| Common Name: | ROHPER 1-GL 2PK HIGH HEAT HP BLACK, 286512 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 1/27/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 36ND79 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
DATE PRINTED: 1/27/2016
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: ROHPER 1-GL 2PK HIGH HEAT HP BLACK
PRODUCT IDENTIFIER: 286512
PRODUCT USE/CLASS: HIGH TEMPERATURE PAINT/SOLVENTBORNE
REVISION DATE: 1/27/2016
SUPERCEDES DATE: 2/25/2015
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: WARNING
POSSIBLE HAZARDS:
23% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
GHS HAZARD STATEMENTS:
FLAMMABLE LIQUID, CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOR.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
STOT, SINGLE EXPOSURE, CATEGORY 3, RTI:
H335: MAY CAUSE RESPIRATORY IRRITATION.
REPRODUCTIVE TOXICITY, CATEGORY 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT, REPEATED EXPOSURE, CATEGORY 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P260: DO NOT BREATHE DUST, FUMES, GASES, MISTS, VAPORS, OR SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
GHS SDS PRECAUTIONARY STATEMENTS:
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
PIGMENT 68186-94-7 10-25 NOT AVAILABLE NOT AVAILABLE
1-CHLORO-4- 98-56-6 10-25 GHS07 H315-319-
(TRIFLUOROMETHYL) 332-335
BENZENE
XYLENE 1330-20-7 10-25 GHS02-GHS07 H226-315-
(MIXED ISOMERS) 319-332
MICA 12001-26-2 2.5-10 NOT AVAILABLE NOT AVAILABLE
ETHYLBENZENE 100-41-4 2.5-10 GHS02-GHS07- H225-304-
GHS08 332-373
TOLUENE 108-88-3 1.0-2.5 GHS02-GHS07- H225-304-
GHS08 315-332-336-
361-373
CRYSTALLINE 14808-60-7 0.1-1.0 NOT AVAILABLE NOT AVAILABLE
SILICA / QUARTZ
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION: IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP
OF STEAM. KEEP CONTAINERS TIGHTLY CLOSED. COMBUSTIBLE LIQUID AND VAPOR. NO
UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL. CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE WITH INERT
ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL, STATE
(PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE. KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL
EQUIPMENT, SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEG. F. STORE
LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA
CLASS II COMBUSTIBLE LIQUIDS. AVOID EXCESS HEAT.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
PIGMENT 68186-94-7 25.0
1-CHLORO-4-(TRIFLUOROMETHYL) BENZENE 98-56-6 25.0
XYLENE (MIXED ISOMERS) 1330-20-7 20.0
MICA 12001-26-2 5.0
ETHYLBENZENE 100-41-4 5.0
TOLUENE 108-88-3 5.0
CRYSTALLINE SILICA / QUARTZ 14808-60-7 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
PIGMENT N.E. N.E. N.E. N.E.
1-CHLORO-4-(TRIFLUOROMETHYL) N.E. N.E. N.E. N.E.
BENZENE
XYLENE (MIXED ISOMERS) 100 PPM 150 PPM 100 PPM N.E.
MICA 3 MG/M3 N.E. N.E. N.E.
ETHYLBENZENE 20 PPM N.E. 100 PPM N.E.
TOLUENE 20 PPM N.E. 200 PPM 300 PPM
CRYSTALLINE 0.025 MG/M3 N.E. N.E. N.E.
SILICA / QUARTZ
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.413
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: NO INFORMATION
SOLUBILITY IN WATER: NEGLIGIBLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: 135 - 537
EXPLOSIVE LIMITS, VOL%: 0.9 - 10.5
FLAMMABILITY: SUPPORTS COMBUSTION
FLASH POINT, DEG. C: 38
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F (49 DEG. C). AVOID CONTACT WITH STRONG
ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
CONTAINS SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND
FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
SUBSTANCE CAUSES MODERATE EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. MAY BE ABSORBED THROUGH THE
SKIN IN HARMFUL AMOUNTS.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED.
AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. HIGH VAPOR CONCENTRATIONS
ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS. PROLONGED OR EXCESSIVE
INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
IRRITATING TO THE NOSE, THROAT AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. OVEREXPOSURE TO
XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER ABNORMALITIES,
KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS REPRODUCTIVE
DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE, HAVE INCLUDED
LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE. IARC LISTS
ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
98-56-6 1-CHLORO-4- 13000 MG/KG >2684 MG/KG 33 MG/L
(TRIFLUOROMETHYL) RAT RABBIT RAT
BENZENE
1330-20-7 XYLENE 3500 MG/KG >4350 MG/KG 29.08 MG/L
(MIXED ISOMERS) RAT RABBIT RAT
100-41-4 ETHYLBENZENE 3500 MG/KG 15400 MG/KG 17.2 MG/L
RAT RABBIT RAT
108-88-3 TOLUENE 2600 MG/KG 12000 MG/KG 12.5 MG/L
RAT RABBIT RAT
14808-60-7 CRYSTALLINE 5500 MG/KG 5500 100 MG/L
SILICA / QUARTZ RAT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1263 1263 N.A.
PROPER SHIPPING NOT REGULATED PAINT PAINT NOT REGULATED
NAME
HAZARD CLASS N.A. 3 3 N.A.
PACKING GROUP N.A. III III N.A.
LIMITED QUANTITY NO YES, >5L NO YES, >5L NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
PIGMENT 68186-94-7
XYLENE (MIXED ISOMERS) 1330-20-7
ETHYLBENZENE 100-41-4
TOLUENE 108-88-3
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
CHEMICAL NAME CAS-NO.
1-CHLORO-4-(TRIFLUOROMETHYL)BENZENE 98-56-6
| 16. OTHER INFORMATION | |
HMIS RATINGS
HEALTH 2*
FLAMMABILITY 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 403
SDS REVISION DATE: 1/27/2016
REASON FOR REVISION: PRODUCT COMPOSITION CHANGED
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
01 - IDENTIFICATION
02 - HAZARD IDENTIFICATION
05 - FIRE-FIGHTING MEASURES
09 - PHYSICAL & CHEMICAL PROPERTIES
15 - REGULATORY INFORMATION
16 - OTHER INFORMATION
STATEMENT(S) CHANGED
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE
AS OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS
OF HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL,
WE ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY
OF THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.