| Common Name: | PTG-4003 |
| Manufacturer: | PRAXAIR |
| SDS Revision Date: | 7/1/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 36LR49, 49WN11, 60JJ80 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PORTAGAS
BY PRAXAIR
PTG-4003
SAFETY DATA SHEET
PTG-4003
ACCORDING TO U.S. CODE OF FEDERAL REGULATIONS 29 CFR 1910.1200, HAZARD
COMMUNICATION.
DATE OF ISSUE: 05/11/2015
REVISION DATE: 07/01/2015
SUPERSEDES: 06/08/2015
VERSION: 1.1
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
FORMULA:
NON-FLAMMABLE, NON-OXIDIZING GAS MIXTURE CONTAINING ONE OR MORE OF THE
FOLLOWING COMPONENTS:
AMMONIA, OXYGEN, NITROGEN.
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: CALIBRATION / REFERENCE
USE OF THE SUBSTANCE/MIXTURE: INDUSTRIAL USE. USE AS DIRECTED.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
PORTAGAS (PRAXAIR, INC.)
1202 E SAM HOUSTON PKWY S
PASADENA, TX 77503
USA
T: +1 713-928-6477
F: +1 713-928-9961
WWW.PRAXAIR.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
ONSITE EMERGENCIES: 1-800-645-4633
CHEMTREC:
USA: 1-800-424-9300
INTERNATIONAL: 001-703-527-3887 (COLLECT CALLS ACCEPTED, CONTRACT 17729)
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
COMPRESSED GAS: H280
AQUATIC ACUTE 3: H402
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS04: GAS CYLINDER
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H402: HARMFUL TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (GHS-US):
P273: AVOID RELEASE TO THE ENVIRONMENT.
P403: USE AND STORE ONLY OUDOORS OR IN A WELL-VENTILATED PLACE.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
CONTACT SUPPLIER FOR ANY SPECIAL REQUIREMENTS.
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS
52 DEG. C (125 DEG. F).
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING.
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CGA-PG11:
NEVER PUT CYLINDERS INTO UNVENTILATED AREAS OF PASSENGER VEHICLES.
CGA-PG12: DO NOT OPEN VALVE UNTIL CONNECTED TO EQUIPMENT PREPARED FOR USE.
CGA-PG21: OPEN VALVE SLOWLY.
CGA-PG27: READ AND FOLLOW THE SAFETY DATA SHEET (SDS) BEFORE USE.
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION
(GHS-US)
NITROGEN (CAS NO) 7727-37-9 74.1 - 99.9998 COMPRESSED GAS,
H280
OXYGEN (CAS NO) 7782-44-7 0.0001 - 20.9 OX. GAS 1, H270
COMPRESSED GAS,
H280
AMMONIA (CAS NO) 7664-41-7 0.0001 - 1 LIQUEFIED GAS, H280
ACUTE TOX. 4
(INHALATION:GAS),
H332
SKIN CORR. 1B, H314
AQUATIC ACUTE 1,
H400
FULL TEXT OF H-PHRASES: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO UNCONTAMINATED AREA WEARING SELF CONTAINED BREATHING
APPARATUS. KEEP VICTIM WARM AND RESTED. CALL A DOCTOR. APPLY ARTIFICIAL
RESPIRATION IF BREATHING STOPPED. IMMEDIATELY REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
QUALIFIED PERSONNEL MAY GIVE OXYGEN. CALL A PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. DRENCH AFFECTED AREA WITH WATER FOR AT
LEAST 15 MINUTES.
FIRST-AID MEASURES AFTER EYE CONTACT:
IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. HOLD
THE EYELIDS OPEN AND AWAY FROM THE EYEBALLS TO ENSURE THAT ALL SURFACES
ARE FLUSHED THOROUGHLY. CONTACT AN OPHTHALMOLOGIST IMMEDIATELY.
FIRST-AID MEASURES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO ADDITIONAL INFORMATION AVAILABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EVACUATE ALL PERSONNEL FROM THE DANGER AREA. USE SELF-CONTAINED BREATHING
APPARATUS (SCBA) AND PROTECTIVE CLOTHING. IMMEDIATELY COOL CONTAINERS WITH
WATER FROM MAXIMUM DISTANCE. STOP FLOW OF GAS IF SAFE TO DO SO, WHILE
CONTINUING COOLING WATER SPRAY. REMOVE IGNITION SOURCES IF SAFE TO DO SO.
REMOVE CONTAINERS FROM AREA OF FIRE IF SAFE TO DO SO. ON-SITE FIRE
BRIGADES MUST COMPLY WITH OSHA 29 CFR 1910.156 AND APPLICABLE STANDARDS
UNDER 29 CFR 1910 SUBPART L-FIRE PROTECTION.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS:
WEAR GAS TIGHT CHEMICALLY PROTECTIVE CLOTHING IN COMBINATION WITH SELF
CONTAINED BREATHING APPARATUS. STANDARD PROTECTIVE CLOTHING AND EQUIPMENT
(SELF CONTAINED BREATHING APPARATUS) FOR FIRE FIGHTERS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
DANGER:
TOXIC. CORROSIVE. WEAR A SELF-CONTAINED BREATHING APPARATUS AND
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (PPE). (GAS TIGHT,
CHEMICAL-PROTECTIVE) EVACUATE PERSONNEL TO A SAFE AREA. APPROACH SUSPECTED
LEAK AREA WITH CAUTION. REMOVE ALL SOURCES OF IGNITION. TOXIC, CORROSIVE
VAPOR CAN SPREAD FROM SPILL. VENTILATE AREA OR MOVE CONTAINER TO A
WELL-VENTILATED AREA. BEFORE ENTERING THE AREA, ESPECIALLY A CONFINED
AREA, CHECK THE ATMOSPHERE WITH AN APPROPRIATE DEVICE.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS: NO ADDITIONAL INFORMATION AVAILABLE
6.2. ENVIRONMENTAL PRECAUTIONS:
TRY TO STOP RELEASE. REDUCE VAPOR WITH FOG OR FINE WATER SPRAY. PREVENT
WASTE FROM CONTAMINATING THE SURROUNDING ENVIRONMENT. PREVENT SOIL AND
WATER POLLUTION. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS. CONTACT SUPPLIER FOR
ANY SPECIAL REQUIREMENTS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
NO ADDITIONAL INFORMATION AVAILABLE
6.4. REFERENCE TO OTHER SECTIONS: SEE ALSO SECTIONS 8 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WEAR LEATHER SAFETY GLOVES AND SAFETY SHOES WHEN HANDLING CYLINDERS.
PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT DRAG, ROLL, SLIDE OR DROP.
WHILE MOVING CYLINDER, ALWAYS KEEP IN PLACE REMOVABLE VALVE COVER. NEVER
ATTEMPT TO LIFT A CYLINDER BY ITS CAP; THE CAP IS INTENDED SOLELY TO
PROTECT THE VALVE. WHEN MOVING CYLINDERS, EVEN FOR SHORT DISTANCES, USE
A CART (TROLLEY, HAND TRUCK, ETC.) DESIGNED TO TRANSPORT CYLINDERS. NEVER
INSERT AN OBJECT (E.G., WRENCH, SCREWDRIVER, PRY BAR) INTO CAP OPENINGS;
DOING SO MAY DAMAGE THE VALVE AND CAUSE A LEAK. USE AN ADJUSTABLE STRAP
WRENCH TO REMOVE OVER-TIGHT OR RUSTED CAPS. SLOWLY OPEN THE VALVE. IF THE
VALVE IS HARD TO OPEN, DISCONTINUE USE AND CONTACT YOUR SUPPLIER. CLOSE
THE CONTAINER VALVE AFTER EACH USE; KEEP CLOSED EVEN WHEN EMPTY. NEVER
APPLY FLAME OR LOCALIZED HEAT DIRECTLY TO ANY PART OF THE CONTAINER.
HIGH TEMPERATURES MAY DAMAGE THE CONTAINER AND COULD CAUSE THE PRESSURE
RELIEF DEVICE TO FAIL PREMATURELY, VENTING THE CONTAINER CONTENTS. FOR
OTHER PRECAUTIONS IN USING THIS PRODUCT, SEE SECTION 16.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE IN A COOL, WELL-VENTILATED PLACE. STORE AND USE WITH ADEQUATE
VENTILATION. STORE ONLY WHERE TEMPERATURE WILL NOT EXCEED 125 DEG. F
(52 DEG. C). FIRMLY SECURE CONTAINERS UPRIGHT TO KEEP THEM FROM FALLING
OR BEING KNOCKED OVER. INSTALL VALVE PROTECTION CAP, IF PROVIDED, FIRMLY
IN PLACE BY HAND. STORE FULL AND EMPTY CONTAINERS SEPARATELY. USE A
FIRST-IN, FIRST-OUT INVENTORY SYSTEM TO PREVENT STORING FULL CONTAINERS
FOR LONG PERIODS. OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE:
WHEN HANDLING PRODUCT UNDER PRESSURE, USE PIPING AND EQUIPMENT ADEQUATELY
DESIGNED TO WITHSTAND THE PRESSURES TO BE ENCOUNTERED. NEVER WORK ON A
PRESSURIZED SYSTEM. USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING. GASES
CAN CAUSE RAPID SUFFOCATION BECAUSE OF OXYGEN DEFICIENCY; STORE AND USE
WITH ADEQUATE VENTILATION. IF A LEAK OCCURS, CLOSE THE CONTAINER VALVE AND
BLOW DOWN THE SYSTEM IN A SAFE AND ENVIRONMENTALLY CORRECT MANNER IN
COMPLIANCE WITH ALL INTERNATIONAL, FEDERAL/NATIONAL, STATE/PROVINCIAL, AND
LOCAL LAWS; THEN REPAIR THE LEAK. NEVER PLACE A CONTAINER WHERE IT MAY
BECOME PART OF AN ELECTRICAL CIRCUIT.
7.3. SPECIFIC END USE(S): NONE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PTG-4003:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
DNEL:
DNEL: <=
NITROGEN (7727-37-9):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
OXYGEN (7782-44-7):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
AMMONIA (7664-41-7):
ACGIH:
ACGIH TLV-TWA (PPM): 25 PPM
ACGIH:
ACGIH TLV-STEL (PPM): 35 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 35 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. ALARM DETECTORS
SHOULD BE USED WHEN TOXIC GASES MAY BE RELEASED. PRODUCT TO BE HANDLED
IN A CLOSED SYSTEM. ENSURE EXPOSURE IS BELOW OCCUPATIONAL EXPOSURE LIMITS
(WHERE AVAILABLE).
PERSONAL PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
EYE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS OR GOGGLES WHEN TRANSFILLING OR
BREAKING TRANSFER CONNECTIONS. PROVIDE READILY ACCESSIBLE EYE WASH
STATIONS AND SAFETY SHOWERS. WEAR SAFETY GLASSES WHEN HANDLING CYLINDERS;
VAPOR-PROOF GOGGLES AND A FACE SHIELD DURING CYLINDER CHANGEOUT OR
WHENEVER CONTACT WITH PRODUCT IS POSSIBLE. SELECT EYE PROTECTION IN
ACCORDANCE WITH OSHA 29 CFR 1910.133.
SKIN AND BODY PROTECTION:
WEAR METATARSAL SHOES FOR CONTAINER HANDLING. WEAR METATARSAL SHOES AND
WORK GLOVES FOR CYLINDER HANDLING, AND PROTECTIVE CLOTHING WHERE NEEDED.
WEAR APPROPRIATE CHEMICAL GLOVES DURING CYLINDER CHANGEOUT OR WHEREVER
CONTACT WITH PRODUCT IS POSSIBLE. SELECT PER OSHA 29 CFR 1910.132,
1910.136, AND 1910.138.
RESPIRATORY PROTECTION:
WHEN WORKPLACE CONDITIONS WARRANT RESPIRATOR USE, FOLLOW A RESPIRATORY
PROTECTION PROGRAM THAT MEETS OSHA 29 CFR 1910.134, ANSI Z88.2, OR MSHA
30 CFR 72.710 (WHERE APPLICABLE). USE AN AIR-SUPPLIED OR AIR-PURIFYING
CARTRIDGE IF THE ACTION LEVEL IS EXCEEDED. ENSURE THAT THE RESPIRATOR HAS
THE APPROPRIATE PROTECTION FACTOR FOR THE EXPOSURE LEVEL. IF CARTRIDGE
TYPE RESPIRATORS ARE USED, THE CARTRIDGE MUST BE APPROPRIATE FOR THE
CHEMICAL EXPOSURE (E.G., AN ORGANIC VAPOR CARTRIDGE). FOR EMERGENCIES OR
INSTANCES WITH UNKNOWN EXPOSURE LEVELS, USE A SELF-CONTAINED BREATHING
APPARATUS (SCBA).
THERMAL HAZARD PROTECTION:
WEAR COLD INSULATING GLOVES WHEN TRANSFILLING OR BREAKING TRANSFER
CONNECTIONS.
OTHER INFORMATION:
KEEP SUITABLE CHEMICALLY RESISTANT PROTECTIVE CLOTHING READILY AVAILABLE
FOR EMERGENCY USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GAS
APPEARANCE: COLORLESS GAS.
COLOR: COLORLESS
ODOR: AMMONIA-LIKE
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE.
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE.
VAPOR PRESSURE: NOT APPLICABLE.
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
SOLUBILITY:
WATER: NO DATA AVAILABLE
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NOT APPLICABLE.
VISCOSITY, DYNAMIC: NOT APPLICABLE.
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
NO ADDITIONAL INFORMATION AVAILABLE
10.4. CONDITIONS TO AVOID: AVOID MOISTURE IN INSTALLATION SYSTEMS.
10.5. INCOMPATIBLE MATERIALS: NO ADDITIONAL INFORMATION AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
AMMONIA (7664-41-7):
LC50 INHALATION RAT (PPM): 7338 PPM/1H
ATE US (GASES): 3669.000 PPMV/4H
SKIN CORROSION/IRRITATION:
NOT CLASSIFIED
PH: NOT APPLICABLE.
SERIOUS EYE DAMAGE/IRRITATION:
NOT CLASSIFIED
PH: NOT APPLICABLE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
AMMONIA (7664-41-7):
LC50 FISH 1: 0.44 MG/L (EXPOSURE TIME: 96 H - SPECIES: CYPRINUS CARPIO)
EC50 DAPHNIA 1: 25.4 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2: 2.43 MG/L (EXPOSURE TIME: 96 H - SPECIES: LEPOMIS MACROCHIRUS)
12.2. PERSISTENCE AND DEGRADABILITY:
PTG-4003:
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
OXYGEN (7782-44-7):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
AMMONIA (7664-41-7):
PERSISTENCE AND DEGRADABILITY:
THE SUBSTANCE IS BIODEGRADABLE. UNLIKELY TO PERSIST.
12.3. BIOACCUMULATIVE POTENTIAL:
PTG-4003:
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
OXYGEN (7782-44-7):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
AMMONIA (7664-41-7):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL:
NOT EXPECTED TO BIOACCUMULATE DUE TO THE LOW LOG KOW (LOG KOW < 4).
REFER TO SECTION 9.
12.4. MOBILITY IN SOIL:
PTG-4003:
MOBILITY IN SOIL: NO DATA AVAILABLE.
NITROGEN (7727-37-9):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
OXYGEN (7782-44-7):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
AMMONIA (7664-41-7):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND
OR WATER POLLUTION.
12.5. OTHER ADVERSE EFFECTS:
OTHER ADVERSE EFFECTS: MAY CAUSE PH CHANGES IN AQUEOUS ECOLOGICAL SYSTEMS.
EFFECT ON OZONE LAYER: NONE.
EFFECT ON THE GLOBAL WARMING:
NO KNOWN ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED QUANTITIES. RETURN
CONTAINER TO SUPPLIER.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1956 COMPRESSED GAS, N.O.S., 2.2
UN-NO.(DOT): UN1956
PROPER SHIPPING NAME (DOT): COMPRESSED GAS, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
2.2 - CLASS 2.2 - NON-FLAMMABLE COMPRESSED GAS 49 CFR 173.115
HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS
DOT PACKAGING NON BULK (49 CFR 173.XXX): 302;305
DOT PACKAGING BULK (49 CFR 173.XXX): 314;315
DOT SYMBOLS:
G - IDENTIFIES PROPER SHIPPING NAME (PSN) REQUIRING THE ADDITION OF
TECHNICAL NAME(S) IN PARENTHESES FOLLOWING THE PSN.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 306;307
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 172.101 HMT,
COLUMN 9A):
75 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 172.101 HMT,
COLUMN 9B):
150 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED ''ON DECK'' OR ''UNDER DECK'' ON A CARGO
VESSEL AND ON A PASSENGER VESSEL.
ADDITIONAL INFORMATION:
EMERGENCY RESPONSE GUIDE (ERG) NUMBER: 126
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
SPECIAL TRANSPORT PRECAUTIONS:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY. BEFORE TRANSPORTING PRODUCT CONTAINERS: - ENSURE THERE IS
ADEQUATE VENTILATION. - ENSURE THAT CONTAINERS ARE FIRMLY SECURED. - ENSURE
CYLINDER VALVE IS CLOSED AND NOT LEAKING. - ENSURE VALVE OUTLET CAP NUT
OR PLUG (WHERE PROVIDED) IS CORRECTLY FITTED. - ENSURE VALVE PROTECTION
DEVICE (WHERE PROVIDED) IS CORRECTLY FITTED.
ADR:
TRANSPORT DOCUMENT DESCRIPTION:
UN 1956 COMPRESSED GAS, N.O.S. (NITROGEN, AMMONIA), 2.2, (E)
CLASS (ADR): 2 - GASES
HAZARD IDENTIFICATION NUMBER (KEMLER NO.): 20
CLASSIFICATION CODE (ADR): 1A
HAZARD CLASS LABELS (ADR): 2.2 - NON-FLAMMABLE COMPRESSED GAS
ORANGE PLATES:
20
1956
TUNNEL RESTRICTION CODE (ADR): E
LIMITED QUANTITIES (ADR): 120ML
EXCEPTED QUANTITIES (ADR): E1
TRANSPORT BY SEA:
UN-NO. (IMDG): 1956
PROPER SHIPPING NAME (IMDG): COMPRESSED GAS, N.O.S.
CLASS (IMDG): 2 - GASES
LIMITED QUANTITIES (IMDG): 120ML
EMS-NO. (1): F-C
MFAG-NO: 620
EMS-NO. (2): S-V
AIR TRANSPORT:
UN-NO. (IATA): 1956
PROPER SHIPPING NAME (IATA): COMPRESSED GAS, N.O.S.
CLASS (IATA): 2
INSTRUCTION "CARGO" (ICAO): 200
INSTRUCTION "PASSENGER" (ICAO): 200
INSTRUCTION "PASSENGER" - LIMITED QUANTITIES (ICAO): FORBIDDEN
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
OXYGEN (7782-44-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
AMMONIA (7664-41-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON THE UNITED STATES SARA SECTION 302
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
SUDDEN RELEASE OF PRESSURE HAZARD
FIRE HAZARD
SARA SECTION 313 - EMISSION REPORTING:
1.0 % (INCLUDES ANHYDROUS AMMONIA AND AQUEOUS AMMONIA FROM WATER
DISSOCIABLE AMMONIUM SALTS AND OTHER SOURCES, 10% OF TOTAL AQUEOUS
AMMONIA IS REPORTABLE UNDER THIS LISTING)
15.2. INTERNATIONAL REGULATIONS:
CANADA:
NITROGEN (7727-37-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST):
WHMIS CLASSIFICATION: CLASS A - COMPRESSED GAS
OXYGEN (7782-44-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST):
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS C - OXIDIZING MATERIAL
AMMONIA (7664-41-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST):
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS B DIVISION 1 - FLAMMABLE GAS
CLASS D DIVISION 1 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING IMMEDIATE
AND SERIOUS TOXIC EFFECTS
CLASS E - CORROSIVE MATERIAL
EU-REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
OXYGEN (7782-44-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
AMMONIA (7664-41-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
OX. GAS 1 H270
COMPRESSED GAS H280
ACUTE TOX. 3 (INHALATION:GAS) H331
SKIN CORR. 1B H314
FULL TEXT OF H-PHRASES: SEE SECTION 16
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC
[DPD]:
NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
OXYGEN (7782-44-7):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED
OR IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
AMMONIA (7664-41-7):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED
OR IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES)
INVENTORY LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
JAPANESE POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
NITROGEN (7727-37-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
OXYGEN (7782-44-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
AMMONIA (7664-41-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 07/01/2015
TRAINING ADVICE: USERS OF BREATHING APPARATUS MUST BE TRAINED.
OTHER INFORMATION:
WHEN YOU MIX TWO OR MORE CHEMICALS, YOU CAN CREATE ADDITIONAL, UNEXPECTED
HAZARDS. OBTAIN AND EVALUATE THE SAFETY INFORMATION FOR EACH COMPONENT
BEFORE YOU PRODUCE THE MIXTURE. CONSULT AN INDUSTRIAL HYGIENIST OR OTHER
TRAINED PERSON WHEN YOU EVALUATE THE END PRODUCT. BEFORE USING ANY
PLASTICS, CONFIRM THEIR COMPATIBILITY WITH THIS PRODUCT. PRAXAIR ASKS
USERS OF THIS PRODUCT TO STUDY THIS SDS AND BECOME AWARE OF THE PRODUCT
HAZARDS AND SAFETY INFORMATION. TO PROMOTE SAFE USE OF THIS PRODUCT, A
USER SHOULD (1) NOTIFY EMPLOYEES, AGENTS, AND CONTRACTORS OF THE
INFORMATION IN THIS SDS AND OF ANY OTHER KNOWN PRODUCT HAZARDS AND SAFETY
INFORMATION, (2) FURNISH THIS INFORMATION TO EACH PURCHASER OF THE
PRODUCT, AND (3) ASK EACH PURCHASER TO NOTIFY ITS EMPLOYEES AND CUSTOMERS
OF THE PRODUCT HAZARDS AND SAFETY INFORMATION. THE OPINIONS EXPRESSED
HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN PRAXAIR, INC. WE BELIEVE THAT
THE INFORMATION CONTAINED HEREIN IS CURRENT AS OF THE DATE OF THIS SAFETY
DATA SHEET. SINCE THE USE OF THIS INFORMATION AND THE CONDITIONS OF USE
ARE NOT WITHIN THE CONTROL OF PRAXAIR, INC., IT IS THE USER'S OBLIGATION
TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCT. PRAXAIR SDSS ARE
FURNISHED ON SALE OR DELIVERY BY PRAXAIR OR THE INDEPENDENT DISTRIBUTORS
AND SUPPLIERS WHO PACKAGE AND SELL OUR PRODUCTS. TO OBTAIN CURRENT SDSS
FOR THESE PRODUCTS, CONTACT YOUR PRAXAIR SALES REPRESENTATIVE, LOCAL
DISTRIBUTOR, OR SUPPLIER, OR DOWNLOAD FROM WWW.PRAXAIR.COM. IF YOU HAVE
QUESTIONS REGARDING PRAXAIR SDSS, WOULD LIKE THE DOCUMENT NUMBER AND DATE
OF THE LATEST SDS, OR WOULD LIKE THE NAMES OF THE PRAXAIR SUPPLIERS IN
YOUR AREA, PHONE OR WRITE THE PRAXAIR CALL CENTER (PHONE:
1-800-PRAXAIR/1-800-772-9247; ADDRESS: PRAXAIR CALL CENTER, PRAXAIR, INC.,
P.O. BOX 44, TONAWANDA, NY 14151-0044). PRAXAIR AND THE FLOWING AIRSTREAM
DESIGN ARE TRADEMARKS OR REGISTERED TRADEMARKS OF PRAXAIR TECHNOLOGY, INC.
IN THE UNITED STATES AND/OR OTHER COUNTRIES.
FULL TEXT OF H-PHRASES:
ACUTE TOX. 4 (INHALATION:GAS): ACUTE TOXICITY (INHALATION:GAS) CATEGORY 4
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1
AQUATIC ACUTE 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3
COMPRESSED GAS: GASES UNDER PRESSURE COMPRESSED GAS
LIQUEFIED GAS: GASES UNDER PRESSURE LIQUEFIED GAS
OX. GAS 1: OXIDIZING GASES CATEGORY 1
SKIN CORR. 1B: SKIN CORROSION/IRRITATION CATEGORY 1B
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDIZER
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H332: HARMFUL IF INHALED
H400: VERY TOXIC TO AQUATIC LIFE
H402: HARMFUL TO AQUATIC LIFE
SDS US (GHS HAZCOM 2012)
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING
ANY SPECIFIC PROPERTY OF THE PRODUCT.S
EN (ENGLISH US)
SDS ID: PTG-4003