| Common Name: | HYDROGEN SULFIDE 0.0001% - 0.0999% IN AIR, CO 0.0001% TO 0.0999%, CH4, PTG-4065 |
| Manufacturer: | NORLAB |
| SDS Revision Date: | 5/28/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 36T520 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NORLAB
A DIVISION OF NORCO, INC.
SAFETY DATA SHEET (SDS)
NORLAB - A DIVISION OF NORCO, INC.
HYDROGEN SULFIDE 0.0001% - 0.0999% IN AIR
SDS NUMBER: 2090
REVISION DATE: 5/28/2015
| 1 PRODUCT AND COMPANY IDENTIFICATION |  |
MANUFACTURER:
NORLAB - A DIVISION OF NORCO, INC.
898 W. GOWEN RD.
BOISE, ID 83705
CONTACT: QUALITY DEPARTMENT
PHONE: (208) 336-1643
WEB: WWW.NORLAB-GAS.COM
PRODUCT NAME: HYDROGEN SULFIDE 0.0001% - 0.0999% IN AIR
REVISION DATE: 5/28/2015
VERSION: 2
SDS NUMBER: 2090
COMMON NAME: NONE
CAS NUMBER: MIXTURE
CHEMICAL FAMILY: GAS MIXTURE
CHEMICAL FORMULA: H2S IN AIR
SYNONYMS: NONE
EMERGENCY TELEPHONE NUMBER: (800) 424-9300 (CHEMTREC)
| 2 HAZARDS IDENTIFICATION | |
INHALATION:
LETHAL CONCENTRATIONS OF HYDROGEN SULFIDE CAUSE RESPIRATORY PARALYSIS AND
BREATHING STOPS. LIFE THREATENING PULMONARY EDEMA IS COMMON FOLLOWING
PROLONGED EXPOSURE TO CONCENTRATIONS BETWEEN 250 AND 600 PPM. EDEMA HAS
BEEN REPORTED FOLLOWING PROLONGED EXPOSURE AT CONCENTRATIONS AS LOW AS
50 PPM.
SENSE OF SMELL BECOMES RAPIDLY FATIGUED AND CANNOT BE USED AS WARNING OF
EXPOSURE.
SKIN CONTACT:
MAY IRRITATE THE SKIN UPON CONTACT. CONTACT WITH RAPIDLY EXPANDING GAS
NEAR THE POINT OF RELEASE MAY CAUSE FROSTBITE WITH REDNESS, SKIN COLOR
CHANGE TO GRAY OR WHITE, AND BLISTERING.
EYE CONTACT:
LOW CONCENTRATIONS WILL GENERALLY CAUSE IRRITATION TO THE CONJUNCTIVA.
REPEATED EXPOSURE TO LOW CONCENTRATIONS IS REPORTED TO CAUSE
CONJUNCTIVITIS, PHOTOPHOBIA, TEARS, PAIN AND BLURRED VISION. CONTACT WITH
RAPIDLY EXPANDING GAS NEAR THE POINT OF RELEASE MAY CAUSE FROSTBITE.
INGESTION:
INGESTION IS UNLIKELY. HYDROGEN SULFIDE WILL IRRITATE THE MUCOUS MEMBRANES
CAUSING A BURNING FEELING WITH EXCESS SALIVATION LIKELY. IRRITATION OF THE
GASTROINTESTINAL TRACT MAY ALSO OCCUR.
NFPA:
HEALTH 1
FIRE 0
REACTIVITY 0
HMIS III:
H 1
F 0
PH 3
NFPA:
HEALTH 1
FIRE HAZARD 0
REACTIVITY 0
SPECIFIC HAZARD
HMIS III:
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARDS 3
PERSONAL PROTECTION B SAFETY GLASSES, GLOVES
PERSONAL PROTECTION INDEX:
A: SAFETY GLASSES
B:
SAFETY GLASSES
GLOVES
C:
SAFETY GLASSES
GLOVES
APRON
D:
FACE SHIELD
GLOVES
APRON
E:
SAFETY GLASSES
GLOVES
DUST RESPIRATOR
F:
SAFETY GLASSES
GLOVES
APRON
DUST RESPIRATOR
G:
SAFETY GLASSES
GLOVES
VAPOR RESPIRATOR
H:
SPLASH GOGGLES
GLOVES
APRON
VAPOR RESPIRATOR
I:
SAFETY GOGGLES
GLOVES
DUST AND VAPOR RESPIRATOR
J:
SPLASH GOGGLES
GLOVES
APRON
DUST AND VAPOR RESPIRATOR
K:
AIR-LINE HOOD OR MASK
GLOVES
FULL SUIT
BOOTS
X: CONSULT YOUR SUPERVISOR OR S.O.P. FOR SPECIAL HANDLING DIRECTIONS
A: SAFETY GLASSES
N: SPLASH GOGGLES
O: FACE SHIELD & EYE PROTECTION
P: GLOVES
Q: BOOTS
R: SYNTHETIC APRON
S: FULL SUIT
T: DUST RESPIRATOR
U: VAPOR RESPIRATOR
W: DUST & VAPOR RESPIRATOR
Y: FULL FACE RESPIRATOR
Z: AIRLINE HOOD OR MASK
GHS SIGNAL WORD: WARNING
GHS HAZARD PICTOGRAMS: GAS CYLINDER
GHS CLASSIFICATIONS:
PHYSICAL, GASES UNDER PRESSURE, COMPRESSED GAS
HEALTH, ACUTE TOXICITY, 5 INHALATION
GHS PHRASES:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H333: MAY BE HARMFUL IF INHALED
CGA-HG24: SUPPORTS COMBUSTION
GHS PRECAUTIONARY STATEMENTS:
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P304+340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P308+313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P403+233: STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C
(125 DEG. F).
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CGA-PG20: USE ONLY EQUIPMENT OF COMPATIBLE MATERIALS OF CONSTRUCTIONS.
COLORLESS GAS WITH CHARACTERISTIC "ROTTEN EGG" ODOR. PRODUCT IS A COLORLESS
NON-FLAMMABLE GAS WITH A DISTINCTIVE ROTTEN EGG LIKE ODOR. DO NOT RELY ON
SMELL TO DETECT HYDROGEN SULFIDE BECAUSE OF OLFACTORY FATIGUE. EXPOSURE TO
LOW LEVELS OF HYDROGEN SULFIDE CAUSES IRRITATION OF MUCOUS MEMBRANES.
HYDROGEN SULFIDE CAN CAUSE RESPIRATORY PARALYSIS, SUDDEN COLLAPSE AND
DEATH. CONTENTS UNDER PRESSURE. USE AND STORE BELOW 125 DEG. F (52 DEG. C).
IDHL: 100 PPM (H2S)
| 3 COMPOSITION / INFORMATION ON INGREDIENTS | |
INGREDIENTS:
CAS # PERCENTAGE CHEMICAL NAME
N/A 99.9-99.9999% AIR
7783-06-4 0.0001-0.0999 HYDROGEN SULFIDE
| 4 FIRST AID MEASURES | |
INHALATION:
PROMPT REMOVAL FROM THE CONTAMINATED AREA AND IMMEDIATE MEDICAL ATTENTION
IS MANDATORY IN ALL CASES OF OVEREXPOSURE. RESCUE PERSONNEL SHOULD BE
EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS. RESCUE PERSONNEL SHOULD
RECOGNIZE THE HAZARDS OF OVEREXPOSURE DUE TO OLFACTORY FATIGUE.
IMMEDIATELY REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER
OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. KEEP VICTIM
WARM AND CALM. FURTHER TREATMENT SHOULD BE SYMPTOMATIC AND SUPPORTIVE.
SEEK IMMEDIATE MEDICAL ATTENTION.
NOTE TO PHYSICIAN:
ACUTE HYDROGEN SULFIDE POISONING CAN BE TREATED BY INDUCTION OF
METHEMOGLOBINEMIA THROUGH PARENTERAL INJECTION OF METHEMOGLOBIN GENERATING
AGENTS (I.E. SODIUM NITRILE). THIS ACTS AS AN ANTIDOTE BY RESTORING THE
NORMAL ACTIVITY OF THE SULFIDE INHIBITED ENZYME.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FLUSH AFFECTED AREA WITH LARGE QUANTITIES
OF WATER. IF IRRITATION PERSISTS OR SYMPTOMS OCCUR, SEEK MEDICAL ATTENTION.
EYE CONTACT:
PERSONS WITH POTENTIAL EXPOSURE TO HYDROGEN SULFIDE SHOULD NOT WEAR
CONTACT LENSES. FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST
15 MINUTES, HOLDING EYELIDS OPEN TO ENSURE ADEQUATE RINSING. IF IRRITATION
PERSISTS, SEEK IMMEDIATE MEDICAL ATTENTION.
INGESTION: NONE ANTICIPATED; PRODUCT IS A GAS.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELLING (SEE SECTION 2) AND/OR SECTION 11.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO DATA AVAILABLE.
| 5 FIRE FIGHTING MEASURES | |
FLAMMABILITY: NOT FLAMMABLE
FLASH POINT: NA
FLASH POINT METHOD: NA
BURNING RATE: NOT DETERMINED
AUTOIGNITION TEMP: NOT DETERMINED
LEL: NA
UEL: NA
EXTINGUISHING MEDIA: USE AS APPROPRIATE FOR SURROUNDING MATERIAL.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HYDROGEN GAS (TRACE)
HYDROGEN SULFIDE
NITROGEN GAS
NITROGEN OXIDES (NOX)
OXYGEN GAS
SULFUR OXIDES
ADVICE FOR FIREFIGHTERS:
STOP THE FLOW OF GAS IF IT CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO
COOL SURROUNDING CONTAINERS. CONTINUE TO COOL HEAT OR FLAME EXPOSED
CONTAINERS UNTIL WELL AFTER THE FLAMES ARE EXTINGUISHED. FIREFIGHTERS
SHOULD WEAR A FULL-FACEPIECE, NIOSH/MSHA-APPROVED SELF-CONTAINED BREATHING
APPARATUS (SCBA) OPERATED IN POSITIVE PRESSURE MODE AND FULL TURNOUT GEAR.
FURTHER INFORMATION:
IF INCINERATED, MAY RELEASE TOXIC FUMES.
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
THE MAJORITY OF THIS PRODUCT IS A NONFLAMMABLE, INERT GAS. THIS PRODUCT
DOES CONTAIN 0.0001 - 0.1000% HYDROGEN SULFIDE, A FLAMMABLE COMPONENT BUT
BELOW ITS FLAMMABLE LIMIT.
CYLINDERS MAY RUPTURE VIOLENTLY FROM PRESSURE WHEN INVOLVED IN A FIRE
SITUATION.
SEE SECTION 7 FOR MORE INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR MORE INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ISOLATE HAZARD AREA, EVACUATE PERSONNEL AND DENY ENTRY TO
UNAUTHORIZED/UNPROTECTED INDIVIDUALS. EXTINGUISH ALL IGNITION SOURCES AND
VENTILATE CLOSED SPACES AND LOW AREAS. HYDROGEN SULFIDE IS SOLUBLE, USE
WATER SPRAY TO KNOCK DOWN VAPORS AND PROTECT PERSONNEL. DIKE RUN-OFF
WATERS FOR LATER DISPOSAL. PERSONNEL ENTERING AREA SHOULD WEAR APPROPRIATE
PROTECTIVE EQUIPMENT, INCLUDING RESPIRATORY PROTECTION SUITABLE FOR
UNKNOWN CONCENTRATIONS. PERSONNEL SHOULD NOT RE-ENTER AN AREA UNTIL
HYDROGEN SULFIDE HAS SUFFICIENTLY DISPERSED AND ADEQUATE OXYGEN
RE-ESTABLISHED. IF A LEAK IS IN USER'S EQUIPMENT, BE CERTAIN TO PURGE
PIPING WITH AN INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN
CONTAINER VALVE, CONTACT THE APPROPRIATE EMERGENCY TELEPHONE NUMBER LISTED
IN SECTION 1 OR CALL YOUR CLOSEST NORCO/NORLAB LOCATION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER RELEASE (LEAKAGE/SPILLAGE) IF SAFE TO DO SO.
METHODS AND MATERIALS FOR CONTAINMENTS AND CLEANING UP:
CONTACT THE APPROPRIATE EMERGENCY TELEPHONE NUMBER LISTED IN SECTION 1 OR
CALL YOUR CLOSEST NORCO/NORLAB LOCATION. ENSURE ADEQUATE VENTILATION.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR INFORMATION ON PROPER DISPOSAL.
| 7 HANDLING AND STORAGE | |
HANDLING PRECAUTIONS:
USE ONLY IN WELL-VENTILATED AREAS. VALVE PROTECTION CAPS MUST REMAIN IN
PLACE ON REFILLABLE CYLINDERS UNLESS CYLINDER IS SECURED WITH VALVE OUTLET
PIPED TO USE POINT. DO NOT DRAG, SLIDE OR ROLL CYLINDERS. USE A SUITABLE
HAND TRUCK FOR CYLINDER MOVEMENT. USE A PRESSURE REDUCING REGULATOR WHEN
CONNECTING CYLINDER TO LOWER PRESSURE PIPING OR SYSTEMS. DO NOT HEAT
CYLINDER BY ANY MEANS TO INCREASE THE DISCHARGE RATE OF PRODUCT FROM THE
CYLINDER. USE A CHECK VALVE OR TRAP IN THE DISCHARGE LINE TO PREVENT
HAZARDOUS BACK FLOW INTO THE CYLINDER.
NEVER CARRY A COMPRESSED GAS CYLINDER OR A CONTAINER OF A GAS IN CRYOGENIC
LIQUID FROM IN AN ENCLOSED SPACE SUCH AS A CAR TRUNK, VAN OR STATION WAGON.
A LEAK CAN RESULT IN A FIRE, EXPLOSION, ASPHYXIATION OR A TOXIC EXPOSURE.
STORAGE REQUIREMENTS: ENSURE ADEQUATE VENTILATION.
PROTECT CYLINDERS FROM PHYSICAL DAMAGE. STORE IN A COOL, DRY, WELL
VENTILATED AREA OF NON-COMBUSTIBLE CONSTRUCTION AWAY FROM HEAVY TRAFFIC
AREAS AND EMERGENCY EXITS. DO NOT ALLOW THE TEMPERATURE WHERE CYLINDERS
ARE STORED TO EXCEED 125 DEG. F (52 DEG. C). CYLINDERS SHOULD BE STORED
UPRIGHT AND FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED OVER. FULL
AND EMPTY CYLINDERS SHOULD BE SEGREGATED. USE A "FIRST IN - FIRST OUT"
INVENTORY SYSTEM TO PREVENT FULL CYLINDERS FROM BEING STORED FOR EXCESSIVE
PERIODS OF TIME.
DO NOT RELY ON THE OLFACTORY SENSE TO DETECT THE PRESENCE OF HYDROGEN
SULFIDE. ANALYTICAL DEVICES AND INSTRUMENTATION ARE READILY AVAILABLE FOR
THIS PURPOSE. PERFORM FREQUENT ANALYTICAL TESTS TO BE CERTAIN THAT THE TWA
IS NOT EXCEEDED. MANY METALS CORRODE RAPIDLY WITH WET HYDROGEN SULFIDE.
ANHYDROUS HYDROGEN SULFIDE CAN BE HANDLED IN CARBON STEEL, ALUMINUM,
INCONEL(R*), STELITE(R*), 304 AND 316 STAINLESS STEELS. AVOID HARD
STEELS, WHICH ARE HIGHLY STRESSED SINCE THEY MAY BE SUSCEPTIBLE TO
HYDROGEN EMBRITTLEMENT FROM HYDROGEN SULFIDE. MULTIPOINT AIR SAMPLERS WITH
ALARMS FOR PLANT PRODUCTION UNITS SHOULD BE PROVIDED TO CONSTANTLY MONITOR
THE AIR IN AND AROUND THE UNITS.
FOR ADDITIONAL RECOMMENDATIONS, CONSULT COMPRESSED GAS ASSOCIATION
PAMPHLET P-1.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
ALL VENTILATION SHOULD BE DESIGNED IN ACCORDANCE WITH OSHA STANDARD
(29 CFR 1910.94). USE LOCAL EXHAUST AT FILLING ZONES AND WHERE LEAKAGE
AND DUST FORMATION IS PROBABLE. USE MECHANICAL (GENERAL) VENTILATION FOR
STORAGE AREAS. USE APPROPRIATE VENTILATION AS REQUIRED TO KEEP EXPOSURE
LIMITS IN AIR BELOW TLV & PEL LIMITS. MAINTAIN ATMOSPHERIC OXYGEN CONTENT
AT OR ABOVE 19.5%
PERSONAL PROTECTIVE EQUIP:
EYE/FACE PROTECTION:
WHEN USING MATERIAL USE SAFETY GOGGLES, GLOVES AND VAPOR RESPIRATOR
ACCORDING TO HMIS, PP G. USE OF A FACE SHIELD ACCORDING TO HMIS, PP O IS
ALSO HIGHLY RECOMMENDED. ALL SAFETY EQUIPMENT SHOULD BE TESTED AND APPROVED
UNDER APPROPRIATE GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR EN 166 (EU).
SKIN PROTECTION:
HANDLE WITH PROTECTIVE GLOVES MADE FROM NEOPRENE, BUTYL RUBBER, PVC OR
POLYETHYLENE. GLOVES MUST BE INSPECTED PRIOR TO USE. DISPOSE OF
CONTAMINATED GLOVES ACCORDING TO APPLICABLE LAWS AND WORKPLACE PRACTICES.
BODY PROTECTION:
CHEMICALLY RESISTANT GLOVES, SAFETY GOGGLES AND FACE SHIELD ARE
RECOMMENDED. TYPE OF PROTECTIVE EQUIPMENT SHOULD BE SELECTED BASED ON
CONCENTRATION AMOUNT AND CONDITIONS OF USE OF THIS MATERIAL. USE SAFETY
SHOES.
RESPIRATORY PROTECTION:
USE OF A VAPOR RESPIRATOR IS HIGHLY RECOMMENDED. A NIOSH/MSHA-APPROVED
FULL-FACE PIECE SCBA OPERATED IN POSITIVE MODE AND/OR ANY SUPPLIED AIR
RESPIRATOR WITH A FULL-FACE PIECE AND OPERATED IN A POSITIVE PRESSURE MODE
IN COMBINATION WITH AN AUXILIARY SELF CONTAINED BREATHING APPARATUS
OPERATED IN POSITIVE PRESSURE MODE SHOULD BE USED FOR HIGH OR UNKNOWN
CONCENTRATIONS. RESPIRATORS SHOULD BE STORED IN AN AREA NOT LIKELY TO BE
CONTAMINATED.
CONTROL OF ENVIRONMENTAL EXPOSURE:
PREVENT LEAKAGE OR SPILLAGE IF SAFE TO DO SO. SAFETY SHOES, SAFETY SHOWERS
AND AN EMERGENCY EYEWASH STATION SHOULD BE AVAILABLE. PERSONNEL WITH
POTENTIAL EXPOSURE TO HYDROGEN SULFIDE SHOULD WORK IN PAIRS, WEAR A GAS
MASK WITH AN ALL PURPOSE CANISTER OR LIGHT THREE MINUTE UNIT WITH A SELF
CONTAINED AIR SUPPLY FOR INSTANTANEOUS USE, AND CARRY WET LEAD ACETATE
PAPER ON WRISTS OR BELT FOR DETECTION OF DANGEROUS CONCENTRATIONS OF
HYDROGEN SULFIDE, (TURNS BLACK IN THE PRESENCE OF MINUTE AMOUNTS OF
HYDROGEN SULFIDE).
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENT(S): AIR; HYDROGEN SULFIDE
CAS NO(S): N/A; 7783-06-4
USA NIOSH (C/REL): 10.0 PPM
USA ACGIH (TWA/TLV): 1.0 PPM
USA ACGIH (STEL/TLV): 5.0 PPM
USA OSHA OCCUPATIONAL EXPOSURE LIMITS TABLE Z-2 (CEII): 20.0 PPM
USA OSHA OCCUPATIONAL EXPOSURE LIMITS TABLE Z-2 (PEAK): 50.0 PPM
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
CONTAINS NO SUBSTANCES WITH BIOLOGICAL OCCUPATIONAL EXPOSURE LIMIT VALUES.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR, COLORLESS GAS
PHYSICAL STATE: GAS
ODOR: ROTTEN EGG
ODOR THRESHOLD: 0.13 PPM
MOLECULAR FORMULA: MIXTURE
PARTICLE SIZE: NOT DETERMINED
SOLUBILITY: SLIGHTLY SOLUBLE
SPEC GRAV./DENSITY: NO DATA AVAILABLE
SOFTENING POINT: NOT DETERMINED
VISCOSITY: NOT DETERMINED
PERCENT VOLATILE: 100%
SAT. VAP. CONC.: NOT DETERMINED
HEAT VALUE: NOT DETERMINED
BOILING POINT: NOT DETERMINED
FREEZING/MELTING PT.: NOT DETERMINED
FLAMMABILITY:
(SOLID, GAS): NO DATA AVAILABLE
FLASH POINT: NOT DETERMINED
PARTITION COEFFICIENT: NOT DETERMINED
OCTANOL: NOT DETERMINED
VAPOR PRESSURE: NOT DETERMINED
VAPOR DENSITY:
(AIR = 1): NOT DETERMINED
PH: NOT DETERMINED
VOC: NA
EVAP. RATE: NOT DETERMINED
BULK DENSITY: NA
MOLECULAR WEIGHT: MIXTURE
AUTO-IGNITION TEMP: NOT DETERMINED
DECOMP TEMP: NOT DETERMINED
UFL/LFL: NA
| 10 STABILITY AND REACTIVITY | |
STABILITY: PRODUCT IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: INCOMPATIBILITIES, FLAMES, IGNITION SOURCES.
MATERIALS TO AVOID:
PURE HYDROGEN SULFIDE IS DANGEROUSLY REACTIVE WITH FUMING OR STRONG NITRIC
ACID AND STRONG OXIDIZERS; MAY IGNITE ON CONTACT WITH A VARIETY OF METAL
OXIDES (I.E. COPPER OXIDE, NICKEL OXIDE, SILVER (I & II) OXIDE, SODIUM
PEROXIDE); IGNITES IN CONTACT WITH FLUORINE AND CHLORINE MONOXIDE; AND
FORMS EXPLOSIVE REACTIONS WITH OXYGEN DIFLUORIDE, NITROGEN TRIFLUORIDE
AND MANY HALOGENIC COMPOUNDS.
HAZARDOUS DECOMPOSITION: NITROGEN OXIDES (NOX) AND SULFUR OXIDES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| 11 TOXICOLOGICAL INFORMATION | |
COMPONENT(S): AIR; HYDROGEN SULFIDE
CAS NO(S): N/A; 7783-06-4
ACUTE TOXICITY:
LC50 INHALATION - RAT: 712 PPM (1 H)
LC50 INHALATION - MOUSE: 634 PPM (1 H)
LC50 INHALATION - DOG: 1000 - 3000 PPM (15 MIN)
SKIN CORROSION/IRRITATION: CAUSES MILD SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION:
MAY CAUSE EYE IRRITATION. CONCENTRATIONS OF 50 - 500 PPM CAUSE EYE
IRRITATION. OCULAR TOXICITY HAS BEEN REPORTED AT CONCENTRATION RANGING
FROM 5 - 30 PPM.
RESPIRATORY OR SKIN SENSITATION: NO DATA AVAILABLE.
GERM CELL MUTAGENICITY: NO DATA AVAILABLE.
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY:
REPRODUCTIVE TOXICITY INHALATION - RAT: EFFECTS ON NEWBORN (PHYSICAL).
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
RESPIRATORY SYSTEM - CONCENTRATIONS OF 50 - 500 PPM CAUSE RESPIRATORY
IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE.
ASPIRATION HAZARD: NO DATA AVAILABLE.
ADDITIONAL INFORMATION:
COMPONENT: AIR; RTECS: N/A
COMPONENT: HYDROGEN SULFIDE; RTECS: MX1225000
| 12 ECOLOGICAL INFORMATION | |
COMPONENT(S): AIR; HYDROGEN SULFIDE
CAS NO(S): N/A; 7783-06-4
TOXICITY:
TOXICITY TO FISH:
LC50 - PIMEPHALES PROMELAS (FATHEAD MINNOW): 0.016 MG/L (96 H)
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES: NO DATA AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
HYDROGEN SULFIDE DOES NOT ABSORB SOLAR RADIATION AND THEREFORE DOES NOT
UNDERGO PHOTOLYSIS OR PHOTOCHEMICAL REACTION WITH OXYGEN. THE PERSISTENCE
OF HYDROGEN SULFIDE IN THE ATMOSPHERE IS DEPENDENT ON SEASON, LATITUDE
AND ATMOSPHERIC CONDITIONS, RANGING FROM 1 TO 40 DAYS WITH DECREASED
TEMPERATURES AND DECREASED LEVELS OF HYDROXIDE IN NORTHERN REGIONS
INCREASING RESIDENCE TIME.
BIOACCUMULATIVE POTENTIAL:
IN SOIL AND WATER, HYDROGEN SULFIDE IS OXIDIZED TO ELEMENTAL SULFUR BY
MICROORGANISMS VIA OXIDATION-REDUCTION REACTIONS, WHICH FORM PART OF THE
GLOBAL SULFUR CYCLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
RESULTS OF PBT AND VPVB ASSESSMENT: NOT REQUIRED/CONDUCTED.
OTHER ADVERSE EFFECTS:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL. VERY TOXIC TO AQUATIC LIFE. PRODUCT DOES NOT CONTAIN
CLASS I OR CLASS II OZONE DEPLETING SUBSTANCES.
| 13 DISPOSAL CONSIDERATIONS | |
PRODUCT AND CONTAMINATED PACKAGING:
DO NOT ATTEMPT TO DISPOSE OF RESIDUAL WASTE OR UNUSED QUANTITIES IN
RETURNABLE CONTAINERS. RETURN IN THE SHIPPING CONTAINER, PROPERLY LABELED,
WITH ANY VALVE OUTLET PLUGS OR CAPS SECURE AND VALVE PROTECTION CAP IN
PLACE TO NORLAB FOR PROPER DISPOSAL. NON-REFILLABLE CONTAINERS SHOULD BE
VENTED IN A WELL-VENTILATED AREA THEN DISPOSED OF IN COMPLIANCE WITH LOCAL
REGULATIONS, OR RETURNED TO NORLAB.
| 14 TRANSPORT INFORMATION | |
DOT CLASS: NON-FLAMMABLE GAS (2.2) #2.2
UN #: UN 1956
CLASS: 2
PROPER SHIPPING NAME: COMPRESSED GAS, N.O.S. (HYDROGEN SULFIDE, AIR)
DOT (US):
UN NUMBER: 1956
CLASS: 2.2
ERG #: 126
PROPER SHIPPING NAME: COMPRESSED GAS, N.O.S. (HYDROGEN SULFIDE, AIR)
IMDG:
UN NUMBER: 1956 CLASS: 2
EMS-NO: F-C, S-V
PROPER SHIPPING NAME: COMPRESSED GAS, N.O.S. (HYDROGEN SULFIDE, AIR)
IATA:
UN NUMBER: 1956
CLASS: 2
PROPER SHIPPING NAME: COMPRESSED GAS, N.O.S. (HYDROGEN SULFIDE, AIR)
CANADA TDG:
UN NUMBER: 1956
CLASS: 2.2
PROPER SHIPPING NAME: COMPRESSED GAS, N.O.S. (HYDROGEN SULFIDE, AIR)
CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
| 15 REGULATORY INFORMATION | |
COMPONENT (CAS/PERC) CODES
*AIR (N/A 99.9-99.9999%) MASS, NJHS, PA,
SARA311/312, TSCA
*HYDROGEN SULFIDE (7783064 0.0001-0.0999%) CERCLA, CSWHS, EHS302, HAP,
MASS, NJEHS, NJHS, OSHAPSM,
OSHAWAC, PA, SARA311/312,
SARA313, TOXICRCRA, TSCA,
TXAIR, TXHWL
HYDROGEN SULFIDE IS LISTED UNDER THE ACCIDENT PREVENTION PROVISIONS OF
SECTION 112 (R) OF THE CLEAN AIR ACT (CAA) WITH A THRESHOLD QUANTITY (TQ)
OF 10,000 POUNDS.
HYDROGEN SULFIDE IS LISTED AS AN EXTREMELY HAZARDOUS SUBSTANCE (EHS)
SUBJECT TO STATE AND LOCAL REPORTING UNDER SECTION 304 OF SARA TITLE III
(EPCRA). THE PRESENCE OF HYDROGEN SULFIDE IN QUANTITIES IN EXCESS OF THE
THRESHOLD PLANNING QUANTITY (TPQ) OF 500 POUNDS REQUIRES CERTAIN EMERGENCY
PLANNING ACTIVITIES TO BE CONDUCTED.
RELEASES OF HYDROGEN SULFIDE IN QUANTITIES EQUAL TO OR GREATER THAN THE
REPORTABLE QUANTITY (RQ) OF 100 POUNDS ARE SUBJECT TO REPORTING TO THE
NATIONAL RESPONSE CENTER UNDER CERCLA, SECTION 304 SARA TITLE III.
REGULATORY KEY DESCRIPTIONS:
CERCLA = SUPERFUND CLEAN UP SUBSTANCE
CSWHS = CLEAN WATER ACT HAZARDOUS SUBSTANCES
EHS302 = EXTREMELY HAZARDOUS SUBSTANCE
HAP = HAZARDOUS AIR POLLUTANTS
MASS = MA MASSACHUSETTS HAZARDOUS SUBSTANCES LIST
NJEHS = NJ EXTRAORDINARILY HAZARDOUS SUBSTANCES
NJHS = NJ RIGHT-TO-KNOW HAZARDOUS SUBSTANCES
OSHAPSM = OSHA CHEMICALS REQUIRING PROCESS SAFETY MANAGEMENT
OSHAWAC = OSHA WORKPLACE AIR CONTAMINANTS
PA = PA RIGHT-TO-KNOW LIST OF HAZARDOUS SUBSTANCES
SARA311/312 = SARA 311/312 TOXIC CHEMICALS
SARA313 = SARA 313 TITLE III TOXIC CHEMICALS
TOXICRCRA = RCRA TOXIC HAZARDOUS WASTES (U-LIST)
TSCA = TOXIC SUBSTANCES CONTROL ACT
TXAIR = TX AIR CONTAMINANTS WITH HEALTH EFFECTS SCREENING LEVEL
TXHWL = TX HAZARDOUS WASTE LIST
| 16 OTHER INFORMATION | |
DISCLAIMER:
THE DATA IN THIS SAFETY DATA SHEET RELATES ONLY TO THE SPECIFIC MATERIAL
DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH ANY OTHER
MATERIAL IN ANY PROCESS. THE INFORMATION SET FORTH HEREIN IS FURNISHED
FREE OF CHARGE AND IS BASED ON TECHNICAL DATA THAT NORLAB BELIEVES TO BE
RELIABLE. IT IS INTENDED FOR USE BY PERSONS HAVING TECHNICAL SKILL AND AT
THEIR OWN DISCRETION AND RISK. SINCE CONDITIONS OF USE ARE OUTSIDE OF
NORLAB'S CONTROL, NORLAB MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, AND
ASSUMES NO LIABILITY IN CONNECTION WITH ANY USE OF THIS INFORMATION.
NOTHING HEREIN IS TO BE TAKEN AS A LICENSE TO OPERATE UNDER, OR A
RECOMMENDATION TO INFRINGE UPON, ANY PATENTS.
NORLAB
A DIVISION OF NORCO, INC.
SDS
SAFETY DATA SHEET
CO 0.0001% TO 0.0999%, CH4 0.0001% TO 2.5%, O2 2.0% TO 23.5%, IN N2
SDS NUMBER: NLB 2280
REVISION DATE: 9/10/2015
| 1 PRODUCT AND COMPANY IDENTIFICATION | |
MANUFACTURER:
NORLAB
898 W. GOWEN RD.
BOISE, ID 83705
CONTACT: QUALITY DEPT.
PHONE: 208-336-1643
WEB: WWW.NORLAB-GAS.COM
PRODUCT NAME:
CO 0.0001% TO 0.0999%, CH4 0.0001% TO 2.5%, O2 2.0% TO 23.5%, IN N2
REVISION DATE: 9/10/2015
VERSION: 1
SDS NUMBER: NLB 2280
COMMON NAME:
CARBON MONOXIDE 0.0001% TO 0.999%, METHANE 0.0001% TO 2.5%, OXYGEN 2.0 TO
23.5%, IN NITROGEN
CAS NUMBER: NOT AVAILABLE - GAS MIXTURE
EPA NUMBER: NOT AVAILABLE
RCRA NUMBER: NOT APPLICABLE
CHEMICAL FAMILY: GAS MIXTURE
CHEMICAL FORMULA: CO, CH4, 02, IN N2
SYNONYMS: CALIBRATION GAS
PRODUCT USE: CALIBRATION OF ANALYTICAL INSTRUMENTATION
FOR TRANSPORTATION EMERGENCY CONTACT CHEMTREC: 800-424-9300
| 2 HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
PHYSICAL, GASES UNDER PRESSURE, COMPRESSED GAS
HEALTH, ACUTE TOXICITY, 5 INHALATION
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS SIGNAL WORD: WARNING
GHS HAZARD PICTOGRAMS: GAS CYLINDER
GHS HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H333: MAY BE HARMFUL IF INHALED
OSHA-H01: MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
GHS PRECAUTIONARY STATEMENTS:
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P271: USE ONLY OUTDOORS OR IN A WE 11-VENT HATED AREA.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P304+340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P403+233: STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P410+412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING.
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CGA-PG29: DO NOT DEPEND ON ODOR TO DETECT PRESENCE OF GAS.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS:
ROUTE OF ENTRY: INHALATION;
TARGET ORGANS: RESPIRATORY SYSTEM;
INHALATION:
THIS PRODUCT CONTAINS CARBON MONOXIDE. INHALATION OF RELATIVE HIGH
CONCENTRATIONS OF THIS GAS MAY CAUSE SYMPTOMS OF CARBON MONOXIDE EXPOSURE.
CARBON MONOXIDE IS ODORLESS AND COLORLESS. THERE MAY BE NO WARNING OF
OVEREXPOSURE UNTIL SYMPTOMS OCCUR. CARBON MONOXIDE IS A CHEMICAL
ASPHYXIANT. INHALED CARBON MONOXIDE BINDS WITH BLOOD HEMOGLOBIN TO FORM
CARBOXYHEMOGLOBIN. CARBOXYHEMOGLOBIN CANNOT TAKE PART IN NORMAL OXYGEN
TRANSPORT, GREATLY REDUCING THE BLOOD'S ABILITY TO TRANSPORT OXYGEN.
DEPENDING ON CONCENTRATION OF CARBON MONOXIDE AND DURATION OF EXPOSURE,
SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, HEART PALPITATIONS, WEAKNESS,
CONFUSION, NAUSEA, AND EVEN CONVULSIONS, EVENTUAL UNCONSCIOUSNESS AND
DEATH. LACK OF OXYGEN FROM CARBON MONOXIDE OVER EXPOSURE MAY PRODUCE
IMMEDIATE AS WELL AS DELAYED NEUROLOGICAL EFFECTS. CARBON MONOXIDE MAY
ALSO ADVERSELY AFFECT FETAL DEVELOPMENT.
SKIN CONTACT:
CONTACT WITH RAPIDLY EXPANDING GAS NEAR THE POINT OF RELEASE MAY CAUSE
FROSTBITE WITH REDNESS, SKIN COLOR CHANGE TO GRAY OR WHITE, AND BLISTERING.
EYE CONTACT:
NONE ANTICIPATED. CONTACT WITH RAPIDLY EXPANDING GAS NEAR THE POINT OF
RELEASE MAY CAUSE FROSTBITE.
NFPA:
HEALTH 1
FIRE 0
REACTIVITY 0
SPECIFIC HAZARD N/A
HMIS III:
HEALTH 1
FIRE 0
PHYSICAL HAZARD 3
HMIS PPE: B - SAFETY GLASSES, GLOVES
NFPA:
HEALTH 1
FIRE HAZARD 0
REACTIVITY 0
SPECIFIC HAZARD
HMIS:
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARD 3
PERSONAL PROTECTION B
PPE:
CHEMICAL GOGGLES
GLOVES
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS:
CAS# % CHEMICAL NAME
630-08-0 0.0001-0.0999% CARBON MONOXIDE
74-82-8 0.0001-2.5% METHANE
7782-44-7 2.0-23.5% OXYGEN
7727-37-9 73.9001-97.9998% NITROGEN
| 4 FIRST AID MEASURES | |
INHALATION:
PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO
PRODUCT. RESCUE PERSONNEL SHOULD BE EQUIPED WITH SELF-CONTAINED BREATHING
APPARATUS. CONSCIOUS PERSONS SHOULD BE ASSISTED TO AN UNCONTAMINATED AREA
AND BE TREATED WITH SUPPLEMENTAL OXYGEN. QUICK REMOVAL FROM THE
CONTAMINATED AREA IS MOST IMPORTANT. UNCONSCIOUS PERSONS SHOULD BE MOVED
TO AN UNCONTAMINATED AREA, GIVEN ASSISTED (ARTIFICIAL) RESPIRATION AND
SUPPLEMENTAL OXYGEN. THE ADMINISTERING OF OXYGEN AT AN ELEVATED PRESSURE
(UP TO 2 TO 2.5 ATMOSPHERES) HAS SHOWN TO BE BENEFICIAL AS HAS TREATMENT
IN A HYPERBARIC CHAMBER. THE PHYSICIAN SHOULD BE INFORMED THAT THE PATIENT
HAS INHALED TOXIC QUANTITIES OF CARBON MONOXIDE.
SKIN CONTACT:
NONE REQUIRED FOR GAS. FOR FROSTBITE, IMMERSE SKIN IN LUKEWARM WATER. DO
NOT USE HOT WATER. OBTAIN MEDICAL ATTENTION.
EYE CONTACT:
NONE REQUIRED FOR GAS. IF FROSTBITE IS SUSPECTED, FLUSH EYES WITH COOL
WATER FOR 15 MINUTES AND OBTAIN IMMEDIATE MEDICAL ATTENTION.
INGESTION: NOT A DIRECT HAZARD.
| 5 FIRE FIGHTING MEASURES | |
FLAMMABILITY: NOT FLAMMABLE
FLASH POINT: NONE
FLASH POINT METHOD: NOT APPLICABLE
BURNING RATE: NOT APPLICABLE
AUTOIGNITION TEMP: NONE
LEL: NONE
UEL: NONE
FIRE AND EXPLOSION HAZARDS:
NONFLAMMABLE. CYLINDERS MAY RUPTURE VIOLENTLY OR VENT RAPIDLY FROM PRESSURE
WHEN INVOLVED IN A FIRE SITUATION.
EXTINGUISHING MEDIA:
NONE REQUIRED. USE AS APPROPRIATE FOR SURROUNDING MATERIALS
FIRE FIGHTING INSTRUCTIONS:
FIREFIGHTERS SHOULD WEAR RESPIRATORY PROTECTION (SCBA) AND FULL TURNOUT
OR BUNKER GEAR. CONTINUE TO COOL FIRE-EXPOSED CYLINDERS UNTIL WELL AFTER
FLAMES ARE EXTINGUISHED.
| 6 ACCIDENTAL RELEASE MEASURES | |
EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE APPROPRIATE PROTECTIVE
EQUIPMENT. IF LEAK IS IN USER'S EQUIPMENT, BE CERTAIN TO PURGE PIPING WITH
INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN CONTAINER OR VALVE,
CONTACT THE APPROPRIATE EMERGENCY TELEPHONE NUMBER LISTED IN SECTION 1, OR
CALL YOUR CLOSEST NORCO/NORLAB LOCATION.
| 7 HANDLING AND STORAGE | |
HANDLING PRECAUTIONS:
USE ONLY IN WELL-VENTILATED AREAS. VALVE PROTECTION CAPS MUST REMAIN IN
PLACE UNLESS THE CYLINDER IS SECURED WITH VALVE OUTLET PIPED TO USE POINT.
DO NOT DRAG, SLIDE OR ROLL CYLINDERS. USE A SUITABLE HAND TRUCK FOR
CYLINDER MOVEMENT. USE A PRESSURE REGULATOR WHEN CONNECTING CYLINDER TO
LOWER PRESSURE (<3000 PSIG) PIPING OR SYSTEMS. DO NOT HEAT CYLINDER BY ANY
MEANS TO INCREASE THE DISCHARGE RATE OF PRODUCT FROM THE CYLINDER. USE A
CHECK VALVE OR TRAP IN THE DISCHARGE LINE TO PREVENT HAZARDOUS BACKFLOW
INTO THE CYLINDER.
FOR ADDITIONAL RECOMMENDATIONS, CONSULT COMPRESSED GAS ASSOCIATION
PAMPHLETS P-1.
NEVER CARRY A COMPRESSED GAS CYLINDER OR A CONTAINER OF A GAS IN CRYOGENIC
LIQUID FROM IN AN ENCLOSED SPACE SUCH AS A CAR TRUNK, VAN OR STATION
WAGON. A LEAK CAN RESULT IN A FIRE, EXPLOSION, ASPHYXIATION OR A TOXIC
EXPOSURE.
STORAGE REQUIREMENTS:
PROTECT CYLINDERS FROM PHYSICAL DAMAGE. STORE IN COOL, DRY, WELL-VENTILATED
AREA AWAY FROM HEAVY TRAFFIC AREAS AND EMERGENCY EXITS. DO NOT ALLOW THE
TEMPERATURE WHERE CYLINDERS ARE STORED TO EXCEED 125 DEGREES F
(52 DEGREES C). CYLINDERS SHOULD BE STORED UPRIGHT AND FIRMLY SECURED TO
PREVENT FALLING OR BEING KNOCKED OVER. FULL AND EMPTY CYLINDERS SHOULD BE
SEGREGATED. USE A "FIRST IN-FIRST OUT" INVENTORY SYSTEM TO PREVENT FULL
CYLINDERS FROM BEING STORED FOR EXCESSIVE PERIODS OF TIME. POST "NO
SMOKING OR OPEN FLAMES" SIGN IN THE STORAGE OR USE AREA.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
ALL VENTILATION SHOULD BE DESIGNED IN ACCORDANCE WITH OSHA STANDARD
(29 CFR 1910.94). USE LOCAL EXHAUST AT FILLING ZONES AND WHERE LEAKAGE
AND DUST FORMATION IS PROBABLE. USE MECHANICAL (GENERAL) VENTILATION FOR
STORAGE AREAS. USE APPROPRIATE VENTILATION AS REQUIRED TO KEEP EXPOSURE
LIMITS IN AIR BELOW TLV & PEL LIMITS. MAINTAIN ATMOSPHERIC OXYGEN CONTENT
AT OR ABOVE 19.5%
PERSONAL PROTECTIVE EQUIPMENT:
HMIS PP, B
SAFETY GLASSES, GLOVES
EYE/FACE PROTECTION: SAFETY GOGGLES OR GLASSES AS APPROPRIATE FOR THE JOB.
SKIN PROTECTION: PROTECTIVE GLOVES OF MATERIAL APPROPRIATE FOR THE JOB.
RESPIRATORY PROTECTION:
POSITIVE PRESSURE AIR LINE WITH FULL-FACE MASK AND ESCAPE BOTTLE OR
SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE.
OTHER/GENERAL PROTECTION: SAFETY SHOES.
CARBON MONOXIDE:
OSHA PEL: 50 PPM TWA
ACGIH PEL: 25 PPM TWA
LC5O OR LD5O: 3760 PPM INHALATION/RAT 1 HR. TIME ADJ.
RTECS #: FG3500000
IDLH: 1200 PPM
METHANE:
OSHA PEL: NONE ESTABLISHED
ACGIH PEL: 1000 PPM
LC5O: NOT AVAILABLE
RTECS #: TX2275000
IDLH: NOT AVAILABLE
OXYGEN:
OSHA PEL: NOT AVAILABLE
ACGIH PEL: NOT AVAILABLE
LC50: NOT AVAILABLE
RTECS#: R0206000
IDLH: NOT AVAILABLE
NITROGEN:
OSHA PEL: NONE ESTABLISHED
ACGIH PEL: SIMPLE ASPHYXIANT
LC50 OR LD50: NOT AVAILABLE
RTECS#: QW9700000
IDLH: NONE ESTABLISHED
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORLESS GAS
PHYSICAL STATE: GAS
ODOR: ODORLESS
ODOR THRESHOLD: NOT APPLICABLE
MOLECULAR FORMULA: CO, CH4, O2, IN N2
PARTICLE SIZE: NOT APPLICABLE
SOLUBILITY: SLIGHTLY SOLUBLE
SPEC GRAV./DENSITY: NOT APPLICABLE
SOFTENING POINT: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
PERCENT VOLATILE: 100%
SAT. VAP. CONE.: NOT DETERMINED
FREEZING/MELTING PT.: NOT DETERMINED
BOILING POINT: NOT DETERMINED
FLASH POINT: NOT APPLICABLE
FLAMMABILITY: NOT FLAMMABLE
UFL/LFL: NONE
| 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: PRODUCT IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: AVOID OPEN FLAMES AND HIGH TEMPERATURES.
MATERIALS TO AVOID:
STRONG OXIDIZING AGENTS, SODIUM/SODIUM OXIDES, POTASSIUM.
HAZARDOUS DECOMPOSITION:
COMBUSTION WILL PRODUCE CARBON DIOXIDE AND, POSSIBLY TOXIC CHEMICALS SUCH
AS CARBON MONOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| 11 TOXICOLOGICAL INFORMATION | |
REPRODUCTIVE:
INHALATION OF 150 PPM CARBON MONOXIDE FOR 24 HOURS BY PREGNANT RATS
PRODUCED CARDIOVASCULAR AND BEHAVIORAL DEFECTS IN OFFSPRING. TOXIC EFFECTS
TO FERTILITY WERE OBSERVED IN FEMALE RATS EXPOSED TO 1 MG/M3 FOR 24 HOURS.
SIMILAR EFFECTS OBSERVED IN OTHER MAMMALIAN SPECIES.
MUTAGENIC:
GENETIC CHANGES OBSERVED IN MAMMALIAN CELL ASSAY SYSTEMS AT EXPOSURE OF
1500 TO 2500 PPM CARBON MONOXIDE FOR 10 MINUTES.
OTHER:
DEGENERATIVE CHANGES WERE OBSERVED IN THE BRAIN OF RATS CHRONICALLY
EXPOSED TO 30 MG/M3 CARBON MONOXIDE.
HIGH CONCENTRATIONS OF ALIPHATIC HYDROCARBON GASES MAY CAUSE CNS
DEPRESSION. RECENT INFORMATION SUGGESTS THAT C1 - C4 ALIPHATIC (ALKANE)
HYDROCARBON GASES CAN CAUSE POTENTIALLY FATAL CARDIAC ARRHYTHMIAS. CARDIAC
SENSITIZATION TO ADRENALIN IN DOGS HAS BEEN NOTED FOLLOWING INHALATION.
IN DOGS, THE HEART WAS MORE SENSITIVE TO EPINEPHRINE INDUCED VENTRICULAR
FIBRILLATIONS FOLLOWING EXPOSURE TO 15 - 90% PROPANE FOR 10 MINUTES.
VENTRICULAR FIBRILLATIONS HAVE BEEN REPORTED IN A 15 YEAR OLD GIRL AND
A 14 YEAR OLD BOY FOLLOWING INHALATION OF N-BUTANE (CONCENTRATION NOT
REPORTED).
| 12 ECOLOGICAL INFORMATION | |
PRODUCT DOES NOT CONTAIN CLASS I OR CLASS II OXONE DEPLETING SUBSTANCES.
NOT TOXIC. WILL NOT BIOCONCENTRATE.
| 13 DISPOSAL CONSIDERATIONS | |
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. DO NOT ATTEMPT TO DISPOSE
OF WASTE OR UNUSED QUANTITIES IN RETURNABLE CYLINDERS. RETURN IN THE
SHIPPING CONTAINER, PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS
SECURE AND VALVE PROTECTION CAP IN PLACE TO NORLAB FOR PROPER DISPOSAL.
NON-REFILLABLE CONTAINERS SHOULD BE VENTED IN A WELL-VENTILATED AREA THEN
DISPOSED OF IN COMPLIANCE WITH LOCAL REGULATIONS, OR RETURNED TO NORLAB.
| 14 TRANSPORT INFORMATION | |
UN1956:
PROPER SHIPPING NAME US:
UN 1956, COMPRESSED GAS N.O.S., (CARBON MONOXIDE, NITROGEN), 2.2
PROPER SHIPPING NAME CANADA:
UNI956, COMPRESSED GAS, N.O.S., (CARBON MONOXIDE, NITROGEN), 2.2
CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
| 15 REGULATORY INFORMATION | |
COMPONENT (CAS#) [%] CODES
CARBON MONOXIDE (630-08-0) [0.0001-0.0999%] MASS, NJEHS, NJHS,
OSHAWAC, PA, PROP65,
SARA311/312, TSCA,
TXAIR
METHANE (74-82-8) [0.0001-2.5%] MASS, NJHS, PA, TSCA,
TXAIR
OXYGEN (7782-44-7) [2.0-23.5%] MASS, PA, TSCA
NITROGEN (7727-37-9) [73.9001-97.9998%] MASS, PA, TSCA
REGULATORY CODE DESCRIPTIONS:
MASS = MA MASSACHUSETTS HAZARDOUS SUBSTANCES LIST
NJEHS = NJ EXTRAORDINARILY HAZARDOUS SUBSTANCES
NJHS = NJ RIGHT-TO-KNOW HAZARDOUS SUBSTANCES
OSHAWAC = OSHA WORKPLACE AIR CONTAMINANTS
PA = PA RIGHT-TO-KNOW LIST OF HAZARDOUS SUBSTANCES
PROP65 = CAPROP 65
SARA311/312 = SARA 311/312 TOXIC CHEMICALS
TSCA = TOXIC SUBSTANCES CONTROL ACT
TXAIR = TX AIR CONTAMINANTS WITH HEALTH EFFECTS SCREENING LEVEL
| 16 OTHER INFORMATION | |
DISCLAIMER:
ALTHOUGH REASONABLE CARE HAS BEEN TAKEN IN THE PREPARATION OF THIS
DOCUMENT, WE EXTEND NO WARRANTIES AND MAKE NO REPRESENTATIONS AS TO THE
ACCURACY OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN, AND ASSUME
NO RESPONSIBILITY REGARDING THE SUITABILITY OF THIS INFORMATION FOR THE
USER'S INTENDED PURPOSES OR FOR THE CONSEQUENCES OF ITS USE. EACH
INDIVIDUAL SHOULD MAKE A DETERMINATION AS TO THE SUITABILITY OF THE
INFORMATION FOR THEIR PARTICULAR PURPOSE(S).
INDUSTRIAL SCIENTIFIC
PTG-4065
SAFETY DATA SHEET
PTG-4065
THIS SDS CONFORMS TO U.S. CODE OF FEDERAL REGULATIONS 29 CFR 1910.1200,
HAZARD COMMUNICATION.
PREPARED IN ACCORDANCE WITH THE SDS REQUIREMENTS OF THE WHMIS CONTROLLED
PRODUCTS REGULATION.
DATE OF ISSUE: 05/11/2015
REVISION DATE: 01/14/2016
SUPERSEDES: 07/01/2015
VERSION: 1.1
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: SUBSTANCE
NAME: PTG-4065
CAS NO: 74-82-8
FORMULA: CH4
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: INDUSTRIAL USE. USE AS DIRECTED.
RECOMMENDED USE AND RESTRICTIONS ON USE: CALIBRATION / REFERENCE
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURED FOR:
INDUSTRIAL SCIENTIFIC CORPORATION
1 LIFE WAY
PITTSBURGH, PA 15205-7500
USA
BY:
PORTAGAS(PRAXAIR, INC)
1202 E SAM HOUSTON PKWY S
PASADENA, TX 77503
CANADA:
PRAXAIR CANADA INC
1 CITY CENTRE DRIVE
SUITE 1200
MISSISSAUGA, ONTARIO, L5B 1M2
1-888-257-5149
USA PHONE:
412-788-4353
1-800-DETECTS (338-3287)
FAX: 412-788-8353
WWW.INDSCI.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
ONSITE EMERGENCIES: 1-800-645-4633
CHEMTREC:
USA: 1-800-424-9300
INTERNATIONAL: 001-703-527-3887 (COLLECT CALLS ACCEPTED, CONTRACT 17729)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAM. GAS 1: H220
COMPRESSED GAS: H280
AQUATIC ACUTE 3: H402
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS04: GAS CYLINDER
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H220: EXTREMELY FLAMMABLE GAS
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H402: HARMFUL TO AQUATIC LIFE
OSHA-H01: MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, HOT SURFACES, OPEN FLAMES, SPARKS. - NO SMOKING
P273: AVOID RELEASE TO THE ENVIRONMENT
P377:
LEAKING GAS FIRE: DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY
P381: ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO
P403: USE AND STORE ONLY OUTDOORS OR IN A WELL-VENTILATED PLACE
P261: AVOID BREATHING GAS, VAPORS
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH CONTAINER SUPPLIER/OWNER
INSTRUCTIONS
CGA-PG27: READ AND FOLLOW THE SAFETY DATA SHEET (SDS) BEFORE USE
CGA-PG21: OPEN VALVE SLOWLY
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE
CGA-PG11: NEVER PUT CYLINDERS INTO UNVENTILATED AREAS OF PASSENGER VEHICLES
CGA-PG12: DO NOT OPEN VALVE UNTIL CONNECTED TO EQUIPMENT PREPARED FOR USE
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C
(125 DEG. F)
CGA-MP01:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
GET MEDICAL ADVICE/ATTENTION
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
ASPHYXIANT IN HIGH CONCENTRATIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE.
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-CA CLASSIFICATION:
FLAM. GAS 1: H220
COMPRESSED GAS: H280
AQUATIC ACUTE 3: H402
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-CA LABELLING:
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS04: GAS CYLINDER
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE GAS
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
HARMFUL TO AQUATIC LIFE
MAY DISPLACE OXYGEN AND CAUSE RAPID
SUFFOCATION
PRECAUTIONARY STATEMENTS:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING
AVOID RELEASE TO THE ENVIRONMENT
LEAKING GAS FIRE:
DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY
IN CASE OF LEAKAGE, ELIMINATE ALL IGNITION SOURCES
USE AND STORE ONLY OUTDOORS OR IN A WELL-VENTILATED PLACE
AVOID BREATHING GAS, VAPORS
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH CONTAINER
SUPPLIER/OWNER INSTRUCTIONS
READ AND FOLLOW THE SAFETY DATA SHEET (SDS) BEFORE USE
OPEN VALVE SLOWLY
USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE
NEVER PUT CYLINDERS INTO UNVENTILATED AREAS OF PASSENGER VEHICLES
DO NOT OPEN VALVE UNTIL CONNECTED TO EQUIPMENT PREPARED FOR USE
CLOSE VALVE AFTER EACH USE AND WHEN EMPTY
USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C
(125 DEG. F)
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. GET MEDICAL
ADVICE/ATTENTION
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
ASPHYXIANT IN HIGH CONCENTRATIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS-CA): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE:
NAME: PTG-4065
CAS NO: 74-82-8
NAME PRODUCT IDENTIFIER % COMMON NAME (SYNONYMS)
METHANE (CAS NO) 74-82-8 <=100 MARSH GAS / NATURAL GAS,
REFRIGERATED LIQUID / METHANE,
COMPRESSED
3.2. MIXTURE: NOT APPLICABLE
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES AFTER INHALATION:
REMOVE TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, TRAINED PERSONNEL SHOULD GIVE OXYGEN. CALL A PHYSICIAN.
FIRST-AID MEASURES AFTER EYE CONTACT:
IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. HOLD
THE EYELIDS OPEN AND AWAY FROM THE EYEBALLS TO ENSURE THAT ALL SURFACES ARE
FLUSHED THOROUGHLY. CONTACT AN OPHTHALMOLOGIST IMMEDIATELY.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO ADDITIONAL INFORMATION AVAILABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NONE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY OR FOG. USE EXTINGUISHING MEDIA
APPROPRIATE FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: EXTREMELY FLAMMABLE GAS.
EXPLOSION HAZARD:
EXTREMELY FLAMMABLE GAS. FORMS EXPLOSIVE MIXTURES WITH AIR AND OXIDIZING
AGENTS.
REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EVACUATE ALL PERSONNEL FROM THE DANGER AREA. USE SELF-CONTAINED BREATHING
APPARATUS (SCBA) AND PROTECTIVE CLOTHING. IMMEDIATELY COOL CONTAINERS WITH
WATER FROM MAXIMUM DISTANCE. STOP FLOW OF GAS IF SAFE TO DO SO, WHILE
CONTINUING COOLING WATER SPRAY. REMOVE IGNITION SOURCES IF SAFE TO DO SO.
REMOVE CONTAINERS FROM AREA OF FIRE IF SAFE TO DO SO. ON-SITE FIRE BRIGADES
MUST COMPLY WITH OSHA 29 CFR 1910.156 AND APPLICABLE STANDARDS UNDER 29 CFR
1910 SUBPART L-FIRE PROTECTION.
PROTECTION DURING FIREFIGHTING:
COMPRESSED GAS: ASPHYXIANT. SUFFOCATION HAZARD BY LACK OF OXYGEN.
DANGER!
FLAMMABLE, HIGH PRESSURE GAS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS.
OTHER INFORMATION:
CONTAINERS ARE EQUIPPED WITH A PRESSURE RELIEF DEVICE. (EXCEPTIONS MAY
EXIST WHERE AUTHORIZED BY DOT.).
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
IF VENTING OR LEAKING GAS CATCHES FIRE, DO NOT EXTINGUISH FLAMES.
FLAMMABLE VAPORS MAY SPREAD FROM LEAK, CREATING AN EXPLOSIVE REIGNITION
HAZARD. VAPORS CAN BE IGNITED BY PILOT LIGHTS, OTHER FLAMES, SMOKING,
SPARKS, HEATERS, ELECTRICAL EQUIPMENT, STATIC DISCHARGE, OR OTHER IGNITION
SOURCES AT LOCATIONS DISTANT FROM PRODUCT HANDLING POINT. EXPLOSIVE
ATMOSPHERES MAY LINGER. BEFORE ENTERING AN AREA, ESPECIALLY A CONFINED
AREA, CHECK THE ATMOSPHERE WITH AN APPROPRIATE DEVICE.
6.1.1. FOR NON-EMERGENCY PERSONNEL: NO ADDITIONAL INFORMATION AVAILABLE
6.1.2. FOR EMERGENCY RESPONDERS: NO ADDITIONAL INFORMATION AVAILABLE
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT WASTE FROM CONTAMINATING THE SURROUNDING ENVIRONMENT. PREVENT SOIL
AND WATER POLLUTION. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS. CONTACT SUPPLIER FOR ANY
SPECIAL REQUIREMENTS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
NO ADDITIONAL INFORMATION AVAILABLE
6.4. REFERENCE TO OTHER SECTIONS:
SEE ALSO SECTIONS 8 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING. USE ONLY NON-SPARKING TOOLS. USE ONLY EXPLOSION-PROOF
EQUIPMENT. WEAR LEATHER SAFETY GLOVES AND SAFETY SHOES WHEN HANDLING
CYLINDERS. PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT DRAG, ROLL,
SLIDE OR DROP. WHILE MOVING CYLINDER, ALWAYS KEEP IN PLACE REMOVABLE VALVE
COVER. NEVER ATTEMPT TO LIFT A CYLINDER BY ITS CAP; THE CAP IS INTENDED
SOLELY TO PROTECT THE VALVE. WHEN MOVING CYLINDERS, EVEN FOR SHORT
DISTANCES, USE A CART (TROLLEY, HAND TRUCK, ETC.) DESIGNED TO TRANSPORT
CYLINDERS. NEVER INSERT AN OBJECT (E.G, WRENCH, SCREWDRIVER, PRY BAR) INTO
CAP OPENINGS; DOING SO MAY DAMAGE THE VALVE AND CAUSE A LEAK. USE AN
ADJUSTABLE STRAP WRENCH TO REMOVE OVER-TIGHT OR RUSTED CAPS. SLOWLY OPEN
THE VALVE. IF THE VALVE IS HARD TO OPEN, DISCONTINUE USE AND CONTACT YOUR
SUPPLIER. CLOSE THE CONTAINER VALVE AFTER EACH USE; KEEP CLOSED EVEN WHEN
EMPTY. NEVER APPLY FLAME OR LOCALIZED HEAT DIRECTLY TO ANY PART OF THE
CONTAINER. HIGH TEMPERATURES MAY DAMAGE THE CONTAINER AND COULD CAUSE THE
PRESSURE RELIEF DEVICE TO FAIL PREMATURELY, VENTING THE CONTAINER CONTENTS.
FOR OTHER PRECAUTIONS IN USING THIS PRODUCT, SEE SECTION 16.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE ONLY WHERE TEMPERATURE WILL NOT EXCEED 125 DEG. F (52 DEG. C). POST
"NO SMOKING/NO OPEN FLAMES" SIGNS IN STORAGE AND USE AREAS. THERE MUST BE
NO SOURCES OF IGNITION. SEPARATE PACKAGES AND PROTECT AGAINST POTENTIAL
FIRE AND/OR EXPLOSION DAMAGE FOLLOWING APPROPRIATE CODES AND REQUIREMENTS
(E.G, NFPA 30, NFPA 55, NFPA 70, AND/OR NFPA 221 IN THE U.S.) OR ACCORDING
TO REQUIREMENTS DETERMINED BY THE AUTHORITY HAVING JURISDICTION (AHJ).
ALWAYS SECURE CONTAINERS UPRIGHT TO KEEP THEM FROM FALLING OR BEING KNOCKED
OVER. INSTALL VALVE PROTECTION CAP, IF PROVIDED, FIRMLY IN PLACE BY HAND
WHEN THE CONTAINER IS NOT IN USE. STORE FULL AND EMPTY CONTAINERS
SEPARATELY. USE A FIRST-IN, FIRST-OUT INVENTORY SYSTEM TO PREVENT STORING
FULL CONTAINERS FOR LONG PERIODS. FOR OTHER PRECAUTIONS IN USING THIS
PRODUCT, SEE SECTION 16
STORE IN A COOL, WELL-VENTILATED PLACE. STORE AND USE WITH ADEQUATE
VENTILATION. STORE ONLY WHERE TEMPERATURE WILL NOT EXCEED 125 DEG. F
(52 DEG. C). FIRMLY SECURE CONTAINERS UPRIGHT TO KEEP THEM FROM FALLING OR
BEING KNOCKED OVER. INSTALL VALVE PROTECTION CAP, IF PROVIDED, FIRMLY IN
PLACE BY HAND. STORE FULL AND EMPTY CONTAINERS SEPARATELY. USE A FIRST-IN,
FIRST-OUT INVENTORY SYSTEM TO PREVENT STORING FULL CONTAINERS FOR LONG
PERIODS
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE:
WHEN HANDLING PRODUCT UNDER PRESSURE, USE PIPING AND EQUIPMENT ADEQUATELY
DESIGNED TO WITHSTAND THE PRESSURES TO BE ENCOUNTERED. NEVER WORK ON A
PRESSURIZED SYSTEM. USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING. GASES
CAN CAUSE RAPID SUFFOCATION BECAUSE OF OXYGEN DEFICIENCY; STORE AND USE
WITH ADEQUATE VENTILATION. IF A LEAK OCCURS, CLOSE THE CONTAINER VALVE AND
BLOW DOWN THE SYSTEM IN A SAFE AND ENVIRONMENTALLY CORRECT MANNER IN
COMPLIANCE WITH ALL INTERNATIONAL, FEDERAL/NATIONAL, STATE/PROVINCIAL,
AND LOCAL LAWS; THEN REPAIR THE LEAK. NEVER PLACE A CONTAINER WHERE IT MAY
BECOME PART OF AN ELECTRICAL CIRCUIT.
7.3. SPECIFIC END USE(S): NONE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PTG-4065 (74-82-8):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
METHANE (74-82-8):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
METHANE (74-82-8):
BRITISH COLUMBIA:
OEL TWA (PPM): 1000 PPM
NUNAVUT:
OEL STEL (PPM): 1250 PPM
NUNAVUT:
OEL TWA (PPM): 1000 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 1250 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 1000 PPM
SASKATCHEWAN:
OEL STEL (PPM): 1250 PPM
SASKATCHEWAN:
OEL TWA (PPM): 1000 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
USE AN EXPLOSION-PROOF LOCAL EXHAUST SYSTEM. LOCAL EXHAUST AND GENERAL
VENTILATION MUST BE ADEQUATE TO MEET EXPOSURE STANDARDS.
MECHANICAL (GENERAL):
INADEQUATE - USE ONLY IN A CLOSED SYSTEM. USE EXPLOSION PROOF EQUIPMENT
AND LIGHTING. PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION.
ENSURE EXPOSURE IS BELOW OCCUPATIONAL EXPOSURE LIMITS (WHERE AVAILABLE).
PERSONAL PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
EYE PROTECTION:
WEAR SAFETY GLASSES WHEN HANDLING CYLINDERS; VAPOR-PROOF GOGGLES AND A
FACE SHIELD DURING CYLINDER CHANGE OUT OR WHENEVER CONTACT WITH PRODUCT IS
POSSIBLE. SELECT EYE PROTECTION IN ACCORDANCE WITH OSHA 29 CFR 1910.133.
SELECT IN ACCORDANCE WITH THE CURRENT CSA STANDARD Z94.3, "INDUSTRIAL EYE
AND FACE PROTECTION", AND ANY PROVINCIAL REGULATIONS, LOCAL BYLAWS OR
GUIDELINES.
SKIN AND BODY PROTECTION:
WEAR METATARSAL SHOES AND WORK GLOVES FOR CYLINDER HANDLING, AND PROTECTIVE
CLOTHING WHERE NEEDED. WEAR APPROPRIATE CHEMICAL GLOVES DURING CYLINDER
CHANGE OUT OR WHEREVER CONTACT WITH PRODUCT IS POSSIBLE. SELECT PER OSHA 29
CFR 1910.132, 1910.136, AND 1910.138. SAFETY SHOES: SELECT IN ACCORDANCE
WITH THE CURRENT CSA STANDARD Z195, "PROTECTIVE FOOT WEAR", AND ANY
PROVINCIAL REGULATIONS, LOCAL BYLAWS OR GUIDELINES.
RESPIRATORY PROTECTION:
WHEN WORKPLACE CONDITIONS WARRANT RESPIRATOR USE, FOLLOW A RESPIRATORY
PROTECTION PROGRAM THAT MEETS OSHA 29 CFR 1910.134, ANSI Z88.2, OR MSHA
30 CFR 72.710 (WHERE APPLICABLE). USE AN AIR-SUPPLIED OR AIR-PURIFYING
CARTRIDGE IF THE ACTION LEVEL IS EXCEEDED. ENSURE THAT THE RESPIRATOR HAS
THE APPROPRIATE PROTECTION FACTOR FOR THE EXPOSURE LEVEL. IF CARTRIDGE
TYPE RESPIRATORS ARE USED, THE CARTRIDGE MUST BE APPROPRIATE FOR THE
CHEMICAL EXPOSURE. FOR EMERGENCIES OR INSTANCES WITH UNKNOWN EXPOSURE
LEVELS, USE A SELF-CONTAINED BREATHING APPARATUS (SCBA)
RESPIRATORY PROTECTION:
USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WORKING IN
CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP
EXPOSURE BELOW TLV. SELECT IN ACCORDANCE WITH PROVINCIAL REGULATIONS,
LOCAL BYLAWS OR GUIDELINES. SELECTION SHOULD BE BASED ON THE CURRENT CSA
STANDARD Z94.4, "SELECTION, CARE, AND USE OF RESPIRATORS." RESPIRATORS
SHOULD ALSO BE APPROVED BY NIOSH AND MSHA. FOR EMERGENCIES OR INSTANCES
WITH UNKNOWN EXPOSURE LEVELS, USE A SELF-CONTAINED BREATHING APPARATUS
(SCBA).
THERMAL HAZARD PROTECTION:
WEAR COLD INSULATING GLOVES WHEN TRANSFILLING OR BREAKING TRANSFER
CONNECTIONS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GAS
COLOR: COLORLESS
ODOR: NO DATA AVAILABLE
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE.
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1):
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE.
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: -161.5 DEG. C
CRITICAL TEMPERATURE: -82.5 DEG. C
CRITICAL PRESSURE: 4633 KPA
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
EXPLOSION LIMITS: 5 - 15 VOL %
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE.
VAPOR PRESSURE: NOT APPLICABLE.
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
SOLUBILITY: WATER: NO DATA AVAILABLE
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: 537 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NOT APPLICABLE.
VISCOSITY, DYNAMIC: NOT APPLICABLE.
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
NO ADDITIONAL INFORMATION AVAILABLE
10.4. CONDITIONS TO AVOID;
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
10.5. INCOMPATIBLE MATERIALS: NO ADDITIONAL INFORMATION AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: HARMFUL TO AQUATIC LIFE.
12.2. PERSISTENCE AND DEGRADABILITY:
PTG-4065 (74-82-8):
PERSISTENCE AND DEGRADABILITY:
NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
PERSISTENCE AND DEGRADABILITY:
THE SUBSTANCE IS BIODEGRADABLE. UNLIKELY TO PERSIST.
12.3. BIOACCUMULATIVE POTENTIAL:
PTG-4065 (74-82-8):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
LOG POW: 1.09
BIOACCUMULATIVE POTENTIAL:
NOT EXPECTED TO BIOACCUMULATE DUE TO THE LOW LOG KOW (LOG KOW <4). REFER
TO SECTION 9.
12.4. MOBILITY IN SOIL:
PTG-4065 (74-82-8):
MOBILITY IN SOIL: NO DATA AVAILABLE.
METHANE (74-82-8):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND OR
WATER POLLUTION.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON OZONE LAYER: NONE
EFFECT ON THE GLOBAL WARMING:
CONTAINS GREENHOUSE GAS(ES) NOT COVERED BY 842/2006/EC.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE TREATMENT METHODS:
DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED QUANTITIES. RETURN
CONTAINER TO SUPPLIER.
WASTE DISPOSAL RECOMMENDATIONS:
DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED QUANTITIES. RETURN
CONTAINER TO SUPPLIER.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN1971 METHANE, COMPRESSED (WITH HIGH METHANE CONTENT), 2.1
UN-NO.(DOT): UN1971
PROPER SHIPPING NAME (DOT):
METHANE, COMPRESSED (WITH HIGH METHANE CONTENT)
CLASS (DOT): 2.1 - CLASS 2.1 - FLAMMABLE GAS 49 CFR 173.115
HAZARD LABELS (DOT): 2.1 - FLAMMABLE GAS
FLAMMABLE GAS, CLASS/DIVISION 2.1
DOT PACKAGING NON BULK (49 CFR 173.XXX): 302
DOT PACKAGING BULK (49 CFR 173.XXX): 302
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 306
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 172.101 HMT,
COLUMN 9A): FORBIDDEN
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 172.101 HMT,
COLUMN 9B): 150 KG
DOT VESSEL STOWAGE LOCATION:
E - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO NOT
MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH, BUT IS PROHIBITED FROM CARRIAGE ON PASSENGER VESSELS
IN WHICH THE LIMITING NUMBER OF PASSENGERS IS EXCEEDED
DOT VESSEL STOWAGE OTHER: 40 - STOW "CLEAR OF LIVING QUARTERS"
ADDITIONAL INFORMATION:
EMERGENCY RESPONSE GUIDE (ERG) NUMBER: 115
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
SPECIAL TRANSPORT PRECAUTIONS:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY. BEFORE TRANSPORTING PRODUCT CONTAINERS:
ENSURE THERE IS ADEQUATE VENTILATION.
ENSURE THAT CONTAINERS ARE FIRMLY SECURED.
ENSURE CYLINDER VALVE IS CLOSED AND NOT LEAKING.
ENSURE VALVE OUTLET CAP NUT OR PLUG (WHERE PROVIDED) IS CORRECTLY FITTED.
ENSURE VALVE PROTECTION DEVICE (WHERE PROVIDED) IS CORRECTLY FITTED.
IN ACCORDANCE WITH TDG:
TDG:
UN-NO. (TDG): UN1971
PROPER SHIPPING NAME (TDG): METHANE, COMPRESSED
TDG PRIMARY HAZARD CLASSES: 2.1 - CLASS 2.1 - FLAMMABLE GAS.
ERAP INDEX: 3000
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 0.125L
PASSENGER CARRYING SHIP INDEX: FORBIDDEN
PASSENGER CARRYING ROAD VEHICLE OR PASSENGER CARRYING RAILWAY VEHICLE
INDEX: FORBIDDEN
TRANSPORT BY SEA:
UN-NO. (IMDG): 1971
PROPER SHIPPING NAME (IMDG): METHANE, COMPRESSED
CLASS (IMDG): 2 - GASES
LIMITED QUANTITIES (IMDG): NONE.
AIR TRANSPORT:
UN-NO. (IATA): 1971
PROPER SHIPPING NAME (IATA): METHANE, COMPRESSED
CLASS (IATA): 2
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
METHANE (74-82-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
METHANE (74-82-8):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST):
WHMIS:
CLASSIFICATION CLASS A - COMPRESSED GAS
CLASS B DIVISION 1 - FLAMMABLE GAS
EU-REGULATIONS:
METHANE (74-82-8):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
COMPRESSED GAS: H280
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
NOT CLASSIFIED
NATIONAL REGULATIONS:
METHANE (74-82-8):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON INSQ (MEXICAN NATIONAL INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON CICR (TURKISH INVENTORY AND CONTROL OF CHEMICALS)
15.3. US STATE REGULATIONS:
METHANE (74-82-8):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 01/14/2016
TRAINING ADVICE: ENSURE OPERATORS UNDERSTAND THE FLAMMABILITY HAZARD.
OTHER INFORMATION:
WHEN YOU MIX TWO OR MORE CHEMICALS, YOU CAN CREATE ADDITIONAL, UNEXPECTED
HAZARDS. OBTAIN AND EVALUATE THE SAFETY INFORMATION FOR EACH COMPONENT
BEFORE YOU PRODUCE THE MIXTURE. CONSULT AN INDUSTRIAL HYGIENIST OR OTHER
TRAINED PERSON WHEN YOU EVALUATE THE END PRODUCT. BEFORE USING ANY
PLASTICS, CONFIRM THEIR COMPATIBILITY WITH THIS PRODUCT
PRAXAIR ASKS USERS OF THIS PRODUCT TO STUDY THIS SDS AND BECOME AWARE OF
THE PRODUCT HAZARDS AND SAFETY INFORMATION. TO PROMOTE SAFE USE OF THIS
PRODUCT, A USER SHOULD
(1) NOTIFY EMPLOYEES, AGENTS, AND CONTRACTORS OF THE INFORMATION IN THIS
SDS AND OF ANY OTHER KNOWN PRODUCT HAZARDS AND SAFETY INFORMATION,
(2) FURNISH THIS INFORMATION TO EACH PURCHASER OF THE PRODUCT, AND
(3) ASK EACH PURCHASER TO NOTIFY ITS EMPLOYEES AND CUSTOMERS OF THE
PRODUCT HAZARDS AND SAFETY INFORMATION
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09/16/2016
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SDS ID: PTG-4065