| Common Name: | NON-FLAMMABLE GAS MIXTURE, 50010 |
| Manufacturer: | AIR LIQUIDE |
| SDS Revision Date: | 10/15/2014 |
| SDS Format: | No Format Specified |
| Item Number(s): | 36J508, 36J513, 5HP82 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NON-FLAMMABLE GAS MIXTURE CONTAINING ONE OR MORE OF THE FOLLOWING
COMPONENTS IN A NITROGEN BALANCE GAS:
N-HEXANE; 0-0.48%; N-PENTANE, 0-0.75%; CARBON MONOXIDE, 0.0005-1.0%;
PROPANE, 0-1.1%; OXYGEN, 0-23.5%
INDUSTRIAL SCIENTIFIC
1 LIFE WAY
PITTSBURGH, PA 15205-7500
PHONE: (412) 788-4353
TOLL-FREE: 800-DETECTS
FAX: (412) 788-8353
SAFETY DATA SHEET
(REPLACES ISC MSDS NO. 1810-1253, 1810-1576, 1810-2258, 1810-2324,
1810-4448, 1810-4455, 1810-4463, 1810-5122, 1810-5676, 1810-9161,
1810-9165, 1810-9190, 1810-9410)
| SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
PRODUCT NAME:
NON-FLAMMABLE GAS MIXTURE CONTAINING ONE OR MORE OF THE FOLLOWING
COMPONENTS IN A NITROGEN BALANCE GAS:
N-HEXANE; 0-0.48%; N-PENTANE, 0-0.75%; CARBON MONOXIDE, 0.0005-1.0%;
PROPANE, 0-1.1%; OXYGEN, 0-23.5%
DOCUMENT NO.: 50010
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RELEVANT IDENTIFIED USE(S):
CALIBRATION OF MONITORING AND RESEARCH EQUIPMENT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
AIR LIQUIDE
2700 POST OAK BLVD.
HOUSTON, TX 77056
UNITED STATES
WWW.US.AIRLIQUIDE.COM
SDS@AIRLIQUIDE.COM
TELEPHONE (TECHNICAL): 713-896-2896
TELEPHONE (TECHNICAL): 800-819-1704
1.4 EMERGENCY TELEPHONE NUMBER:
MANUFACTURER: 800-424-9300
MANUFACTURER: +1 703-527-3887
| SECTION 2 - HAZARDS IDENTIFICATION | |
EU/EEC:
ACCORDING TO REGULATION (EC) NO 1272/2008 (CLP)/REACH 1907/2006 [AMENDED BY
453/2010] ACCORDING TO EU DIRECTIVE 67/548/EEC (DSD) OR 1999/45/EC (DPD)
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLP:
COMPRESSED GAS - H280
REPRODUCTIVE TOXICITY 1A - H360D
SPECIFIC TARGET ORGAN TOXICITY REPEATED EXPOSURE 2 - H373
DSD/DPD:
HARMFUL (XN)
SUBSTANCES TOXIC TO REPRODUCTION - CATEGORY 1
R20, R48/20, R61
2.2 LABEL ELEMENTS:
CLP:
DANGER:
GAS CYLINDER
HEALTH HAZARD
HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H360D: MAY DAMAGE THE UNBORN CHILD.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P260: DO NOT BREATHE GAS.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
RESPONSE:
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
STORAGE/DISPOSAL:
P403: STORE IN A WELL-VENTILATED PLACE.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
DSD/DPD:
HARMFUL OR IRRITANT
TOXIC OR VERY TOXIC
RISK PHRASES:
R20: HARMFUL BY INHALATION.
R48/20:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
R61: MAY CAUSE HARM TO THE UNBORN CHILD.
SAFETY PHRASES:
S53: AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
2.3 OTHER HAZARDS:
CLP:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
ACCORDING TO REGULATION (EC) NO. 1272/2008 (CLP) THIS MATERIAL IS
CONSIDERED HAZARDOUS.
DSD/DPD:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
ACCORDING TO EUROPEAN DIRECTIVE 1999/45/EC THIS PREPARATION IS CONSIDERED
DANGEROUS.
UNITED STATES (US): ACCORDING TO OSHA 29 CFR 1910.1200 HCS
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012:
COMPRESSED GAS - H280
REPRODUCTIVE TOXICITY 1A - H360
SIMPLE ASPHYXIANT
2.2 LABEL ELEMENTS:
OSHA HCS 2012:
DANGER:
GAS CYLINDER
HEALTH HAZARD
HAZARD STATEMENTS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED - H280
MAY DAMAGE FERTILITY OR THE UNBORN CHILD. - H360
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. - P201
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
- P202
DO NOT BREATHE GAS. - P260
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
- P280
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. - P308+P313
STORAGE/DISPOSAL:
STORE IN A WELL-VENTILATED PLACE. - P403
STORE LOCKED UP. - P405
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS. - P501
2.3 OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
CANADA:
ACCORDING TO WHMIS:
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
WHMIS:
COMPRESSED GAS - A
VERY TOXIC - D1A
OTHER TOXIC EFFECTS - D2A
2.2 LABEL ELEMENTS:
WHMIS:
COMPRESSED GAS - A
VERY TOXIC - D1A
OTHER TOXIC EFFECTS - D2A
2.3 OTHER HAZARDS:
WHMIS:
THIS MATERIAL IS A SIMPLE ASPHYXIANT. MAY DISPLACE OR REDUCE OXYGEN
AVAILABLE FOR BREATHING ESPECIALLY IN CONFINED SPACES.
IN CANADA, THE PRODUCT MENTIONED ABOVE IS CONSIDERED HAZARDOUS UNDER THE
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS).
2.4 OTHER INFORMATION:
NFPA:
HEALTH 1
FIRE 0
INSTABILITY 0
SPECIAL
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE IN ACCORDANCE WITH
REGULATION (EC) NO 1272/2008.
3.2 MIXTURES:
COMPOSITION:
CHEMICAL NAME IDENTIFIERS %
OXYGEN CAS: 7782-44-7 0.0015% TO 23.5%
EINECS: 231-956-9
PROPANE CAS: 74-98-6 0% TO 1.1%
EINECS: 200-827-9
CARBON MONOXIDE CAS: 630-08-0 0.0005% TO 1%
EINECS: 211-128-3
PENTANE CAS: 109-66-0 0% TO 0.75%
EINECS: 203-692-4
HEXANE CAS: 110-54-3 0% TO 0.48%
EINECS: 203-777-6
NITROGEN CAS: 7727-37-9 BALANCE
EINECS: 231-783-9
CHEMICAL NAME LD50/LC50 CLASSIFICATIONS ACCORDING TO
REGULATION/DIRECTIVE
OXYGEN NDA EU DSD/DPD:
ANNEX VI, TABLE 3.2 - O; R8
EU CLP:
ANNEX VI, TABLE 3.1 - OX. GAS 1,
H270; PRESS. GAS - COMP., H280
OSHA HCS 2012:
OX. GAS 1; PRESS GAS. - COMP.
PROPANE NDA EU DSD/DPD:
ANNEX VI, TABLE 3.2 - F+; R12
EU CLP:
ANNEX VI, TABLE 3.1 - FLAM. GAS 1,
H220; PRESS. GAS - COMP., H280
OSHA HCS 2012:
FLAM. GAS 1; PRESS. GAS - COMP.;
SIMP. ASPHYX.
CARBON MONOXIDE INHALATION-RAT LC50: EU DSD/DPD:
1807 PPM 4 HOUR(S) ANNEX VI, TABLE 3.2 - F+; R12;
REPR. CAT. 1; R61; T; R23-48/23
EU CLP:
ANNEX VI, TABLE 3.1 - FLAM. GAS 1,
H220; PRESS. GAS - COMP., H280;
REPR. 1A, H360D; ACUTE TOX. 3 *,
H331; STOT RE 1, H372
OSHA HCS 2012:
REPR 1A; ACUTE TOX 3 (INHL); FLAM.
GAS 1; PRESS. GAS - COMP
PENTANE INHALATION-RAT LC50: EU DSD/DPD:
364 G/M3 4 HOUR(S) ANNEX VI, TABLE 3.2 - F+; R12 N;
R51-53 XN; R65 R66 R67
INGESTION/ORAL-RAT
LD50: >2000 MG/KG EU CLP:
ANNEX VI, TABLE 3.1 - FLAM. LIQ.
1, H224; ASP. TOX. 1, H304; STOT
SE 3, H336; AQUATIC CHRONIC 2,
H411; EUH066
OSHA HCS 2012:
FLAM LIQ 1; ASP TOX 1. EYE IRRIT
2A, SKIN IRRIT 2, STOT SE 3: NARC.
HEXANE INGESTION/ORAL-RAT EU DSD/DPD:
LD50: 25 G/KG ANNEX VI, TABLE 3.2 - F; R11;
REPR. 3; R62; XN; R65-48/20; XI;
INHALATION-RAT LC50: R38; R67; N; R51-53
48000 PPM 4 HOUR(S)
EU CLP:
ANNEX VI, TABLE 3.1 - FLAM. LIQ.
2, H225; REPR. 2, H361F; ASP. TOX.
1, H304; STOT RE 2*, H373; SKIN
IRRIT. 2, H315; STOT SE 3:
NARC., H336; AQUATIC CHRONIC 2,
H411
OSHA HCS 2012:
FLAM. LIQ. 2; REPR. 2; STOT RE 2 -
CNS & NERVOUS SYSTEM; SKIN IRRIT.
2; EYE IRRIT. 2B; STOT SE 3:
NARC. & RESP. IRRIT.; ASP. TOX. 1
NITROGEN NDA EU DSD/DPD: NOT CLASSIFIED
EU CLP:
SELF CLASSIFIED - PRESS. GAS -
COMP. H280
OSHA HCS 2012:
PRESS. GAS - COMP.; SIMP. ASPHYX.
SEE SECTION 16 FOR FULL TEXT OF H-STATEMENTS AND R-PHRASES.
| SECTION 4 - FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL
RESPIRATION IF VICTIM IS NOT BREATHING. IF SIGNS/SYMPTOMS CONTINUE, GET
MEDICAL ATTENTION.
SKIN:
ALTHOUGH EXPOSURE IS UNLIKELY, IN CASE OF CONTACT IMMEDIATELY FLUSH SKIN
WITH RUNNING WATER. IF SKIN IRRITATION DEVELOPS GET MEDICAL
ADVICE/ATTENTION.
EYE:
FIRST AID IS NOT EXPECTED TO BE NECESSARY IF MATERIAL IS USED UNDER
ORDINARY CONDITIONS AND AS RECOMMENDED. IF IRRITATION DEVELOPS AND
PERSISTS, GET MEDICAL ATTENTION.
INGESTION: INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED. A
POTENTIAL HEALTH HAZARD ASSOCIATED WITH THIS GAS IS ANOXIA.
4.4 OTHER INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. RESCUERS SHOULD NOT ATTEMPT TO
RETRIEVE VICTIMS OF EXPOSURE TO GASES WITHOUT ADEQUATE PERSONAL PROTECTIVE
EQUIPMENT. AT A MINIMUM, SELF-CONTAINED BREATHING APPARATUS MUST BE WORN.
VICTIM(S) WHO EXPERIENCE ANY ADVERSE EFFECT AFTER OVEREXPOSURE TO THIS GAS
MIXTURE MUST BE TAKEN FOR MEDICAL ATTENTION. RESCUERS SHOULD BE TAKEN FOR
MEDICAL ATTENTION IF NECESSARY. TAKE A COPY OF THE LABEL AND THE MSDS TO
PHYSICIAN OR OTHER HEALTH PROFESSIONAL WITH VICTIM(S).
| SECTION 5 - FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO DATA AVAILABLE
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN HEATED.
RUPTURED CYLINDERS MAY ROCKET.
HAZARDOUS COMBUSTION PRODUCTS: NONE KNOWN.
5.3 ADVICE FOR FIREFIGHTERS:
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING PROVIDES LIMITED PROTECTION IN
FIRE SITUATIONS ONLY; IT IS NOT EFFECTIVE IN SPILL SITUATIONS WHERE DIRECT
CONTACT WITH THE SUBSTANCE IS POSSIBLE.
ALWAYS WEAR THERMAL PROTECTIVE CLOTHING WHEN HANDLING REFRIGERATED/
CRYOGENIC LIQUIDS. WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS (SCBA).
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK.
FIRE:
IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN A FIRE, ISOLATE FOR 800
METERS (1/2 MILE) IN ALL DIRECTIONS; ALSO, CONSIDER INITIAL EVACUATION FOR
800 METERS (1/2 MILE) IN ALL DIRECTIONS.
FIRE INVOLVING TANKS:
FIGHT FIRE FROM MAXIMUM DISTANCE OR USE UNMANNED HOSE HOLDERS OR MONITOR
NOZZLES.
FIRE INVOLVING TANKS:
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS
OUT.
FIRE INVOLVING TANKS:
DO NOT DIRECT WATER AT SOURCE OF LEAK OR SAFETY DEVICES; ICING MAY OCCUR.
FIRE INVOLVING TANKS:
WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICES OR
DISCOLORATION OF TANK.
FIRE INVOLVING TANKS: ALWAYS STAY AWAY FROM TANKS ENGULFED IN FIRE.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING
APPROPRIATE PROTECTIVE CLOTHING. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. VENTILATE THE AREA BEFORE ENTRY.
EMERGENCY PROCEDURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. KEEP UNAUTHORIZED PERSONNEL AWAY.
KEEP OUT OF LOW AREAS. STAY UPWIND. DO NOT DIRECT WATER AT SPILL OR SOURCE
OF LEAK. LARGE SPILL: CONSIDER INITIAL DOWNWIND EVACUATION FOR AT LEAST
500 METERS (1/3 MILE)
6.2 ENVIRONMENTAL PRECAUTIONS:
NO SPECIAL ENVIRONMENTAL PRECAUTIONS NECESSARY.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK.
USE WATER SPRAY TO REDUCE VAPORS; DO NOT PUT WATER DIRECTLY ON LEAK,
SPILL AREA OR INSIDE CONTAINER.
IF POSSIBLE, TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN
LIQUID. ISOLATE AREA UNTIL GAS HAS DISPERSED.
VENTILATE THE AREA.
6.4 REFERENCE TO OTHER SECTIONS:
REFER TO SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION AND SECTION
13 - DISPOSAL CONSIDERATIONS.
| SECTION 7 - HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. VENTILATE CLOSED SPACES BEFORE
ENTERING. BE AWARE OF ANY SIGNS OF DIZZINESS OR FATIGUE, ESPECIALLY IF WORK
IS DONE IN A POORLY VENTILATED AREA; EXPOSURES TO FATAL CONCENTRATIONS OF
THIS GAS MIXTURE COULD OCCUR WITHOUT ANY SIGNIFICANT WARNING SYMPTOMS, DUE
TO OLFACTORY FATIGUE OR OXYGEN DEFICIENCY. CYLINDERS SHOULD BE FIRMLY
SECURED TO PREVENT FALLING OR BEING KNOCKED-OVER. DO NOT ATTEMPT TO REPAIR,
ADJUST, OR IN ANY OTHER WAY MODIFY CYLINDERS. IF THERE IS A MALFUNCTION OR
ANOTHER TYPE OF OPERATIONAL PROBLEM, CONTACT NEAREST DISTRIBUTOR
IMMEDIATELY. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
DO NOT CUT, WELD, PUNCTURE OR INCINERATE CONTAINER.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
STORE IN A COOL, DRY, WELL-VENTILATED PLACE. PROTECT CYLINDERS AGAINST
PHYSICAL DAMAGE. CYLINDERS SHOULD BE FIRMLY SECURED TO PREVENT FALLING OR
BEING KNOCKED-OVER.
7.3 SPECIFIC END USE(S): REFER TO SECTION 1.2 - RELEVANT IDENTIFIED USES.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
EXPOSURE LIMITS/GUIDELINES:
RESULT ACGIH CANADA ONTARIO CANADA QUEBEC
PENTANE STELS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
(109-66-0)
TWAS 600 PPM TWA 600 PPM TWA 120 PPRR TWAEV
(LISTED UNDER 350 MG/M3 TWAEV
PENTANE, ALL
ISOMERS)
HEXANE STELS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
(110-54-3)
TWAS 50 PPM TWA 50 PPM TWA 50 PPM TWAEV
176 MG/M3 TWAEV
PROPANE TWAS 1000 PPM TWA 1000 PPM TWA 1000 PPM TWAEV
(74-98-6) (LISTED UNDER
ALIPHATIC 1800 MG/M3
HYDROCARBON TWAEV
GASES: ALKANE
C1-4)
CARBON CEILINGS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
MONOXIDE
(630-08-0) STELS NOT ESTABLISHED NOT ESTABLISHED 200 PPM STEV
230 MG/M3 STEV
TWAS 25 PPM TWA 25 PPM TWA 35 PPM TWAEV
40 MG/M3 TWAEV
RESULT CHINA CHINA HIGHLY TOXIC GOODS
PENTANE STELS 1000 MG/M3 STEL NOT ESTABLISHED
(LISTED UNDER
PENTANE (ALL
ISOMERS))
TWAS 500 MG/M3 TWA NOT ESTABLISHED
(LISTED UNDER
PENTANE (ALL
ISOMERS))
HEXANE STELS 180 MG/M3 STEL NOT ESTABLISHED
TWAS 100 MG/M3 TWA NOT ESTABLISHED
PROPANE TWAS NOT ESTABLISHED NOT ESTABLISHED
CARBON CEILINGS 20 MG/M3 CEILING NOT ESTABLISHED
MONOXIDE [MAC] (HIGH
ALTITUDE AREA,
2000-3000M)
15 MG/M3 CEILING
[MAC] (HIGH
ALTITUDE AREA,
>3000M)
STELS 30 MG/M3 STEL (NOT 30 MG/M3 STEL (NOT
IN HIGH ALTITUDE IN HIGH ALTITUDE AREA)
AREA)
TWAS 20 MG/M3 TWA (NOT 20 MG/M3 TWA (NOT
IN HIGH ALTITUDE IN HIGH ALTITUDE AREA)
AREA)
RESULT EUROPE FRANCE GERMANY DFG
PENTANE TWAS 1000 PPM TWA 1000 PPM TWA NOT ESTABLISHED
(109-66-0) 3000 MG/M3 TWA [VME]
(RESTRICTIVE
LIMIT)
3000 MG/M3 TWA
[VME]
(RESTRICTIVE
LIMIT)
STELS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 2000 PPM PEAK
(LISTED UNDER
PENTANE)
6000 MG/M3 PEAK
(LISTED UNDER
PENTANE)
MAKS NOT ESTABLISHED NOT ESTABLISHED 1000 PPM TWA
MAK
3000 MG/M3 TWA
MAK
HEXANE TWAS 20 PPM TWA 20 PPM TWA NOT ESTABLISHED
(110-54-3) 72 MG/M3 TWA [VME]
(RESTRICTIVE
LIMIT)
72 MG/M3 TWA
[VME]
(RESTRICTIVE
LIMIT)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 400 PPM PEAK
1440 MG/M3 PEAK
MAKS NOT ESTABLISHED NOT ESTABLISHED 50 PPM TWA MAK
180 MG/M3 TWA
MAK
PROPANE TWAS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
(74-98-6)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 4000 PPM PEAK
7200 MG/M3 PEAK
MAKS NOT ESTABLISHED NOT ESTABLISHED 1000 PPM TWA
MAK
1800 MG/M3 TWA
MAK
CARBON TWAS NOT ESTABLISHED 50 PPM TWA NOT ESTABLISHED
MONOXIDE [VME]
(630-08-0)
55 MG/M3 TWA
[VME]
STELS NOT ESTABLISHED NOT ESTABLISHED NOT ESTABLISHED
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 60 PPM PEAK
70 MG/M3 PEAK
MAKS NOT ESTABLISHED NOT ESTABLISHED 30 PPM TWA MAK
35 MG/M3 TWA
MAK
RESULT GERMANY TRGS IRELAND
PENTANE TWAS 1000 PPM TWA AGW 1000 PPM TWA
(THE RISK OF DAMAGE 3000 MG/M3 TWA
TO THE EMBRYO OR
FETUS CAN BE
EXCLUDED WHEN AGW
AND BGW VALUES ARE
OBSERVED, EXPOSURE
FACTOR 2)
3000 MG/M3 TWA AGW
(THE RISK OF DAMAGE
TO THE EMBRYO OR
FETUS CAN BE
EXCLUDED WHEN AGW
AND BGW VALUES ARE
OBSERVED, EXPOSURE
FACTOR 2)
STELS NOT ESTABLISHED 750 PPM STEL
2250 MG/M3 STEL
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
HEXANE TWAS 50 PPM TWA AGW 20 PPM TWA
(EXPOSURE FACTOR 8) 72 MG/M3 TWA
180 MG/M3 TWA
AGW (EXPOSURE
FACTOR 8)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
PROPANE TWAS 1000 PPM TWA AGW 1000 PPM TWA
(EXPOSURE FACTOR 4)
1800 MG/M3 TWA
AGW (EXPOSURE FACTOR 4)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
CARBON TWAS 30 PPM TWA AGW 20 PPM TWA
MONOXIDE (THE RISK OF DAMAGE 23 MG/M3 TWA
TO THE EMBRYO OR
FETUS CANNOT BE
EXCLUDED EVEN WHEN
AGW AND BGW
VALUES ARE OBSERVED,
EXPOSURE FACTOR 2)
35 MG/M3 TWA AGW
(THE RISK OF DAMAGE
TO THE EMBRYO OR
FETUS CANNOT BE
EXCLUDED EVEN WHEN
AGW AND BGW
VALUES ARE OBSERVED,
EXPOSURE FACTOR 2)
STELS NOT ESTABLISHED 100 PPM STEL
115 MG/M3 STEL
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
MAKS NOT ESTABLISHED NOT ESTABLISHED
RESULT ISRAEL ITALY NIOSH
PENTANE TWAS 600 PPM TWA 667 PPM TWA 120 PPM TWA
(109-66-0) (LISTED UNDER 2000 MG/M3 TWA 350 MG/M3 TWA
PENTANE, ALL
ISOMERS)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 610 PPM CEILING
(15 MIN)
1800 MG/M3
CEILING
(15 MIN)
HEXANE TWAS 50 PPM TWA 20 PPM TWA 50 PPM TWA
(110-54-3) 72 MG/M3 TWA 180 MG/M3 TWA
PROPANE TWAS 1000 PPM TWA NOT ESTABLISHED 1000 PPM TWA
(74-98-6) (GAS) 1800 MG/M3 TWA
CARBON TWAS 25 PPM TWA NOT ESTABLISHED 35 PPM TWA
MONOXIDE 40 MG/M3 TWA
(630-08-0)
CEILINGS NOT ESTABLISHED NOT ESTABLISHED 200 PPM CEILING
229 MG/M3
CEILING
RESULT OSHA PORTUGAL
PENTANE TWAS 1000 PPM TWA 600 PPM TWA [VLE-MP]
2950 MG/M3 TWA
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
HEXANE TWAS 500 PPM TWA 50 PPM TWA [VLE-MP]
1800 MG/M3 TWA
PROPANE TWAS 1000 PPM TWA 1000 PPM TWA [VLE-MP]
1800 MG/M3 TWA
CARBON TWAS 50 PPM TWA 25 PPM TWA [VLE-MP]
MONOXIDE 55 MG/M3 TWA
CEILINGS NOT ESTABLISHED NOT ESTABLISHED
RESULT SPAIN SWEDEN
PENTANE TWAS 1000 PPM TWA [VLA-ED] 600 PPM LLV
(109-66-0) (INDICATIVE LIMIT VALUE) 1800 MG/M3 LLV
3000 MG/M3 TWA [VLA-ED]
(INDICATIVE LIMIT VALUE)
STELS NOT ESTABLISHED 750 PPM STV
2000 MG/M3 STV
HEXANE TWAS 20 PPM TWA [VLA-ED] 25 PPM LLV
(110-54-3) (INDICATIVE LIMIT VALUE) 90 MG/M3 LLV
72 MG/M3 TWA [VLA-ED]
(INDICATIVE LIMIT VALUE)
UNDER 0.2 MG/L MEDIUM: URINE NOT ESTABLISHED
REVIEW
TIME:
END OF WORKWEEK
PARAMETER:
2,5-HEXANEDIONE
(WITHOUT HYDROLYSIS;
MEANS FREE 2,5-
HEXANEDIONE,
UNCONJUGATED. THIS
SUBSTANCE IS A
METABOLITE OF N-HEXANE
AND METHYL-N-BUTYL
KETONE IT MEANS AFTER
FOUR OR FIVE
CONSECUTIVE DAYS OF
WORK WITH EXPOSURE,
AS SOON AS POSSIBLE
AFTER THE END OF THE
LAST WORKING DAY, AS
BIOLOGICAL INDICATORS
ARE ELIMINATED WITH
HALF-LIVES GREATER THAN
FIVE HOURS; THESE
INDICATORS ACCUMULATE
IN THE BODY DURING THE
WORK WEEK, THEREFORE
THE SAMPLING TIME IS
CRITICAL IN RELATION
TO PREVIOUS
EXPOSURES.)
BIOLOGICAL 0.4 MG/L URINE END OF NOT ESTABLISHED
LIMIT WORKWEEK 2,5-
VALUES HEXANEDIONE (WITHOUT
(BLV) HYDROLYSIS) (1,8)
STELS NOT ESTABLISHED 50 PPM STV
180 MG/M3 STV
PROPANE TWAS 1000 PPM TWA [VLA-ED] NOT ESTABLISHED
(74-98-6)
CARBON TWAS 25 PPM TWA [VLA-ED] 20 PPM LLV (REGULATED
MONOXIDE 29 MG/M3 TWA [VLA-ED] UNDER EXHAUST FUMES,
(630-08-0) LISTED UNDER EXHAUST
FUMES)
25 MG/M3 LLV
(REGULATED UNDER
EXHAUST FUMES, LISTED
UNDER EXHAUST FUMES)
35 PPM LLV
40 MG/M3 LLV
BIOLOGICAL 3.5% OF CARBOXYHEMOGLOBIN NOT ESTABLISHED
LIMIT IN TOTAL HEMOGLOBIN BLOOD
VALUES END OF SHIFT
(BLV) CARBOXYHEMOGLOBIN
(2,F,I)
20 PPM ALVEOLAR AIR
END OF SHIFT CO END-
CUT OF EXHALED AIR
(2,F,I)
STELS NOT ESTABLISHED 100 PPM STV
120 MG/M3 STV
EXPOSURE CONTROL NOTATIONS:
PORTUGAL:
HEXANE (110-54-3):
SKIN: (SKIN - POTENTIAL FOR CUTANEOUS EXPOSURE)
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (SIMPLE ASPHYXIANT)
FRANCE:
HEXANE (110-54-3):
REPRODUCTIVE TOXINS: (REPRODUCTIVE TOXIN CATEGORY 3)
CARBON MONOXIDE (630-08-0):
REPRODUCTIVE TOXINS: (REPRODUCTIVE TOXIN CATEGORY 1)
IRELAND:
CARBON MONOXIDE (630-08-0):
SUBSTANCES WITH POTENTIAL CHRONIC HEALTH EFFECTS: (REPR 1A)
PROPANE (74-98-6):
SIMPLE ASPHYXIANTS: (ASPHYXIANT)
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (ASPHYXIANT)
SPAIN:
CARBON MONOXIDE (630-08-0):
REPRODUCTIVE TOXINS:
(KNOWN REPRODUCTIVE TOXINS WITH CLASSIFICATION FROM HUMAN DATA)
NITROGEN (7727-37-9):
SIMPLE ASPHYXIANTS: (SIMPLE ASPHYXIANT)
SWEDEN:
CARBON MONOXIDE (630-08-0):
REPRODUCTIVE TOXINS: (CAUSES REPRODUCTIVE DISTURBANCES)
GERMANY DFG:
HEXANE (110-54-3):
PREGNANCY: (NO RISK TO EMBRYO/FETUS IF EXPOSURE LIMITS ADHERED TO)
PENTANE (109-66-0):
PREGNANCY: (NO RISK TO EMBRYO/FETUS IF EXPOSURE LIMITS ADHERED TO)
CARBON MONOXIDE (630-08-0):
PREGNANCY: (RISK TO EMBRYO/FETUS PROBABLE)
PROPANE (74-98-6):
PREGNANCY: (CLASSIFICATION NOT YET POSSIBLE)
8.2 EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS
BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN
ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN
STANDARD EN 149. USE A NIOSH/MSHA OR EUROPEAN STANDARD EN 149 APPROVED
RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS ARE EXPERIENCED.
EYE/FACE: WEAR SAFETY GLASSES.
SKIN/BODY: WEAR LEATHER GLOVES WHEN HANDLING CYLINDERS.
ENVIRONMENTAL EXPOSURE CONTROLS:
FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF WASTE. CONTROLS
SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT, INCLUDING
PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO WATERWAYS.
KEY TO ABBREVIATIONS:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
LLV: LIMIT LEVEL VALUE IS THE EXPOSURE LIMIT FOR 8-HOUR WORK DAY
MAK:
MAXIMALE ARBEITSPLATZ KONZENTRATION IS THE MAXIMUM PERMISSIBLE
CONCENTRATION
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
STEL: SHORT TERM EXPOSURE LIMITS ARE BASED ON 15-MINUTE EXPOSURES
STEV: SHORT TERM EXPOSURE VALUE
TWAEV: TIME-WEIGHTED AVERAGE EXPOSURE VALUE
TWA: TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: GAS
APPEARANCE/DESCRIPTION:
COLORLESS GAS WITH NO ODOR OR A FAINT, SOLVENT-LIKE ODOR.
COLOR: COLORLESS
ODOR: ODORLESS OR FAINT, SOLVENT-LIKE ODOR.
ODOR THRESHOLD: DATA LACKING
GENERAL PROPERTIES:
BOILING POINT: -195.8 C (-320.44 F) (NITROGEN)
MELTING POINT: -210 C (-346 F) (NITROGEN)
DECOMPOSITION TEMPERATURE: DATA LACKING
PH: DATA LACKING
SPECIFIC GRAVITY/RELATIVE DENSITY: 0.906 WATER = 1 (NITROGEN)
WATER SOLUBILITY: DATA LACKING
VISCOSITY: DATA LACKING
EXPLOSIVE PROPERTIES: DATA LACKING
OXIDIZING PROPERTIES: DATA LACKING
VOLATILITY:
VAPOR PRESSURE: DATA LACKING
VAPOR DENSITY: DATA LACKING
EVAPORATION RATE: DATA LACKING
FLAMMABILITY:
FLASH POINT: DATA LACKING
UEL: DATA LACKING
LEL: DATA LACKING
AUTOIGNITION: DATA LACKING
FLAMMABILITY (SOLID, GAS): DATA LACKING
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: DATA LACKING
9.2 OTHER INFORMATION:
NO ADDITIONAL PHYSICAL AND CHEMICAL PARAMETERS NOTED.
| SECTION 10 - STABILITY AND REACTIVITY | |
10.1 REACTIVITY:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.2 CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4 CONDITIONS TO AVOID: EXCESS HEAT.
10.5 INCOMPATIBLE MATERIALS:
NITROGEN REACTS WITH Li, Nd, AND Ti AT HIGH TEMPERATURES.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS: NO DATA AVAILABLE
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
COMPONENTS:
HEXANE (0% TO 0.48%) 110-54-3:
ACUTE TOXICITY:
INGESTION/ORAL-RAT LD50: 25 G/KG
INHALATION-RAT LC50: 48000 PPM 4 HOUR(S)
IRRITATION:
EYE-RABBIT: 10 MG MILD IRRITATION
REPRODUCTIVE:
INHALATION-RAT TCLO: 5000 PPM 20 HOUR(S)(6-19D PREG)
REPRODUCTIVE EFFECTS:
EFFECTS ON EMBRYO OR FETUS:
FETOTOXICITY (EXCEPT DEATH, E.G., STUNTED FETUS)
PENTANE (0% TO 0.75%) 109-66-0:
ACUTE TOXICITY:
INGESTION/ORAL-RAT LD50: >2000 MG/KG
INHALATION-RAT LC50: 364 G/M3 4 HOUR(S)
CARBON MONOXIDE (0.0005% TO 1%) 630-08-0:
ACUTE TOXICITY:
INHALATION-RAT LC50: 1807 PPM 4 HOUR(S)
REPRODUCTIVE:
INHALATION-RAT TCLO: 150 PPM (0-20D PREG)
REPRODUCTIVE EFFECTS:
MATERNAL EFFECTS: OTHER EFFECTS
REPRODUCTIVE EFFECTS:
EFFECTS ON NEWBORN: BIOCHEMICAL AND METABOLIC
REPRODUCTIVE EFFECTS:
EFFECTS ON NEWBORN: PHYSICAL
OXYGEN (0.0015% TO 23.5%) 7782-44-7:
REPRODUCTIVE:
INHALATION-RAT TCLO: 10 PPH 9 HOUR(S)(22D PREG)
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES: RESPIRATORY SYSTEM
REPRODUCTIVE EFFECTS:
EFFECTS ON NEWBORN: PHYSICAL
GHS PROPERTIES CLASSIFICATION
ACUTE TOXICITY EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
ASPIRATION HAZARD EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
CARCINOGENICITY EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
GERM CELL MUTAGENICITY EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
SKIN CORROSION/IRRITATION EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
SKIN SENSITIZATION EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
STOT RE EU/CLP:
SPECIFIC TARGET ORGAN TOXICITY REPEATED
EXPOSURE 2
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
STOT-SE EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
TOXICITY FOR REPRODUCTION EU/CLP:
H360D:
MAY DAMAGE THE UNBORN CHILD; TOXIC TO
REPRODUCTION 1A
OSHA HCS 2012: TOXIC TO REPRODUCTION 1A
RESPIRATORY SENSITIZATION EU/CLP: CLASSIFICATION CRITERIA NOT MET
OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
SERIOUS EYE DAMAGE/ EU/CLP: CLASSIFICATION CRITERIA NOT MET
IRRITATION OSHA HCS 2012: CLASSIFICATION CRITERIA NOT MET
ROUTE(S) OF ENTRY/EXPOSURE: INHALATION, SKIN, EYE
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE):
INHALATION OF CARBON DIOXIDE CAN INCREASE RESPIRATION AND HEART RATE. IF
THIS MATERIAL IS RELEASED IN A SMALL, POORLY VENTILATED AREA (I.E. AN
ENCLOSED OR CONFINED SPACE), AN OXYGEN-DEFICIENT ENVIRONMENT MAY OCCUR.
INDIVIDUALS BREATHING SUCH AN ATMOSPHERE MAY EXPERIENCE SYMPTOMS WHICH
INCLUDE HEADACHES, RINGING IN EARS, DIZZINESS, DROWSINESS, UNCONSCIOUSNESS,
NAUSEA, VOMITING, AND DEPRESSION OF ALL THE SENSES. UNDER SOME
CIRCUMSTANCES OF OVER-EXPOSURE, DEATH MAY OCCUR. THE FOLLOWING EFFECTS
ASSOCIATED WITH DECREASED LEVELS OF OXYGEN:
INCREASE IN BREATHING AND PULSE RATE, EMOTIONAL UPSET, ABNORMAL FATIGUE,
NAUSEA, VOMITING, COLLAPSE, LOSS OF CONSCIOUSNESS, CONVULSIVE MOVEMENTS,
RESPIRATORY COLLAPSE AND DEATH. INHALATION OVER-EXPOSURES TO ATMOSPHERES
CONTAINING MORE THAN THE THRESHOLD LIMIT VALUE OF CARBON MONOXIDE (25 PPM),
ANOTHER COMPONENT OF THIS GAS MIXTURE, CAN RESULT IN SERIOUS HEALTH
CONSEQUENCES. CARBON MONOXIDE IS CLASSIFIED AS A CHEMICAL ASPHYXIANT,
PRODUCING A TOXIC ACTION BY COMBINING WITH THE HEMOGLOBIN OF THE BLOOD AND
REPLACING THE AVAILABLE OXYGEN. THROUGH THIS REPLACEMENT, THE BODY IS
DEPRIVED OF THE REQUIRED OXYGEN, AND ASPHYXIATION OCCURS. SINCE THE
AFFINITY OF CARBON MONOXIDE FOR HEMOGLOBIN IS ABOUT 200-300 TIMES THAT OF
OXYGEN, ONLY A SMALL AMOUNT OF CARBON MONOXIDE WILL CAUSE A TOXIC REACTION
TO OCCUR. CARBON MONOXIDE EXPOSURES IN EXCESS OF 50 PPM WILL PRODUCE
SYMPTOMS OF POISONING IF BREATHED FOR A SUFFICIENTLY LONG TIME. IF THIS GAS
MIXTURE IS RELEASED IN A SMALL, POORLY VENTILATED AREA (I.E. AN ENCLOSED OR
CONFINED SPACE), SYMPTOMS WHICH MAY DEVELOP INCLUDE THE FOLLOWING:
BRIGHT RED LIPS AND FINGERNAILS, HEADACHE PROGESSING TO HEART PALPITATIONS,
STAGGERING, CONFUSION, NAUSEA, DIZZINESS AND UNCONSCIOUSNESS WITH HIGHER
CONCENTRATION EXPOSURES. FOR EXPOSURES GREATER THAN 2500 PPM THERE IS
POTENTIAL FOR COLLAPSE AND DEATH BEFORE WARNING SYMPTOMS ARE EXPERIENCED.
CHRONIC (DELAYED): NO DATA AVAILABLE
SKIN:
ACUTE (IMMEDIATE):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
CHRONIC (DELAYED):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
EYE:
ACUTE (IMMEDIATE):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
CHRONIC (DELAYED):
UNDER NORMAL CONDITIONS OF USE, NO HEALTH EFFECTS ARE EXPECTED.
INGESTION:
ACUTE (IMMEDIATE):
INGESTION IS NOT ANTICIPATED TO BE A LIKELY ROUTE OF EXPOSURE TO THIS
PRODUCT.
CHRONIC (DELAYED):
INGESTION IS NOT ANTICIPATED TO BE A LIKELY ROUTE OF EXPOSURE TO THIS
PRODUCT.
OTHER:
CHRONIC (DELAYED):
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENIC EFFECTS:
THE COMPONENTS OF THIS MATERIAL ARE NOT FOUND ON THE FOLLOWING LISTS:
FEDERAL OSHA Z LIST, NTP AND IARC; THEREFORE, THEY ARE NOT CONSIDERED
TO BE, NOR SUSPECTED TO BE, CANCER-CAUSING AGENTS BY THESE AGENCIES.
REPRODUCTIVE EFFECTS:
THE CARBON MONOXIDE COMPONENT OF THIS GAS MIXTURE CAN CAUSE TERATOGENIC
EFFECTS IN HUMANS. SEVERE EXPOSURE TO CARBON MONOXIDE DURING PREGNANCY HAS
CAUSED ADVERSE EFFECTS AND THE DEATH OF THE FETUS. IN GENERAL, MATERNAL
SYMPTOMS ARE AN INDICATOR OF THE POTENTIAL RISK TO THE FETUS SINCE CARBON
MONOXIDE IS TOXIC TO THE MOTHER BEFORE IT IS TOXIC TO THE FETUS.
| SECTION 12 - ECOLOGICAL INFORMATION | |
12.1 TOXICITY: MATERIAL DATA LACKING.
12.2 PERSISTENCE AND DEGRADABILITY: MATERIAL DATA LACKING.
12.3 BIOACCUMULATIVE POTENTIAL: MATERIAL DATA LACKING.
12.4 MOBILITY IN SOIL: MATERIAL DATA LACKING.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT AND VPVB ASSESSMENT HAS NOT BEEN CONDUCTED FOR THIS MATERIAL.
12.6 OTHER ADVERSE EFFECTS: NO STUDIES HAVE BEEN FOUND.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
14.1 UN 14.2 UN PROPER 14.3 TRANSPORT 14.4 14.5
NUMBER SHIPPING NAME HAZARD PACKING ENVIRONMENTAL
CLASS(ES) GROUP HAZARDS
DOT UN1956 COMPRESSED GAS, 2.2 NDA NDA
N.O.S. (*OXYGEN,
NITROGEN)* OR
THE GAS
COMPONENT WITH
THE NEXT
HIGHEST
CONCENTRATION
NEXT TO
NITROGEN.
TDG UN1956 COMPRESSED GAS, 2.2 NDA POTENTIAL
N.O.S. (*OXYGEN, MARINE
NITROGEN)* OR POLLUTANT
THE GAS
COMPONENT WITH
THE NEXT HIGHEST
CONCENTRATION
NEXT TO
NITROGEN.
IMO/ UN1956 COMPRESSED GAS, 2.2 NDA NDA
IMDG FLAMMABLE,
N.O.S. (*OXYGEN,
NITROGEN)* OR
THE GAS
COMPONENT WITH
THE NEXT HIGHEST
CONCENTRATION
NEXT TO
NITROGEN.
IATA/ UN1956 COMPRESSED GAS, 2.2 NDA NDA
ICAO N.O.S. (*OXYGEN,
NITROGEN)* OR
THE GAS
COMPONENT WITH
THE NEXT HIGHEST
CONCENTRATION
NEXT TO
NITROGEN.
14.6 SPECIAL PRECAUTIONS FOR USER:
CYLINDERS SHOULD BE TRANSPORTED IN A SECURE POSITION, IN A WELL-VENTILATED
VEHICLE. THE TRANSPORTATION OF COMPRESSED GAS CYLINDERS IN AUTOMOBILES OR
IN CLOSED-BODY VEHICLES CAN PRESENT SERIOUS SAFETY HAZARDS. IF TRANSPORTING
THESE CYLINDERS IN VEHICLES, ENSURE THESE CYLINDERS ARE NOT EXPOSED TO
EXTREMELY HIGH TEMPERATURES (AS MAY OCCUR IN AN ENCLOSED VEHICLE ON A HOT
DAY). ADDITIONALLY, THE VEHICLE SHOULD BE WELL-VENTILATED DURING
TRANSPORTATION.
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: NOT RELEVANT.
| SECTION 15 - REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: PRESSURE(SUDDEN RELEASE OF), ACUTE, CHRONIC
STATE RIGHT TO KNOW:
COMPONENT CAS MA NJ PA
CARBON MONOXIDE 630-08-0 YES YES YES
HEXANE 110-54-3 YES YES YES
NITROGEN 7727-37-9 YES YES YES
OXYGEN 7782-44-7 YES YES YES
PENTANE 109-66-0 YES YES YES
PROPANE 74-98-6 YES YES YES
INVENTORY:
COMPONENT CAS CANADA CANADA CHINA EU EINECS EU ELNICS
DSL NDSL
CARBON MONOXIDE 630-08-0 YES NO YES YES NO
HEXANE 110-54-3 YES NO YES YES NO
NITROGEN 7727-37-9 YES NO YES YES NO
OXYGEN 7782-44-7 YES NO YES YES NO
PENTANE 109-66-0 YES NO YES YES NO
PROPANE 74-98-6 YES NO YES YES NO
COMPONENT CAS TSCA
CARBON MONOXIDE 630-08-0 YES
HEXANE 110-54-3 YES
NITROGEN 7727-37-9 YES
OXYGEN 7782-44-7 YES
PENTANE 109-66-0 YES
PROPANE 74-98-6 YES
CANADA:
LABOR:
CANADA - WHMIS - CLASSIFICATIONS OF SUBSTANCES:
CARBON MONOXIDE 630-08-0 A, B1, D1A, D2A
PENTANE 109-66-0 B2
OXYGEN 7782-44-7 A, C
PROPANE 74-98-6 A, B1
HEXANE 110-54-3 B2, D2A, D2B
NITROGEN 7727-37-9 A
CANADA - WHMIS - INGREDIENT DISCLOSURE LIST:
CARBON MONOXIDE 630-08-0 0.1%
PENTANE 109-66-0 1%
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 1%
NITROGEN 7727-37-9 NOT LISTED
ENVIRONMENT:
CANADA - 2004 NPRI (NATIONAL POLLUTANT RELEASE INVENTORY):
CARBON MONOXIDE 630-08-0 PART 4 SUBSTANCE
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 PART 5 SUBSTANCE
HEXANE 110-54-3 PART 1, GROUP 1
SUBSTANCE
PART 5 SUBSTANCE
NITROGEN 7727-37-9 NOT LISTED
CANADA - 2005 NPRI (NATIONAL POLLUTANT RELEASE INVENTORY):
CARBON MONOXIDE 630-08-0 PART 4 SUBSTANCE
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 PART 5 SUBSTANCE
HEXANE 110-54-3 PART 1, GROUP 1
SUBSTANCE
PART 5 SUBSTANCE
NITROGEN 7727-37-9 NOT LISTED
CANADA - CEPA - GREENHOUSE GASES SUBJECT TO MANDATORY REPORTING:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CANADA - CEPA - PRIORITY SUBSTANCES LIST:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CANADA - DWQ (DRINKING WATER QUALITY) - IMACS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
CANADA - ACCELERATED REDUCTION/ELIMINATION OF TOXICS (ARET):
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CANADA NEW BRUNSWICK:
ENVIRONMENT:
CANADA - NEW BRUNSWICK - OZONE DEPLETING SUBSTANCES - SCHEDULE A:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CANADA - NEW BRUNSWICK - OZONE DEPLETING SUBSTANCES - SCHEDULE B:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA:
ENVIRONMENT:
CHINA - OZONE DEPLETING SUBSTANCES - FIRST SCHEDULE:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - OZONE DEPLETING SUBSTANCES - SECOND SCHEDULE:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - OZONE DEPLETING SUBSTANCES - THIRD SCHEDULE:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
CHINA - ANNEX I & II - CONTROLLED CHEMICALS LISTS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
CHINA - DANGEROUS GOODS LIST:
CARBON MONOXIDE 630-08-0
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 (COMPRESSED OR
REFRIGERATED LIQUID)
PROPANE 74-98-6
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 (COMPRESSED OR
REFRIGERATED LIQUID)
CHINA - EXPORT CONTROL LIST - PART I CHEMICALS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
EUROPE:
OTHER:
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - CLASSIFICATION:
CARBON MONOXIDE 630-08-0 F+; R12 T; R23-48/23
REPR. CAT. 1; R61
PENTANE 109-66-0 F+; R12 N; R51-53 XN;
R65 R66 R67
OXYGEN 7782-44-7 O; R8
PROPANE 74-98-6 F+; R12
HEXANE 110-54-3 F; R11 XI; R38 N; R51-53
REPR. CAT. 3; R62 XN;
R65-48/20 R67
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - CONCENTRATION LIMITS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 5%<=C: XN; R:48/20
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - LABELLING:
CARBON MONOXIDE 630-08-0 F+ T R:61-12-23-48/23
S:53-45
PENTANE 109-66-0 F+ XN N R:12-51/53-
65-66-67
S:(2)-9-16-29-33-61-62
OXYGEN 7782-44-7 O R:8 S:(2)-17
PROPANE 74-98-6 F+ R:12 S:(2)-9-16
HEXANE 110-54-3 F XN N R:11-38-48/20-
62-65-67-51/53
S:(2)-9-16-29-33-
36/37-61-62
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - NOTES - SUBSTANCES AND
PREPARATIONS:
CARBON MONOXIDE 630-08-0 E
PENTANE 109-66-0 C
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
EU - CLP (1272/2008) - ANNEX VI - TABLE 3.2 - SAFETY PHRASES:
CARBON MONOXIDE 630-08-0 S:53-45
PENTANE 109-66-0 S:(2)-9-16-29-33-61-62
OXYGEN 7782-44-7 S:(2)-17
PROPANE 74-98-6 S:(2)-9-16
HEXANE 110-54-3 S:(2)-9-16-29-
33-36/37-61-62
NITROGEN 7727-37-9 NOT LISTED
GERMANY:
ENVIRONMENT:
GERMANY - TA LUFT - TYPES AND CLASSES:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 1:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 ID NUMBER 743, NOT
CONSIDERED HAZARDOUS
TO WATER
PROPANE 74-98-6 ID NUMBER 560, NOT
CONSIDERED HAZARDOUS
TO WATER
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 ID NUMBER 1351, NOT
CONSIDERED HAZARDOUS
TO WATER
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 2 - WATER HAZARD CLASSES:
CARBON MONOXIDE 630-08-0 ID NUMBER 257, HAZARD
CLASS 1 - LOW HAZARD TO
WATERS
PENTANE 109-66-0 ID NUMBER 452, HAZARD
CLASS 2 - HAZARD TO
WATERS
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 ID NUMBER 124, HAZARD
CLASS 2 - HAZARD TO
WATERS
NITROGEN 7727-37-9 NOT LISTED
GERMANY - WATER CLASSIFICATION (VWVWS) - ANNEX 3:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
GERMANY - SPECIFICALLY REGULATED CHEMICALS IN TRGS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
PORTUGAL:
OTHER:
PORTUGAL - PROHIBITED SUBSTANCES:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED KINGDOM:
ENVIRONMENT:
UNITED KINGDOM - POLLUTION INVENTORY - SCHEDULE 1 - THRESHOLDS FOR RELEASES
TO AIR:
CARBON MONOXIDE 630-08-0 100000 KG
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED KINGDOM - SUBSTANCES CONTAINED IN DANGEROUS SUBSTANCES OR
PREPARATIONS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
OTHER:
UNITED KINGDOM - WORKPLACE EXPOSURE LIMITS (WELS) - SUBSTANCES IN REVIEW:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED KINGDOM - LIST OF DANGEROUS SUBSTANCES IN WATER:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 5000 LB FINAL RQ
2270 KG FINAL RQ
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - RADIONUCLIDES AND THEIR REPORTABLE QUANTITIES:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 1.0% DE MINIMIS
CONCENTRATION
NITROGEN 7727-37-9 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES - CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
CARBON MONOXIDE 630-08-0 DEVELOPMENTAL TOXICITY,
INITIAL DATE 7/1/89
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
UNITED STATES - PENNSYLVANIA:
LABOR:
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST:
CARBON MONOXIDE 630-08-0
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - SPECIAL HAZARDOUS SUBSTANCES:
CARBON MONOXIDE 630-08-0 NOT LISTED
PENTANE 109-66-0 NOT LISTED
OXYGEN 7782-44-7 NOT LISTED
PROPANE 74-98-6 NOT LISTED
HEXANE 110-54-3 NOT LISTED
NITROGEN 7727-37-9 NOT LISTED
15.2 CHEMICAL SAFETY ASSESSMENT:
NO CHEMICAL SAFETY ASSESSMENT HAS BEEN CARRIED OUT.
15.3 OTHER INFORMATION:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
RELEVANT PHRASES (CODE & FULL TEXT):
H220: EXTREMELY FLAMMABLE GAS
H224: EXTREMELY FLAMMABLE LIQUID AND VAPOUR
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDIZER
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H315: CAUSES SKIN IRRITATION
H331: TOXIC IF INHALED
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H361F: SUSPECTED OF DAMAGING FERTILITY.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
R8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
R11: HIGHLY FLAMMABLE.
R12: EXTREMELY FLAMMABLE.
R23: TOXIC BY INHALATION.
R38: IRRITATING TO SKIN.
R48/23:
TOXIC:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
R51: TOXIC TO AQUATIC ORGANISMS.
R53: MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
R62: POSSIBLE RISK OF IMPAIRED FERTILITY.
R65:
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
R66: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
R67: VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
LAST REVISION DATE: 15/OCTOBER/2014
PREPARATION DATE: 15/OCTOBER/2014
DISCLAIMER/STATEMENT OF LIABILITY:
TO THE BEST OF AIR LIQUIDE'S KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS
RELIABLE AND ACCURATE AS OF THIS DATE; HOWEVER, ACCURACY, SUITABILITY OR
COMPLETENESS ARE NOT GUARANTEED AND NO WARRANTIES OF ANY TYPE, EITHER
EXPRESS OR IMPLIED, ARE PROVIDED. THE INFORMATION CONTAINED HEREIN RELATES
ONLY TO THIS SPECIFIC PRODUCT. IF THIS GAS MIXTURE IS COMBINED WITH OTHER
MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED. DATA MAY BE CHANGED
FROM TIME TO TIME. BE SURE TO CONSULT THE LATEST EDITION.
KEY TO ABBREVIATIONS:
NDA = NO DATA AVAILABLE
REVISION DATE: 15/OCTOBER/2014
FORMAT: EU CLP/REACH
LANGUAGE: ENGLISH (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
P/N: 3473