT CONTROL LIST - PART I CHEMICALS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
EUROPE:
OTHER:
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - CLASSIFICATION:
HYDROGEN SULFIDE 7783-06-4 F+; R12 T+; R26 N;
R50
CARBON MONOXIDE 630-08-0 F+; R12 T; R23-48/23
REPR.CAT.1; R61
OXYGEN 7782-44-7 O; R8
PROPANE 74-98-6 F+; R12
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - CONCENTRATION LIMITS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - LABELLING:
HYDROGEN SULFIDE 7783-06-4 F+ T+ N R: 12-26-50
S: (1/2)-9-16-36-38-
45-61
CARBON MONOXIDE 630-08-0 F+ T R:
61-12-23-48/23
S: 53-45
OXYGEN 7782-44-7 O R: 8 S:(2)-17
PROPANE 74-98-6 F+ R: 12 S:(2)-9-16
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - NOTES - SUBSTANCES AND
PREPARATIONS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 E
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - SAFETY PHRASES:
HYDROGEN SULFIDE 7783-06-4 S: (1/2)-9-16-36-38-
45-61
CARBON MONOXIDE 630-08-0 S: 53-45
OXYGEN 7782-44-7 S: (2)-17
PROPANE 74-98-6 S: (2)-9-16
NITROGEN 7727-37-9 NOT LISTED
GERMANY:
ENVIRONMENT:
GERMANY - TA LUFT - TYPES AND CLASSES:
HYDROGEN SULFIDE 7783-06-4 INORGANIC GAS
SUBSTANCE:
5.2.4, CLASS II
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 1:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 ID NUMBER 743, NOT
CONSIDERED HAZARDOUS
TO WATER
PROPANE 74-98-6 ID NUMBER 560, NOT
CONSIDERED HAZARDOUS
TO WATER
NITROGEN 7727-37-9 ID NUMBER 1351, NOT
CONSIDERED HAZARDOUS
TO WATER
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 2 - WATER HAZARD CLASSES:
HYDROGEN SULFIDE 7783-06-4 ID NUMBER 283, HAZARD
CLASS 2 - HAZARD TO
WATERS
CARBON MONOXIDE 630-08-0 ID NUMBER 257, HAZARD
CLASS 1 - LOW HAZARD
TO WATERS
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 3:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
GERMANY - SPECIFICALLY REGULATED CHEMICALS IN TRGS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
PORTUGAL:
OTHER:
PORTUGAL - PROHIBITED SUBSTANCES:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED KINGDOM:
ENVIRONMENT:
UNITED KINGDOM - POLLUTION INVENTORY - SCHEDULE 1 - THRESHOLDS FOR RELEASES
TO AIR:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 100000 KG
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
UNITED KINGDOM - WORKPLACE EXPOSURE LIMITS (WELS) - SUBSTANCES IN REVIEW:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED KINGDOM - LIST OF DANGEROUS SUBSTANCES IN WATER:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
HYDROGEN SULFIDE 7783-06-4 1500 LB TQ
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
HYDROGEN SULFIDE 7783-06-4 100 LB FINAL RQ;
45.4 KG FINAL RQ
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - RADIONUCLIDES AND THEIR REPORTABLE QUANTITIES:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
HYDROGEN SULFIDE 7783-06-4 100 LB EPCRA RQ
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
HYDROGEN SULFIDE 7783-06-4 500 LB TPQ
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING:
HYDROGEN SULFIDE 7783-06-4 1.0 % DE MINIMIS
CONCENTRATION
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - RCRA (RESOURCE CONSERVATION & RECOVERY ACT) - HAZARDOUS
CONSTITUENTS - APPENDIX VIII TO 40 CFR 261:
HYDROGEN SULFIDE 7783-06-4 WASTE NUMBER U135
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - RCRA (RESOURCE CONSERVATION & RECOVERY ACT) - U SERIES
WASTES - ACUTELY TOXIC WASTES & OTHER HAZARDOUS CHARACTERISTICS:
HYDROGEN SULFIDE 7783-06-4 WASTE NUMBER U135
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES - CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 DEVELOPMENTAL
TOXICITY,
INITIAL DATE 7/1/89
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES - PENNSYLVANIA:
LABOR:
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST:
HYDROGEN SULFIDE 7783-06-4
CARBON MONOXIDE 630-08-0
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - SPECIAL HAZARDOUS SUBSTANCES:
HYDROGEN SULFIDE 7783-06-4 NOT LISTED
CARBON MONOXIDE 630-08-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
15.2 CHEMICAL SAFETY ASSESSMENT:
NO CHEMICAL SAFETY ASSESSMENT HAS BEEN CARRIED OUT.
15.3 OTHER INFORMATION:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
RELEVANT PHRASES (CODE & FULL TEXT):
H220: EXTREMELY FLAMMABLE GAS
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDIZER
H330: FATAL IF INHALED
H331: TOXIC IF INHALED
H360D: MAY DAMAGE THE UNBORN CHILD.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H400: VERY TOXIC TO AQUATIC LIFE
R8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
R12: EXTREMELY FLAMMABLE.
R23: TOXIC BY INHALATION.
R26: VERY TOXIC BY INHALATION.
R48/23:
TOXIC: DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
R50: VERY TOXIC TO AQUATIC ORGANISMS.
LAST REVISION DATE: 21/JANUARY/2014
PREPARATION DATE: 21/JANUARY/2014
DISCLAIMER/STATEMENT OF LIABILITY:
TO THE BEST OF AIR LIQUIDE'S KNOWLEDGE, THE INFORMATION CONTAINED HEREIN
IS RELIABLE AND ACCURATE AS OF THIS DATE; HOWEVER, ACCURACY, SUITABILITY
OR COMPLETENESS ARE NOT GUARANTEED AND NO WARRANTIES OF ANY TYPE, EITHER
EXPRESS OR IMPLIED, ARE PROVIDED. THE INFORMATION CONTAINED HEREIN RELATES
ONLY TO THIS SPECIFIC PRODUCT. IF THIS GAS MIXTURE IS COMBINED WITH OTHER
MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED. DATA MAY BE CHANGED
FROM TIME TO TIME. BE SURE TO CONSULT THE LATEST EDITION.
KEY TO ABBREVIATIONS:
NDA: NO DATA AVAILABLE
REVISION DATE: 21/JANUARY/2014
FORMAT:
EU CLP/REACH LANGUAGE: ENGLISH (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
P/N: 3489